[go: up one dir, main page]

AR092990A1 - Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion - Google Patents

Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion

Info

Publication number
AR092990A1
AR092990A1 ARP130103702A ARP130103702A AR092990A1 AR 092990 A1 AR092990 A1 AR 092990A1 AR P130103702 A ARP130103702 A AR P130103702A AR P130103702 A ARP130103702 A AR P130103702A AR 092990 A1 AR092990 A1 AR 092990A1
Authority
AR
Argentina
Prior art keywords
asymmetric
reaction
bisphosphite
bifosphite
hydroformilation
Prior art date
Application number
ARP130103702A
Other languages
English (en)
Inventor
Prof Franke Robert
Dr Christiansen Andrea
Fridag Dirk
Dr Hannebauer Bernd
Dr Hess Dieter
Marie Dr Dyballa Katrin
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE201310219506 external-priority patent/DE102013219506A1/de
Priority claimed from DE201310219510 external-priority patent/DE102013219510A1/de
Priority claimed from DE201310219512 external-priority patent/DE102013219512A1/de
Priority claimed from DE201310219508 external-priority patent/DE102013219508A1/de
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of AR092990A1 publication Critical patent/AR092990A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65685—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine oxide or thioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un bisfosfito asimétrico de la fórmula (1), a un procedimiento para su preparación, así como su reacción con metales en mezclas que contienen compuestos complejos de bifosfito asimétrico y el metal, así como su uso como composición catalíticamente activa en reacciones de hidroformilación, en donde la composición activa a la hidroformilación comprende, además del compuesto complejo de metal, así como bisfosfito asimétrico, bisfosfito no ligado y por lo menos otro componente. Reivindicación 14: Procedimiento para la hidroformilación de un compuesto insaturado o de una mezcla de compuestos insaturados que comprende las etapas de procedimiento de: a) disposición de un compuesto de acuerdo con la reivindicación 1 o de una composición de acuerdo con las reivindicaciones 11 a 13, b) introducción de una mezcla gaseosa que comprende monóxido de carbono e hidrógeno c) adición de al menos un compuesto insaturado o de una mezcla de compuestos insaturados.
ARP130103702A 2012-10-12 2013-10-11 Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion AR092990A1 (es)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
DE102012218630 2012-10-12
DE102012218625 2012-10-12
DE102012218629 2012-10-12
DE102012218627 2012-10-12
DE201310219506 DE102013219506A1 (de) 2012-10-12 2013-09-27 Unsymmetrisches Bisphosphit
DE201310219510 DE102013219510A1 (de) 2012-10-12 2013-09-27 Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE201310219512 DE102013219512A1 (de) 2012-10-12 2013-09-27 Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE201310219508 DE102013219508A1 (de) 2012-10-12 2013-09-27 Gemische konstitutionsisomerer Bisphosphite

Publications (1)

Publication Number Publication Date
AR092990A1 true AR092990A1 (es) 2015-05-13

Family

ID=49237234

Family Applications (4)

Application Number Title Priority Date Filing Date
ARP130103702A AR092990A1 (es) 2012-10-12 2013-10-11 Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion
ARP130103701A AR092989A1 (es) 2012-10-12 2013-10-11 Mezcla de distintos bisfosfitos asimetricos y su uso como mezcla catalizadora en la hidroformilacion
ARP130103699A AR092987A1 (es) 2012-10-12 2013-10-11 Mezclas de bifosfitos isomericos constitucionales utilizadas en una composicion catalitica para la reaccion de hidroformilacion
ARP130103700A AR092988A1 (es) 2012-10-12 2013-10-11 Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion

Family Applications After (3)

Application Number Title Priority Date Filing Date
ARP130103701A AR092989A1 (es) 2012-10-12 2013-10-11 Mezcla de distintos bisfosfitos asimetricos y su uso como mezcla catalizadora en la hidroformilacion
ARP130103699A AR092987A1 (es) 2012-10-12 2013-10-11 Mezclas de bifosfitos isomericos constitucionales utilizadas en una composicion catalitica para la reaccion de hidroformilacion
ARP130103700A AR092988A1 (es) 2012-10-12 2013-10-11 Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion

