AR004986A1 - Materiales organicos transparentes o fotocromaticos, procedimiento para preparar dichos materiales y articulos que los contienen. - Google Patents
Materiales organicos transparentes o fotocromaticos, procedimiento para preparar dichos materiales y articulos que los contienen.Info
- Publication number
- AR004986A1 AR004986A1 ARP960105482A ARP960105482A AR004986A1 AR 004986 A1 AR004986 A1 AR 004986A1 AR P960105482 A ARP960105482 A AR P960105482A AR P960105482 A ARP960105482 A AR P960105482A AR 004986 A1 AR004986 A1 AR 004986A1
- Authority
- AR
- Argentina
- Prior art keywords
- weight
- photochromic
- monomer represented
- general formula
- materials
- Prior art date
Links
- 239000000463 material Substances 0.000 title abstract 5
- 239000011368 organic material Substances 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 4
- 241000220304 Prunus dulcis Species 0.000 abstract 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 235000020224 almond Nutrition 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/23—Photochromic filters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/062—Polyethers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Eyeglasses (AREA)
- Materials For Medical Uses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
La invencion se refiere a materiales organicos transparentes, fotocromaticos o no fotocromaticos, que presentan un indice de refraccion mayora 1,55, consistiendo el material esencialmente en un copolimero de: a) 50-90% en peso de alm enos un monomero representado por la formula general (I), en queR = H o CH3; y m y n son independientemente 1 o 2; b) 10-30% en peso de al menos un monomero monovinilico aromatico representado por la formula general(II); c)1-20% en peso de alme nos un monomero (met)acrilico representado por la formula general (IV): CH2 0 C(R) - COOR1, en que R = H o CH3; R1 es un radicalalquilo C4 a C16 lineal o ramificado, o un grupo polietoxilado con la formula -(CH2-CH2 O)n R11, en que n = 1 a 10 yR11 = CH3 o C2H5. Opcionalmente, elmaterial fotocromatico puede contener hasta un 10% de peso de al menos un agente colorante fotocromatico para comunicarle las propiedades fotocromaticasdeseadas. El material, que puede asimismo contener hastaun 15% en peso de un monomero divinilico aromatico representado por la formula (III), en que R1 = Ho CH3, puede ser polimerizado en presencia de hasta un 0,5% en peso de al menos un iniciador de reaccion de polimerizacion radical no peroxido. Elmater ialorganico resulta particularmente util para la elaboracion de lentes oftalmicas y vidrios para objetos tales como vehiculos y edificios.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9514343A FR2741959B1 (fr) | 1995-12-05 | 1995-12-05 | Nouveaux verres organiques, photochromiques ou non, de qualite optique, leur preparation et articles formes a partir de ces verres |
| US1142996P | 1996-02-08 | 1996-02-08 | |
| US2333096P | 1996-07-31 | 1996-07-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR004986A1 true AR004986A1 (es) | 1999-04-07 |
Family
ID=27253125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP960105482A AR004986A1 (es) | 1995-12-05 | 1996-12-04 | Materiales organicos transparentes o fotocromaticos, procedimiento para preparar dichos materiales y articulos que los contienen. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6221284B1 (es) |
