AR067866A1 - Copmposicones de catalizadores de varias capas - Google Patents
Copmposicones de catalizadores de varias capasInfo
- Publication number
- AR067866A1 AR067866A1 ARP080103148A ARP080103148A AR067866A1 AR 067866 A1 AR067866 A1 AR 067866A1 AR P080103148 A ARP080103148 A AR P080103148A AR P080103148 A ARP080103148 A AR P080103148A AR 067866 A1 AR067866 A1 AR 067866A1
- Authority
- AR
- Argentina
- Prior art keywords
- support
- component
- catalyst
- layer comprises
- copmpositions
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000003870 refractory metal Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1025—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/902—Multilayered catalyst
- B01D2255/9025—Three layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/908—O2-storage component incorporated in the catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
Abstract
Se divulga un catalizador de capas para conversion de tres vías que tiene la capacidad de catalizar simultáneamente la oxidacion de hidrocarburos y monoxido de carbono y la reduccion de oxidos de nitrogeno. Además se proveen métodos para preparar y usar dicho catalizador. En una o más formas de realizacion, el catalizador comprende tres capas de material catalítico en combinacion con un portador. Una primera capa comprende un componente de platino sobre un primer soporte; una segunda capa comprende un componente de rodio sobre un segundo soporte; y una tercera capa comprende un componente de paladio y un tercer soporte. El paladio, rodio, y/o platino, en forma independiente, se pueden depositar sobre un soporte de oxido de metal refractario de área superficial elevada, o de un componente de almacenamiento de oxígeno, o ambos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/780,094 US8007750B2 (en) | 2007-07-19 | 2007-07-19 | Multilayered catalyst compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR067866A1 true AR067866A1 (es) | 2009-10-28 |
Family
ID=39790863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP080103148A AR067866A1 (es) | 2007-07-19 | 2008-07-21 | Copmposicones de catalizadores de varias capas |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8007750B2 (es) |
| EP (1) | EP2180948A1 (es) |
| KR (1) | KR101538183B1 (es) |
| AR (1) | AR067866A1 (es) |
| WO (1) | WO2009012348A1 (es) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5210306B2 (ja) * | 2006-06-29 | 2013-06-12 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | 三元触媒 |
| DE502007002874D1 (de) * | 2007-09-28 | 2010-04-01 | Umicore Ag & Co Kg | Entfernung von Partikeln aus dem Abgas von mit überwiegend stöchiometrischem Luft/Kraftstoff-Gemisch betriebenen Verbrennungsmotoren |
| US20090155525A1 (en) * | 2007-12-18 | 2009-06-18 | Yuejin Li | Passivation-Free Coating Process For A CSF |
| US20090175773A1 (en) * | 2008-01-08 | 2009-07-09 | Chen Shau-Lin F | Multilayered Catalyst Compositions |
| JP5273446B2 (ja) * | 2008-05-12 | 2013-08-28 | 日産自動車株式会社 | 排ガス浄化用触媒及びその製造方法 |
| JP4751916B2 (ja) * | 2008-06-30 | 2011-08-17 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| JP5322526B2 (ja) * | 2008-07-17 | 2013-10-23 | エヌ・イーケムキャット株式会社 | 自動車から排出される排気ガスを浄化するためのハニカム構造型触媒及びその製造方法、並びに、その触媒を使用した排気ガス浄化方法 |
| US8273681B2 (en) * | 2008-09-02 | 2012-09-25 | Nissan Motor Co., Ltd. | Exhaust gas purifying catalyst and method for manufacturing the same |
| EP2368630A4 (en) * | 2008-12-19 | 2013-07-31 | Cataler Corp | EMISSION CONTROL CATALYST |
| CA2747648A1 (en) * | 2008-12-23 | 2010-07-01 | Shell Internationale Research Maatschappij B.V. | Catalysts for the production of hydrogen |
| US10773209B2 (en) * | 2009-02-20 | 2020-09-15 | Basf Corporation | Aging-resistant catalyst article for internal combustion engines |
| US8568675B2 (en) * | 2009-02-20 | 2013-10-29 | Basf Corporation | Palladium-supported catalyst composites |
| JP5492448B2 (ja) * | 2009-04-28 | 2014-05-14 | 株式会社キャタラー | 排ガス浄化用触媒 |
| KR101712684B1 (ko) * | 2009-05-04 | 2017-03-06 | 바스프 코포레이션 | 희박 연소 가솔린 엔진을 위한 twc의 개선된 희박 hc 전환 |
