AR044073A2 - Un proceso para la produccion simultanea de anhidrido maleico y sus derivados hidrogenados - Google Patents
Un proceso para la produccion simultanea de anhidrido maleico y sus derivados hidrogenadosInfo
- Publication number
- AR044073A2 AR044073A2 ARP040101386A ARP040101386A AR044073A2 AR 044073 A2 AR044073 A2 AR 044073A2 AR P040101386 A ARP040101386 A AR P040101386A AR P040101386 A ARP040101386 A AR P040101386A AR 044073 A2 AR044073 A2 AR 044073A2
- Authority
- AR
- Argentina
- Prior art keywords
- maleic anhydride
- hydrogenation
- stream
- recovering
- stage
- Prior art date
Links
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 title abstract 12
- 238000000034 method Methods 0.000 title abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052739 hydrogen Chemical class 0.000 title abstract 2
- 239000001257 hydrogen Chemical class 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 8
- 239000000463 material Substances 0.000 abstract 6
- 238000010521 absorption reaction Methods 0.000 abstract 5
- 239000000945 filler Substances 0.000 abstract 5
- 230000003647 oxidation Effects 0.000 abstract 5
- 238000007254 oxidation reaction Methods 0.000 abstract 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- 239000011574 phosphorus Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000009833 condensation Methods 0.000 abstract 2
- 230000005494 condensation Effects 0.000 abstract 2
- 150000002688 maleic acid derivatives Chemical class 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- AILDTIZEPVHXBF-UHFFFAOYSA-N Argentine Natural products C1C(C2)C3=CC=CC(=O)N3CC1CN2C(=O)N1CC(C=2N(C(=O)C=CC=2)C2)CC2C1 AILDTIZEPVHXBF-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 244000308495 Potentilla anserina Species 0.000 abstract 1
- 235000016594 Potentilla anserina Nutrition 0.000 abstract 1
- 239000011358 absorbing material Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
- C07C27/12—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/573—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D307/08—Preparation of tetrahydrofuran
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyrrole Compounds (AREA)
Abstract
Un proceso para la co-producción de anhidrido maleico y al menos un compuesto C4 seleccionado de butano-1,4-diol, gama-butirolactona y tetrahidrofurano, como divional de la solicitud de patente argentina No. P00 0105007, proceso en el cual: anhidrido maleico es producido por etapas que comprenden: i) alimentar una fuente de oxígeno gaseoso y un material de carga de hidrocarburos C4 a una zona de oxidación parcial catalítica que contiene una carga de un catalizador de oxidación parcial que contiene fósforo capaz de efectuar la oxidación parcial del material de carga de hidrocarburos C4 para formar anhidrido maleico y que es mantenida bajo condiciones de oxidación parcial catalítica; ii) recuperar de la zona de oxidación parcial una corriente de efluente de reacción en forma de vapor que comprende anhidrido maleico, agua, material de carga de hidrocarburos no convertidos y óxidos de carbono; iii) condensar una parte del anhidrido maleico presente en la corriente de efluente de reacción en forma de vapor en una zona de condensación para formar una corriente de anhidrido maleico crudo; iv) recuperar de la etapa de condensación iii) una corriente de vapor residual que contiene cantidades residuales de anhidrido maleico; v) absorber anhidrido maleico adicional de la corriente de vapor residual de la etapa iv) por absorción en un medio de absorción líquido seleccionado de un solvente orgánico, agua, y una solución acuosa; vi) recuperar de la etapa de absorción v) un medio de absorción líquido cargado; y vii) recuperar anhidrido maleico del medio de absorción líquido cargado; y en el cual: dicho al menos un compuesto C4 seleccionado del butano-1,4-diol, gama-butirolactona, y tetrahidrofurano es producido por etapas que comprenden: viii) proveer un material de carga de hidrogenación C4+ seleccionado de anhidrido maleico, ácido maleico, maleatos de monoalquilo, maleatos de dialquilo, y mezclas de dos o más de los mismos; ix) alimentar dicho material de carga de hidrogenación C4+ e hidrógeno a una zona de hidrogenación que contiene una carga de un catalizador de hidrogenación capaz de hidrogenar