Country Status (13)

Country Link
US (5) US9556096B2 (es)
EP (5) EP2802550B1 (es)
JP (5) JP2015536912A (es)
KR (5) KR20150065869A (es)
CN (5) CN104854118B (es)
AR (4) AR092990A1 (es)
CA (4) CA2887582A1 (es)
ES (4) ES2603929T3 (es)
MX (4) MX2015004616A (es)
SG (5) SG11201502843SA (es)
TW (1) TW201422632A (es)
WO (5) WO2014056737A1 (es)
ZA (4) ZA201503227B (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012202779A1 (de) 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
MX2015004616A (es) 2012-10-12 2015-07-17 Evonik Degussa Gmbh Bifosfito asimetrico.
DE102013217174A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Zusammensetzung und deren Verwendung in Verfahren zur Hydroformylierung von ungesättigten Verbindungen
DE102013217166A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Verfahren zur Hydroformylierung von ungesättigten Verbindungen durch SILP-Katalyse
DE102014201756A1 (de) 2014-01-31 2015-08-06 Evonik Degussa Gmbh Reinigung chlorverschmutzter Organophosphorverbindungen
DE102015202722A1 (de) * 2014-05-20 2015-11-26 Evonik Degussa Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Monophosphit-Gemischen
DE102014209534A1 (de) * 2014-05-20 2015-11-26 Evonik Degussa Gmbh Neue Monophosphitliganden mit einer Carbonat-Gruppe
DE102014209536A1 (de) * 2014-05-20 2015-11-26 Evonik Degussa Gmbh Herstellung qualitativ hochwertiger Oxo-Alkohole aus unsteten Rohstoffquellen
EP3101022B1 (de) * 2014-12-04 2018-02-28 Evonik Degussa GmbH Monophosphite die einen unsymmetrischen biaryl-baustein aufweisen
EP3029051A1 (de) * 2014-12-04 2016-06-08 Evonik Degussa GmbH Bisphosphite die eine Naphthyl-Phenyl-Einheit als Flügel-Baustein und eine 2,3'-Bisphenol-Einheit als Zentral-Baustein aufweisen
EP3029050B1 (de) 2014-12-04 2018-02-28 Evonik Degussa GmbH Bisphosphite die eine Naphthyl-Phenyl-Einheit als Flügel-Baustein aufweisen
ES2733102T3 (es) 2014-12-04 2019-11-27 Evonik Operations Gmbh Bisfosfitos que presentan un componente central de biarilo asimétrico
EP3029048B1 (de) 2014-12-04 2017-04-12 Evonik Degussa GmbH Bisphosphite die einen unsymmetrischen Biphenol-Flügel-Baustein aufweisen
EP3029045B1 (de) * 2014-12-04 2018-06-13 Evonik Degussa GmbH Bisphosphite die eine 2,3 -Biphenol-Einheit als Zentral-Baustein aufweisen
EP3075449A1 (de) 2015-04-02 2016-10-05 Evonik Degussa GmbH Verfahren zur untersuchung der langzeiteigenschaften homogener katalysatorsysteme im kontinuierlichen betrieb
ES2701843T3 (es) 2015-11-19 2019-02-26 Evonik Degussa Gmbh Influencia de la viscosidad de mezclas de ésteres basadas en n-buteno mediante empleo selectivo de eteno en la obtención de productos previos de ésteres
CA3014177C (en) * 2016-02-11 2023-12-12 Dow Technology Investments Llc Processes for converting olefins to alcohols, ethers, or combinations thereof
EP3246303B8 (de) 2016-05-19 2020-01-01 Evonik Operations GmbH Herstellung von n-pentanal aus butenarmen einsatzstoffgemischen
US10227279B2 (en) 2016-09-12 2019-03-12 Evonik Degussa Gmbh Dehydrogenation of LPG or NGL and flexible utilization of the olefins thus obtained
PL3318569T3 (pl) 2016-11-08 2020-03-31 Evonik Degussa Gmbh Bisfosfoniany z jednostkami 2,4-tert.-butylofenylu i ich zastosowanie jako ligandów w hydroformylowaniu
EP3318570B1 (de) * 2016-11-08 2019-08-07 Evonik Degussa GmbH Phosphorigsäure-p,p'-[5,5',6,6'-tetramethyl-3,3'-bis(1-methylethyl)[1,1'-biphenyl]-2,2'-diyl] p,p,p',p'-tetrakis(2,4-dimethylphenyl)-ester in der hydroformylierung
KR20200018442A (ko) * 2017-06-13 2020-02-19 바스프 에스이 1,6-헥산디올 유도체를 제조하기 위한 히드로포르밀화 방법
CN109666044B (zh) * 2018-07-04 2021-03-05 浙江大学 基于[2.2]对环芳烷骨架的有机磷化合物及其中间体和制备方法与用途
CN110862307A (zh) * 2018-08-27 2020-03-06 中国石油化工股份有限公司 一种混合碳四氢甲酰化反应制备醛的方法
SE543296C2 (en) * 2019-07-05 2020-11-17 Perstorp Ab A use of epoxide in order to reduce the formation of heavy ends in a hydroformylation process
EP4074686B1 (de) 2021-04-16 2023-05-31 Evonik Operations GmbH Verfahren zur herstellung von biphenyl-2,2'-diolen
EP4074720B1 (de) * 2021-04-16 2023-07-19 Evonik Operations GmbH Gemisch von bisphosphiten mit einem offenen und einem geschlossenen flügelbaustein und dessen verwendung als katalysatorgemisch in der hydroformylierung
ES2987273T3 (es) 2021-05-18 2024-11-14 Evonik Oxeno Gmbh & Co Kg Procedimiento para la regeneración de un catalizador para la hidroformilación de olefinas en la fase gaseosa
ES2992252T3 (es) 2021-12-17 2024-12-11 Evonik Oxeno Gmbh & Co Kg Procedimiento para la hidroformilación de olefinas empleando Pt y DPEfos
EP4273119A1 (de) 2022-05-03 2023-11-08 Evonik Operations GmbH Verfahren zur herstellung von c5-aldehyden
CN114988992B (zh) * 2022-05-31 2024-07-12 中海油天津化工研究设计院有限公司 一种干气乙烯氢甲酰化制备丙醛的方法
PL4403545T3 (pl) 2023-01-18 2025-10-20 Evonik Oxeno Gmbh & Co. Kg Mieszanina dwóch konstytucyjnie izomerycznych bisfosforynów
CN116102412A (zh) * 2023-02-14 2023-05-12 国家能源集团宁夏煤业有限责任公司 费托混合烯烃氢甲酰化制备醛的方法
EP4484437A1 (de) * 2023-06-27 2025-01-01 Evonik Oxeno GmbH & Co. KG Verfahren zur herstellung von diphosphiten

