BR9709250A - Processo para preparação de gama-butirolactona, butano-1,4 diol e tetrahidrofurano - Google Patents
Processo para preparação de gama-butirolactona, butano-1,4 diol e tetrahidrofuranoInfo
- Publication number
- BR9709250A BR9709250A BR9709250-9A BR9709250A BR9709250A BR 9709250 A BR9709250 A BR 9709250A BR 9709250 A BR9709250 A BR 9709250A BR 9709250 A BR9709250 A BR 9709250A
- Authority
- BR
- Brazil
- Prior art keywords
- anhydride
- butane
- diol
- tetrahydrofuran
- hydrogenation
- Prior art date
Links
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 title abstract 8
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract 8
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 title abstract 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 abstract 5
- 150000008064 anhydrides Chemical class 0.000 abstract 4
- 238000009835 boiling Methods 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 3
- 238000010521 absorption reaction Methods 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- KPYCVQASEGGKEG-UHFFFAOYSA-N 3-hydroxyoxolane-2,5-dione Chemical compound OC1CC(=O)OC1=O KPYCVQASEGGKEG-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000009904 heterogeneous catalytic hydrogenation reaction Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D307/08—Preparation of tetrahydrofuran
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
Abstract
Patente de Invenção:<B>"PROCESSO PARA PREPARAçãO DE GAMA-BUTIROLACTONA, BUTANO-1, 4 DIOL E TETRAHIDROFURANO"<D>. Processo é descrito para a produção de pelo menos um composto de C4 selecionado do butano-1,4-diol, gama-butirolactona e tetrahidrofurano, que inclui a etapa de hidrogenação na fase de vapor de anidrido malÞico na presença de um catalisador de hidrogenação, heterogêneo, cujo processo compreende: (a) contactar um fluxo vaporoso contendo vapor de anidrido malÞico, vapor d'água e óxidos de carbono em uma zona de absorção com um solvente orgânico de alto ponto de ebulição tendo m ponto de ebulição em pressão atmosférica que fica pelo menos em torno de 30°C mais alto do que aquele de anidrido malÞico, desta forma para formar uma solução de anidrido malÞico no solvente orgânico de alto ponto de ebulição; (b) recuperar da zona de absorção um fluxo de gás residual; (c) contactar a solução de anidrido malÞico no solvente de alto ponto de ebulição com um fluxo gasoso contendo hidrogênio, para deste modo separar anidrido malÞico daí e formar um fluxo vaporoso compreendendo hidrogênio e anidrido malÞico; (d) contactar material de fluxo vaporoso da etapa (e) em uma zona de hidrogenação sob condições de hidrogenação na presença de um catalisador de hidrogenação heterogêneo, para deste modo converter anidrido malÞico em pelo menos um composto de C4 selecionado do butano-1,4-diol, gama-butirolactona e tetrahidrofurano; e (e) recuperar da zona de hidrogenação um fluxo do produto contendo o dito pelo menos um composto de C4.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96303428 | 1996-05-15 | ||
| PCT/GB1997/001286 WO1997043234A1 (en) | 1996-05-15 | 1997-05-12 | Process for preparing gamma-butyrolactone, butane-1,4-diol and tetrahydrofuran |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9709250A true BR9709250A (pt) | 2000-05-09 |
