WO2017051622A1 - 表示装置及びその製造方法 - Google Patents
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- WO2017051622A1 WO2017051622A1 PCT/JP2016/073096 JP2016073096W WO2017051622A1 WO 2017051622 A1 WO2017051622 A1 WO 2017051622A1 JP 2016073096 W JP2016073096 W JP 2016073096W WO 2017051622 A1 WO2017051622 A1 WO 2017051622A1
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- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
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- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/22—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
- H05B33/24—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers of metallic reflective layers
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- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
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- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
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- H05B33/22—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
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- H10K50/852—Arrangements for extracting light from the devices comprising a resonant cavity structure, e.g. Bragg reflector pair
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- H10K59/12—Active-matrix OLED [AMOLED] displays
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- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/121—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements
- H10K59/1213—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements the pixel elements being TFTs
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- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
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- H10K59/38—Devices specially adapted for multicolour light emission comprising colour filters or colour changing media [CCM]
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- H10K59/876—Arrangements for extracting light from the devices comprising a resonant cavity structure, e.g. Bragg reflector pair
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- H10K50/86—Arrangements for improving contrast, e.g. preventing reflection of ambient light
- H10K50/865—Arrangements for improving contrast, e.g. preventing reflection of ambient light comprising light absorbing layers, e.g. light-blocking layers
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- H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light
- H10K59/8792—Arrangements for improving contrast, e.g. preventing reflection of ambient light comprising light absorbing layers, e.g. black layers
Definitions
- the present disclosure relates to a display device and a manufacturing method thereof.
- an organic electroluminescence display device (hereinafter simply referred to as an “organic EL display device”) using an organic electroluminescence element (hereinafter sometimes simply referred to as “organic EL element”). ” May be abbreviated as“) ”.
- the organic EL display device is a self-luminous type, has characteristics of low power consumption, and is considered to have sufficient responsiveness to high-definition high-speed video signals, Development and commercialization for practical application are underway.
- one pixel has a red light emitting layer, a sub-pixel composed of a light emitting element that emits red light, and a light emitting element that has a green light emitting layer and emits green light.
- a red light emitting layer a sub-pixel composed of a light emitting element that emits red light
- a light emitting element that has a green light emitting layer and emits green light.
- a method of forming a white light emitting layer over all pixels and coloring white light using a color filter that is, a combination of a light emitting element having a white light emitting layer (referred to as “white light emitting element”) and a red color filter.
- Red subpixel referred to as “red light emitting element”
- green subpixel referred to as “green light emitting element”
- blue by combination of white light emitting element and blue color filter
- the white light emitting layer is formed as a continuous layer over the all white light emitting element. Since it is not necessary to form a red light emitting layer, a green light emitting layer, and a blue light emitting layer for each subpixel, the pixel pitch can be reduced.
- the white light emitting layer is formed between the first electrode and the second electrode, and the first electrode is independently formed in each light emitting element, while the second electrode is formed in each light emitting element. It is common.
- the light emitted from each light emitting element is There is technology to amplify.
- a light reflecting layer is formed below the first electrode made of a transparent electrode, and the second electrode made of a semi-light transmissive material and the light reflecting material are formed.
- the resonator structure is constituted by the layers. Then, the light emitted from the light emitting layer is resonated between the light reflecting layer and the second electrode, and a part of the light is emitted from the second electrode.
- the light emitted from the light emitting layer propagates in all directions. Accordingly, as shown in the schematic partial cross-sectional view of FIG. 8, light emitted from a certain light emitting element (referred to as “adjacent light emitting element” for convenience) adjacent to a certain light emitting element (FIG. 8). May be intruded). Alternatively, multiple reflection may occur inside the display device, and light emitted from a certain light emitting element may enter an adjacent light emitting element. For the symbols in FIG. 8, see FIG. As a result, the chromaticity of the entire pixel may be deviated from the desired chromaticity.
