AR070284A1 - Composiciones de polietileno, metodo para su produccion, articulos realizados a partir de dichas composiciones y metodos lpara fabricarlos. - Google Patents
Composiciones de polietileno, metodo para su produccion, articulos realizados a partir de dichas composiciones y metodos lpara fabricarlos.Info
- Publication number
- AR070284A1 AR070284A1 ARP090100271A ARP090100271A AR070284A1 AR 070284 A1 AR070284 A1 AR 070284A1 AR P090100271 A ARP090100271 A AR P090100271A AR P090100271 A ARP090100271 A AR P090100271A AR 070284 A1 AR070284 A1 AR 070284A1
- Authority
- AR
- Argentina
- Prior art keywords
- range
- less
- polyethylene composition
- molecular weight
- vinyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 17
- -1 POLYETHYLENE Polymers 0.000 title abstract 12
- 239000004698 Polyethylene Substances 0.000 title abstract 12
- 229920000573 polyethylene Polymers 0.000 title abstract 12
- 238000004519 manufacturing process Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 8
- 229920002554 vinyl polymer Polymers 0.000 abstract 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 4
- 239000005977 Ethylene Substances 0.000 abstract 4
- 238000009434 installation Methods 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 238000002347 injection Methods 0.000 abstract 3
- 239000007924 injection Substances 0.000 abstract 3
- 239000000155 melt Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Una composicion de polietileno, un método para producirla, artículos realizados a partir de ella y un método para fabricar dichos artículos. La composicion de polietileno de acuerdo con la presente invencion comprende (1) una cantidad inferior o igual a 100 por ciento en peso de las unidades derivadas de etileno; y (2) menos de 15 por ciento en peso de unidades derivadas de uno o más comonomeros de ?-olefina. La composicion polietileno de acuerdo con la presente posee una densidad en el rango de 0,907 a 0,975 g/cm3, una distribucion del peso molecular (Mw/Mn) en el rango de 1,70 a 3,62, un índice de fusion (I2) en el rango de 2 a 1000 g/10 minutos, una distribucion del peso molecular (Mz/Mw) en el rango de menos de 2,5 y una instauracion de vinilo inferior a 0,06 vinilos cada mil átomos de carbono presentes en la estructura principal de la composicion. El progreso para producir una composicion de polietileno de acuerdo con la presente invencion comprende los siguientes pasos: (1) (co) polimerizar etileno y por lo menos uno o más comonomeros de ?-olefina en presencia de un catalizador de metaloceno a base de hafnio mediante un proceso de (co) polimerizacion de fase gaseosa en un reactor de una sola etapa; y (2) producir de este modo la composicion de polietileno inventiva, en donde la composicion de polietileno posee una densidad en el rango de 0,907 a 0,975 g/cm3, una distribucion del peso molecular (Mw/Mn) en el rango de 1,70 a 3,62, un índice de distribucion del peso molecular (Mw/Mn) en el rango de 1,70 a 3,62, un índice de fusion (I2) en el rango de 2 a 1000 g/10 minutos, una distribucion del peso molecular (Mz/Mw) en el rango inferior a 2,5, y una instauracion de vinilo inferior a 0,06 vinilos cada mil átomos de carbono presentes en la estructura principal de dicha composicion. Los artículos moldeados por inyeccion de acuerdo con la presente invencion comprende una composicion de polietileno que comprende (1) una cantidad inferior o igual a 100 por ciento en peso de las unidades derivadas de etileno; y (2) menos de 15 por ciento en peso de unidades derivadas de uno o más comonomeros de ?