AR012836A1 - Compuesto de 4-(3-heterociclil-1-benzoil)-pirazoles, procedimiento para prepararlos, agentes herbicidas que los contienen, procedimiento para preparar dichos agentes, procedimiento para combatir vegetacion no deseada con dichos compuestos y la utilizacion de los mismos como herbicidas - Google Patents
Compuesto de 4-(3-heterociclil-1-benzoil)-pirazoles, procedimiento para prepararlos, agentes herbicidas que los contienen, procedimiento para preparar dichos agentes, procedimiento para combatir vegetacion no deseada con dichos compuestos y la utilizacion de los mismos como herbicidasInfo
- Publication number
- AR012836A1 AR012836A1 ARP980100214A ARP980100214A AR012836A1 AR 012836 A1 AR012836 A1 AR 012836A1 AR P980100214 A ARP980100214 A AR P980100214A AR P980100214 A ARP980100214 A AR P980100214A AR 012836 A1 AR012836 A1 AR 012836A1
- Authority
- AR
- Argentina
- Prior art keywords
- procedure
- prepare
- agents
- pyrazoles
- alkylsulfonyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000003795 chemical substances by application Substances 0.000 title abstract 3
- 239000002131 composite material Substances 0.000 title 2
- 239000004009 herbicide Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- -1 halogenalkylalkoxy Chemical group 0.000 abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- NOIXNOMHHWGUTG-UHFFFAOYSA-N 2-[[4-[4-pyridin-4-yl-1-(2,2,2-trifluoroethyl)pyrazol-3-yl]phenoxy]methyl]quinoline Chemical group C=1C=C(OCC=2N=C3C=CC=CC3=CC=2)C=CC=1C1=NN(CC(F)(F)F)C=C1C1=CC=NC=C1 NOIXNOMHHWGUTG-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000004471 alkyl aminosulfonyl group Chemical group 0.000 abstract 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000003217 pyrazoles Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D419/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen, oxygen, and sulfur atoms as the only ring hetero atoms
- C07D419/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen, oxygen, and sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D419/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen, oxygen, and sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/04—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/20—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings condensed with carbocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
La presente invencion se refiere a los compuestos 4-(3-heterociclil-1- benzoil)-pirazoles, con actividad herbicida de la formula (I), donde lasvariables tienen los siguientes significados: R1, R3 es hidrogeno, nitro, halogeno, ciano,alqui lo, halogenalquilalcoxi, halogenalcoxi, alquiltio,halogenalquiltio, alquilsulfinilo, halogenalquilsulfinilo, alquilsulfonilo, halogenalquilsulfonilo, aminosulfonilo, alquilaminosulfonilo, N, N-dialquilaminosulfonilo, N-alquilsulfonil-amino, N-hal ogenalquilsulfonilamino, N-alquil-N-alquilsulfonilamino o N-alquil-N-halogenalquilsulfonilamino; R2es un radical heterociclilo de 5 o 6 miembros eventualmente sustituido, que contiene de uno a cuatro heteroátomos iguales odiferentes, s eleccionados delsiguiente grupo: oxígeno, azufre o nitrogeno; R4 es hidrogeno, halogeno o alquilo; R5 es un pirazol sustituido, enlazado en la posicion 4; así comolas sales de los mismos de utilizacion en agricultura;procedimientos y p roductos intermedios para preparar los 4-(3-heterociclil-1-benzoil)pirazoles;agentes que los contienen, así como aplicacion de estos derivados o de los agentes que los contienen para combatir las plantas daninas.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19701446 | 1997-01-17 | ||
