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AR044137A1 - Derivados plaguicidas de benzotiazol y benzoxazol sustituidos con (dihalopropenil) fenilalquilo - Google Patents

Derivados plaguicidas de benzotiazol y benzoxazol sustituidos con (dihalopropenil) fenilalquilo

Info

Publication number
AR044137A1
AR044137A1 ARP040101473A ARP040101473A AR044137A1 AR 044137 A1 AR044137 A1 AR 044137A1 AR P040101473 A ARP040101473 A AR P040101473A AR P040101473 A ARP040101473 A AR P040101473A AR 044137 A1 AR044137 A1 AR 044137A1
Authority
AR
Argentina
Prior art keywords
alkyl
optionally substituted
alkoxy
haloalkyl
independently selected
Prior art date
Application number
ARP040101473A
Other languages
English (en)
Original Assignee
Fmc Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fmc Corp filed Critical Fmc Corp
Publication of AR044137A1 publication Critical patent/AR044137A1/es

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D211/20—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms
    • C07D211/22—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
    • C07D307/82—Benzo [b] furans; Hydrogenated benzo [b] furans with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • C07D307/83—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/10—Spiro-condensed systems

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Furan Compounds (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Fertilizers (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Reivindicación 1: Un compuesto de fórmula (1) donde R y R3 se seleccionan independientemente a partir de H, halógeno, hidroxi, alquilo C1-3, cicloalquilo C3-6, alquenilo, C2-5, alquinilo C2-5, haloalquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3,. haloalquiltio C1-3, alquil(C1-3)sulfonilo, haloalquil(C1-3)sulfonilo, ciano, nitro, amino opcionalmente sustituido donde el sustituyente opcional se selecciona entre alquilo C1-4, alquil(C1-3)carbonilo y alcoxi (C1-3)carbonilo, imidazolilo opcionalmente sustituido, imidazolinilo opcionalmente sustituido, oxazolinilo opcionalmente sustituido, oxazolilo opcionalmente sustituido, oxadiazolilo opcionalmente sustituido, tiazolilo opcionalmente sustituido, pirazolilo opcionalmente sustituido, triazolilo opcionalmente sustituido, furanilo opcionalmente sustituido, tetrahidrofuranilo opcionalmente sustituido, dioxolanilo opcionalmente sustituido, dioxanilo opcionalmente sustituido, -C(=J)-K, y -C(R12)-Q-R13, donde el sustituyente opcional se selecciona entre alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, alcoxi(C1-4)alquilo(C1-4), cicloalquilo C1-6, alquenilo C2-5, alquinilo C2-5, ciano, nitro y arilo; donde J se selecciona entre O, S, NR14, y NOR14, donde R14 es H, alquilo C1-4, haloalquilo C1-4, arilo y arilalquilo C1-4; K se selecciona entre H, alquilo C1-3, haloalquilo C1-3, alcoxi C1-3, alquil(C1-3)amino, y dialquil(C1-3)amino; Q se selecciona a partir de O, S, y NR14, donde R14 es como se definió precedentemente; R12 y R13 se seleccionan independientemente a partir de H, alquilo C1-4 y haloalquilo C1-4, y R12 y R13 pueden tomarse juntos con -T(CHR14)m-, donde m es un número entero de 2 a 4; T se selecciona a partir de O, S, y NR14, donde R14 es tal como se definió precedentemente; R1 y R2 se seleccionan independientemente a partir de H, halógeno y alquilo C1-3; R4 es H; R5 y R6 se seleccionan independientemente a partir de halógeno; E se selecciona a partir de CH2, O, S y NR15, donde R15 se selecciona a partir de H, alquilo C1-3, alcoxi (C1-3)alquilo(C1-3), arilalquilo C1-3, alquenilo(C2-4)alquilo(C1-3), haloalquenilo(C2-4)alquilo(C1-3), dialquil(C1-3)fosfonato, formilo, alquil(C1-3)carbonilo, haloalquil(C1-3)carbonilo, alcoxi(C1-3)alquil(C1-3)carbonilo, arilcarbonilo y alquil(C1-3)sulfonilo; G se selecciona a partir de O, S, CH2O* y (CH2)n donde el asterisco denota la unión a E, y n es un número entero seleccionado entre 1, 2 y 3, con la condición que E y G no sean simultáneamente O o S; x es un número entero seleccionado a partir de 0 y1; y cuando x es 1, A se selecciona a partir de O, S(O)p y -NR15, donde p es un número entero seleccionado a partir de 0, 1 y 2, y R15 es tal como se describió precedentemente; B es un grupo puente; *-(CR16R17)q-(CR18R19)r-(CR20R21)s-Lt-(CR22R23)u-(CR24R25)v-(CR26R27)w-; donde el asterisco denota la unión en A; q, r s, u, v y w son números enteros independientemente seleccionados a partir de 0, 1 y 2; y cuando q, r, s, u, v, o w son 1 o 2, R16 a R27, inclusive, se seleccionan independientemente a partir de H, alquilo C1-3, haloalquilo C1-3, alcoxi(C1-3)alquilo(C1-3), y cicloalquilo C3-6; t es un número entero seleccionado entre 0 o 1; y cuando t es 1, L se selecciona a partir de CH=CH; O, S(O)p; OS(O)2, S(O)2O, NR28; N(óxido)R28; NR28SO2, NR28C(=O)NR29, Si(CH3)2, C(=O), OC(=O), NHC(=O); ON=CH, HC=NO, C(=O)O, C(=O)NH, C(=NOR14) y [CR30R31]z, donde p es como se describió precedentemente, R28 y R29 se seleccionan independientemente a partir de H,. alquilo C1-3, alquil(C1-3)sulfonilo, alquil(C1-3)carbonilo, alquenilo C2-5 y alquinilo C2-5; z es un número entero seleccionado entre 1 o 2; y R30 y R31 se seleccionan independientemente a partir de H y alquilo C1-3; y es un número entero seleccionado entre 0 o 1; y cuando "y" es 1, D se selecciona a partir de O, S(O)p, y NR15, donde p y R15 son como se describieron precedentemente, donde D se encuentra unido a la fracción del anillo benzofusionado establecido en la fórmula (1) en cualquiera de las posiciones designadas 4-, 5-, 6-, o 7-; R7, R8, R9 y R10 se seleccionan independientemente a partir de H, halógeno, alquilo C1-4, cicloalquilo C3-6, alquenilo C2-5, alquinilo C2-5, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquil(C1-4)sulfonilo, haloalquilo(C1-4)sulfonilo, ciano, nitro, arilo, alquilcarbonilamino, arilcarbonilamino y alcoxi(C1-4)carbonilamino; R11 se selecciona a partir de H, halógeno, hidroxilo, ciano, alquilo C1-6, alcoxi C1-6, haloalquilo C1-6, haloalcoxi C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C1-6, amino, alquilamino C1-6,.dialquil(C1-6)amino, alquiltio C1-6, arilo, ariltio, trialquil(C1-6)sililo, SF5, C(=O)NR14 y NOR14, donde R14 es como se definió precedentemente; M es O o S; y sales agrícolamente aceptables de los mismos.
ARP040101473A 2003-04-30 2004-04-29 Derivados plaguicidas de benzotiazol y benzoxazol sustituidos con (dihalopropenil) fenilalquilo AR044137A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US46667403P 2003-04-30 2003-04-30

