MX9605431A - Procedimientos de polimerizacion de acrilato. - Google Patents
Procedimientos de polimerizacion de acrilato.Info
- Publication number
- MX9605431A MX9605431A MX9605431A MX9605431A MX9605431A MX 9605431 A MX9605431 A MX 9605431A MX 9605431 A MX9605431 A MX 9605431A MX 9605431 A MX9605431 A MX 9605431A MX 9605431 A MX9605431 A MX 9605431A
- Authority
- MX
- Mexico
- Prior art keywords
- polymerization processes
- resins
- thermoplastic resin
- free radical
- containing thermoplastic
- Prior art date
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 229920005992 thermoplastic resin Polymers 0.000 abstract 4
- 229920001519 homopolymer Polymers 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 150000003254 radicals Chemical class 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 oxo nitroxide Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invencion se refiere a un procedimiento de polimerizacion para la preparacion de resina o resinas termoplásticas que contienen acrilato homopolimérico, que comprende calentar una mezcla constituida por un iniciador de radicales libres, un agente de radicales libres estable oxo nitroxido, al menos un compuesto de monomero acrilato polimerizable y opcionalmente un solvente, para formar una resina o resinas termoplásticas que contienen acrilato homopolimérico con una alta conversion de monomero a polímero y una restringida polidispersidad.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/242,490 US5412047A (en) | 1994-05-13 | 1994-05-13 | Homoacrylate polymerization processes with oxonitroxides |
| PCT/US1995/005559 WO1995031484A1 (en) | 1994-05-13 | 1995-05-02 | Acrylate polymerization processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9605431A true MX9605431A (es) | 1997-12-31 |
Family
ID=22914975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9605431A MX9605431A (es) | 1994-05-13 | 1995-05-02 | Procedimientos de polimerizacion de acrilato. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5412047A (es) |
| EP (1) | EP0759039B1 (es) |
| JP (1) | JP3496764B2 (es) |
| KR (1) | KR970703370A (es) |
| CN (1) | CN1147820A (es) |
| AT (1) | ATE188221T1 (es) |
| AU (1) | AU2469195A (es) |
| BR (1) | BR9507868A (es) |
| CA (1) | CA2187754C (es) |
| DE (1) | DE69514222T2 (es) |
| MX (1) | MX9605431A (es) |
| WO (1) | WO1995031484A1 (es) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6258911B1 (en) * | 1994-08-18 | 2001-07-10 | Xerox Corporation | Bifunctional macromolecules and toner compositions therefrom |
| US5545504A (en) * | 1994-10-03 | 1996-08-13 | Xerox Corporation | Ink jettable toner compositions and processes for making and using |
| FR2730241B1 (fr) | 1995-02-07 | 1997-02-28 | Atofina | Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable |
| FR2730240A1 (fr) * | 1995-02-07 | 1996-08-09 | Atochem Elf Sa | Stabilisation d'un polymere par un radical libre stable |
| US5627248A (en) * | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
| US5552502A (en) * | 1995-11-16 | 1996-09-03 | Xerox Corporation | Polymerization process and compositions thereof |
| CN1209817A (zh) * | 1996-01-25 | 1999-03-03 | Basf公司 | 嵌段共聚物 |
| DE19602541A1 (de) * | 1996-01-25 | 1997-07-31 | Basf Magnetics Gmbh | Magnetische Aufzeichnungsträger |
| DE19602544A1 (de) * | 1996-01-25 | 1997-07-31 | Basf Ag | Als Dispergierharze geeignete Polymerisate |
| DE19613994A1 (de) * | 1996-04-09 | 1997-10-16 | Basf Ag | Stabilisierte wäßrige Dispersionen von Polymeren mit ethylenisch ungesättigten Gruppen |
| FR2748484B1 (fr) * | 1996-05-13 | 1998-07-24 | Atochem Elf Sa | Polymerisation en presence d'un radical libre stable et d'un initiateur de radicaux libres |
| US5723511A (en) * | 1996-06-17 | 1998-03-03 | Xerox Corporation | Processes for preparing telechelic, branched and star thermoplastic resin polymers |
| US5711767A (en) * | 1996-07-11 | 1998-01-27 | Ciba Specialty Chemicals Corporation | Stabilizers for the prevention of gum formation in gasoline |
| US6160070A (en) * | 1996-07-25 | 2000-12-12 | Mitsubishi Rayon Co., Ltd. | Process for the preparation of poly(meth)acrylic acid ester |
| FR2754535A1 (fr) * | 1996-10-16 | 1998-04-17 | Atochem Elf Sa | Polymeres greffes a viscosite controlee |
