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AR081778A1 - Derivados y los herbicidas de 6-acil-1,2,4-triazina-3,5-diona - Google Patents

Derivados y los herbicidas de 6-acil-1,2,4-triazina-3,5-diona

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Publication number
AR081778A1
AR081778A1 ARP110102275A ARP110102275A AR081778A1 AR 081778 A1 AR081778 A1 AR 081778A1 AR P110102275 A ARP110102275 A AR P110102275A AR P110102275 A ARP110102275 A AR P110102275A AR 081778 A1 AR081778 A1 AR 081778A1
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AR
Argentina
Prior art keywords
group
substituted
alkyl
substituent
substituents selected
Prior art date
Application number
ARP110102275A
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English (en)
Original Assignee
Kumiai Chemical Industry Co
Ihara Chemical Ind Co
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Filing date
Publication date
Application filed by Kumiai Chemical Industry Co, Ihara Chemical Ind Co filed Critical Kumiai Chemical Industry Co
Publication of AR081778A1 publication Critical patent/AR081778A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07D253/00—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00
    • C07D253/02—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00 not condensed with other rings
    • C07D253/06—1,2,4-Triazines
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    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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Abstract

Se revelan los compuestos que exhiben suficiente actividad herbicida en bajas dosis de aplicación, cuando se aplican al suelo y al follaje, y una composición agroquímica que utiliza los mismos, en particular los herbicidas.Reivindicación 1: Un derivado de la triazina o una sal de la misma representada por la fórmula [1] [en la fórmula, R1 representa un átomo de hidrógeno; un grupo alquilo C1-12; un grupo alquenilo C2-6; un grupo alquinilo C2-6; un grupo cicloalquilo C3-6; un grupo cicloalquenilo C3-6; un grupo cicloalquilo C3-6alquilo C1-6; un grupo halo-alquilo C1-6; un grupo halo-alquenilo C2-6; un grupo halo-alquinilo C2-6; un grupo halo-cicloalquilo C3-6; un grupo halocicloalquilo C3-6alquilo C1-6; un grupo aminoalquilo C1-6; un grupo nitroalquilo C1-6; un grupo alquilamino C1-6alquilo C1-6; un di(alquil C1-6)aminoalquilo C1-6; un grupo alquiltio C1-6alquilo C1-6; un grupo alquilsulfinilo C1-6alquilo C1-6; un grupo alquilsulfonilo C1-6alquilo C1-6; un grupo haloalquiltio C1-6alquilo C1-6; un grupo haloalquilsulfinilo C1-6alquilo C1-6; un grupo haloalquilsulfonilo C1-6alquilo C1-6; un grupo alcoxi C1-6alquilo C1-6; un grupo hidroxialquilo C1-6; un grupo fenilo-alcoxi C1-6alquilo C1-6 (el fenilo en el grupo puede ser substituido con un grupo substituyente seleccionado del Grupo substituyente a o los grupos 2 a 5 substituyentes que son los mismos o diferentes el uno del otro y seleccionados del Grupo substituyente a); un grupo alcoxi C1-6alcoxi C1-6alquilo C1-6; un grupo cicloalquiloxi C3-6alquilo C1-6; un grupo cicloalquilo C3-6alquiloxi C1-6alquilo C1-6; un grupo feniloxi-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 a 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo feniltio-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo fenilsulfinilo-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo fenilsulfonilo-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo haloalcoxi C1-6alquilo C1-6; el grupo fenilo, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilo-alquilo C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilo-alquenilo C2-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilo-alquinilo C2-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo alcoxiimino C1-6alquilo C1-6; un grupo fenoxiimino-alquilo C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo di(alcoxi C1-6)alquilo C1-6; un grupo (R31R32N-C=O)alquilo C1-6; un grupo alcoxicarbonilo C1-6alquilo C1-6; un grupo alquilcarbonilo C1-6alquilo C1-6; un grupo alquilcarboniloxi C1-6alquilo C1-6; un grupo alquilideno C1-6aminooxi-alquilo C1-6; un grupo formilo-alquilo C1-6; un grupo alquiltio C1-6alcoxi C1-6alquilo C1-6; un grupo alquilsulfinilo C1-6alcoxi C1-6alquilo C1-6; un grupo alquilsulfonilo C1-6alcoxi C1-6alquilo C1-6; un grupo ciano-alcoxi C1-6alquilo C1-6; un grupo ciano-alquilo C1-6; un grupo alquilideno C2-6amino; un grupo di(alquil C1-10)amino-alquiliden C1-6amino; un grupo NR31R32; un grupo alcoxi C1-6; un grupo alqueniloxi C2-6; un grupo alqueniloxi C2-6; un grupo cicloalquiloxi C3-6; un grupo cicloalquilo C3-6alquiloxi C1-6; un grupo haloalcoxi C1-6; un grupo heterocíclico que contiene de 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a, y cuando el heteroátomo en el grupo heterocíclico es un átomo de azufre, el átomo de azufre puede ser oxidado al sulfóxido o la sulfona]; un grupo alquilo C1-6 substituido con un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a]; un grupo alcoxi C1-6alquilo C1-6 substituido con un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a]; o un grupo alcoxi C1-6alquilo C1-6 substituido con un grupo heterocíclico-oxi en el cual el grupo heterocíclico en el grupo heterocíclico-oxi que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a]; R2 representa un átomo de hidrógeno; un grupo alquilo C1-6; un grupo alquenilo C2-6; un grupo alquinilo C2-6; un grupo cicloalquilo C3-6; un grupo haloalquilo C1-6; un grupo haloalquenilo C2-6; un grupo haloalquinilo C2-6; un grupo alcoxi C1-6alquilo C1-6; un grupo cicloalquiloxi C3-6alquilo C1-6; un grupo di(alcoxi C1-6)alquilo C1-6; un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno (el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); el grupo fenilo, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenil-alquilo C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenil-alquenilo C2-6 el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; o un grupo fenil-alquinilo C2-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; Y y Z representan un átomo de oxígeno o un átomo de azufre; A representa cualquiera de las fórmulas (A-1) a la (A-5); R4 representa un grupo hidroxilo; O-M+ (M+ representa un catión de metal alcali o un catión de amoniaco); un grupo amino; un átomo de halógeno; un grupo ciano; un grupo isotiocianato; un grupo isocianato; un grupo hidroxicarboniloxi; un grupo alcoxicarboniloxi C1-6; un grupo benciloxicarboniloxi, el cual puede ser substituido con un substituyente del grupo seleccionado desde el grupo substituyente a; un grupo alcoxi C1-6; un grupo alqueniloxi C2-6; un grupo alqueniloxi C2-6; un grupo cicloalquiloxi C3-6; un grupo cianometilenoxi; un grupo cicloalquilo C3-6alquiloxi C1-6; un grupo alquilcarbonil C1-6oxi; un grupo haloalquilcarboniloxi C1-6; un grupo alquenilcarboniloxi C2-6; un grupo haloalquenilcarboniloxi C2-6; un grupo alquinilocarboniloxi C2-6; un grupo haloalquinilocarboniloxi C2-6; un grupo alcoxicarbonilo C1-6alcoxi C1-6; un grupo feniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo benciloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilcarboniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo bencil carboniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilcarbonil-alquiloxi C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo alquilsulfoniloxi C1-10; un grupo haloalquilsulfoniloxi C1-6; un grupo fenilsulfoniloxi el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo bencilsulfoniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo alquiltio C1-10; un grupo alquilsulfinilo C1-10; un grupo alquilsulfonilo C1-10; un grupo haloalquiltio C1-6; un grupo haloalquilsulfinilo C1-6; un grupo haloalquilsulfonilo C1-6; un grupo alqueniltio C2-6; un grupo alquenilsulfinilo C2-6; un grupo alquenilsulfonilo C2-6; un grupo alquinilotio C2-6; un grupo alquinilsulfinilo C2-6; un grupo alquinilsulfonilo C2-6; un grupo feniltio, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo benciltio, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo fenilsulfinilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo bencilsulfinilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo fenilsulfonilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo bencilsulfonilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo alquilamino C1-10; un grupo di(alquil C1-10)amino; un grupo alcoxicarbonil C1-6amino; un grupo alcoxi C1-6 substituido con un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo d
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