- an object of the present disclosure is to provide a display device including a light-emitting element having a configuration and a structure in which light does not easily enter an adjacent light-emitting element, and a manufacturing method thereof.
- a method for manufacturing a display device includes: A plurality of pixels composed of the first light emitting element, the second light emitting element, and the third light emitting element are arranged in a two-dimensional matrix,
- the pixel includes a lowermost layer / interlayer insulation layer, a first interlayer insulation layer formed on the lowermost layer / interlayer insulation layer, a second interlayer insulation layer formed on the first interlayer insulation layer, and an uppermost layer / interlayer insulation.
- Each light emitting element A first electrode formed on the uppermost layer / interlayer insulating layer; An insulating film formed on a region of the uppermost layer / interlayer insulating layer where at least the first electrode is not formed; An organic layer formed on the insulating film from the first electrode and having a light emitting layer made of an organic light emitting material; and A second electrode formed on the organic layer;
- the first light emitting element includes a first light reflecting layer formed on the lowermost layer / interlayer insulating layer
- the second light emitting element includes a second light reflecting layer formed on the first interlayer insulating layer
- the third light emitting element is a method of manufacturing a display device including a third light reflecting layer formed on the second interlayer insulating layer, (A) forming a lowermost layer / interlayer insulating layer, a patterned first interlayer insulating layer, and a patterned second interlayer insulating layer; (B) After forming the light reflecting layer on the entire surface, the light reflecting layer is patterned
- a display device of the present disclosure is a display device in which a plurality of pixels each including a first light emitting element, a second light emitting element, and a third light emitting element are arranged in a two-dimensional matrix.
- the pixel includes a lowermost layer / interlayer insulation layer, a first interlayer insulation layer formed on the lowermost layer / interlayer insulation layer, a second interlayer insulation layer formed on the first interlayer insulation layer, and an uppermost layer / interlayer insulation.
- Each light emitting element A first electrode formed on the uppermost layer / interlayer insulating layer; An insulating film formed on a region of the uppermost layer / interlayer insulating layer where at least the first electrode is not formed; An organic layer formed on the insulating film from the first electrode and having a light emitting layer made of an organic light emitting material; and A second electrode formed on the organic layer;
- the first light emitting element includes a first light reflecting layer formed on the lowermost layer / interlayer insulating layer
- the second light emitting element includes a second light reflecting layer formed on the first interlayer insulating layer
- the third light emitting element includes a third light reflecting layer formed on the second interlayer insulating layer,
- the uppermost layer / interlayer insulating layer covers the lowermost layer / interlayer insulating layer, the first light reflecting layer, the second light reflecting layer, and the third light reflecting layer,
- a first groove is formed in a portion of the uppermost layer / interlayer insulating layer located in the boundary region between
- the display device since the light shielding layer is formed inside the first groove portion, the second groove portion, and the third groove portion in the step (E), the display device according to the present disclosure Since the light shielding layer is formed inside the first groove portion, the second groove portion, and the third groove portion, it is possible to manufacture a display device in which light does not easily enter the adjacent light emitting element. Moreover, in the step (D), the uppermost layer / interlayer insulating layer is formed on the entire surface, and then the uppermost layer / interlayer insulating layer is subjected to planarization treatment, so that the first groove portion, the second groove portion, and the third groove portion are so-called. It can be formed by a self-alignment method.
- the display device since the relationship between the lowest part of the bottom of the groove and the height of the top surface of the light reflection layer is defined, the contact between the groove and the light reflection layer is surely prevented. be able to.
- the groove portion and the light reflection layer are in contact with each other, there is a possibility that the emission color and the luminance may vary as a result of the capacitance change in the light emitting element. Note that the effects described in the present specification are merely examples and are not limited, and may have additional effects.
- FIG. 1 is a schematic partial cross-sectional view of the display device according to the first embodiment.
- 2A, 2B, and 2C are schematic partial end views of the lowermost layer, the interlayer insulating layer, and the like for explaining the manufacturing method of the display device of Example 1.