Family
ID=8224940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9709250-9A BR9709250A (pt) | 1996-05-15 | 1997-05-12 | Processo para preparação de gama-butirolactona, butano-1,4 diol e tetrahidrofurano |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6077964A (pt) |
| EP (1) | EP0922022B1 (pt) |
| JP (1) | JP4021490B2 (pt) |
| KR (1) | KR100464610B1 (pt) |
| CN (1) | CN1089743C (pt) |
| AR (1) | AR007126A1 (pt) |
| AU (1) | AU707824B2 (pt) |
| BR (1) | BR9709250A (pt) |
| CA (1) | CA2255912C (pt) |
| DE (1) | DE69715640T2 (pt) |
| ES (1) | ES2184088T3 (pt) |
| MX (1) | MX204063B (pt) |
| NO (1) | NO311932B1 (pt) |
| SA (1) | SA97180160B1 (pt) |
| TW (1) | TW413673B (pt) |
| WO (1) | WO1997043234A1 (pt) |
| ZA (1) | ZA973971B (pt) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9724195D0 (en) * | 1997-11-14 | 1998-01-14 | Kvaerner Process Tech Ltd | Process |
| BE1011699A6 (fr) * | 1998-01-08 | 1999-12-07 | Pantochim Sa | Procede de production de tetrahydrofuranne et de gamma-butyrolactone. |
| DE19806038A1 (de) * | 1998-02-13 | 1999-08-19 | Basf Ag | Verfahren zur Abtrennung von Maleinsäureanhydrid aus maleinsäureanhydridhaltigen Gemischen durch Strippung |
| DE69800886T2 (de) * | 1998-03-23 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung von 1,4-Butandiol, Butyrolacton und Tetrahydrofuran |
| BE1012274A7 (fr) | 1998-11-10 | 2000-08-01 | Pantochim Sa | Procede a haute productivite pour la preparation de gamma butyrolactone et de tetrahydrofurane. |
| US6235930B1 (en) * | 1999-03-31 | 2001-05-22 | Board Of Trustees Operating Michigan State University | Process for the preparation of 3,4-dihydroxybutanoic acid and derivatives thereof from substituted pentose sugars |
| MY122525A (en) * | 1999-10-12 | 2006-04-29 | Kvaerner Process Tech Ltd | Process for the simultaneous production of maleic anyhydride and its hydrogenated derivatives |
| DE10021703A1 (de) | 2000-05-04 | 2001-11-08 | Basf Ag | Verfahren zur destillativen Trennung von Tetrahydrofuran, gamma-Butyrolacton und/oder 1,4-Butandiol enthaltenden Gemischen |
| GB0117090D0 (en) | 2001-07-12 | 2001-09-05 | Kvaerner Process Tech Ltd | Process |
| DE10137534A1 (de) | 2001-08-01 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Maleinsäureanhydrid |
| DE10219224A1 (de) * | 2002-04-30 | 2003-11-13 | Basf Ag | Verfahren zur Herstellung von gamma-Butyrolacton |
| DE10225927A1 (de) | 2002-06-11 | 2003-12-24 | Basf Ag | Verfahren zur Herstellung von Butandiol durch kombinierte Gasphasen- und Flüssigphasensynthese |
| DE10225929A1 (de) * | 2002-06-11 | 2003-12-24 | Basf Ag | Zweistufiges Verfahren zur Herstellung von Butandiol mit Zwischenabtrennung von Bernsteinsäureanhydrid |
| DE10225928A1 (de) * | 2002-06-11 | 2003-12-24 | Basf Ag | Zweistufiges Verfahren zur Herstellung von Butandiol in zwei Reaktoren |
| DE10225926A1 (de) * | 2002-06-11 | 2003-12-24 | Basf Ag | Verfahren zur Herstellung von Butandiol |
| GB0325530D0 (en) | 2003-10-31 | 2003-12-03 | Davy Process Techn Ltd | Process |
| GB0325526D0 (en) | 2003-10-31 | 2003-12-03 | Davy Process Techn Ltd | Process |
| DE10357715A1 (de) | 2003-12-09 | 2005-07-14 | Basf Ag | Verfahren zur Herstellung von definierten Gemischen aus THF, BDO und GBL durch Gasphasenhydierung |