| DE19740494 | 1997-09-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR012836A1 true AR012836A1 (es) | 2000-11-22 |
Family
ID=26033168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP980100214A AR012836A1 (es) | 1997-01-17 | 1998-01-16 | Compuesto de 4-(3-heterociclil-1-benzoil)-pirazoles, procedimiento para prepararlos, agentes herbicidas que los contienen, procedimiento para preparar dichos agentes, procedimiento para combatir vegetacion no deseada con dichos compuestos y la utilizacion de los mismos como herbicidas |
Country Status (31)
| Country | Link |
|---|---|
| US (1) | US6165944A (es) |
| EP (1) | EP0958292B1 (es) |
| JP (1) | JP4259620B2 (es) |
| KR (2) | KR100571463B1 (es) |
| CN (1) | CN1104429C (es) |
| AR (1) | AR012836A1 (es) |
| AT (1) | ATE350380T1 (es) |
| AU (1) | AU742514B2 (es) |
| BG (1) | BG64389B1 (es) |
| BR (1) | BR9806917B1 (es) |
| CA (1) | CA2277893C (es) |
| CZ (1) | CZ298050B6 (es) |
| DE (1) | DE59813869D1 (es) |
| DK (1) | DK0958292T3 (es) |
| EA (1) | EA009338B1 (es) |
| EE (1) | EE05291B1 (es) |
| ES (1) | ES2279569T3 (es) |
| GE (1) | GEP20022765B (es) |
| HU (1) | HU226012B1 (es) |
| IL (1) | IL130778A0 (es) |
| MX (1) | MX209959B (es) |
| NO (1) | NO314728B1 (es) |
| NZ (1) | NZ336640A (es) |
| PL (1) | PL195943B1 (es) |
| PT (1) | PT958292E (es) |
| SI (1) | SI0958292T1 (es) |
| SK (1) | SK286364B6 (es) |
| TR (1) | TR199901665T2 (es) |
| TW (1) | TW513414B (es) |
| UA (1) | UA60325C2 (es) |
| WO (1) | WO1998031682A1 (es) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4131337B2 (ja) * | 1996-03-26 | 2008-08-13 | 日本曹達株式会社 | ３―（イソオキサゾール―５―イル）置換安息香酸誘導体およびその製造法 |
| EA006633B1 (ru) * | 1997-01-17 | 2006-02-24 | Басф Акциенгезельшафт | Замещенные 3-гетероциклилом производные бензоила |
| AU9647998A (en) * | 1997-10-27 | 1999-05-17 | Nippon Soda Co., Ltd. | Novel benzoylpyrazole derivatives and herbicides |
| WO1999023094A1 (en) * | 1997-10-30 | 1999-05-14 | Nippon Soda Co., Ltd. | Novel benzoylpyrazole compounds, intermediates, and herbicides |
| KR100604302B1 (ko) | 1998-05-11 | 2006-07-28 | 바스프 악티엔게젤샤프트 | 이소옥사졸린-3-일-아실벤젠의 제조 방법 |
| DE19846792A1 (de) * | 1998-10-10 | 2000-04-13 | Hoechst Schering Agrevo Gmbh | Benzoylcyclohexandione, Verfahren zur ihrer Herstellung und ihre Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| ES2188278T3 (es) * | 1998-12-04 | 2003-06-16 | Basf Ag | Derivados de 3-(heterociclil)-benzoilpirazol. |
| IL143449A0 (en) | 1998-12-04 | 2002-04-21 | Basf Ag | 3-(heterocyclyl)-substituted benzoylpyrazols |
| DE19914140A1 (de) | 1999-03-27 | 2000-09-28 | Bayer Ag | Substituierte Benzoylpyrazole |
| WO2000058290A1 (en) | 1999-03-29 | 2000-10-05 | Nippon Soda Co., Ltd. | Process for the preparation of (e)-3-(1-propenyl)isoxazoline |
| AU4296700A (en) | 1999-04-27 | 2000-11-10 | Basf Aktiengesellschaft | Phosphoric benzoyl derivatives and their use as herbicides |
| AR024845A1 (es) | 1999-08-06 | 2002-10-30 | Basf Ag | Derivados de 1-cicloalquilpirazolil-benzoilo y sus sales, procedimiento para obtener dichos derivados, las composiciones herbicidas que los contienen y supreparacion, el procedimiento para controlar el crecimiento de plantas indeseadas con dichos derivados y el uso de dichos derivados como herbicida |