- FIG. 3A and 3B are schematic partial end views of the lowermost layer, the interlayer insulating layer, and the like for explaining the manufacturing method of the display device of Example 1 following FIG. 2C.
- 4A and 4B are schematic partial end views of the lowermost layer, the interlayer insulating layer, and the like for explaining the manufacturing method of the display device of Example 1 following FIG. 3B.
- FIG. 5A and 5B are schematic partial end views of the lowermost layer, the interlayer insulating layer, and the like for explaining the manufacturing method of the display device of Example 1 following FIG. 4B.
- FIG. 6 is a schematic partial end view of the lowermost layer, the interlayer insulating layer, and the like for explaining the manufacturing method of the display device of Example 1 following FIG. 5B.
- FIG. 7 is a schematic partial cross-sectional view of the display device according to the second embodiment.
- FIG. 8 is a schematic partial cross-sectional view of a display device for explaining problems of a conventional display device.
- the laminated structure of the first interlayer insulating layer, the second interlayer insulating layer, and the uppermost layer / interlayer insulating layer may be referred to as an “interlayer insulating layer / laminated structure” for convenience.
- step (C) Etching the lowermost layer / interlayer insulating layer part and the first interlayer insulating layer part located in the boundary region between the first light emitting element and the second light emitting element to form the first recess, Etching the portion of the first interlayer insulating layer and the portion of the second interlayer insulating layer located in the boundary region between the second light emitting element and the third light emitting element to form a second recess,
- the bottom layer / interlayer insulating layer portion, the first interlayer insulating layer portion, and the second interlayer insulating layer portion located in the boundary region between the first light emitting device and the third light emitting device are etched to form a third recess. It can be in the form.
- the lowest part of the bottom of the first groove and the lowest part of the bottom of the third groove are located higher than the top surface of the first light reflecting layer,
- the lowest part of the bottom part of the second groove part can be configured to be located higher than the top surface of the second light reflecting layer.
- the lowest part of the bottom part of the first groove part and the lowest part of the bottom part of the third groove part are located closer to the first light emitting element than the third light emitting element,
- the lowest part of the bottom of the second groove may be located closer to the second light emitting element than the third light emitting element.
- the display device of the present disclosure including the various preferred embodiments described above or the display device obtained by the method for manufacturing the display device of the present disclosure (hereinafter, these may be collectively referred to as “the display device of the present disclosure”).
- the display device of the present disclosure specifically, as a light shielding material constituting the light shielding layer, specifically, light such as titanium (Ti), chromium (Cr), tungsten (W), tantalum (Ta), aluminum (Al), MoSi 2 or the like is shielded.
- the material which can be mentioned can be mentioned.
- the light shielding layer can be formed by an electron beam evaporation method, a hot filament evaporation method, an evaporation method including a vacuum evaporation method, a sputtering method, a CVD method, an ion plating method, or the like.
- the groove may be formed so as to surround the light emitting element.
- the groove is formed by a so-called self-alignment method.
- the groove portion may not be completely filled with the light shielding layer.
- the light shielding layer only needs to cover at least the side surface and the bottom of the groove.
- the light shielding layer may be in contact with the first electrode. Alternatively, the light shielding layer may be grounded.
- the first light reflecting layer constituting the first light emitting element may be electrically connected to the first electrode constituting the first light emitting element, or the second light reflecting layer constituting the second light emitting element is:
- the third light emitting element may be electrically connected to the first electrode constituting the second light emitting element, and the third light reflecting layer constituting the third light emitting element may be electrically connected to the first electrode constituting the third light emitting element. It may be connected. Alternatively, each light reflecting layer may be grounded.
- the insulating film may be formed on the uppermost layer / interlayer insulating layer region where the first electrode is not formed and on the edge of the first electrode. That is, an insulating film can be formed on the uppermost layer / interlayer insulating layer and the first electrode, an opening is provided in the insulating film on the first electrode, and the first electrode can be exposed at the bottom of the opening. .