| EP2436441B1 (en) * | 2009-05-27 | 2017-06-14 | Cataler Corporation | Exhaust gas-purifying catalyst |
| KR20100129465A (ko) * | 2009-06-01 | 2010-12-09 | 희성촉매 주식회사 | 3중층 코팅구조의 삼원 촉매 |
| JP5380534B2 (ja) * | 2009-06-16 | 2014-01-08 | 株式会社キャタラー | 排ガス浄化用触媒及びその製造方法 |
| US8530372B2 (en) * | 2009-07-22 | 2013-09-10 | Basf Corporation | Oxygen storage catalyst with decreased ceria reduction temperature |
| US8833064B2 (en) * | 2009-11-06 | 2014-09-16 | Basf Corporation | Small engine layered catalyst article and method of making |
| US8828343B2 (en) * | 2010-03-05 | 2014-09-09 | Basf Corporation | Carbon monoxide conversion catalyst |
| JP5515939B2 (ja) * | 2010-03-26 | 2014-06-11 | マツダ株式会社 | 排気ガス浄化用触媒 |
| US8323599B2 (en) | 2010-11-22 | 2012-12-04 | Umicore Ag & Co. Kg | Three-way catalyst having an upstream multi-layer catalyst |
| US8557204B2 (en) | 2010-11-22 | 2013-10-15 | Umicore Ag & Co. Kg | Three-way catalyst having an upstream single-layer catalyst |
| JP5232258B2 (ja) * | 2011-02-25 | 2013-07-10 | 本田技研工業株式会社 | 内燃機関の排気浄化装置 |
| JP5376261B2 (ja) * | 2011-03-10 | 2013-12-25 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| JP5578369B2 (ja) * | 2011-06-24 | 2014-08-27 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| EP2780559A4 (en) * | 2011-08-10 | 2016-01-13 | Clean Diesel Tech Inc | Palladium mixed crystalline catalyst and method of preparation |
| US8449852B1 (en) * | 2011-12-01 | 2013-05-28 | Basf Corporation | Diesel oxidation catalysts, systems and methods of treatment |
| RU2502561C1 (ru) * | 2012-11-28 | 2013-12-27 | Федеральное государственное бюджетное учреждение науки Институт металлургии и материаловедения им. А.А. Байкова Российской академии наук (ИМЕТ РАН) | Способ приготовления катализатора для очистки отработавших газов двигателей внутреннего сгорания и катализатор, полученный этим способом |
| KR101459436B1 (ko) * | 2012-12-17 | 2014-11-07 | 현대자동차 주식회사 | 내연 기관용 가스 정화 촉매 |
| US9266092B2 (en) * | 2013-01-24 | 2016-02-23 | Basf Corporation | Automotive catalyst composites having a two-metal layer |
| KR20150131017A (ko) * | 2013-03-14 | 2015-11-24 | 바스프 코포레이션 | 분리된 워시코트를 갖는 촉매 물품 및 이의 제조 방법 |
| JP6474809B2 (ja) * | 2013-07-30 | 2019-02-27 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | アンモニアスリップ触媒 |
| EP3045226B1 (de) * | 2015-01-19 | 2024-08-21 | Umicore AG & Co. KG | Doppelschichtiger Dreiweg-Katalysator mit verbesserter Alterungsstabilität |
| WO2016124943A1 (en) * | 2015-02-05 | 2016-08-11 | Johnson Matthey Public Limited Company | Three-way catalyst |
| US9656209B2 (en) * | 2015-02-06 | 2017-05-23 | Johnson Matthey Public Limited Company | Three-way catalyst and its use in exhaust systems |
| WO2017134585A1 (en) * | 2016-02-03 | 2017-08-10 | Basf Corporation | Multi-layer catalyst composition for internal combustion engines |
| DE102016207484A1 (de) * | 2016-05-02 | 2017-11-02 | Umicore Ag & Co. Kg | Dieseloxidationskatalysator |
| EP3501646A1 (de) | 2017-12-19 | 2019-06-26 | Umicore Ag & Co. Kg | Katalytisch aktives partikelfilter |
| EP3501647A1 (de) | 2017-12-19 | 2019-06-26 | Umicore Ag & Co. Kg | Katalytisch aktives partikelfilter |
| EP3501648B1 (de) | 2017-12-19 | 2023-10-04 | Umicore Ag & Co. Kg | Katalytisch aktives partikelfilter |
| EP3849700A1 (en) * | 2018-09-13 | 2021-07-21 | BASF Corporation | A three-way conversion catalyst in gasoline-natural gas applications |
| WO2020200398A1 (de) | 2019-03-29 | 2020-10-08 | Umicore Ag & Co. Kg | Katalytisch aktives partikelfilter |
| KR20220025717A (ko) * | 2019-06-27 | 2022-03-03 | 바스프 코포레이션 | 촉매 물품 및 촉매 물품의 제조 방법 |
| JP7386651B2 (ja) * | 2019-09-02 | 2023-11-27 | 株式会社キャタラー | 排ガス浄化用触媒 |
| DE102020101876A1 (de) | 2020-01-27 | 2021-07-29 | Umicore Ag & Co. Kg | Doppelschichtiger Dreiweg-Katalysator mit weiter verbesserter Alterungsstabilität |
| JP7235417B2 (ja) * | 2020-08-28 | 2023-03-08 | トヨタ自動車株式会社 | 排ガス浄化装置 |
| JP2023543159A (ja) * | 2020-09-11 | 2023-10-13 | ビーエーエスエフ コーポレーション | 層状触媒物品及び触媒物品の製造方法 |
