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AR126717A1 - Método para producir aldehídos grasos y derivados de los mismos - Google Patents

Método para producir aldehídos grasos y derivados de los mismos

Info

Publication number
AR126717A1
AR126717A1 ARP220102108A ARP220102108A AR126717A1 AR 126717 A1 AR126717 A1 AR 126717A1 AR P220102108 A ARP220102108 A AR P220102108A AR P220102108 A ARP220102108 A AR P220102108A AR 126717 A1 AR126717 A1 AR 126717A1
Authority
AR
Argentina
Prior art keywords
fatty
weight
alcohol
reaction mixture
aldehyde
Prior art date
Application number
ARP220102108A
Other languages
English (en)
Inventor
Anders Gabrielsson
Andrea Mazziotta
Original Assignee
Biophero Aps
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biophero Aps filed Critical Biophero Aps
Publication of AR126717A1 publication Critical patent/AR126717A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/76—Dehydrogenation
    • B01J2231/763—Dehydrogenation of -CH-XH (X= O, NH/N, S) to -C=X or -CX triple bond species
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/004—Ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un método para convertir alcoholes en aldehídos, en particular alcoholes grasos, en aldehídos grasos, donde dicho método utiliza un catalizador, y el método es capaz de proveer una alta conversión de dicho alcohol, por ejemplo a gran escala, donde en la reacción y la purificación se utiliza una cantidad relativamente pequeña de solvente, y donde la purificación es capaz de eliminar el catalizador del producto aldehído. Reivindicación 1: Un método para la conversión a gran escala de un alcohol graso en un aldehído graso, caracterizado porque dicho método comprende los siguientes pasos: a) proveer una mezcla de reacción que comprende por lo menos 1 kilogramo de alcohol graso, un catalizador que comprende una fuente de cobre, por lo menos 1 kilogramo de solvente y un material que absorbe o adsorbe agua, y b) disolver por lo menos 0,01 mmol de O₂ por minuto por μmol de cobre en la mezcla de reacción o por lo menos 0,001 mmol de O₂ por minuto por μmol (cantidad inicial) de alcohol graso en la mezcla de reacción a la mezcla de reacción alimentando un gas o un líquido que comprende O₂ al medio de reacción para oxidar de esa manera más del 50% en peso del alcohol graso a aldehído graso y menos del 50% en peso a ácido graso. Reivindicación 25: Una composición caracterizada porque comprende más del 93% en peso de aldehído graso, menos del 7% en peso de alcohol graso y menos del 2% en peso de agua.
ARP220102108A 2021-08-06 2022-08-05 Método para producir aldehídos grasos y derivados de los mismos AR126717A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21190097 2021-08-06
EP22161123 2022-03-09

Publications (1)

Publication Number Publication Date
AR126717A1 true AR126717A1 (es) 2023-11-08

Family

ID=83113041

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP220102108A AR126717A1 (es) 2021-08-06 2022-08-05 Método para producir aldehídos grasos y derivados de los mismos

Country Status (12)

Country Link
US (1) US20240327324A1 (es)
EP (1) EP4380916A1 (es)
JP (1) JP2024537933A (es)
KR (1) KR20240042428A (es)
AR (1) AR126717A1 (es)
AU (1) AU2022321753A1 (es)
CA (1) CA3225388A1 (es)
CL (1) CL2024000256A1 (es)
IL (1) IL309880A (es)
MX (1) MX2024001309A (es)
TW (1) TW202313546A (es)
WO (1) WO2023012151A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025027140A1 (en) 2023-08-02 2025-02-06 FMC Agricultural Solutions A/S N-alkoxyamine marker and processes

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5155280A (en) 1991-09-30 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
ES2789823T3 (es) 2015-06-26 2020-10-26 Univ Danmarks Tekniske Procedimiento de producción de feromonas de polilla en levadura
EP3555268B1 (en) 2016-12-16 2021-05-26 Danmarks Tekniske Universitet Methods for producing fatty alcohols and derivatives thereof in yeast
WO2018109167A1 (en) 2016-12-16 2018-06-21 Danmarks Tekniske Universitet Production of desaturated fatty alcohols and desaturated fatty acyl acetates in yeast
US20230332096A1 (en) 2019-02-19 2023-10-19 Biophero Aps Methods and cell factories for producing insect pheromones
BR112022006218A2 (pt) 2019-10-22 2022-06-28 Biophero Aps Método para produzir um composto hidrofóbico, para aumentar o título de um composto hidrofóbico, para aumentar a secreção de um composto hidrofóbico e para monitorar a presença de praga ou romper a reprodução de praga, e, composto hidrofóbico
CN115103900A (zh) 2019-12-20 2022-09-23 费罗生物公司 产生e8,e10-十二碳二烯基辅酶a、可得蒙及其衍生物的酵母细胞和方法

Also Published As

Publication number Publication date
EP4380916A1 (en) 2024-06-12
CA3225388A1 (en) 2023-02-09
MX2024001309A (es) 2024-05-17
US20240327324A1 (en) 2024-10-03
KR20240042428A (ko) 2024-04-02
WO2023012151A1 (en) 2023-02-09
TW202313546A (zh) 2023-04-01
AU2022321753A1 (en) 2024-01-25
IL309880A (en) 2024-03-01
JP2024537933A (ja) 2024-10-17
CL2024000256A1 (es) 2024-06-07

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