catalíticamente el material de carga de hidrogenación C4+ para proveer dicho al menos un producto C4 y que es mantenida bajo condiciones de hidrogenación catalítica; y x) recuperar de la zona de hidrogenación una corriente de producto de hidrogenación que contiene al menos un producto C4; estando el proceso caracterizado porque se enfría la corriente del efluente de reacción en forma de vapor previo a la etapa iii), porque se coloca un lecho protector de un material que absorbe fósforo en la trayectoria de la corriente del efluente de reacción en forma de vapor enfriada previo a la etapa iii), de modo de separar materiales que contienen fósforo de dicha corriente, y porque se usa el material de la corriente de anhídrido maleico crudo de la etapa iiii) como el material de carga de hidrogenación C4+ de la etapa viii) o para preparar dicho material de carga.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99308020 | 1999-10-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR044073A2 true AR044073A2 (es) | 2005-08-24 |
Family
ID=8241667
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP000105077A AR025798A1 (es) | 1999-10-12 | 2000-09-27 | Un proceso para la co-produccion de anhidrido maleico y al menos un compuesto c4 seleccionado de butano-1,4-diol, gamma-butirolactona y tetrahidrofurano. |
| ARP040101386A AR044073A2 (es) | 1999-10-12 | 2004-04-23 | Un proceso para la produccion simultanea de anhidrido maleico y sus derivados hidrogenados |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP000105077A AR025798A1 (es) | 1999-10-12 | 2000-09-27 | Un proceso para la co-produccion de anhidrido maleico y al menos un compuesto c4 seleccionado de butano-1,4-diol, gamma-butirolactona y tetrahidrofurano. |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | USRE39794E1 (es) |
| EP (2) | EP1220822B1 (es) |
| JP (2) | JP4933011B2 (es) |
| KR (2) | KR100549732B1 (es) |
| CN (2) | CN1241887C (es) |
| AR (2) | AR025798A1 (es) |
| AT (2) | ATE300511T1 (es) |
| AU (1) | AU775354C (es) |
| BR (2) | BR0017431B1 (es) |
| CA (1) | CA2387268C (es) |
| DE (2) | DE60021632T2 (es) |
| ES (2) | ES2245773T3 (es) |
| MX (1) | MXPA02003676A (es) |
| MY (2) | MY122525A (es) |
| NO (2) | NO327782B1 (es) |
| SG (1) | SG144711A1 (es) |
| TW (2) | TWI232213B (es) |
| WO (1) | WO2001027058A1 (es) |
| ZA (1) | ZA200202572B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY122525A (en) * | 1999-10-12 | 2006-04-29 | Kvaerner Process Tech Ltd | Process for the simultaneous production of maleic anyhydride and its hydrogenated derivatives |
| GB0325526D0 (en) | 2003-10-31 | 2003-12-03 | Davy Process Techn Ltd | Process |
| GB0421928D0 (en) | 2004-10-01 | 2004-11-03 | Davy Process Techn Ltd | Process |
| JP2006321995A (ja) * | 2005-04-22 | 2006-11-30 | Mitsubishi Chemicals Corp | ポリエステルの製造方法 |
| DE102006024903A1 (de) * | 2006-05-24 | 2007-11-29 | Basf Ag | Verfahren zur Vermeidung von Fumarsäureablagerungen bei der Herstellung von Maleinsäureanhydrid |
| US20080009652A1 (en) * | 2006-07-05 | 2008-01-10 | Huntsman Petrochemical Corporation | Process of Making Butyric Acid |
| WO2013076747A1 (en) | 2011-11-25 | 2013-05-30 | Conser Spa | Process for producing 1,4- butanediol by hydrogenating dialkyl maleate in mixed liquid/vapor phase |
| CN104096376B (zh) * | 2014-06-27 | 2016-03-09 | 常州瑞华化工工程技术有限公司 | 一种防止顺酐装置氧化产物冷凝器堵塞的方法和装置 |
| EP3559156A1 (en) * | 2016-12-20 | 2019-10-30 | SABIC Global Technologies B.V. | Utilization of normal carbon 4 (nc4) recycle stream for secondary and tertiary products |
| CA3144222C (en) * | 2019-07-16 | 2024-01-23 | Thirumalai Chemicals Limited | Production of malic acid |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2574644A (en) * | 1948-07-06 | 1951-11-13 | Chempatents Inc | Recovery of polycarboxylic acid anhydrides |
| US3741993A (en) * | 1970-02-03 | 1973-06-26 | Tenneco Chem | Maleic anhydride process |
| US3904652A (en) * | 1972-11-16 | 1975-09-09 | Standard Oil Co Indiana | Recycle process for oxidation of n-butane to maleic anhydride |
| GB2207914A (en) * | 1987-07-30 | 1989-02-15 | Davy Mckee | Process for the production of a mixture of butane 1,4-diol gamma-butyrolactone and tetrahydrofuran |
| TW341568B (en) * | 1995-12-27 | 1998-10-01 | Akzo Nobel Nv | Process for manufacturing Gamma-butyrolactone and its use |