| EP4237141A1 (en) | 2020-10-30 | 2023-09-06 | Johnson Matthey Public Limited Company | Novel tri-metal pgm catalysts for gasoline engine exhaust gas treatments |
| US11788450B2 (en) * | 2020-10-30 | 2023-10-17 | Johnson Matthey Public Limited Company | TWC catalysts for gasoline engine exhaust gas treatments |
| JP7600910B2 (ja) * | 2021-07-06 | 2024-12-17 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| DE102021118803A1 (de) | 2021-07-21 | 2023-01-26 | Umicore Ag & Co. Kg | Abgasreinigungssystem zur Reinigung von Abgasen von Benzinmotoren |
| DE102021118802A1 (de) | 2021-07-21 | 2023-01-26 | Umicore Ag & Co. Kg | Abgasreinigungssystem zur Reinigung von Abgasen von Benzinmotoren |
| DE102021118801A1 (de) | 2021-07-21 | 2023-01-26 | Umicore Ag & Co. Kg | Abgasreinigungssystem zur Reinigung von Abgasen von Benzinmotoren |
| DE102022130469A1 (de) | 2022-11-17 | 2024-05-23 | Umicore Ag & Co. Kg | Verfahren und Vorrichtung zum Herstellen eines Substrats für eine Abgasnachbehandlungseinrichtung |
| DE102023117464A1 (de) | 2023-07-03 | 2025-01-09 | Umicore Ag & Co. Kg | Verfahren und Vorrichtung zum Herstellen eines Substrats für eine Abgasnachbehandlungseinrichtung |
| DE102023132075A1 (de) * | 2023-11-17 | 2025-05-22 | Umicore Ag & Co. Kg | Katalytischer Partikelfilter |
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| US6777370B2 (en) | 2001-04-13 | 2004-08-17 | Engelhard Corporation | SOx tolerant NOx trap catalysts and methods of making and using the same |
| US7276212B2 (en) * | 2001-10-01 | 2007-10-02 | Engelhard Corporation | Exhaust articles for internal combustion engines |
| JP2003112049A (ja) | 2001-10-03 | 2003-04-15 | Tokyo Roki Co Ltd | 3層構造型三元触媒 |
| US6764665B2 (en) * | 2001-10-26 | 2004-07-20 | Engelhard Corporation | Layered catalyst composite |
| US20030186805A1 (en) | 2002-03-28 | 2003-10-02 | Vanderspurt Thomas Henry | Ceria-based mixed-metal oxide structure, including method of making and use |
| US20040001781A1 (en) | 2002-06-27 | 2004-01-01 | Engelhard Corporation | Multi-zone catalytic converter |
| US7022646B2 (en) | 2003-01-31 | 2006-04-04 | Engelhard Corporation | Layered catalyst composite |
| KR100527943B1 (ko) | 2003-06-04 | 2005-11-09 | 현대자동차주식회사 | 2중층 코팅구조의 팔라듐 삼원촉매 제조방법 |
| US20050164879A1 (en) | 2004-01-28 | 2005-07-28 | Engelhard Corporation | Layered SOx tolerant NOx trap catalysts and methods of making and using the same |
| US7374729B2 (en) * | 2004-03-30 | 2008-05-20 | Basf Catalysts Llc | Exhaust gas treatment catalyst |
| US7795172B2 (en) | 2004-06-22 | 2010-09-14 | Basf Corporation | Layered exhaust treatment catalyst |
| US7678347B2 (en) | 2005-07-15 | 2010-03-16 | Basf Catalysts Llc | High phosphorous poisoning resistant catalysts for treating automobile exhaust |
| US7758834B2 (en) * | 2006-08-21 | 2010-07-20 | Basf Corporation | Layered catalyst composite |
| US20080044330A1 (en) * | 2006-08-21 | 2008-02-21 | Shau-Lin Franklin Chen | Layered catalyst composite |
| US7550124B2 (en) * | 2006-08-21 | 2009-06-23 | Basf Catalysts Llc | Layered catalyst composite |
| US7517510B2 (en) * | 2006-08-21 | 2009-04-14 | Basf Catalysts Llc | Layered catalyst composite |
| US7754171B2 (en) | 2007-02-02 | 2010-07-13 | Basf Corporation | Multilayered catalyst compositions |
| US20090175773A1 (en) * | 2008-01-08 | 2009-07-09 | Chen Shau-Lin F | Multilayered Catalyst Compositions |
-
2007
- 2007-07-19 US US11/780,094 patent/US8007750B2/en not_active Expired - Fee Related
-
2008
- 2008-07-17 WO PCT/US2008/070248 patent/WO2009012348A1/en not_active Ceased
- 2008-07-17 KR KR1020107003541A patent/KR101538183B1/ko not_active Expired - Fee Related
- 2008-07-17 EP EP08826437A patent/EP2180948A1/en not_active Withdrawn
- 2008-07-21 AR ARP080103148A patent/AR067866A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR20100057812A (ko) | 2010-06-01 |
| WO2009012348A1 (en) | 2009-01-22 |
| US8007750B2 (en) | 2011-08-30 |
| KR101538183B1 (ko) | 2015-07-22 |
| US20090022641A1 (en) | 2009-01-22 |
| EP2180948A1 (en) | 2010-05-05 |
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