MX2009000711A - Composiciones de polietileno de alta densidad, metodo para hacer las mismas, articulos moldeados por inyeccion hechos a partir de las mismas y metodo para hacer tales articulos. - Google Patents
Composiciones de polietileno de alta densidad, metodo para hacer las mismas, articulos moldeados por inyeccion hechos a partir de las mismas y metodo para hacer tales articulos.Info
- Publication number
- MX2009000711A MX2009000711A MX2009000711A MX2009000711A MX2009000711A MX 2009000711 A MX2009000711 A MX 2009000711A MX 2009000711 A MX2009000711 A MX 2009000711A MX 2009000711 A MX2009000711 A MX 2009000711A MX 2009000711 A MX2009000711 A MX 2009000711A
- Authority
- MX
- Mexico
- Prior art keywords
- range
- component
- density polyethylene
- high density
- making
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
- B65D41/02—Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
- B65D41/24—Caps or cap-like covers made of shrinkable material or formed in situ by dipping, e.g. using gelatine or celluloid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D53/00—Sealing or packing elements; Sealings formed by liquid or plastics material
- B65D53/06—Sealings formed by liquid or plastic material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/52—Heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/065—HDPE, i.e. high density polyethylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0094—Condition, form or state of moulded material or of the material to be shaped having particular viscosity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0063—Density
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/56—Stoppers or lids for bottles, jars, or the like, e.g. closures
- B29L2031/565—Stoppers or lids for bottles, jars, or the like, e.g. closures for containers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Inorganic Chemistry (AREA)
Abstract
La presente invención es una composición de polietileno de alta densidad, método para producir la misma, artículos moldeados por inyección a partir de la misma y método para hacer tales artículos. La composición de polietileno de alta densidad de la presente invención incluye un primer componente y un segundo componente. El primer componente es un copolímero de etileno alfa-olefina de alto peso molecular teniendo una densidad en el rango de 0.920 a 0.946 g/cm3, y un índice de fusión (I21.6) en el rango de 1 a 15 g/10 minutos. El segundo componente es un polímero de etileno de bajo peso molecular teniendo una densidad en el rango de 0.965 a 0.980 g/cm3, y un índice de fusión (l2) en el rango de 30 a 1500 g/10 minutos. La composición de polietileno de alta densidad tiene un índice de fusión (I2) de al menos 1, una densidad en el rango de 0.950 a 0.960 g/cm3. El método para producir una composición de polietileno de alta densidad incluye los siguientes pasos: (1) introducir etileno y uno o más comonómeros de alfa-olefina en un primer reactor; (2) (co)copolimerizar el etileno en la presencia de uno o más comonómeros de alfa-olefina en el primer reactor produciendo por ello un primer componente, en donde el primer componente es un copolímero de etileno alfa-olefina de alto peso molecular teniendo una densidad en el rango de 0.920 a 0.946 g/cm3, y un índice de fusión (I21.6) en el rango de 1 a 15 g/10 minutos; (3) introducir el primer componente y etileno adicional en un segundo reactor; (4) polimerizar el etileno adicional en el segundo reactor produciendo por ello un segundo componente, en donde el segundo componente es un polímero de etileno de baja peso molecular teniendo una densidad en el rango de 0.965 a 0.980 g/cm3, y un índice de fusión (I2) en el rango de 30 a 1500 g/10 minutos; y (5) produciendo por ello la composición de polietileno de alta densidad, en donde la composición de polietileno de alta densidad tiene un índice de fusión (I2) de al menos 1, una densidad en el rango de 0.950 a 0.960 g/cm3. los artículos moldeados por inyección de acuerdo con la presente invención comprenden las composiciones de polietileno de alta densidad inventivas antes descritas, y tales artículos son hechos vía moldeado por inyección.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US92717607P | 2007-05-02 | 2007-05-02 | |