- the organic layer is formed over the insulating film from above the first electrode exposed at the bottom of the opening.
- an insulating film may be formed on the uppermost layer / interlayer insulating layer exposed between the first electrode and the first electrode. The organic layer is formed over the insulating film from above the first electrode.
- the material constituting the insulating film and the material constituting the uppermost layer / interlayer insulating layer may be the same or different.
- the display device and the like of the present disclosure can be configured by an organic electroluminescence display device (organic EL display device), and the light emitting element can be configured by an organic electroluminescence element (organic EL element). .
- organic EL display device organic electroluminescence display device
- organic EL element organic electroluminescence element
- the lowermost layer / interlayer insulating layer, the interlayer insulating layer / laminated structure, the organic layer, and the second electrode can be shared by a plurality of light emitting elements.
- the light-emitting layer can be configured to include at least two light-emitting layers that emit different colors.
- the light emitted from the organic layer is white. can do.
- the light emitting layer has a red light emitting layer that emits red light (wavelength: 620 nm to 750 nm), a green light emitting layer that emits green light (wavelength: 495 nm to 570 nm), and blue light (wavelength: 450 nm to 495 nm).
- a structure in which three layers of the blue light-emitting layer that emits light are stacked can emit white light as a whole.
- a white light emitting element that emits white light includes a red color filter to configure a red light emitting element, and a white light emitting element includes a green color filter to configure a green light emitting element, and the white light emitting element is blue.
- a blue light emitting element is formed by providing the color filter.
- One pixel is constituted by the red light emitting element, the green light emitting element, and the blue light emitting element.
- one pixel may be constituted by a red light emitting element, a green light emitting element, a blue light emitting element, and a white light emitting element (or a light emitting element that emits complementary color light).
- the light-emitting layer is composed of at least two light-emitting layers emitting different colors, the light-emitting layers emitting different colors may actually be mixed and not clearly separated into each layer. .
- the color filter is made of a resin to which a colorant composed of a desired pigment or dye is added.
- a colorant composed of a desired pigment or dye
- the light transmittance in the target wavelength range such as red, green, and blue is high.
- the light transmittance in other wavelength ranges is adjusted to be low.
- a transparent filter may be provided.
- a black matrix layer may be formed between the color filters.
- the black matrix layer is, for example, a black resin film having an optical density of 1 or more mixed with a black colorant (specifically, made of, for example, a black polyimide resin), or a thin film filter using thin film interference.
- the thin film filter is formed, for example, by stacking two or more thin films made of metal, metal nitride, or metal oxide, and attenuates light by utilizing interference of the thin film.
- Specific examples of the thin film filter include one in which Cr and chromium oxide (III) (Cr 2 O 3 ) are alternately laminated.
- a transistor (specifically, for example, a MOSFET) formed on a silicon semiconductor substrate is provided below the lowermost layer / interlayer insulating layer, although not limited thereto, and the transistor formed on the silicon semiconductor substrate.
- the first electrode and the first electrode can be connected via a contact hole (contact plug) formed in the lowermost layer / interlayer insulating layer and the interlayer insulating layer / stacked structure.
- TFTs provided on various substrates may be provided below the lowermost layer / interlayer insulating layer.
- the first electrode is provided on the interlayer insulating layer / laminated structure.
- the lowermost layer / interlayer insulating layer covers the light emitting element driving unit formed on the first substrate.
- the light emitting element driving unit is composed of one or a plurality of transistors (for example, MOSFET and TFT). As described above, the transistor and the first electrode are the lowermost layer / interlayer insulating layer and the interlayer insulating layer / laminated structure. It is electrically connected through a contact hole provided in the.
- the light emitting element driving unit can have a known circuit configuration.
- the display device includes a first substrate, a second substrate, and an image display unit sandwiched between the first substrate and the second substrate.
- a plurality of the light-emitting elements of the present disclosure including the preferable modes and configurations described above are arranged in a two-dimensional matrix.
- a light emitting element is formed on the first substrate side.