Publications (1)

Publication Number Publication Date
AR044137A1 true AR044137A1 (es) 2005-08-24

Family

ID=33418411

Family Applications (4)

Application Number Title Priority Date Filing Date
ARP040101474A AR044138A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzodioxol y benzodioxolano sustituidos con (dihalopropenilo) fenilalquilo
ARP040101472A AR045679A1 (es) 2003-04-30 2004-04-29 Derivados insecticidas de dihidrobenzopiran y dihidrobenzofuran sustituidos con (dihalopropenil)fenilalquilo
ARP040101473A AR044137A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzotiazol y benzoxazol sustituidos con (dihalopropenil) fenilalquilo
ARP040101471A AR045678A1 (es) 2003-04-30 2004-04-29 Derivados ciclicos fenil substituidos

Family Applications Before (2)

Application Number Title Priority Date Filing Date
ARP040101474A AR044138A1 (es) 2003-04-30 2004-04-29 Derivados plaguicidas de benzodioxol y benzodioxolano sustituidos con (dihalopropenilo) fenilalquilo
ARP040101472A AR045679A1 (es) 2003-04-30 2004-04-29 Derivados insecticidas de dihidrobenzopiran y dihidrobenzofuran sustituidos con (dihalopropenil)fenilalquilo

Family Applications After (1)

Application Number Title Priority Date Filing Date
ARP040101471A AR045678A1 (es) 2003-04-30 2004-04-29 Derivados ciclicos fenil substituidos

Country Status (16)

Country Link
US (5) US6987194B2 (es)
EP (4) EP1620421B1 (es)
JP (4) JP2006525335A (es)
KR (4) KR20060003055A (es)
CN (4) CN1780818A (es)
AR (4) AR044138A1 (es)
AT (2) ATE434612T1 (es)
AU (4) AU2004237745A1 (es)
BR (4) BRPI0409684A (es)
CA (4) CA2523191A1 (es)
DE (2) DE602004021689D1 (es)
MX (4) MXPA05011323A (es)
TW (4) TW200503618A (es)
UA (1) UA82875C2 (es)
WO (4) WO2004099145A2 (es)
ZA (4) ZA200508622B (es)

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CN104447677B (zh) * 2014-12-18 2016-07-06 湖南海利常德农药化工有限公司 4-羟基-2,2-二甲基-1,3-苯并二噁茂的制备方法
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CN111812229B (zh) * 2020-06-19 2023-08-01 广电计量检测(合肥)有限公司 一种气相色谱-质谱测定土壤/沉积物中2-甲基苯并噻唑的分析方法
CN113024528B (zh) * 2021-03-11 2024-01-09 西华大学 2-(2-噻吩甲酰氨基)苯并吡喃类化合物及其在农药中的用途
CN113004260B (zh) * 2021-03-11 2023-12-26 西华大学 2-(2-呋喃甲酰氨基)苯并吡喃类化合物及其在农药中的用途
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