| DE19946853A1 (de) | 1999-09-30 | 2001-04-05 | Bayer Ag | Substituierte Arylketone |
| JP2003515606A (ja) * | 1999-12-02 | 2003-05-07 | ビーエーエスエフ アクチェンゲゼルシャフト | ３−（４，５−ジヒドロイソオキサゾール−３−イル）−置換ベンゾイルピラゾール |
| PL357366A1 (en) * | 1999-12-02 | 2004-07-26 | Basf Aktiengesellschaft | Cyclopropyl-anellated 3-(4,5-dihydroisoxazol-3-yl)-substituted benzoylpyrazoles as herbicides |
| KR100707330B1 (ko) * | 1999-12-22 | 2007-04-16 | 바스프 악티엔게젤샤프트 | 3-(4,5-디히드로이속사졸-5-일)벤조일피라졸 |
| JP2004504266A (ja) * | 2000-01-17 | 2004-02-12 | バイエル アクチェンゲゼルシャフト | 置換アリールケトン類 |
| AR032779A1 (es) * | 2000-12-11 | 2003-11-26 | Basf Ag | Derivados de ciclohexenona de benzazolonas, acidos benzazolonacarboxilicos, agentes que contienen por lo menos un derivado de ciclohexenona, procedimiento para combatir el crecimiento indeseado de plantas y uso de dichos derivados como herbicidas |
| BRPI0209099B8 (pt) * | 2001-04-27 | 2018-08-14 | Syngenta Participations Ag | composição seletivamente herbicida e método para controlar o desenvolvimento de plantas indesejadas em colheitas de plantas úteis. |
| PL365734A1 (en) * | 2001-05-09 | 2005-01-10 | Bayer Cropscience Ag | Substituted arylketones |
| DE10136449A1 (de) * | 2001-05-09 | 2002-11-14 | Bayer Ag | Substituierte Arylketone |
| DE10138577A1 (de) * | 2001-05-21 | 2002-11-28 | Bayer Ag | Substituierte Benzoylpyrazole |
| DE10142336A1 (de) * | 2001-08-30 | 2003-03-20 | Bayer Cropscience Ag | Selektive Herbizide enthaltend ein Tetrazolinon-Derivat |
| DE10142333A1 (de) * | 2001-08-30 | 2003-03-20 | Bayer Cropscience Ag | Herbizide Mischungen auf Basis von substituierten Arylketonen |
| WO2003022800A1 (de) * | 2001-09-11 | 2003-03-20 | Bayer Cropscience Gmbh | Verfahren zur herstellung von 3-brommethylbenzoesäuren |
| DE10159659A1 (de) * | 2001-12-05 | 2003-06-26 | Bayer Cropscience Ag | Herbizide auf Basis von substituierten Carbonsäureaniliden |
| DE10209645A1 (de) * | 2002-03-05 | 2003-09-18 | Bayer Cropscience Ag | Substituierte Arylketone |
| AU2003250132A1 (en) * | 2002-07-23 | 2004-02-09 | Basf Aktiengesellschaft | Synergistically acting herbicidal mixtures |
| US20060009358A1 (en) * | 2002-07-24 | 2006-01-12 | Elmar Kibler | Synergistically acting herbicidal mixtures |
| UA94003C2 (uk) * | 2006-11-28 | 2011-03-25 | Ишихара Санджай Кайша, Лтд. | Сполуки бензоїлпіразолу, гербіцид на їх основі та спосіб боротьби з небажаними рослинами |
| MX2010005231A (es) * | 2007-11-12 | 2010-05-27 | Du Pont | Mezcla herbicida. |
| WO2011067184A1 (de) | 2009-12-01 | 2011-06-09 | Basf Se | 3- (4, 5 -dihydroisoxazol- 5 -yl) benzoylpyrazolverbindungen und ihre mischungen mit safenern |
| DK2921491T3 (da) * | 2011-12-27 | 2017-11-27 | Bayer Ip Gmbh | Mellemforbindelser til fremstilling af heteroarylpiperidiner og ¿piperazinderivater som fungicider |
| CN105503728B (zh) | 2015-12-31 | 2017-03-22 | 青岛清原化合物有限公司 | 吡唑类化合物或其盐、制备方法、除草剂组合物及用途 |
| CN105399674B (zh) | 2015-12-31 | 2017-02-15 | 青岛清原化合物有限公司 | 吡唑类化合物或其盐、制备方法、除草剂组合物及用途 |
| CN107629046B (zh) * | 2017-10-24 | 2021-07-06 | 青岛清原化合物有限公司 | 吡唑酮类化合物或其盐、除草剂组合物及用途 |
| WO2020114212A1 (zh) * | 2018-12-07 | 2020-06-11 | 青岛清原化合物有限公司 | 4-(3-杂环基-1-苯甲酰基)吡唑类化合物或其盐、制备方法、除草剂组合物及用途 |
| CN112624974B (zh) * | 2019-10-08 | 2024-01-30 | 沈阳中化农药化工研发有限公司 | 一种肉桂羧酸酯类化合物及其应用 |
| AU2020363069B2 (en) * | 2019-10-08 | 2024-02-15 | Jiangsu Yangnong Chemical Co., Ltd. | Alkene-containing carboxylate compound and use thereof |
| CN116120234B (zh) * | 2021-11-15 | 2024-12-17 | 沈阳中化农药化工研发有限公司 | 一种苯甲酰吡唑类化合物及其应用 |