| PCT/US2007/082502 WO2008136849A1 (en) | 2007-05-02 | 2007-10-25 | High-density polyethylene compositions, method of making the same, injection molded articles made therefrom, and method of making such articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009000711A true MX2009000711A (es) | 2009-04-22 |
Family
ID=39247259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009000711A MX2009000711A (es) | 2007-05-02 | 2007-10-25 | Composiciones de polietileno de alta densidad, metodo para hacer las mismas, articulos moldeados por inyeccion hechos a partir de las mismas y metodo para hacer tales articulos. |
Country Status (17)
| Country | Link |
|---|---|
| US (4) | US20100084363A1 (es) |
| EP (1) | EP2052026B2 (es) |
| JP (1) | JP2010526169A (es) |
| KR (1) | KR20100014214A (es) |
| CN (2) | CN103396604B (es) |
| AR (1) | AR063766A1 (es) |
| AT (1) | ATE450569T1 (es) |
| AU (1) | AU2007352541B2 (es) |
| BR (1) | BRPI0713185B1 (es) |
| CA (1) | CA2656845C (es) |
| DE (1) | DE602007003611D1 (es) |
| ES (1) | ES2333828T3 (es) |
| MX (1) | MX2009000711A (es) |
| NO (1) | NO20090444L (es) |
| PL (1) | PL2052026T5 (es) |
| RU (1) | RU2464287C2 (es) |
| WO (1) | WO2008136849A1 (es) |
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|---|---|---|---|---|
| BRPI0706048A2 (pt) | 2006-05-02 | 2011-03-22 | Dow Global Technologies Inc | composição de polietileno de alta densidade, método para produzir uma composição de polietileno de alta densidade, artigo, fechamento de tampa de garrafa, método para melhorar fechamentos de tampas de garrafas, e método para produzir um artigo |
| CA2629576C (en) * | 2008-04-21 | 2016-01-05 | Nova Chemicals Corporation | Closures for bottles |
| WO2010022941A1 (en) | 2008-08-29 | 2010-03-04 | Basell Polyolefine Gmbh | Polyethylene for injection moldings |
| MX2011008053A (es) | 2009-01-30 | 2012-01-12 | Dow Global Technologies Llc | Composiciones de polietileno de alta densidad, metodo para producir las mismas, dispositivos de cierre elaborados de las mismas, y metodo para elaborar dichos dispositivos de cierre. |
| US9371442B2 (en) | 2011-09-19 | 2016-06-21 | Nova Chemicals (International) S.A. | Polyethylene compositions and closures made from them |
| CA2752407C (en) | 2011-09-19 | 2018-12-04 | Nova Chemicals Corporation | Polyethylene compositions and closures for bottles |
| US9359493B2 (en) | 2011-09-30 | 2016-06-07 | Total Research & Technology Feluy | High-density polyethylene for caps and closures |
| BR202012006190Y1 (pt) * | 2012-03-20 | 2022-04-19 | Guido Hamlet Caputo Guillier | Dispositivo de leitura braile aplicado em tampas e similares |
| RU2647852C2 (ru) | 2012-06-11 | 2018-03-21 | Унилевер Н.В. | Высокоплотная полиэтиленовая композиция и контейнер |
| RU2015105810A (ru) * | 2012-07-20 | 2016-09-10 | Клоужер Системз Интернэшнл Инк. | Легковесное укупорочное средство и упаковка емкости |
| CN103627063A (zh) * | 2012-08-29 | 2014-03-12 | 中国石油化工股份有限公司 | 一种乙烯聚合物组合物和乙烯聚合物材料以及瓶盖 |
| CA2881702C (en) | 2012-09-13 | 2021-03-09 | Dow Global Technologies Llc | Ethylene-based polymer compositions, and articles prepared from the same |
| WO2014060391A1 (en) | 2012-10-15 | 2014-04-24 | Saudi Basic Industries Corporation | Polyethylene compositions comprising polypropylene |
| CA2798854C (en) * | 2012-12-14 | 2020-02-18 | Nova Chemicals Corporation | Polyethylene compositions having high dimensional stability and excellent processability for caps and closures |
| US9783663B2 (en) | 2012-12-14 | 2017-10-10 | Nova Chemicals (International) S.A. | Polyethylene compositions having high dimensional stability and excellent processability for caps and closures |
| US9475927B2 (en) | 2012-12-14 | 2016-10-25 | Nova Chemicals (International) S.A. | Polyethylene compositions having high dimensional stability and excellent processability for caps and closures |
| US20150315401A1 (en) * | 2012-12-21 | 2015-11-05 | Dow Global Technologies Llc | Polyolefin-Based Compound for Cable Jacket with Reduced Shrinkage and Enhanced Processability |
| MX370206B (es) * | 2012-12-21 | 2019-12-05 | Dow Global Technologies Llc | Tubos protectores a base de hdpe con un largo de fibra excedente mejorado en calbles de fibra optica. |