-olefina; en donde la composicion de polietileno posee una densidad en el rango de 0,907 a 0,975 g/cm3 una distribucion del peso molecular (Mz/Mw) en el rango inferior a 2,5 una instauracion de vinilo inferior a 0,06 vinilos cada mil átomos de carbono presentes en la estructura principal de dicha composicion . El proceso para preparar un artículo moldeado por inyeccion de acuerdo con la presente invencion comprende los siguientes pasos (a) seleccionar una composicion de polietileno que comprende (1) una cantidad inferior o igual a 100 por ciento en peso de las unidades derivadas de etileno; y (2) menos de 15 por ciento en peso de unidades derivadas de uno o más comonomeros de ?-olefina ; en donde la composicion de polietileno posee una densidad en el rango de 0,907 a o,975 g/cm3, una distribucion del peso molecular (Mz/Mw) en el rango de 1,70 a 3,62, un índice de fusion (I2) en el rango de 2 a 1000 g/10 minutos, una distribucion del peso molecular (Mz/Mw) en el rango inferior a 2,5, una instauracion de vinilo inferior a 0,06 vinilos cada mil átomos de carbono presentes en la estructura principal de dicha composicion; (b) moldear por inyeccion de dicha composicion de polietileno ; y (c) formar de ese4 modo el artículo moldeado por inyeccion.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2423708P | 2008-01-29 | 2008-01-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR070284A1 true AR070284A1 (es) | 2010-03-25 |
Family
ID=40568246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP090100271A AR070284A1 (es) | 2008-01-29 | 2009-01-28 | Composiciones de polietileno, metodo para su produccion, articulos realizados a partir de dichas composiciones y metodos lpara fabricarlos. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8481666B2 (es) |
| EP (1) | EP2188100B1 (es) |
| JP (1) | JP5555183B2 (es) |
| KR (1) | KR101450936B1 (es) |
| CN (1) | CN101778707B (es) |
| AR (1) | AR070284A1 (es) |
| AU (1) | AU2009209329B2 (es) |
| BR (1) | BRPI0903706B1 (es) |
| ES (1) | ES2399313T3 (es) |
| MX (1) | MX2009013622A (es) |
| RU (1) | RU2487015C2 (es) |
| TW (1) | TWI575009B (es) |
| WO (1) | WO2009097222A1 (es) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9181362B2 (en) * | 2008-01-29 | 2015-11-10 | Dow Global Technologies Llc | Polyethylene compositions, method of producing the same, articles made therefrom, and method of making the same |
| CN101952363B (zh) * | 2008-07-10 | 2013-11-06 | 陶氏环球技术有限责任公司 | 聚乙烯组合物,其制备方法,由其制造的纤维和所述纤维的制造方法 |
| EP2448979B1 (en) * | 2009-07-01 | 2013-05-01 | Dow Global Technologies LLC | Ethylenic polymer and its use |
| MY162909A (en) * | 2009-08-28 | 2017-07-31 | Univation Tech Llc | Rotational molded articles, and method of making the same |
| JP5972887B2 (ja) * | 2010-10-29 | 2016-08-17 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレン系延伸モノフィラメントおよび延伸ストリップならびにこれらの調製方法 |
| BR112013030295B1 (pt) * | 2011-05-27 | 2021-01-05 | Dow Global Technologies Llc | composição de mistura de polietileno e artigo |
| JP6129190B2 (ja) * | 2011-10-05 | 2017-05-17 | ダウ グローバル テクノロジーズ エルエルシー | 二成分繊維およびそれから製造された布 |
| BR112014009439A2 (pt) * | 2011-10-21 | 2017-04-11 | Dow Global Technologies Llc | película encolhível em multicamada |
| KR20140080502A (ko) * | 2011-10-24 | 2014-06-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 인조 잔디 원사 |
| EP2610269A1 (en) * | 2011-12-28 | 2013-07-03 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
| CN103360521B (zh) * | 2012-03-30 | 2016-03-30 | 中国石油化工股份有限公司 | 一种聚乙烯颗粒及其制备方法和应用 |
| RU2647852C2 (ru) * | 2012-06-11 | 2018-03-21 | Унилевер Н.В. | Высокоплотная полиэтиленовая композиция и контейнер |
| US9926441B2 (en) | 2012-06-26 | 2018-03-27 | Dow Global Technologies Llc | Polyethylene blend-composition suitable for blown films, and films made therefrom |
