AR007272A1 - Proceso para la polimerizacion de olefinas y para reducir el indice de polidispersidad de un polimero olefinico - Google Patents
Proceso para la polimerizacion de olefinas y para reducir el indice de polidispersidad de un polimero olefinicoInfo
- Publication number
- AR007272A1 AR007272A1 ARP970102204A ARP970102204A AR007272A1 AR 007272 A1 AR007272 A1 AR 007272A1 AR P970102204 A ARP970102204 A AR P970102204A AR P970102204 A ARP970102204 A AR P970102204A AR 007272 A1 AR007272 A1 AR 007272A1
- Authority
- AR
- Argentina
- Prior art keywords
- polymerization
- olefins
- polydispersity index
- phase
- reduce
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000012071 phase Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000011951 cationic catalyst Substances 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00065—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/0013—Controlling the temperature by direct heating or cooling by condensation of reactants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Se relaciona con un proceso para la producción de un polímero olefínico de bajo índice de polidispersidad en una polimerización en solución realizadaen presencia de un catalizador catiónico en un reactor que contiene una fase de hidrocarburol íquido hirviendo y un espacio de vapor por encima de dichafase. La polimerización se efectua en presencia de un agente no mecánico capaz de suprimir la formación de espuma durante dicha polimerización. Elagente puede ser elegido entre (a)una pulverización de hidrocarburo líquido introducida en el espacio de vapor del reactor; (b) una alimentación líquida deolefina u olefinas nuevas a una temperatura menor que la temperatura de la fase líquida y (c) un supresor químico de laespum a, por ejemplo, unpolioxialquilenglicol o una silicona.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9606691A FR2749015B1 (fr) | 1996-05-24 | 1996-05-24 | Procede de polymerisation d'olefine(s) |
| FR9606690A FR2749014B1 (fr) | 1996-05-24 | 1996-05-24 | Procede de polymerisation d'olefine(s) |
| FR9606692A FR2749016B1 (fr) | 1996-05-24 | 1996-05-24 | Procede de polymerisation d'olefine(s) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR007272A1 true AR007272A1 (es) | 1999-10-27 |
Family
ID=27253188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970102204A AR007272A1 (es) | 1996-05-24 | 1997-05-23 | Proceso para la polimerizacion de olefinas y para reducir el indice de polidispersidad de un polimero olefinico |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6187881B1 (es) |
| EP (1) | EP0902798B1 (es) |
| JP (2) | JP4128220B2 (es) |
| CN (1) | CN1123582C (es) |
| AR (1) | AR007272A1 (es) |
| BR (1) | BR9709266A (es) |
| DE (1) | DE69703973T2 (es) |
| ID (1) | ID16964A (es) |
| MY (1) | MY118041A (es) |
| WO (1) | WO1997045462A1 (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7601255B2 (en) * | 2006-09-06 | 2009-10-13 | Chemtura Corporation | Process for removal of residual catalyst components |
| EP2311554A1 (en) * | 2009-10-07 | 2011-04-20 | Linde Aktiengesellschaft | Method for reaction control of exothermic reaction and apparatus therefore |
| ES2672893T3 (es) * | 2010-01-14 | 2018-06-18 | Exxonmobil Chemical Patents Inc. | Procesos y aparato para polimerización continua en disolución |
| CA2809718C (en) * | 2013-03-15 | 2020-03-24 | Nova Chemicals Corporation | Improved energy utilization in a solution polymerization plant |
| CN103641939A (zh) * | 2013-11-27 | 2014-03-19 | 河北科技大学 | 一种聚异丁烯的制备系统和制备方法 |
| RU2659395C9 (ru) * | 2015-06-15 | 2018-08-30 | Базелл Полиолефин Гмбх | Установка полимеризации с параллельными охлаждающими каналами и рециркуляционной схемой соединения |