- the display device or the like of the present disclosure is a top emission type (top emission type) display device (upper emission type display device) that emits light from the second substrate.
- a color filter and a black matrix layer may be formed on the surface side of the second substrate facing the first substrate.
- a color filter may be formed on the surface side of the first substrate facing the second substrate. That is, an OCCF (on-chip color filter) may be formed on the first substrate.
- the arrangement of pixels (or subpixels) is not limited, but may be a stripe arrangement or a diagonal arrangement. Delta arrangement, stripe arrangement, or rectangle arrangement.
- a stripe arrangement can be mentioned.
- the first substrate or the second substrate is a high strain point glass substrate, soda glass (Na 2 O ⁇ CaO ⁇ SiO 2 ) substrate, borosilicate glass (Na 2 O ⁇ B 2 O 3 ⁇ SiO 2 ).
- Tic sheet can be composed of the form of a polymer material such as a plastic substrate).
- the materials constituting the first substrate and the second substrate may be the same or different. However, in the top emission display device, the second substrate is required to be transparent to light from the light emitting element.
- the first electrode functions as an anode electrode as a material constituting the first electrode, for example, indium oxide, indium-tin oxide (ITO, Indium Tin Oxide, Sn-doped In 2 O 3 , crystalline ITO and amorphous ITO), indium-zinc oxide (IZO), indium-gallium oxide (IGO), indium-doped gallium-zinc oxide (IGZO, In-GaZnO 4 ), IFO (F-doped) In 2 O 3 ), ITiO (Ti-doped In 2 O 3 ), InSn, InSnZnO, tin oxide (SnO 2 ), ATO (Sb-doped SnO 2 ), FTO (F-doped SnO 2 ), zinc oxide (ZnO ), Aluminum oxide-doped zinc oxide (AZO), gallium-doped zinc oxide (GZO), B-doped ZnO, LMgZnO (zinc oxide aluminum oxide and magnesium oxide
- the second electrode functions as a cathode electrode as a material constituting the second electrode (semi-light transmissive material or light transmissive material), the luminescent light is transmitted and electrons are efficiently transmitted to the organic layer. It is desirable to use a conductive material having a small work function so that it can be injected.
- the thickness of the second electrode include 4 nm to 50 nm, preferably 4 nm to 20 nm, and more preferably 6 nm to 12 nm.
- the second electrode is laminated from the organic layer side with the material layer described above and a so-called transparent electrode made of, for example, ITO or IZO (for example, a thickness of 3 ⁇ 10 ⁇ 8 m to 1 ⁇ 10 ⁇ 6 m). It can also be a structure.
- a bus electrode (auxiliary electrode) made of a low-resistance material such as aluminum, aluminum alloy, silver, silver alloy, copper, copper alloy, gold, or gold alloy is provided for the second electrode, thereby reducing the resistance of the second electrode as a whole. You may plan.
- the average light transmittance of the second electrode is 50% to 90%, preferably 60% to 90%.
- an electron beam evaporation method for example, an electron beam evaporation method, a hot filament evaporation method, an evaporation method including a vacuum evaporation method, a sputtering method, a chemical vapor deposition method (CVD method), an MOCVD method, an ion Combination of plating method and etching method;
- Various printing methods such as screen printing method, inkjet printing method, metal mask printing method; plating method (electroplating method and electroless plating method); lift-off method; laser ablation method; sol-gel The law etc. can be mentioned.
- the second electrode When the second electrode is formed after the organic layer is formed, the second electrode may be formed on the basis of a film forming method having a small energy of film forming particles such as a vacuum evaporation method or a film forming method such as an MOCVD method. From the viewpoint of preventing damage to the organic layer. When the organic layer is damaged, there is a possibility that a non-light emitting pixel (or non-light emitting sub-pixel) called a “dark spot” is generated due to generation of a leak current. Further, it is preferable to perform the formation from the formation of the organic layer to the formation of these electrodes without exposure to the atmosphere from the viewpoint of preventing the deterioration of the organic layer due to moisture in the atmosphere. As described above, the second electrode is preferably not a pattern but a so-called common electrode.