| US20140067069A1 (en) | 2012-08-30 | 2014-03-06 | Interventional Spine, Inc. | Artificial disc |
| EP2906624B1 (en) * | 2012-10-12 | 2016-12-14 | Dow Global Technologies LLC | Linear low density composition suitable for film applications and films made therefrom |
| US20150232711A1 (en) * | 2012-10-12 | 2015-08-20 | Dow Global Technologies Llc | Sealant composition |
| CN104837914A (zh) * | 2012-10-12 | 2015-08-12 | 陶氏环球技术有限责任公司 | 适于拉伸膜应用的聚乙烯组合物及其制备方法 |
| US9273219B2 (en) * | 2012-10-12 | 2016-03-01 | Dow Global Technologies Llc | Polyolefin blend composition |
| JP2016500395A (ja) * | 2012-12-17 | 2016-01-12 | ダウ グローバル テクノロジーズ エルエルシー | フィルム用途に好適なポリエチレン組成物およびそれから作製されるフィルム |
| CN106113851A (zh) * | 2012-12-18 | 2016-11-16 | 埃克森美孚化学专利公司 | 聚乙烯膜及其制造方法 |
| US9988473B2 (en) * | 2013-05-02 | 2018-06-05 | Dow Global Technologies Llc | Polyethylene composition and articles made therefrom |
| EP3059291B1 (en) | 2013-10-18 | 2019-12-18 | Mitsui Chemicals, Inc. | Adhesive agent comprising ethylene-( -olefin) copolymer |
| JP6596017B2 (ja) | 2014-04-09 | 2019-10-23 | ダウ グローバル テクノロジーズ エルエルシー | 配向ポリエチレンフィルム及びそれを作製するための方法 |
| ES2767500T3 (es) * | 2014-04-17 | 2020-06-17 | Chevron Phillips Chemical Co Lp | Sistemas catalíticos de metaloceno con puentes de boro y polímeros producidos a partir de estos |
| US9765164B2 (en) | 2014-06-27 | 2017-09-19 | Dow Global Technologies Llc | Polyolefin compositions and uses thereof |
| ES3021214T3 (en) * | 2015-02-06 | 2025-05-26 | Dow Global Technologies Llc | Method of manufacturing an artificial turf filament |
| EP3377421B1 (en) * | 2015-11-19 | 2020-12-23 | Dow Global Technologies LLC | Polyethylene compositions having living hinge properties |
| EP3387169B1 (en) * | 2015-12-10 | 2019-10-23 | Dow Global Technologies, LLC | Polyethylene tapes, fibers or monofilaments comprising ethylene/alpha-olefin polymer |
| US9783664B1 (en) * | 2016-06-01 | 2017-10-10 | Nova Chemicals (International) S.A. | Hinged component comprising polyethylene composition |
| MX2019011052A (es) * | 2017-03-17 | 2019-10-17 | Dow Global Technologies Llc | Polimeros para usarse en fibras y telas no tejidas, articulos de estos y compuestos de estos. |
| US10358506B2 (en) * | 2017-10-03 | 2019-07-23 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with improved processability |
| KR101932533B1 (ko) * | 2017-11-28 | 2019-03-15 | 롯데케미칼 주식회사 | 우수한 표면 특성과 빠른 결정화 속도를 나타내는 섬유용 폴리에틸렌 수지 |
| EP3768739B1 (en) | 2018-03-19 | 2025-07-23 | Univation Technologies, LLC | Ethylene/1-hexene copolymer |
| CA3110886A1 (en) * | 2018-09-17 | 2020-03-26 | Chevron Phillips Chemical Company Lp | Modified supported chromium catalysts and ethylene-based polymers produced therefrom |
| WO2020222916A1 (en) * | 2019-05-01 | 2020-11-05 | Exxonmobil Chemical Patents Inc. | Polyolefin films having in-situ formed elongated polyolefin structures therein |
| US20240400804A1 (en) | 2021-10-04 | 2024-12-05 | ExxonMobil Technology and Engineering Company-Chem | Polyethylene Blends, Films Thereof, and Methods Thereof |
| EP4536718A1 (en) * | 2022-06-13 | 2025-04-16 | ExxonMobil Chemical Patents Inc. | Polyethylene compositions and related bicomponent fibers, nonwoven fabrics, and methods |
| US20250368761A1 (en) * | 2022-08-05 | 2025-12-04 | Dow Global Technologies Llc | Unimodal high density polyethylene for cap and closure devices |
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| US4621952A (en) | 1981-07-28 | 1986-11-11 | Union Carbide Corporation | Fluidized bed discharge process |
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| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
