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KR830006406A - 메탄올과 고급알콜의 "연료급" 혼합물의 제조방법 - Google Patents

메탄올과 고급알콜의 "연료급" 혼합물의 제조방법 Download PDF

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Publication number
KR830006406A
KR830006406A KR1019810001658A KR810001658A KR830006406A KR 830006406 A KR830006406 A KR 830006406A KR 1019810001658 A KR1019810001658 A KR 1019810001658A KR 810001658 A KR810001658 A KR 810001658A KR 830006406 A KR830006406 A KR 830006406A
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process according
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temperature
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pressure
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KR840001860B1 (ko
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디 피에트르 라피레
파기니 알버토
라가나 빈센조
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칼로 시오니
스남프로게티 엣세. 피. 아
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

내용 없음

Description

메탄올과 고급알콜의 "연료급" 혼합물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도와 2도는 본 발명의 공정도.

Claims (17)

  1. (a) CO와 H2로 구성된 가스 혼합물을 합성기에 주입 :
    (b) 메탄올, 고급알콜, 물 및 미반응가스로 구성된 반응 혼합물을 냉각
    (c) 냉각된 혼합물을 전환 반응기에 송환 :
    (d) 메탄올, 고급알콜, 미반응가스, 이산화탄소와 미량의 물로 구성된 반응생성물을 냉각 :
    (e) 연료급 알콜 혼합물로 구성된 액상과 CO,H2와 CO2로 구성된 반응생성물을 냉각 :
    (f) 기체상은 흡수기에 보내서 CO2를 제거하고 정제된 가스의 일부는 재순환되고 일부는 불활성 물질의 축적을 피하기 위하여 배출시킴 :
    (g) 액상은 배출가스를 세정제로서 사용하는 세정기에 보내서 액상내에 용해된 가스를 제거 및
    (h) 정제된 액상을 흡수 액체로서 사용하기 위하여 흡수기에 송환하는 단계들로 구성된 "연료급"의 메탄올과 고급알콜 혼합물의 제조방법
  2. 합성 반응기를 300-500℃의 온도에서 조작하는 청구범위 1에 따른 방법.
  3. 합성 반응기가 150ata 이상의 압력에서 조작되는 청구범위 1에 따른 방법.
  4. 온도를 360°-420C 내에서 선택한 청구범위 2에 따른 방법.
  5. 압력이 200ata 이상인 청구범위 3에 따른 방법.
  6. 합성 반응기에 200°-300℃의 온도에서 조작되는 청구범위 1에 따른 방법.
  7. 합성 반응기가 30-150ata의 압력에서 조작되는 청구범위 1에 따른 방법.
  8. 온도는 230°-270℃에서 선택되는 청구범위 6에 따른 방법.
  9. 압력을 50-100ata에서 선택한 청구범위 7에 따른 방법.
  10. 전환 반응을 150°-250℃의 온도에서 조작하는 청구범위 1에 따른 방법.
  11. 온도를 160°-220℃에서 선택한 청구범위 10에 따른 방법.
  12. 전환 반응기를 합성 반응기와 동일한 압력에서 조작하는 청구범위 1에 따른 방법.
  13. 합성 반응을 알카리 금속이나 알카리 토금속으로 변형시킨 아연과 크롬으로 기초로 한 촉매의 존재하에 실시하는 청구범위 2와 3에 따른 방법.
  14. 합성반응을 동 Al,Cr,V 및 Mn을 함유하여 알카리 금속이나 토금속을 변형시킨 동, 아연을 기초로 한 촉매의 존재하에서 실시하는 청구범위 6과 7에 따른 방법.
  15. 전환반응을 동을 기초로한 촉매의 존재하에 실시하는 청구범위 10과 12에 따른 방법.
  16. 흡수 액체를 저압으로 하거나 또는 세정탑에 재순환시킴에 의하여 흡수된 가스로부터 유리 및 재생시키는 청구범위 1에 따른 공정.
  17. CO2의 흡수탑이 합성 반응기와 동일한 압력에서 작동되는 청구범위 1에 따른 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810001658A 1980-05-16 1981-05-14 메탄올과 고급알콜의 "연료급" 혼합물의 제조방법 Expired KR840001860B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT22117A 1980-05-16
IT22117A/80 1980-05-16
IT22117/80A IT1148864B (it) 1980-05-16 1980-05-16 Processo pe la produzione di una miscela di metanolo ed alcoli superiori grado carburante