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1071179A (en) 1974-08-23 1980-02-05 Thomas F. Rutledge Oxidative coupling of alkylphenols, alkoxyphenols, and naphthols, catalyzed by metal complexes of amino carboxylic and amino sulfonic acids
US4067890A (en) 1975-02-18 1978-01-10 Ici America Inc. Oxidative coupling of alkylphenols, alkoxyphenols and naphthols catalyzed by metal complexes of amino carboxylic and amino sulfonic acids
US4248802A (en) 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
US4193943A (en) 1976-01-19 1980-03-18 Celanese Corporation Hydroformylation catalysts
US4169861A (en) 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
US4201714A (en) 1977-08-19 1980-05-06 Celanese Corporation Stabilized catalyst complex of rhodium metal, bidentate ligand and monodentate ligand
EP0016285B2 (en) 1979-03-21 1986-03-05 DAVY McKEE (LONDON) LIMITED Process for the production of valeraldehydes by hydroformylation of butene-1
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4748261A (en) * 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4885401A (en) 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4694109A (en) 1986-06-13 1987-09-15 Eastman Kodak Company Chelate ligands for low pressure hydroformylation catalyst and process employing same
US4879416A (en) 1987-11-23 1989-11-07 Eastman Kodak Company Preparation of bidentate ligands
DE4026406A1 (de) 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
DE4210026A1 (de) 1992-03-27 1993-09-30 Hoechst Ag Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
US5312996A (en) 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5288918A (en) 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5364950A (en) 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
WO1995014659A1 (en) 1993-11-23 1995-06-01 E.I. Du Pont De Nemours And Company Processes and catalyst compositions for hydrocyanation of monoolefins
ATE196745T1 (de) * 1994-04-14 2000-10-15 Du Pont Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen
US5512695A (en) 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
BE1008343A3 (nl) 1994-05-06 1996-04-02 Dsm Nv Bidentaat fosfineligand
US5741942A (en) 1996-11-26 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5763679A (en) * 1995-12-06 1998-06-09 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5886237A (en) * 1996-04-24 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing alkenals and alkenols
MY124170A (en) * 1997-07-29 2006-06-30 Invista Tech Sarl Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor
ZA986369B (en) * 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
US6635775B1 (en) 2000-02-04 2003-10-21 Finetex, Inc. Reduced odor esters and process for producing same
DE10031493A1 (de) * 2000-06-28 2002-01-10 Oxeno Olefinchemie Gmbh Neue Bisphosphitverbindungen und deren Metallkomplexe
DE10034360A1 (de) 2000-07-14 2002-01-24 Oxeno Olefinchemie Gmbh Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen
DE10048301A1 (de) 2000-09-29 2002-04-11 Oxeno Olefinchemie Gmbh Stabilisierung von Rhodiumkatalysatoren für die Hydroformylierung von Olefinen
DE10108476A1 (de) 2001-02-22 2002-09-12 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10108474A1 (de) 2001-02-22 2002-09-12 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10108475A1 (de) 2001-02-22 2002-09-12 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
EP1485341A2 (de) 2002-03-15 2004-12-15 Oxeno Olefinchemie GmbH Verfahren zur hydroformylierung von olefinen