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| US5292845A (en) | 1992-01-23 | 1994-03-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene/alpha-olefin/7-methyl-1,6-octadiene copolymer rubber and composition of the same |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| KR100190268B1 (ko) | 1993-04-26 | 1999-06-01 | 에인혼 해롤드 | 유동상에서 단량체를 중합시키는 방법 |
| RU2156779C2 (ru) * | 1993-05-13 | 2000-09-27 | Эксон Кемикэл Пейтентс Инк. | Пленки, полученные из сополимеров этилена |
| US5443399A (en) * | 1994-02-01 | 1995-08-22 | Jing; Wang S. | Electric light bulb socket positioner for lamp assemblies |
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| US6485662B1 (en) | 1996-12-03 | 2002-11-26 | Union Carbide Chemicals & Plastics Technology Corporation | Process for preparing a simulated in situ polyethylene blend |
| EP1023390B1 (en) * | 1997-09-19 | 2004-02-04 | The Dow Chemical Company | Narrow mwd, compositionally optimized ethylene interpolymer composition, process for making the same and article made therefrom |
| US6242545B1 (en) | 1997-12-08 | 2001-06-05 | Univation Technologies | Polymerization catalyst systems comprising substituted hafinocenes |
| BR0010289B1 (pt) * | 1999-05-05 | 2011-01-25 | copolìmeros de etileno, processo para preparar os mesmos, e filmes destes. | |
| JP2001192413A (ja) * | 1999-11-05 | 2001-07-17 | Japan Polychem Corp | エチレン・α−オレフィン共重合体及びそれからなるフィルム |
| GB0315275D0 (en) * | 2003-06-30 | 2003-08-06 | Borealis Tech Oy | Extrusion coating |
| KR101216515B1 (ko) * | 2004-11-02 | 2012-12-31 | 다우 글로벌 테크놀로지스 엘엘씨 | 저 밀도 폴리에틸렌 조성물의 제조 방법 및 이로부터생성된 중합체 |
| PL1655338T3 (pl) * | 2004-11-03 | 2007-07-31 | Borealis Tech Oy | Wielomodalna kompozycja polietylenowa do wytwarzania wtryskiwanych opakowań do transportowania |
| US7078467B1 (en) * | 2005-06-14 | 2006-07-18 | Univation Technologies, Llc | Single catalyst low, medium and high density polyethylenes |
| US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
-
2009
- 2009-01-23 MX MX2009013622A patent/MX2009013622A/es active IP Right Grant
- 2009-01-23 WO PCT/US2009/031808 patent/WO2009097222A1/en not_active Ceased
- 2009-01-23 KR KR1020097026970A patent/KR101450936B1/ko active Active
- 2009-01-23 ES ES09706717T patent/ES2399313T3/es active Active
- 2009-01-23 BR BRPI0903706-3A patent/BRPI0903706B1/pt active IP Right Grant
- 2009-01-23 US US12/663,871 patent/US8481666B2/en active Active
- 2009-01-23 CN CN200980100138.6A patent/CN101778707B/zh active Active
- 2009-01-23 JP JP2010544433A patent/JP5555183B2/ja active Active
- 2009-01-23 EP EP09706717A patent/EP2188100B1/en not_active Revoked
- 2009-01-23 AU AU2009209329A patent/AU2009209329B2/en not_active Expired - Fee Related
- 2009-01-23 RU RU2009146381/05A patent/RU2487015C2/ru not_active IP Right Cessation
- 2009-01-28 AR ARP090100271A patent/AR070284A1/es not_active Application Discontinuation
- 2009-02-02 TW TW098103217A patent/TWI575009B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CN101778707A (zh) | 2010-07-14 |
| AU2009209329B2 (en) | 2013-12-05 |
| EP2188100A1 (en) | 2010-05-26 |
| JP2011511107A (ja) | 2011-04-07 |
| CN101778707B (zh) | 2014-05-21 |
| AU2009209329A1 (en) | 2009-08-06 |
| EP2188100B1 (en) | 2012-11-28 |
| KR20100115700A (ko) | 2010-10-28 |
| RU2487015C2 (ru) | 2013-07-10 |
| JP5555183B2 (ja) | 2014-07-23 |
| WO2009097222A1 (en) | 2009-08-06 |
| US8481666B2 (en) | 2013-07-09 |
| TW200942571A (en) | 2009-10-16 |
| MX2009013622A (es) | 2010-01-20 |
| RU2009146381A (ru) | 2011-06-20 |
| BRPI0903706A2 (pt) | 2020-08-18 |
| TWI575009B (zh) | 2017-03-21 |
| ES2399313T3 (es) | 2013-03-27 |
| BRPI0903706B1 (pt) | 2021-09-08 |
| KR101450936B1 (ko) | 2014-10-14 |
| US20100298508A1 (en) | 2010-11-25 |
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