Publications (2)

Publication Number Publication Date
KR830006406A true KR830006406A (ko) 1983-09-24
KR840001860B1 KR840001860B1 (ko) 1984-10-23

Family

ID=11191737

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Application Number Title Priority Date Filing Date
KR1019810001658A Expired KR840001860B1 (ko) 1980-05-16 1981-05-14 메탄올과 고급알콜의 "연료급" 혼합물의 제조방법

Country Status (35)

Country Link
US (1) US4460378A (ko)
JP (1) JPS5710690A (ko)
KR (1) KR840001860B1 (ko)
AT (1) AT379580B (ko)
AU (1) AU543346B2 (ko)
BE (1) BE888799A (ko)
BR (1) BR8102808A (ko)
CA (1) CA1159256A (ko)
CH (1) CH648342A5 (ko)
CS (1) CS224613B2 (ko)
CU (1) CU21284A3 (ko)
DD (1) DD158913A5 (ko)
DE (1) DE3119306C2 (ko)
DK (1) DK203681A (ko)
EG (1) EG15388A (ko)
ES (1) ES502752A0 (ko)
FI (1) FI75142C (ko)
FR (1) FR2482584A1 (ko)
GB (1) GB2076423B (ko)
GR (1) GR75228B (ko)
IE (1) IE51105B1 (ko)
IN (1) IN155671B (ko)
IT (1) IT1148864B (ko)
LU (1) LU83366A1 (ko)
NL (1) NL8102404A (ko)
NO (1) NO154171C (ko)
NZ (1) NZ196806A (ko)
PH (1) PH16550A (ko)
PL (1) PL129214B1 (ko)
RO (1) RO82284A (ko)
SE (1) SE451142B (ko)
SU (1) SU1442066A3 (ko)
TR (1) TR20809A (ko)
YU (1) YU121281A (ko)
ZA (1) ZA813274B (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4787915A (en) * 1981-03-24 1988-11-29 Carbon Fuels Corporation Method of varying rheology characteristics of novel coal derived fuel system
IT1169281B (it) * 1981-12-02 1987-05-27 Assoreni & Snamprogetti Spa Sistema catalitico e procedimento per la produzione di miscele di metanolo ed alcoli superiori
FR2529544B1 (fr) * 1982-07-05 1987-11-13 Inst Francais Du Petrole Produit d'alcools a partir de gaz de synthese
US4705532A (en) * 1985-07-15 1987-11-10 The Standard Oil Company Alcohol compositions for blending with gasoline
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
JP2560311B2 (ja) * 1987-02-27 1996-12-04 三菱瓦斯化学株式会社 メタノ−ルないし混合アルコ−ルの製造法
DE3810421A1 (de) * 1988-03-26 1989-10-05 Union Rheinische Braunkohlen Verbessertes verfahren zur katalytischen herstellung eines alkoholgemischs mit erhoehtem isobutanolgehalt
IT1276931B1 (it) * 1995-10-13 1997-11-03 Snam Progetti Procedimento per produrre miscele di metanolo ed alcoli superiori
ATE302257T1 (de) * 1997-10-28 2005-09-15 Univ Kansas Ct For Res Inc Treibstoffmischung für kompressionszündmaschine mit leichten synthetischen roh- und mischbestandteilen
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
GB201808019D0 (en) * 2018-05-17 2018-07-04 Johnson Matthey Davy Technologies Ltd Process for synthesising methanol