DE10217186A1 (de) 2002-04-18 2003-11-13 Oxeno Olefinchemie Gmbh Benzoesäureisononylester und deren Verwendung
DE10220801A1 (de) 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10220799A1 (de) 2002-05-10 2003-12-11 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von C13-Alkoholgemischen
DE10225282A1 (de) 2002-06-07 2003-12-18 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
JP2005537330A (ja) 2002-08-31 2005-12-08 オクセノ　オレフィンヒェミー　ゲゼルシャフト　ミット　ベシュレンクテル　ハフツング 環状カルボン酸エステルの存在で非変性金属錯体により触媒活性されるオレフィン不飽和化合物のヒドロホルミル化によりアルデヒドを製造する方法
US7317130B2 (en) 2002-08-31 2008-01-08 Oxeno Olefinchemie Gmbh Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters
US7015360B2 (en) * 2003-03-28 2006-03-21 Dow Global Technologies, Inc. Asymmetric catalysts prepared from optically active bisphosphites bridged by achiral diols
DE10360771A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen
DE102004033410A1 (de) 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
DE102004059292A1 (de) 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102004059293A1 (de) 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE102005042464A1 (de) 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102005046250B4 (de) 2005-09-27 2020-10-08 Evonik Operations Gmbh Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren
DE102006003618A1 (de) 2006-01-26 2007-08-02 Oxeno Olefinchemie Gmbh Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen
WO2007114445A1 (ja) * 2006-04-04 2007-10-11 Kuraray Co., Ltd. ビスホスファイトおよび第８～１０族金属化合物を用いたアルデヒドの製造方法、並びに該ビスホスファイト
US7888414B2 (en) 2006-06-20 2011-02-15 Chemtura Corporation Liquid phosphite blends as stabilizers
US9266808B2 (en) * 2006-11-30 2016-02-23 Basf Se Method for the hydroformylation of olefins
JP5298119B2 (ja) * 2007-04-09 2013-09-25 エルジー・ケム・リミテッド ホスファイト配位子を含む触媒組成物およびこれを用いたヒドロホルミル化方法
DE102007061649A1 (de) 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Einstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
DE102007061648A1 (de) 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Mehrstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
DE102008002188A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung
DE102008002187A1 (de) 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Herstellung von C5-Aldehydgemischen mit hohem n-Pentanalanteil
EP2297077B1 (en) * 2008-07-03 2014-06-04 Dow Technology Investments LLC Process of controlling heavies in a recycle catalyst stream
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
DE102009001230A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009027406A1 (de) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Verfahren zur Herstellung von geruchsarmen n-Butan
JP6125229B2 (ja) 2009-07-23 2017-05-10 エボニック ファイバース ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｆｉｂｒｅｓ ＧｍｂＨ 重合溶液から製造されるポリイミド膜
DE102009045139A1 (de) 2009-09-30 2011-03-31 Evonik Oxeno Gmbh Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe
DE102009047351A1 (de) 2009-12-01 2011-06-09 Evonik Goldschmidt Gmbh Komposit-Siliconmembranen mit hoher Trennwirkung
DE102010030209A1 (de) 2010-06-17 2011-12-22 Evonik Oxeno Gmbh Energieeffiziente Synthese von aliphatischen Adelhyden aus Alkanen und Kohlendioxid
DE102011002639A1 (de) * 2011-01-13 2012-07-19 Evonik Oxeno Gmbh Verfahren zur Herstellung von Biphephos
DE102011002640B4 (de) 2011-01-13 2021-10-07 Evonik Operations Gmbh Verfahren zur Aufreinigung von Biphephos
DE102012202779A1 (de) 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
MX2015004616A (es) 2012-10-12 2015-07-17 Evonik Degussa Gmbh Bifosfito asimetrico.