| ZA973972B (en) | 1996-05-14 | 1998-03-23 | Kvaerner Process Tech Ltd | A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran. |
| ZA973971B (en) * | 1996-05-15 | 1998-03-23 | Kvaerner Process Tech Ltd | A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran. |
| JP3873464B2 (ja) * | 1997-07-22 | 2007-01-24 | 三菱化学株式会社 | 無水マレイン酸の製造方法 |
| CA2243402A1 (en) * | 1997-07-22 | 1999-01-22 | Hideo Suwa | Process for producing maleic anhydride |
| IT1297120B1 (it) * | 1997-12-16 | 1999-08-03 | Sigma Tau Ind Farmaceuti | Procedimento per la produzione di (r)-3-idrossi-4-butirrolattone utile nella preparazione della (r)-carnitina |
| BE1012342A6 (fr) * | 1998-01-08 | 2000-10-03 | Pantochim Sa | Procede de production de butanediol par hydrogenation en phase liquide. |
| US5972174A (en) * | 1998-01-13 | 1999-10-26 | Huntsman Petrochemical Corporation | Process for the purification of maleic anhydride |
| IT1298535B1 (it) * | 1998-02-02 | 2000-01-12 | Lonza Spa | Procedimento per la produzione di gamma-butirrolattone |
| DE69800886T2 (de) * | 1998-03-23 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung von 1,4-Butandiol, Butyrolacton und Tetrahydrofuran |
| BE1012274A7 (fr) * | 1998-11-10 | 2000-08-01 | Pantochim Sa | Procede a haute productivite pour la preparation de gamma butyrolactone et de tetrahydrofurane. |
| MY122525A (en) * | 1999-10-12 | 2006-04-29 | Kvaerner Process Tech Ltd | Process for the simultaneous production of maleic anyhydride and its hydrogenated derivatives |
| KR100344962B1 (ko) * | 2000-04-10 | 2002-07-20 | 한국에너지기술연구원 | 무수말레인산을 원료로 한 감마 부티로락톤 제조방법 |
| EP1167361A3 (en) * | 2000-06-19 | 2002-01-23 | Haldor Topsoe A/S | Process and catalyst for the production of y-butyrolactones |
-
2000
- 2000-09-15 MY MYPI20004305A patent/MY122525A/en unknown
- 2000-09-15 MY MYPI20041088A patent/MY139259A/en unknown
- 2000-09-27 AR ARP000105077A patent/AR025798A1/es active IP Right Grant
- 2000-10-04 CN CNB008142076A patent/CN1241887C/zh not_active Expired - Fee Related
- 2000-10-04 KR KR1020027004658A patent/KR100549732B1/ko not_active Expired - Fee Related
- 2000-10-04 BR BRPI0017431-9A patent/BR0017431B1/pt not_active IP Right Cessation
- 2000-10-04 MX MXPA02003676A patent/MXPA02003676A/es active IP Right Grant
- 2000-10-04 WO PCT/GB2000/003805 patent/WO2001027058A1/en not_active Ceased
- 2000-10-04 ES ES04006321T patent/ES2245773T3/es not_active Expired - Lifetime
- 2000-10-04 US US11/229,446 patent/USRE39794E1/en not_active Expired - Lifetime
- 2000-10-04 JP JP2001530080A patent/JP4933011B2/ja not_active Expired - Fee Related
- 2000-10-04 SG SG200402002-0A patent/SG144711A1/en unknown
- 2000-10-04 KR KR1020047004807A patent/KR100578997B1/ko not_active Expired - Fee Related
- 2000-10-04 AT AT04006321T patent/ATE300511T1/de not_active IP Right Cessation
- 2000-10-04 DE DE60021632T patent/DE60021632T2/de not_active Expired - Lifetime
- 2000-10-04 EP EP00964500A patent/EP1220822B1/en not_active Expired - Lifetime
- 2000-10-04 EP EP04006321A patent/EP1428812B1/en not_active Expired - Lifetime
- 2000-10-04 AT AT00964500T patent/ATE274487T1/de not_active IP Right Cessation
- 2000-10-04 ES ES00964500T patent/ES2226920T3/es not_active Expired - Lifetime
- 2000-10-04 BR BR0014696-0A patent/BR0014696A/pt not_active Application Discontinuation
- 2000-10-04 CA CA002387268A patent/CA2387268C/en not_active Expired - Fee Related
- 2000-10-04 AU AU75431/00A patent/AU775354C/en not_active Ceased
- 2000-10-04 US US10/110,444 patent/US6620949B1/en not_active Ceased
- 2000-10-04 DE DE60013311T patent/DE60013311T2/de not_active Expired - Lifetime
- 2000-10-04 CN CNB2004100325955A patent/CN100355741C/zh not_active Expired - Fee Related
- 2000-11-02 TW TW093114988A patent/TWI232213B/zh not_active IP Right Cessation
- 2000-11-02 TW TW089123115A patent/TWI228502B/zh not_active IP Right Cessation
-
2002
- 2002-04-02 ZA ZA200202572A patent/ZA200202572B/en unknown
- 2002-04-11 NO NO20021715A patent/NO327782B1/no not_active IP Right Cessation
-
2004
- 2004-04-23 AR ARP040101386A patent/AR044073A2/es active IP Right Grant
- 2004-04-26 NO NO20041707A patent/NO329594B1/no not_active IP Right Cessation
- 2004-07-29 JP JP2004221745A patent/JP4933037B2/ja not_active Expired - Fee Related
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |