AR089882A1 - Compuestos fungicidas de pirimidina - Google Patents
Compuestos fungicidas de pirimidinaInfo
- Publication number
- AR089882A1 AR089882A1 ARP130100326A AR089882A1 AR 089882 A1 AR089882 A1 AR 089882A1 AR P130100326 A ARP130100326 A AR P130100326A AR 089882 A1 AR089882 A1 AR 089882A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- alkoxy
- haloalkoxy
- haloalkyl
- alkynyl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 230000000855 fungicidal effect Effects 0.000 title abstract 2
- 239000000417 fungicide Substances 0.000 title 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 23
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 10
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 9
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 8
- 229910052736 halogen Inorganic materials 0.000 abstract 8
- 150000002367 halogens Chemical class 0.000 abstract 8
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 7
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 abstract 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract 7
- 239000001257 hydrogen Substances 0.000 abstract 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 7
- 125000004429 atom Chemical group 0.000 abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 abstract 6
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 5
- 125000000623 heterocyclic group Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 4
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 4
- 125000005842 heteroatom Chemical group 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 4
- 125000001424 substituent group Chemical group 0.000 abstract 4
- 229910052717 sulfur Inorganic materials 0.000 abstract 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 3
- 125000001072 heteroaryl group Chemical group 0.000 abstract 3
- 229920006395 saturated elastomer Polymers 0.000 abstract 3
- 125000006625 (C3-C8) cycloalkyloxy group Chemical group 0.000 abstract 2
- 125000006570 (C5-C6) heteroaryl group Chemical group 0.000 abstract 2
- 125000004414 alkyl thio group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004995 haloalkylthio group Chemical group 0.000 abstract 2
- 125000004768 (C1-C4) alkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000004771 (C1-C4) haloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 1
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 1
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004741 (C1-C6) haloalkylsulfonyl group Chemical group 0.000 abstract 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- 241000233866 Fungi Species 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 abstract 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 1
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 230000003032 phytopathogenic effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Compuestos I fungicidas de pirimidina, su uso y los métodos para combatir hongos fitopatogénicos. Asimismo, procesos para preparar compuestos de la fórmula (1) e intermediarios. Reivindicación 1: Compuestos de la fórmula (1) en donde: Rᵃ⁵ es metoxi o halometoxi; Rᵃ², Rᵃ⁶ son, independientemente entre sí, hidrógeno, halógeno, CN, NO₂, OH, SH, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alquiltio C₁₋₄, haloalquiltio C₁₋₄, alquilsulfinilo C₁₋₄, haloalquilsulfinilo C₁₋₄, alquilsulfonilo C₁₋₄, haloalquilsulfonilo C₁₋₄, alcoxi C₁₋₄-alquilo C₁₋₄, alcoxi C₁₋₄-alcoxi C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, haloalquenilo C₂₋₄, haloalquinilo C₂₋₄, cicloalquilo C₃₋₈, cicloalquiloxi C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₄, NRARB, C(=O)R, C(=NOR)R o C(=NH)-O-R; RA, RB son, independientemente entre sí, hidrógeno, alquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, fenilo, bencilo, cicloalquilo C₃₋₈, cicloalquenilo C₃₋₈ o C(=O)-R; R es hidrógeno, OH, NH₂, alquilo C₁₋₄, haloalquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alquilamino C₁₋₄ o di(alquil C₁₋₄)amino; R es hidrógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alquenilo C₂₋₄, alquinilo C₂₋₄ o alcoxi C₁₋₄-alquilo C₁₋₄, R es hidrógeno o alquilo C₁₋₄; R es hidrógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alcoxi C₁₋₄-alquilo C₁₋₄, haloalcoxi C₁₋₄-alquilo C₁₋₄, alquenilo C₂₋₄, haloalquenilo C₂₋₄, alquinilo C₂₋₄, haloalquinilo C₂₋₄, CN, CH₂CN, NRARB o CH₂-O-C(=O)R; R¹, R² son, independientemente entre sí, hidrógeno, halógeno, OH, CN, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alcoxi C₁₋₄-alquilo C₁₋₄, haloalcoxi C₁₋₄-alquilo C₁₋₄, alquenilo C₂₋₄, haloalquenilo C₂₋₄, alquinilo C₂₋₄, haloalquinilo C₂₋₄, cicloalquilo C₃₋₈, cicloalquiloxi C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₄, NRARB, C(=O)R, C(=NOR)R, C(=NH)-O-R o bencilo, en donde la porción fenilo de bencilo es no sustituida o tiene 1, 2, 3, 4 ó 5 sustituyentes seleccionados del grupo que consiste en CN, halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, (alcoxi C₁₋₄)carbonilo y di(alquil