| US9815975B2 (en) | 2013-03-25 | 2017-11-14 | Dow Global Technologies Llc | Film having good barrier properties together with good physical characteristics |
| KR20160042925A (ko) * | 2013-08-12 | 2016-04-20 | 토탈 리서치 앤드 테크놀로지 펠루이 | 사출 연신 취입 성형 적용을 위한 폴리에틸렌 |
| PL3186311T3 (pl) * | 2014-08-29 | 2023-09-18 | Dow Global Technologies Llc | Żywice na bazie etylenu do stosowania w zamknięciach |
| KR101625753B1 (ko) * | 2014-11-05 | 2016-05-30 | 한화토탈 주식회사 | 폴리에틸렌 수지 조성물 및 이로 제조된 성형품 |
| US10370527B2 (en) | 2014-12-11 | 2019-08-06 | Dow Global Technologies Llc | Polyethylene compositions having living hinge properties |
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| US9758653B2 (en) | 2015-08-19 | 2017-09-12 | Nova Chemicals (International) S.A. | Polyethylene compositions, process and closures |
| EP3377421B1 (en) | 2015-11-19 | 2020-12-23 | Dow Global Technologies LLC | Polyethylene compositions having living hinge properties |
| EP3394167B1 (en) | 2015-12-21 | 2022-03-09 | Dow Global Technologies LLC | Polyethylene formulations with improved barrier and environmental stress crack resistance |
| EP3394169B1 (en) | 2015-12-21 | 2024-06-12 | Dow Global Technologies LLC | Polyethylene formulations with improved barrier and toughness for molding applications |
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| Publication number | Priority date | Publication date | Assignee | Title |
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-
2007
- 2007-10-25 ES ES07863496T patent/ES2333828T3/es active Active
- 2007-10-25 US US12/377,334 patent/US20100084363A1/en not_active Abandoned
- 2007-10-25 CA CA2656845A patent/CA2656845C/en active Active
- 2007-10-25 RU RU2009106863/05A patent/RU2464287C2/ru not_active IP Right Cessation
- 2007-10-25 BR BRPI0713185A patent/BRPI0713185B1/pt active IP Right Grant
- 2007-10-25 KR KR1020097000566A patent/KR20100014214A/ko not_active Ceased
- 2007-10-25 EP EP07863496.1A patent/EP2052026B2/en active Active
- 2007-10-25 JP JP2010506180A patent/JP2010526169A/ja active Pending
- 2007-10-25 AU AU2007352541A patent/AU2007352541B2/en not_active Ceased
- 2007-10-25 CN CN201310238328.2A patent/CN103396604B/zh active Active
- 2007-10-25 DE DE602007003611T patent/DE602007003611D1/de active Active
- 2007-10-25 MX MX2009000711A patent/MX2009000711A/es active IP Right Grant
- 2007-10-25 CN CNA2007800274160A patent/CN101490163A/zh active Pending
- 2007-10-25 WO PCT/US2007/082502 patent/WO2008136849A1/en not_active Ceased
- 2007-10-25 AT AT07863496T patent/ATE450569T1/de not_active IP Right Cessation
- 2007-10-25 PL PL07863496.1T patent/PL2052026T5/pl unknown
- 2007-10-31 AR ARP070104853A patent/AR063766A1/es unknown
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2009
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2016
- 2016-04-21 US US15/135,044 patent/US10844202B2/en active Active
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2018
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- 2020-10-15 US US17/036,566 patent/US11447620B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0713185A2 (pt) | 2012-04-17 |
| US20160237266A1 (en) | 2016-08-18 |
| AU2007352541A1 (en) | 2008-11-13 |
| EP2052026A1 (en) | 2009-04-29 |
| AR063766A1 (es) | 2009-02-18 |
| RU2009106863A (ru) | 2010-09-10 |
| EP2052026B1 (en) | 2009-12-02 |
| PL2052026T3 (pl) | 2010-05-31 |
| CA2656845C (en) | 2015-09-22 |
| CN103396604B (zh) | 2021-05-25 |
| KR20100014214A (ko) | 2010-02-10 |
| PL2052026T5 (pl) | 2023-09-18 |
| US20210024727A1 (en) | 2021-01-28 |
| ATE450569T1 (de) | 2009-12-15 |
| DE602007003611D1 (de) | 2010-01-14 |
| CN103396604A (zh) | 2013-11-20 |
| WO2008136849A1 (en) | 2008-11-13 |
| AU2007352541B2 (en) | 2013-03-28 |
| ES2333828T3 (es) | 2010-03-01 |
| JP2010526169A (ja) | 2010-07-29 |
| US11447620B2 (en) | 2022-09-20 |
| US20190031867A1 (en) | 2019-01-31 |
| BRPI0713185B1 (pt) | 2018-08-28 |
| CN101490163A (zh) | 2009-07-22 |
| EP2052026B2 (en) | 2021-07-14 |
| NO20090444L (no) | 2010-01-26 |
| CA2656845A1 (en) | 2008-11-13 |
| US20100084363A1 (en) | 2010-04-08 |
| RU2464287C2 (ru) | 2012-10-20 |
| US10844202B2 (en) | 2020-11-24 |
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