| GB0421928D0 (en) | 2004-10-01 | 2004-11-03 | Davy Process Techn Ltd | Process |
| DE102005031314A1 (de) * | 2005-07-05 | 2007-01-18 | Basf Ag | Verfahren zur Abtrennung von Maleinsäureanhydrid aus maleinsäureanhydridhaltigen Gemischen durch Strippung |
| KR100922998B1 (ko) * | 2008-03-06 | 2009-10-22 | 한국화학연구원 | 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법 |
| KR200458108Y1 (ko) * | 2009-01-14 | 2012-01-20 | 제이씨코리아 주식회사 | 손톱 장신구 |
| GB0906031D0 (en) * | 2009-04-07 | 2009-05-20 | Davy Process Techn Ltd | Process |
| WO2016008904A1 (en) | 2014-07-16 | 2016-01-21 | Basf Se | METHOD FOR PURIFYING RAW γ-BUTYROLACTONE |
| CN107245026A (zh) * | 2017-06-22 | 2017-10-13 | 江苏飞翔化工股份有限公司 | 无溶剂由内酯制备二醇的方法 |
| CN116768700B (zh) * | 2023-05-15 | 2026-01-09 | 浙江环化科技有限公司 | 一种用马来酸酐加氢制备1,4-丁二醇的方法 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE271126C (pt) * | ||||
| US2638481A (en) * | 1950-05-26 | 1953-05-12 | Hercules Powder Co Ltd | Maleic acid manufacture |
| GB727828A (en) * | 1952-12-09 | 1955-04-06 | Chempatents Inc | Recovery of polycarboxylic acid anhydrides |
| GB763339A (en) * | 1953-03-23 | 1956-12-12 | Chempatents Inc | Improvements in recovery of maleic and phthalic acid anhydrides |
| FR1089012A (fr) * | 1953-10-08 | 1955-03-14 | Chempatents | Procédé de récupération des anhydrides d'acides polycarboxyliques à partir de mélanges gazeux dilués |
| NL98195C (pt) * | 1955-04-20 | |||
| US2893924A (en) * | 1956-04-17 | 1959-07-07 | Saint Gobain | Separation and purification of anhydrides of organic diacids |
| US3040059A (en) * | 1959-07-02 | 1962-06-19 | Foster Wheeler Corp | Recovery of the anhydrides of polycarboxylic acids |
| BE792879A (fr) * | 1971-12-17 | 1973-03-30 | Chevron Res | Procede d'isolement de l'anhydride maleique |
| US3891680A (en) * | 1972-11-29 | 1975-06-24 | Chevron Res | Maleic anhydride recovery using nonaqueous medium |
| US3850758A (en) * | 1973-07-02 | 1974-11-26 | Allied Chem | Purification of crude maleic anhydride by treatment with dimethylbenzophenone |
| DE2444824A1 (de) * | 1974-09-19 | 1976-04-08 | Basf Ag | Verfahren zur gewinnung von maleinsaeureanhydrid |
| US4071540A (en) * | 1976-07-08 | 1978-01-31 | Chevron Research Company | Anhydride separation process |
| DE2642533C2 (de) * | 1976-09-22 | 1985-08-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von gamma- Butyrolacton aus Maleinsäureanhydrid |
| US4118403A (en) * | 1976-11-18 | 1978-10-03 | Monsanto Company | Recovery of maleic anhydride |
| GB8331793D0 (en) * | 1983-11-29 | 1984-01-04 | Davy Mckee Ltd | Process |
| EP0204730A1 (en) * | 1984-11-21 | 1986-12-17 | DAVY McKEE (LONDON) LIMITED | Process for the production of butane-1,4-diol |
| WO1988000937A1 (en) * | 1986-08-01 | 1988-02-11 | Davy Mckee (London) Limited | Process for the co-production of butane-1,4-diol and gamma-butyrolactone |
| GB8618890D0 (en) * | 1986-08-01 | 1986-09-10 | Davy Mckee Ltd | Process |
| GB8717992D0 (en) * | 1987-07-29 | 1987-09-03 | Davy Mckee Ltd | Process |
| GB8717993D0 (en) * | 1987-07-29 | 1987-09-03 | Davy Mckee Ltd | Process |
| JP2596604B2 (ja) * | 1988-12-14 | 1997-04-02 | 東燃株式会社 | 1,4−ブタンジオールおよびテトラヒドロフランの製造方法 |