| DE19648811A1 (de) * | 1996-11-27 | 1998-05-28 | Basf Ag | Verfahren zur Polymerisation vinylischer Monomerer |
| US5744560A (en) * | 1997-01-21 | 1998-04-28 | Xerox Corporation | Metal accelerated polymerization processes |
| US6281311B1 (en) * | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| US6111025A (en) * | 1997-06-24 | 2000-08-29 | The Lubrizol Corporation | Block copolymer surfactants prepared by stabilized free-radical polymerization |
| US6156858A (en) * | 1997-06-25 | 2000-12-05 | Xerox Corporation | Stable free radical polymerization processes |
| DE19727505A1 (de) | 1997-06-27 | 1999-01-07 | Basf Ag | Verfahren der radikalisch initiierten wäßrigen Emulsionspolymerisation zur Herstellung einer wäßrigen Polymerisatdispersion |
| DE19727502A1 (de) | 1997-06-27 | 1999-01-07 | Basf Ag | Verfahren der radikalisch initiierten wäßrigen Emulsionspolymerisation zur Herstellung einer wäßrigen Polymerisatdispersion |
| US5817824A (en) * | 1997-08-01 | 1998-10-06 | Xerox Corporation | Processes for stabel free radicals |
| EP1056711B1 (de) | 1997-08-07 | 2004-10-06 | Basf Aktiengesellschaft | Verfahren zur stabilisierung von (meth)acrylsäureestern gegen unerwünschte radikalische polymerisation |
| US5891971A (en) * | 1997-08-15 | 1999-04-06 | Xerox Corporation | Polymerization processes |
| WO1999023174A1 (en) | 1997-10-31 | 1999-05-14 | Cabot Corporation | Particles having an attached stable free radical, polymerized modified particles, and methods of making the same |
| US6068688A (en) * | 1997-11-12 | 2000-05-30 | Cabot Corporation | Particle having an attached stable free radical and methods of making the same |
| US6368239B1 (en) | 1998-06-03 | 2002-04-09 | Cabot Corporation | Methods of making a particle having an attached stable free radical |
| DE19752394A1 (de) * | 1997-11-19 | 1999-05-20 | Basf Ag | Verfahren zur Herstellung von Pfropfpolymerisaten |
| FR2773158B1 (fr) | 1997-12-30 | 2000-02-04 | Atochem Elf Sa | Procede de polymerisation radicalaire controlee faisant intervenir une faible quantite de radical libre stable |
| CA2265345A1 (en) | 1998-03-25 | 1999-09-25 | The Lubrizol Corporation | Vinyl aromatic-(vinyl aromatic-co-acrylic) block copolymers prepared by stabilized free radical polymerization |
| DE19813353A1 (de) | 1998-03-26 | 1999-09-30 | Bayer Ag | Verfahren zur Herstellung von Telechelen, so hergestellte Telechele und ihre Verwendung |
| US6103380A (en) | 1998-06-03 | 2000-08-15 | Cabot Corporation | Particle having an attached halide group and methods of making the same |
| US6864313B2 (en) * | 1998-06-25 | 2005-03-08 | Ciba Specialty Chemicals Corp. | Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators |
| TWI246519B (en) | 1998-06-25 | 2006-01-01 | Ciba Sc Holding Ag | Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators |
| JP2002520432A (ja) | 1998-07-10 | 2002-07-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ミクロゲルおよびその調製方法 |
| DE69916455T2 (de) | 1998-07-31 | 2004-09-09 | Ciba Specialty Chemicals Holding Inc. | Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler |
| WO2000017242A1 (en) * | 1998-09-23 | 2000-03-30 | The Dow Chemical Company | Preparation of a water-soluble polymeric dispersant having low polydispersity |
| AU755095B2 (en) | 1998-10-26 | 2002-12-05 | Lubrizol Corporation, The | Radial polymers prepared by stabilized free radical polymerization |
| DE19858103A1 (de) * | 1998-12-16 | 2000-06-21 | Basf Ag | Verfahren zur lebenden freien radikalischen Polymerisation |
| US6143820A (en) * | 1998-12-18 | 2000-11-07 | The Dow Chemical Company | Preparation of a low polydisperse water-soluble polymeric composition |
| US6355756B1 (en) | 1999-05-18 | 2002-03-12 | International Business Machines Corporation | Dual purpose electroactive copolymers, preparation thereof, and use in opto-electronic devices |
| DE19939031A1 (de) * | 1999-08-18 | 2001-02-22 | Basf Ag | N-Oxyl-Radikale |
| US6569968B1 (en) * | 1999-08-19 | 2003-05-27 | Kurita Water Industries Ltd. | Polymer of a water-soluble radical-polymerizable monomer, process for producing the polymer and flocculant comprising the polymer |
| US6713552B1 (en) | 1999-08-23 | 2004-03-30 | Rohm And Haas Company | Pressure sensitive adhesive with improved peel strength and tack |