C₁₋₄)aminocarbonilo, o dos radicales R¹ y R² que se unen al mismo átomo de carbono forman, junto con dicho átomo de carbono, un carbociclo saturado o parcialmente insaturado de 3, 4, 5, 6 ó 7 miembros o un heterociclo saturado o parcialmente insaturado de 3, 4, 5, 6 ó 7 miembros, en donde los átomos miembros del anillo del heterociclo antes mencionado incluyen, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados del grupo de N, O y S, y en donde el ciclo antes mencionado es no sustituido o tiene 1, 2, 3 ó 4 sustituyentes seleccionados de halógeno, CN, OH, SH, alquilo C₁₋₄, alcoxi C₁₋₄ o alquiltio C₁₋₄; y uno o dos grupos CH₂ de los ciclos antes mencionados se pueden reemplazar por uno o dos grupos C(=O) o C(=S), respectivamente; n indica la cantidad de sustituyentes Rᵇ en el anillo fenilo, y n es 0, 1, 2, 3 ó 4; Rᵇ es halógeno, CN, NO₂, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alquenilo C₂₋₄, haloalquenilo C₂₋₄, alquinilo C₂₋₄, haloalquinilo C₂₋₄, NRARB, C(=NOR)R o C(=NH)-O-R, en donde es posible para n = 2, 3 ó 4 que Rᵇ sean idénticos o diferentes; Het es un heteroarilo de 5 ó 6 miembros, en donde los átomos miembros del anillo del heteroarilo incluyen, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados del grupo de N, O y S y en donde el heteroarilo es no sustituido o tiene 1, 2, 3 ó 4 grupos Rᶜ idénticos o diferentes: Rᶜ es halógeno, CN, NO₂, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquiltio C₁₋₆, haloalquiltio C₁₋₆, alquilsulfinilo C₁₋₆, haloalquilsulfinilo C₁₋₆, alquilsulfonilo C₁₋₆, haloalquilsulfonilo C₁₋₆, alcoxi C₁₋₆-alquilo C₁₋₄, haloalcoxi C₁₋₆-alquilo C₁₋₄, alquenilo C₂₋₆, alquinilo C₂₋₆, NRARB, C(=O)R, C(=NOR)R, C(=NH)-O-R, cicloalquilo C₃₋₈, cicloalquil C₃₋₈-alquilo C₁₋₄, fenilo, fenil-alquilo C₁₋₄, fenoxi, fenoxi-alquilo C₁₋₄ o un heteroarilo de 5 ó 6 miembros, en donde los átomos miembros del anillo del heteroarilo incluyen, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados del grupo de N, O y S, y en donde los radicales cíclicos antes mencionados son no sustituidos o tienen 1, 2, 3 ó 4 sustituyentes Rᵈ idénticos o diferentes: Rᵈ es halógeno, CN, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄ o haloalcoxi C₁₋₄; o dos radicales Rᶜ que se unen a los átomos miembros del anillo adyacente del grupo Het forman, junto con dichos átomos miembros del anillo, un carbociclo o heterociclo fusionado, saturado, parcialmente insaturado o aromático de 5, 6 ó 7 miembros, en donde los átomos miembros del anillo del heterociclo fusionado incluyen, además de átomos de carbono, 1, 2, 3 ó 4 heteroátomos seleccionados del grupo de N, O y S, y en donde el carbociclo o heterociclo fusionado es no sustituido o tiene 1, 2, 3 ó 4 grupos radicales Rᵉ idénticos o diferentes: Rᵉ es halógeno, CN, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄ o haloalcoxi C₁₋₄; y los N-óxidos y las sales de estos aceptables en la agricultura.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12153758 | 2012-02-03 | ||
| EP12154196 | 2012-02-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR089882A1 true AR089882A1 (es) | 2014-09-24 |
Family
ID=47624098
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130100327 AR089883A1 (es) | 2012-02-03 | 2013-02-01 | Compuesto fungicidas de pirimidina |
| ARP130100325 AR089881A1 (es) | 2012-02-03 | 2013-02-01 | Compuestos fungicidas de pirimidina |
| ARP130100326 AR089882A1 (es) | 2012-02-03 | 2013-02-01 | Compuestos fungicidas de pirimidina |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130100327 AR089883A1 (es) | 2012-02-03 | 2013-02-01 | Compuesto fungicidas de pirimidina |
| ARP130100325 AR089881A1 (es) | 2012-02-03 | 2013-02-01 | Compuestos fungicidas de pirimidina |
Country Status (2)
| Country | Link |
|---|---|
| AR (3) | AR089883A1 (es) |
| WO (3) | WO2013113787A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2913325B1 (en) | 2012-10-25 | 2021-04-21 | Shenyang Sinochem Agrochemicals R & D Co., Ltd. | Substituted pyrimidine compound and uses thereof |
| CN105722833A (zh) * | 2013-09-16 | 2016-06-29 | 巴斯夫欧洲公司 | 杀真菌的嘧啶化合物 |
| CN105753791B (zh) * | 2014-12-19 | 2019-09-13 | 沈阳中化农药化工研发有限公司 | 取代嘧啶类化合物及其用途 |
| CN111789120B (zh) * | 2020-07-29 | 2022-04-01 | 湖南省植物保护研究所 | 杀菌剂抑霉唑离子液、及其制备方法和应用 |
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-
2013
- 2013-01-31 WO PCT/EP2013/051854 patent/WO2013113787A1/en not_active Ceased
- 2013-01-31 WO PCT/EP2013/051855 patent/WO2013113788A1/en not_active Ceased
- 2013-01-31 WO PCT/EP2013/051859 patent/WO2013113791A1/en not_active Ceased
- 2013-02-01 AR ARP130100327 patent/AR089883A1/es unknown
- 2013-02-01 AR ARP130100325 patent/AR089881A1/es unknown
- 2013-02-01 AR ARP130100326 patent/AR089882A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR089883A1 (es) | 2014-09-24 |
| AR089881A1 (es) | 2014-09-24 |
| WO2013113787A1 (en) | 2013-08-08 |
| WO2013113788A1 (en) | 2013-08-08 |
| WO2013113791A1 (en) | 2013-08-08 |
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