| GB8917864D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| GB8917862D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| GB8917859D0 (en) * | 1989-08-04 | 1989-09-20 | Davy Mckee London | Process |
| US5347021A (en) * | 1990-04-16 | 1994-09-13 | Isp Investments Inc. | Process of vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone in high conversion and high selectivity using an activated catalyst |
-
1997
- 1997-05-08 ZA ZA9703971A patent/ZA973971B/xx unknown
- 1997-05-10 TW TW086106241A patent/TW413673B/zh not_active IP Right Cessation
- 1997-05-12 CN CN97194570A patent/CN1089743C/zh not_active Expired - Lifetime
- 1997-05-12 EP EP97921941A patent/EP0922022B1/en not_active Expired - Lifetime
- 1997-05-12 KR KR19980709165A patent/KR100464610B1/ko not_active Expired - Fee Related
- 1997-05-12 ES ES97921941T patent/ES2184088T3/es not_active Expired - Lifetime
- 1997-05-12 CA CA002255912A patent/CA2255912C/en not_active Expired - Fee Related
- 1997-05-12 BR BR9709250-9A patent/BR9709250A/pt not_active IP Right Cessation
- 1997-05-12 AU AU27820/97A patent/AU707824B2/en not_active Ceased
- 1997-05-12 JP JP54065097A patent/JP4021490B2/ja not_active Expired - Fee Related
- 1997-05-12 US US09/180,766 patent/US6077964A/en not_active Expired - Lifetime
- 1997-05-12 DE DE69715640T patent/DE69715640T2/de not_active Expired - Lifetime
- 1997-05-12 WO PCT/GB1997/001286 patent/WO1997043234A1/en not_active Ceased
- 1997-05-14 AR ARP970102010A patent/AR007126A1/es active IP Right Grant
- 1997-06-22 SA SA97180160A patent/SA97180160B1/ar unknown
-
1998
- 1998-11-12 MX MX9809480A patent/MX204063B/es active IP Right Grant
- 1998-11-13 NO NO19985291A patent/NO311932B1/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP4021490B2 (ja) | 2007-12-12 |
| CN1089743C (zh) | 2002-08-28 |
| ES2184088T3 (es) | 2003-04-01 |
| EP0922022B1 (en) | 2002-09-18 |
| KR20000011015A (ko) | 2000-02-25 |
| CN1218450A (zh) | 1999-06-02 |
| CA2255912A1 (en) | 1997-11-20 |
| CA2255912C (en) | 2006-10-10 |
| NO985291L (no) | 1998-11-13 |
| WO1997043234A1 (en) | 1997-11-20 |
| TW413673B (en) | 2000-12-01 |
| MX204063B (pt) | 2001-09-03 |
| KR100464610B1 (ko) | 2005-05-19 |
| MX9809480A (pt) | 1999-03-31 |
| AR007126A1 (es) | 1999-10-13 |
| ZA973971B (en) | 1998-03-23 |
| AU707824B2 (en) | 1999-07-22 |
| AU2782097A (en) | 1997-12-05 |
| EP0922022A1 (en) | 1999-06-16 |
| JP2000510475A (ja) | 2000-08-15 |
| DE69715640D1 (de) | 2002-10-24 |
| SA97180160B1 (ar) | 2006-09-05 |
| US6077964A (en) | 2000-06-20 |
| NO311932B1 (no) | 2002-02-18 |
| DE69715640T2 (de) | 2003-02-06 |
| NO985291D0 (no) | 1998-11-13 |
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Legal Events
| Date | Code | Title | Description |
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| PC | Transfer |
Free format text: BASF AKTIENGESELLSCHAFT (DE) |
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| FF | Decision: intention to grant | ||
| HIX | Notification cancelled | ||
| HHFI | Decision: rectification | ||
| FG9A | Patent or certificate of addition granted | ||
| B24C | Patent annual fee: request for for restoration |
Free format text: REFERENTE A 11A E 12A ANUIDADES. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE AO DESPACHO 24.3 PUBLICADO NA RPI 2002 DE 19/05/2009. |