| EP1083169B1 (de) | 1999-09-07 | 2003-10-29 | Bayer Ag | Funktionalisierte Alkoxyamin-Initiatoren |
| US7034079B2 (en) * | 1999-10-20 | 2006-04-25 | The Lubrizol Corporation | Radial polymers prepared by stabilized free radical polymerization |
| EP1152014B1 (en) * | 1999-11-19 | 2009-01-14 | Mitsubishi Rayon Co., Ltd. | Resin composition |
| DE10016651A1 (de) | 2000-04-04 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung von Polymeren |
| TWI225492B (en) | 2000-09-25 | 2004-12-21 | Ciba Sc Holding Ag | Composition and process for enhancing controlled free radical polymerization |
| US20030153708A1 (en) * | 2002-01-11 | 2003-08-14 | Caneba Gerald Tablada | Free radical retrograde precipitation copolymers and process for making same |
| EP1375457A1 (en) | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | One-pot process for the preparation of functionalized alkoxyamines |
| EP1375476A1 (en) * | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | A new process for the synthesis of alkoxyamines active in controlled radical polymerization |
| EP1496091A1 (en) * | 2003-07-08 | 2005-01-12 | Rohm And Haas Company | Aqueous polymer composition |
| US20080262160A1 (en) | 2004-07-01 | 2008-10-23 | Universiteit Gent | Monodisperse Polymers Containing (Alkyl)Acrylic Acid Moieties, Precursors and Methods for Making them and their Applications |
| WO2008006723A1 (en) * | 2006-07-11 | 2008-01-17 | Ciba Holding Inc. | Color filter composition |
| BR112017027167B1 (pt) | 2015-06-17 | 2022-01-04 | Basf Se | Composição, uso de uma composição, e, método para interrupção imediata de polimerização por radicais livres |
| JP6822863B2 (ja) * | 2016-03-31 | 2021-01-27 | 三井化学株式会社 | 熱硬化性組成物、これを含む封止剤、有機el素子用枠封止剤、及び有機el素子用面封止剤、並びにその硬化物 |
| JP6989116B2 (ja) * | 2016-12-27 | 2022-01-05 | 学校法人福岡大学 | 細胞シートの製造方法及び細胞培養支持体 |
| CN109232595B (zh) * | 2018-09-25 | 2020-03-03 | 万华化学集团股份有限公司 | 一种罗丹明b类自由基荧光探针、制备方法及其在丙烯酸及酯生产过程中自由基检测的应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4736004A (en) * | 1983-04-05 | 1988-04-05 | Green Cross Corporation | Persistent perfluoroalkyl free radicals useful as polymerization catalyst |
| US4581429A (en) * | 1983-07-11 | 1986-04-08 | Commonwealth Scientific And Industrial Research Organization | Polymerization process and polymers produced thereby |
| US4546160A (en) * | 1984-02-29 | 1985-10-08 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
| US5059657A (en) * | 1990-08-06 | 1991-10-22 | E. I. Du Pont De Nemours And Company | Polymerization of selected vinyl monomers |
| US5268437A (en) * | 1992-01-22 | 1993-12-07 | Rohm And Haas Company | High temperature aqueous polymerization process |
| US5322912A (en) * | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
-
1994
- 1994-05-13 US US08/242,490 patent/US5412047A/en not_active Expired - Lifetime
-
1995
- 1995-05-02 EP EP95918968A patent/EP0759039B1/en not_active Expired - Lifetime
- 1995-05-02 KR KR1019960706428A patent/KR970703370A/ko not_active Withdrawn
- 1995-05-02 JP JP52969995A patent/JP3496764B2/ja not_active Expired - Fee Related
- 1995-05-02 AT AT95918968T patent/ATE188221T1/de not_active IP Right Cessation
- 1995-05-02 MX MX9605431A patent/MX9605431A/es unknown
- 1995-05-02 BR BR9507868A patent/BR9507868A/pt not_active Application Discontinuation
- 1995-05-02 CN CN95193044A patent/CN1147820A/zh active Pending
- 1995-05-02 WO PCT/US1995/005559 patent/WO1995031484A1/en not_active Ceased
- 1995-05-02 DE DE69514222T patent/DE69514222T2/de not_active Expired - Fee Related
- 1995-05-02 AU AU24691/95A patent/AU2469195A/en not_active Abandoned
- 1995-05-02 CA CA002187754A patent/CA2187754C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69514222T2 (de) | 2000-05-11 |
| US5412047A (en) | 1995-05-02 |
| CN1147820A (zh) | 1997-04-16 |
| WO1995031484A1 (en) | 1995-11-23 |
| AU2469195A (en) | 1995-12-05 |
| EP0759039A4 (es) | 1997-03-26 |
| ATE188221T1 (de) | 2000-01-15 |
| EP0759039A1 (en) | 1997-02-26 |
| JPH10500170A (ja) | 1998-01-06 |
| DE69514222D1 (de) | 2000-02-03 |
| KR970703370A (ko) | 1997-07-03 |
| CA2187754C (en) | 2000-01-11 |
| CA2187754A1 (en) | 1995-11-23 |
| BR9507868A (pt) | 1997-09-23 |
| JP3496764B2 (ja) | 2004-02-16 |
| EP0759039B1 (en) | 1999-12-29 |
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