| EP (1) | EP0866987B1 (es) |
| CN (1) | CN1203672A (es) |
| AR (1) | AR004986A1 (es) |
| AU (1) | AU1057397A (es) |
| DE (1) | DE69624131T2 (es) |
| ES (1) | ES2184899T3 (es) |
| MX (1) | MX9804484A (es) |
| WO (1) | WO1997021122A1 (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2783829B1 (fr) * | 1998-09-29 | 2005-12-09 | Corning Sa | Preparation de pieces organiques de qualite optique et notamment de lentilles organiques |
| AU769249B2 (en) | 1999-07-02 | 2004-01-22 | Ppg Industries Ohio, Inc. | Poly(meth)acrylic photochromic coating |
| US6863844B2 (en) * | 2002-08-30 | 2005-03-08 | Signet Armorlite, Inc. | Photochromic matrix compositions for use in ophthalmic lenses |
| US6863848B2 (en) | 2002-08-30 | 2005-03-08 | Signet Armorlite, Inc. | Methods for preparing composite photochromic ophthalmic lenses |
| US7009032B2 (en) | 2002-12-20 | 2006-03-07 | Ppg Industries Ohio, Inc. | Sulfide-containing polythiols |
| US7488510B2 (en) * | 2003-10-28 | 2009-02-10 | Signet Armorlite, Inc. | Compositions and methods for the preparation of composite photochromic polycarbonate lenses |
| US11591436B2 (en) | 2004-09-01 | 2023-02-28 | Ppg Industries Ohio, Inc. | Polyurethane article and methods of making the same |
| US20090280329A1 (en) | 2004-09-01 | 2009-11-12 | Ppg Industries Ohio, Inc. | Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same |
| US9598527B2 (en) | 2004-09-01 | 2017-03-21 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US20090280709A1 (en) | 2004-09-01 | 2009-11-12 | Ppg Industries Ohio, Inc. | Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same |
| US11008418B2 (en) | 2004-09-01 | 2021-05-18 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US11248083B2 (en) | 2004-09-01 | 2022-02-15 | Ppg Industries Ohio, Inc. | Aircraft windows |
| US11149107B2 (en) | 2004-09-01 | 2021-10-19 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US9464169B2 (en) | 2004-09-01 | 2016-10-11 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| KR20070027293A (ko) * | 2005-09-06 | 2007-03-09 | 주식회사 엘지화학 | 광변색 필름 또는 판 제조방법 |
| KR101029908B1 (ko) | 2006-05-05 | 2011-04-18 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 싸이오에터 작용성 올리고머성 폴리싸이올로부터 제조된 조성물 및 제품 |
| WO2009051370A2 (en) * | 2007-10-18 | 2009-04-23 | Lg Chem, Ltd. | Uv curable photochromic composition and products formed by using the same |
| KR101007100B1 (ko) * | 2007-11-01 | 2011-01-10 | 주식회사 엘지화학 | 광변색성 조성물 및 광변색성 필름 |
| US8188181B2 (en) * | 2009-09-22 | 2012-05-29 | Corning Incorporated | Photochromic compositions, resins and articles obtained therefrom |
| CN106188076B (zh) * | 2016-07-26 | 2018-03-30 | 湖南科技大学 | 一种光致变色链转移剂的制备方法和应用 |
| EP3890534B1 (en) * | 2018-12-06 | 2023-10-18 | Puma Se | Method for monitoring or visualizing the running speed of an athlete and athletic garment |
| US20210284778A1 (en) | 2020-03-11 | 2021-09-16 | Alcon Inc. | Photochromic polydiorganosiloxane vinylic crosslinkers |
| EP4158392A1 (en) | 2020-06-02 | 2023-04-05 | Alcon Inc. | Method for making photochromic contact lenses |
| HUE069854T2 (hu) | 2020-10-28 | 2025-04-28 | Alcon Inc | Eljárás fotokróm kontaktlencsék elõállítására |
| WO2022097049A1 (en) | 2020-11-04 | 2022-05-12 | Alcon Inc. | Method for making photochromic contact lenses |
| HUE070248T2 (hu) | 2020-11-04 | 2025-05-28 | Alcon Inc | Eljárás fotokróm kontaktlencsék elõállítására |
| WO2022189940A1 (en) | 2021-03-08 | 2022-09-15 | Alcon Inc. | Method for making photofunctional contact lenses |
| KR20230144634A (ko) | 2021-04-01 | 2023-10-16 | 알콘 인코포레이티드 | 광변색성 콘택트 렌즈의 제조 방법 |
| WO2023209631A1 (en) | 2022-04-28 | 2023-11-02 | Alcon Inc. | Method for making uv and hevl-absorbing ophthalmic lenses |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5817527B2 (ja) * | 1978-07-17 | 1983-04-07 | 株式会社保谷レンズ | 高屈折率レンズ用共重合体及びそれよりなるレンズ |
| CA1252249A (en) | 1983-09-24 | 1989-04-04 | Teruo Sakagami | Halogen-containing resin lens material |
| DE4010783C2 (de) * | 1990-04-04 | 1994-11-03 | Bayer Ag | Duromere transparente Terpolymerisate und ihre Verwendung zur Herstellung von optischen Formteilen |
| WO1992005209A1 (en) * | 1990-09-18 | 1992-04-02 | Akzo N.V. | Copolymerization process and optical copolymer produced therefrom |
| JP3016533B2 (ja) * | 1992-03-03 | 2000-03-06 | 株式会社トクヤマ | フォトクロミック組成物 |
| US5708064A (en) * | 1993-10-15 | 1998-01-13 | Ppg Industries, Inc. | High refractive index photochromic ophthalmic article |
| JP3471073B2 (ja) * | 1994-04-27 | 2003-11-25 | 株式会社トクヤマ | フォトクロミック組成物 |
| FR2727971A1 (fr) * | 1994-12-12 | 1996-06-14 | Corning Inc | Nouveaux materiaux organiques photochromiques a indice de refraction eleve, leur preparation et articles formes de ces materiaux |
| US5973039A (en) * | 1994-12-12 | 1999-10-26 | Corning Incorporated | Temperature stable and sunlight protected photochromic articles |
| FR2728576A1 (fr) | 1994-12-22 | 1996-06-28 | Corning Inc | Materiaux organiques photochromiques a indice de refraction eleve et a proprietes ajustables, leur preparation et articles formes de ces materiaux |
| JPH08311441A (ja) * | 1995-05-24 | 1996-11-26 | Tokuyama Corp | フォトクロミック硬化体の製造方法 |
| JPH08320534A (ja) * | 1995-05-25 | 1996-12-03 | Tokuyama Corp | フォトクロミック硬化性組成物 |
| US6034193A (en) * | 1995-07-12 | 2000-03-07 | Corning Incorporated | Photochromic organic materials |
| US5811503A (en) * | 1996-11-27 | 1998-09-22 | Ppg Industries, Inc. | Polymerizable composition |
| US5981634A (en) * | 1996-11-27 | 1999-11-09 | Ppg Industries Ohio, Inc. | Method of preparing photochromic articles |
| US5973093A (en) * | 1996-11-27 | 1999-10-26 | Ppg Industries Ohio, Inc. | Polymerizable polyol (allyl carbonate) composition |
-
1996
- 1996-11-21 ES ES96941425T patent/ES2184899T3/es not_active Expired - Lifetime
- 1996-11-21 EP EP96941425A patent/EP0866987B1/en not_active Expired - Lifetime
- 1996-11-21 WO PCT/US1996/018668 patent/WO1997021122A1/en not_active Ceased
- 1996-11-21 AU AU10573/97A patent/AU1057397A/en not_active Abandoned
- 1996-11-21 US US09/051,025 patent/US6221284B1/en not_active Expired - Fee Related
- 1996-11-21 DE DE69624131T patent/DE69624131T2/de not_active Expired - Fee Related
- 1996-11-21 CN CN96198673A patent/CN1203672A/zh active Pending
- 1996-12-04 AR ARP960105482A patent/AR004986A1/es unknown
-
1998
- 1998-06-04 MX MX9804484A patent/MX9804484A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US6221284B1 (en) | 2001-04-24 |
| DE69624131D1 (de) | 2002-11-07 |
| WO1997021122A1 (en) | 1997-06-12 |
| DE69624131T2 (de) | 2003-06-18 |
| AU1057397A (en) | 1997-06-27 |
| ES2184899T3 (es) | 2003-04-16 |
| EP0866987B1 (en) | 2002-10-02 |
| EP0866987A1 (en) | 1998-09-30 |
| EP0866987A4 (en) | 2000-07-12 |
| MX9804484A (es) | 1998-09-30 |
| CN1203672A (zh) | 1998-12-30 |
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