Also Published As

Publication number Publication date
SG11201502756PA (en) 2015-05-28
WO2014056732A1 (de) 2014-04-17
EP2906573B1 (de) 2016-11-23
CN104781225A (zh) 2015-07-15
CA2887582A1 (en) 2014-04-17
US20150266008A1 (en) 2015-09-24
US20150224488A1 (en) 2015-08-13
TW201422632A (zh) 2014-06-16
MX2015004616A (es) 2015-07-17
US20150274627A1 (en) 2015-10-01
CN104837851A (zh) 2015-08-12
US9409844B2 (en) 2016-08-09
EP2906572A1 (de) 2015-08-19
CA2887107A1 (en) 2014-04-17
KR20150070225A (ko) 2015-06-24
ZA201503227B (en) 2016-01-27
MX2015004613A (es) 2015-07-17
ZA201503232B (en) 2016-01-27
JP2015536303A (ja) 2015-12-21
EP2906571A1 (de) 2015-08-19
EP2906571B1 (de) 2016-08-24
US9272973B2 (en) 2016-03-01
JP6335905B2 (ja) 2018-05-30
US20150290633A1 (en) 2015-10-15
AR092988A1 (es) 2015-05-13
WO2014056735A1 (de) 2014-04-17
KR101711770B1 (ko) 2017-03-02
ES2566069T3 (es) 2016-04-08
JP2015536302A (ja) 2015-12-21
US9556096B2 (en) 2017-01-31
EP2906574B1 (de) 2016-11-02
JP2015536912A (ja) 2015-12-24
JP2016500676A (ja) 2016-01-14
SG11201502777VA (en) 2015-05-28
KR20150065869A (ko) 2015-06-15
WO2014056736A1 (de) 2014-04-17
CN104837852A (zh) 2015-08-12
SG11201502824VA (en) 2015-05-28
WO2014056737A1 (de) 2014-04-17
ZA201503226B (en) 2016-05-25
ZA201503228B (en) 2016-12-21
US9499463B2 (en) 2016-11-22
KR101717864B1 (ko) 2017-03-17
MX2015004528A (es) 2015-07-14
SG11201502843SA (en) 2015-05-28
AR092987A1 (es) 2015-05-13
US9206105B2 (en) 2015-12-08
EP2906572B1 (de) 2016-11-23
KR20150070224A (ko) 2015-06-24
ES2614055T3 (es) 2017-05-29
EP2802550A1 (de) 2014-11-19
CN104837852B (zh) 2016-11-09
CN104837853B (zh) 2017-05-10
JP6246218B2 (ja) 2017-12-13
ES2615677T3 (es) 2017-06-07
EP2906573A1 (de) 2015-08-19
US20150273455A1 (en) 2015-10-01
CN104837853A (zh) 2015-08-12
WO2014056733A1 (de) 2014-04-17
CN104854118B (zh) 2016-12-14
CN104837851B (zh) 2017-05-31
CN104854118A (zh) 2015-08-19
AR092989A1 (es) 2015-05-13
EP2906574A1 (de) 2015-08-19
KR20150065886A (ko) 2015-06-15
MX2015004527A (es) 2015-07-14
SG11201502815PA (en) 2015-05-28
ES2603929T3 (es) 2017-03-02
EP2802550B1 (de) 2016-01-13
KR101724219B1 (ko) 2017-04-06
CA2887565A1 (en) 2014-04-17
JP2015531402A (ja) 2015-11-02
CA2887580A1 (en) 2014-04-17
KR20150067322A (ko) 2015-06-17