| CN105879798A (zh) * | 2016-05-23 | 2016-08-24 | 张�浩 | 一种气液闪速反应的工艺 |
| KR102581118B1 (ko) * | 2019-12-09 | 2023-09-20 | 주식회사 엘지화학 | 올리고머 제조 장치 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2443229A (en) * | 1945-07-13 | 1948-06-15 | Standard Oil Dev Co | Extraction of methyl chloride from hydrocarbons |
| US2479418A (en) * | 1946-06-22 | 1949-08-16 | Standard Oil Dev Co | Olefin dimers as promoters in lowtemperature friedel-crafts polymerization |
| US2529318A (en) * | 1946-10-08 | 1950-11-07 | Standard Oil Dev Co | Low-temperature polymerization at the freezing point of the polymerizate material |
| BE591963A (es) * | 1958-09-19 | |||
| GB884116A (en) * | 1960-09-30 | 1961-12-06 | Shell Res Ltd | Improvements in or relating to the manufacture of polyolefins |
| US3259614A (en) * | 1961-08-07 | 1966-07-05 | Phillips Petroleum Co | Polymerization process and control system |
| JPS5410590B1 (es) * | 1970-04-18 | 1979-05-08 | ||
| ZA75737B (en) * | 1974-02-05 | 1976-01-28 | Michelin & Cie | Bulk polymerization using an organosilo xane anti-foam compound |
| US4058652A (en) * | 1976-02-10 | 1977-11-15 | Exxon Research & Engineering Co. | Autorefrigeration process and apparatus |
| US4220580A (en) * | 1978-07-24 | 1980-09-02 | Gulf Oil Corporation | Bingham fluid compositions |
| US4222986A (en) * | 1979-01-09 | 1980-09-16 | Exxon Research & Engineering Co. | Autorefrigeration polymerization apparatus |
| JPS56110701A (en) * | 1980-02-07 | 1981-09-02 | Sumitomo Chem Co Ltd | Method and apparatus for removal of heat from polymerizer |
| US4400493A (en) * | 1982-04-07 | 1983-08-23 | Cosden Technology, Inc. | Polymerization of isobutylene |
| CA1221197A (en) * | 1983-02-04 | 1987-04-28 | Charles A. Trischman | Linear low density polyethylene process |
| JPH02180908A (ja) * | 1989-01-05 | 1990-07-13 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| EP0558595A4 (en) * | 1990-11-08 | 1993-11-03 | The Dow Chemical Company | Reactor with foam shearing means for solution polymerization process |
| DE4231748A1 (de) * | 1992-09-23 | 1994-03-24 | Basf Ag | Verfahren zur Reaktionsregelung bei der Herstellung von Polyisobutylen |
| DE4426756A1 (de) * | 1994-07-28 | 1996-02-01 | Bayer Ag | Verfahren zur Herstellung von C¶4¶-C¶1¶¶6¶-Alkylkautschuken nach dem Slurry-Verfahren |
-
1997
- 1997-05-22 CN CN97196538A patent/CN1123582C/zh not_active Expired - Fee Related
- 1997-05-22 BR BR9709266A patent/BR9709266A/pt not_active IP Right Cessation
- 1997-05-22 DE DE69703973T patent/DE69703973T2/de not_active Expired - Fee Related
- 1997-05-22 JP JP54182297A patent/JP4128220B2/ja not_active Expired - Fee Related
- 1997-05-22 WO PCT/GB1997/001404 patent/WO1997045462A1/en not_active Ceased
- 1997-05-22 EP EP97923235A patent/EP0902798B1/en not_active Expired - Lifetime
- 1997-05-23 AR ARP970102204A patent/AR007272A1/es active IP Right Grant
- 1997-05-23 MY MYPI97002252A patent/MY118041A/en unknown
- 1997-05-23 ID IDP971719A patent/ID16964A/id unknown
-
1998
- 1998-11-24 US US09/198,504 patent/US6187881B1/en not_active Expired - Fee Related
-
2006
- 2006-03-13 JP JP2006068433A patent/JP2006152314A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69703973D1 (de) | 2001-03-01 |
| ID16964A (id) | 1997-11-27 |
| CN1123582C (zh) | 2003-10-08 |
| WO1997045462A1 (en) | 1997-12-04 |
| CN1225650A (zh) | 1999-08-11 |
| DE69703973T2 (de) | 2001-05-10 |
| EP0902798A1 (en) | 1999-03-24 |
| JP4128220B2 (ja) | 2008-07-30 |
| EP0902798B1 (en) | 2001-01-24 |
| JP2000510901A (ja) | 2000-08-22 |
| MY118041A (en) | 2004-08-30 |
| BR9709266A (pt) | 1999-08-10 |
| US6187881B1 (en) | 2001-02-13 |
| JP2006152314A (ja) | 2006-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |