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AR092988A1 - Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion - Google Patents

Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion

Info

Publication number
AR092988A1
AR092988A1 ARP130103700A ARP130103700A AR092988A1 AR 092988 A1 AR092988 A1 AR 092988A1 AR P130103700 A ARP130103700 A AR P130103700A AR P130103700 A ARP130103700 A AR P130103700A AR 092988 A1 AR092988 A1 AR 092988A1
Authority
AR
Argentina
Prior art keywords
tbu
ome
mixture
well
hydroformilation
Prior art date
Application number
ARP130103700A
Other languages
English (en)
Inventor
Prof Franke Robert
Fridag Dirk
Dr Hess Dieter
Dr Christiansen Andrea
Marie Dr Dyballa Katrin
Dr Hannebauer Bernd
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE201310219510 external-priority patent/DE102013219510A1/de
Priority claimed from DE201310219512 external-priority patent/DE102013219512A1/de
Priority claimed from DE201310219506 external-priority patent/DE102013219506A1/de
Priority claimed from DE201310219508 external-priority patent/DE102013219508A1/de
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of AR092988A1 publication Critical patent/AR092988A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65685—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine oxide or thioxide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Mezcla de bisfosfitos, un procedimiento para su preparación, así como su reacción con metales en compuestos complejos que contienen mezclas de los bisfosfitos isoméricos constitucionales y el metal, así como a su uso como composición catalíticamente activa en reacciones de hidroformilación, como también la reacción de hidroformilación propiamente dicha. Reivindicación 1: Mezcla que comprende los compuestos (1) y (2), en donde R¹ está seleccionado de -Me, -tBu, -OMe; R² está seleccionado de -Me, -tBu, -OMe; R³ está seleccionado de -Me, -tBu, -OMe; R⁴ está seleccionado de -Me, -tBu, -OMe; siempre que, para el caso de que R¹ sea R³, R² no sea igual a R⁴, para el caso de que R² sea R⁴, R¹ no sea igual a R³, y P puede generar otros enlaces. Reivindicación 16: Procedimiento para la hidroformilación de compuestos insaturados y sus mezclas usando: de una composición de acuerdo con una de las reivindicaciones 12 ó 13 y de una mezcla gaseosa que comprende monóxido de carbono e hidrógeno.
ARP130103700A 2012-10-12 2013-10-11 Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion AR092988A1 (es)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
DE102012218625 2012-10-12
DE102012218629 2012-10-12
DE102012218627 2012-10-12
DE102012218630 2012-10-12
DE201310219510 DE102013219510A1 (de) 2012-10-12 2013-09-27 Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE201310219512 DE102013219512A1 (de) 2012-10-12 2013-09-27 Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE201310219506 DE102013219506A1 (de) 2012-10-12 2013-09-27 Unsymmetrisches Bisphosphit
DE201310219508 DE102013219508A1 (de) 2012-10-12 2013-09-27 Gemische konstitutionsisomerer Bisphosphite

Publications (1)

Publication Number Publication Date
AR092988A1 true AR092988A1 (es) 2015-05-13

Family

ID=49237234

Family Applications (4)

Application Number Title Priority Date Filing Date
ARP130103699A AR092987A1 (es) 2012-10-12 2013-10-11 Mezclas de bifosfitos isomericos constitucionales utilizadas en una composicion catalitica para la reaccion de hidroformilacion
ARP130103701A AR092989A1 (es) 2012-10-12 2013-10-11 Mezcla de distintos bisfosfitos asimetricos y su uso como mezcla catalizadora en la hidroformilacion
ARP130103700A AR092988A1 (es) 2012-10-12 2013-10-11 Mezcla de bisfosfitos y su uso como mezcla catalizadora en la hidroformilacion
ARP130103702A AR092990A1 (es) 2012-10-12 2013-10-11 Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion

Family Applications Before (2)

Application Number Title Priority Date Filing Date
ARP130103699A AR092987A1 (es) 2012-10-12 2013-10-11 Mezclas de bifosfitos isomericos constitucionales utilizadas en una composicion catalitica para la reaccion de hidroformilacion
ARP130103701A AR092989A1 (es) 2012-10-12 2013-10-11 Mezcla de distintos bisfosfitos asimetricos y su uso como mezcla catalizadora en la hidroformilacion

Family Applications After (1)

Application Number Title Priority Date Filing Date
ARP130103702A AR092990A1 (es) 2012-10-12 2013-10-11 Bifosfito asimetrico utilizado en una composicion catalitica para la reaccion de hidroformilacion

Country Status (13)

Country Link
US (5) US9206105B2 (es)
EP (5) EP2906573B1 (es)
JP (5) JP2015536302A (es)
KR (5) KR101711770B1 (es)
CN (5) CN104854118B (es)
AR (4) AR092987A1 (es)
CA (4) CA2887107A1 (es)
ES (4) ES2566069T3 (es)
MX (4) MX2015004527A (es)
SG (5) SG11201502756PA (es)
TW (1) TW201422632A (es)
WO (5) WO2014056735A1 (es)
ZA (4) ZA201503226B (es)

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CN109666044B (zh) * 2018-07-04 2021-03-05 浙江大学 基于[2.2]对环芳烷骨架的有机磷化合物及其中间体和制备方法与用途
CN110862307A (zh) * 2018-08-27 2020-03-06 中国石油化工股份有限公司 一种混合碳四氢甲酰化反应制备醛的方法
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EP4074720B1 (de) * 2021-04-16 2023-07-19 Evonik Operations GmbH Gemisch von bisphosphiten mit einem offenen und einem geschlossenen flügelbaustein und dessen verwendung als katalysatorgemisch in der hydroformylierung
EP4074686B1 (de) 2021-04-16 2023-05-31 Evonik Operations GmbH Verfahren zur herstellung von biphenyl-2,2'-diolen
EP4091712B1 (de) 2021-05-18 2024-05-15 Evonik Oxeno GmbH & Co. KG Verfahren zur regenerierung eines katalysators für die hydroformylierung von olefinen in der gasphase
ES2992252T3 (es) 2021-12-17 2024-12-11 Evonik Oxeno Gmbh & Co Kg Procedimiento para la hidroformilación de olefinas empleando Pt y DPEfos
EP4273119A1 (de) 2022-05-03 2023-11-08 Evonik Operations GmbH Verfahren zur herstellung von c5-aldehyden
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