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Publication number Priority date Publication date Assignee Title
BE342014A (ko) *
US1791568A (en) * 1923-02-22 1931-02-10 Ig Farbenindustrie Ag Manufacture of oxygenated organic compounds
US1569775A (en) * 1924-09-04 1926-01-12 Basf Ag Synthetic manufacture of methanol
US2010005A (en) * 1932-04-06 1935-08-06 Du Pont Motor fuel
US2281228A (en) * 1939-03-03 1942-04-28 Solvay Process Co Process for synthesizing methanol
DE824038C (de) * 1949-11-10 1951-12-10 Basf Ag Verfahren zur Herstellung von Isobutylalkohol
DE936715C (de) * 1950-12-10 1955-12-22 Linde Eismasch Ag Verfahren zum Reinigen von Gasen durch Tiefkuehlung
DE944186C (de) * 1950-12-22 1956-06-07 Basf Ag Verfahren zur Gewinnung wasserstoffhaltiger Synthesegase
US2964551A (en) * 1957-03-27 1960-12-13 Ici Ltd Production of unsaturated hydrocarbons and methanol
DE1442981A1 (de) * 1963-07-30 1969-01-02 Basf Ag Verfahren zur Herstellung von Wasserstoff
GB1159035A (en) * 1965-08-18 1969-07-23 Ici Ltd Methanol Synthesis.
FR1521405A (fr) * 1966-01-22 1968-04-19 Metallgesellschaft Ag Procédé pour l'élimination partielle de l'anhydride carbonique dans les gaz employés pour la synthèse du méthanol
DE1290123B (de) * 1966-11-11 1969-03-06 Union Rheinische Braunkohlen Verfahren zur kontinuierlichen Reinigung von Methanolsynthesegas
US3950369A (en) * 1968-04-08 1976-04-13 Imperial Chemical Industries Limited Methanol production
US3940428A (en) * 1968-12-30 1976-02-24 Imperial Chemical Industries Limited Methanol production
US3763205A (en) * 1971-05-10 1973-10-02 Du Pont Methanol process with recycle
JPS5243579A (en) * 1975-09-30 1977-04-05 Taishiyou Koruku Kougiyou Kk Method of producing crown stopper
CA1136114A (en) * 1978-05-15 1982-11-23 Harley F. Hardman Preparation of alcohols from synthesis gas
EP0011404B1 (en) * 1978-11-10 1982-12-29 Imperial Chemical Industries Plc Integrated process for synthesis of methanol and of ammonia
DE2904008A1 (de) * 1979-02-02 1980-08-07 Linde Ag Verfahren zur herstellung von rohwasserstoff und methanol

Also Published As

Publication number Publication date
EG15388A (en) 1986-09-30
IE810787L (en) 1981-11-16
PL129214B1 (en) 1984-04-30
AT379580B (de) 1986-01-27
CS224613B2 (en) 1984-01-16
ATA179881A (de) 1985-06-15
ES8204760A1 (es) 1982-04-01
BR8102808A (pt) 1982-02-02
AU7059081A (en) 1981-11-19
PL231186A1 (ko) 1981-12-23
RO82284A (ro) 1983-08-03
TR20809A (tr) 1982-09-16
LU83366A1 (fr) 1982-01-20
GB2076423B (en) 1984-07-04
DD158913A5 (de) 1983-02-09
NO811644L (no) 1981-11-17
NO154171B (no) 1986-04-21
FI811517L (fi) 1981-11-17
NL8102404A (nl) 1981-12-16
DK203681A (da) 1981-11-17
JPH0232312B2 (ko) 1990-07-19
FI75142C (fi) 1988-05-09
FR2482584A1 (fr) 1981-11-20
PH16550A (en) 1983-11-16
KR840001860B1 (ko) 1984-10-23
ZA813274B (en) 1982-05-26
CH648342A5 (it) 1985-03-15
GR75228B (ko) 1984-07-13
US4460378A (en) 1984-07-17
DE3119306C2 (de) 1984-04-19
SE451142B (sv) 1987-09-07
BE888799A (fr) 1981-11-16
AU543346B2 (en) 1985-04-18
CU21284A3 (en) 1985-12-16
IN155671B (ko) 1985-02-23
IT1148864B (it) 1986-12-03
IE51105B1 (en) 1986-10-01
DE3119306A1 (de) 1982-03-04
JPS5710690A (en) 1982-01-20
CA1159256A (en) 1983-12-27
YU121281A (en) 1983-04-30
NZ196806A (en) 1984-03-16
SE8103073L (sv) 1981-11-17
SU1442066A3 (ru) 1988-11-30
RO82284B (ro) 1983-07-30
GB2076423A (en) 1981-12-02
ES502752A0 (es) 1982-04-01
FI75142B (fi) 1988-01-29
FR2482584B1 (ko) 1984-05-04
NO154171C (no) 1986-07-30
IT8022117A0 (it) 1980-05-16

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