Similar Documents

Publication Publication Date Title
AR092990A1 (es) Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion
ES2511049T3 (es) Procedimiento para la separación de gases ácidos con ayuda de materiales de estructura organometálicos impregnados con aminas
AR080641A1 (es) Agente de soporte auto-endurecido de elevada resistencia y metodos para elaborarlo
ECSP10010180A (es) Proceso de hidroconversión para crudos pesados y extra pesados y productos residuales
AR055033A1 (es) Catalizadores que contienen metales de transicion y combinaciones de catalizadores que incluyen catalizadores que contienen metales de transicion y procesos para su preparacion y uso como catalizadores de oxidacion
CL2012000374A1 (es) Metodo para la preparacion de una composicion saborizante activa que comprende una primera reaccion entre un compuesto amino y un carbonilo, resultando una primera mezcla de intermediarios, una segunda reaccion con un segundo compuesto amino solo o en combinacion con un compuesto carbinilo, resultando una segunda mezcla de intermediarios, reacciones serparadas adicionales con compuestos de otras clases quimicas, ultima reaccion que comprende una mezcla de todas las mezclas de intermediarios anteriores.
BR112015017306A2 (pt) processo para a formação de metacrilato de metila
MY184826A (en) Hydroformylation process
BR112015021851A2 (pt) processo de carbonilação
AR092596A1 (es) Sistema de reactor para la produccion de alotropos de carbono
SG179188A1 (en) Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
MX390193B (es) Proceso para purificar (hidro) fluoroalquenos.
IN2013MU02899A (es)
MX2019003614A (es) Lecho fijo de catalizador que comprende cuerpos de espuma metalica.
WO2012030065A3 (en) Catalyst composition for hydroformylation reaction and a hydroformylation process using the same
AR084544A1 (es) Sistema catalitico y su uso para la fabricacion de cloruro de vinilo por adicion de cloruro de hidrogeno al acetileno
GB2513745A (en) Process intensification in the catalytic synthesis of supported catalysts with hierarchic pore structure
MX2015017980A (es) Conversion catalitica de alcohol con al menos tres atomos de carbono a una mezcla de hidrocarburos.
AR086414A1 (es) HIDROGENACION CATALITICA DE FLUORO-OLEFINAS, COMPOSICIONES DE PALADIO CON SOPORTE DE a-ALUMINA Y SU USO COMO CATALITICOS DE HIDROGENACION
BR112012014621A2 (pt) processo para a preparação de compostos de quelato
BR112014016825A2 (pt) processo para oxidação assimétrica de compostos orgânicos com peróxidos na presença de um catalisador de ácido quiral
EA201590636A1 (ru) Способ получения каталитической композиции для гидрирования и каталитическая композиция для гидрирования
CO6741165A2 (es) Aparato para destilación reactiva conformado por una columna con una zona de reacción y destilación combinada, un tubo de carga y una configuración de platos
AR092760A1 (es) Procedimiento para producir complejos de oxalato de metales nobles
AR090778A1 (es) Un proceso para la aromatizacion de una corriente de gas que contiene metano

Legal Events

Date Code Title Description
FB Suspension of granting procedure