| CN117486870B (zh) * | 2023-11-03 | 2024-05-24 | 山东德浩化学有限公司 | 苯唑草酮衍生物及其用途 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58185568A (ja) * | 1982-04-24 | 1983-10-29 | Nissan Chem Ind Ltd | ピラゾ−ル誘導体，その製造方法および該誘導体を含有する選択性除草剤 |
| JPS58206568A (ja) * | 1982-05-25 | 1983-12-01 | Sankyo Co Ltd | ピラゾ−ル誘導体及び除草剤 |
| US4744815A (en) * | 1985-05-11 | 1988-05-17 | Nissan Chemical Industries, Ltd. | 4-benzoyl-1-alkyl (alkenyl) - pyrazoles, composition containing them, herbicidal method of using them, and intermediate in their preparation |
| IL85659A (en) * | 1987-03-17 | 1992-03-29 | Nissan Chemical Ind Ltd | 4-benzoylpyrazole derivatives,method for their preparation and herbicidal compositions containing them |
| US5846907A (en) * | 1995-02-24 | 1998-12-08 | Basf Aktiengesellschaft | Herbicidally active pyrazol-4-ylbenzoyl compounds |
| CN1216534A (zh) * | 1996-04-26 | 1999-05-12 | 日本曹达株式会社 | 杂环取代的新颖苯衍生物和除草剂 |
| CA2257196A1 (en) * | 1996-06-06 | 1997-12-11 | Morris Padgett Rorer | Herbicidal pyridinyl and pyrazolylphenyl ketones |
-
1997
- 1997-01-08 US US09/091,292 patent/US6165944A/en not_active Expired - Fee Related
-
1998
- 1998-01-08 BR BRPI9806917-9A patent/BR9806917B1/pt not_active IP Right Cessation
- 1998-01-08 TR TR1999/01665T patent/TR199901665T2/xx unknown
- 1998-01-08 CZ CZ0252299A patent/CZ298050B6/cs not_active IP Right Cessation
- 1998-01-08 EA EA199900619A patent/EA009338B1/ru not_active IP Right Cessation
- 1998-01-08 PT PT98907930T patent/PT958292E/pt unknown
- 1998-01-08 AT AT98907930T patent/ATE350380T1/de not_active IP Right Cessation
- 1998-01-08 DK DK98907930T patent/DK0958292T3/da active
- 1998-01-08 CN CN98802992A patent/CN1104429C/zh not_active Expired - Fee Related
- 1998-01-08 DE DE59813869T patent/DE59813869D1/de not_active Expired - Lifetime
- 1998-01-08 CA CA002277893A patent/CA2277893C/en not_active Expired - Fee Related
- 1998-01-08 KR KR19997006464A patent/KR100571463B1/ko not_active Expired - Fee Related
- 1998-01-08 SK SK919-99A patent/SK286364B6/sk not_active IP Right Cessation
- 1998-01-08 GE GEAP19984962A patent/GEP20022765B/en unknown
- 1998-01-08 EE EEP199900292A patent/EE05291B1/xx not_active IP Right Cessation
- 1998-01-08 JP JP53362198A patent/JP4259620B2/ja not_active Expired - Fee Related
- 1998-01-08 MX MX9906600A patent/MX209959B/es not_active IP Right Cessation
- 1998-01-08 HU HU0002178A patent/HU226012B1/hu not_active IP Right Cessation
- 1998-01-08 IL IL13077898A patent/IL130778A0/xx unknown
- 1998-01-08 WO PCT/EP1998/000070 patent/WO1998031682A1/de not_active Ceased
- 1998-01-08 KR KR1020067003690A patent/KR20060025610A/ko not_active Ceased
- 1998-01-08 ES ES98907930T patent/ES2279569T3/es not_active Expired - Lifetime
- 1998-01-08 AU AU66133/98A patent/AU742514B2/en not_active Ceased
- 1998-01-08 SI SI9830875T patent/SI0958292T1/sl unknown
- 1998-01-08 PL PL98334849A patent/PL195943B1/pl not_active IP Right Cessation
- 1998-01-08 EP EP98907930A patent/EP0958292B1/de not_active Expired - Lifetime
- 1998-01-08 NZ NZ336640A patent/NZ336640A/xx unknown
- 1998-01-15 TW TW087100464A patent/TW513414B/zh not_active IP Right Cessation
- 1998-01-16 AR ARP980100214A patent/AR012836A1/es active IP Right Grant
- 1998-08-01 UA UA99084709A patent/UA60325C2/uk unknown
-
1999
- 1999-07-16 NO NO19993522A patent/NO314728B1/no not_active IP Right Cessation
- 1999-08-13 BG BG103663A patent/BG64389B1/bg unknown
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