- the light reflecting layer As a material constituting the light reflecting layer, the first light reflecting layer, the second light reflecting layer, and the third light reflecting layer, aluminum, an aluminum alloy (for example, Al—Nd or Al—Cu), an Al / Ti laminated structure, Al -Cu / Ti laminated structure, chromium (Cr), silver (Ag), silver alloy (for example, Ag-Pd-Cu, Ag-Sm-Cu), for example, electron beam evaporation method or hot filament evaporation Vapor deposition method including vacuum deposition method, sputtering method, CVD method and ion plating method; plating method (electroplating method and electroless plating method); lift-off method; laser ablation method; sol-gel method Can do.
- an aluminum alloy for example, Al—Nd or Al—Cu
- an Al / Ti laminated structure Al -Cu / Ti laminated structure
- Cr chromium
- silver silver
- silver alloy for example, Ag-Pd-Cu, Ag-Sm-Cu
- the organic layer includes a light emitting layer made of an organic light emitting material.
- a light emitting layer made of an organic light emitting material.
- a stacked structure of a hole transport layer, a light emitting layer, and an electron transport layer and also serves as a hole transport layer and an electron transport layer.
- a layered structure with a light emitting layer, a layered structure with a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer can be used.
- a physical vapor deposition method such as a vacuum deposition method
- a printing method such as a screen printing method or an ink jet printing method
- the laser transfer method and various coating methods include separating the organic layer on the laser absorption layer by irradiating the structure with laser and transferring the organic layer.
- the organic layer can be obtained by depositing a material that has passed through an opening provided in the metal mask. As described above, it may be formed on the entire surface without patterning. In some cases, at least a part of the organic layer (specifically, for example, a hole injection layer) may be discontinuous at the end of the insulating film.
- the protective film is less affected by the formation of the protective film, particularly by a film forming method such as a vacuum vapor deposition method with a small energy of film forming particles or a film forming method such as a CVD method or a MOCVD method. This is preferable.
- the film forming temperature is set to room temperature, and further, in order to prevent the protective film from peeling off, the protective film is used under the condition that the stress of the protective film is minimized. It is desirable to form a film.
- the protective film is preferably formed without exposing the already formed electrode to the atmosphere, whereby the organic layer can be prevented from being deteriorated by moisture or oxygen in the atmosphere.
- the protective film is made of a material that transmits light generated in the organic layer by, for example, 80% or more.
- an inorganic amorphous insulating material for example, the following materials is exemplified. can do. Since such an inorganic amorphous insulating material does not generate grains, it has low water permeability and constitutes a good protective film.
- amorphous silicon ⁇ -Si
- amorphous silicon carbide ⁇ -SiC
- amorphous silicon nitride ⁇ -Si 1-x N x
- amorphous silicon oxide ⁇ -Si 1-y O y
- amorphous carbon ⁇ -C
- ⁇ -SiON amorphous oxide / silicon nitride
- the protective film When the protective film is made of a conductive material, the protective film may be made of a transparent conductive material such as ITO, IZO, or IGZO.
- the protective film and the second substrate are bonded via, for example, a resin layer (sealing resin layer).
- Thermosetting adhesives such as acrylic adhesives, epoxy adhesives, urethane adhesives, silicone adhesives, cyanoacrylate adhesives, and ultraviolet curable adhesives are used as the material for the resin layer (sealing resin layer). Mention may be made of adhesives.
- an ultraviolet absorbing layer On the outermost surface (outer surface of the second substrate) that emits light of the display device, an ultraviolet absorbing layer, a contamination prevention layer, a hard coat layer, an antistatic layer may be formed, or a protective member may be provided. .
- interlayer insulating layer / laminated structure or insulating film As the insulating material constituting the lowermost layer / interlayer insulating layer, interlayer insulating layer / laminated structure or insulating film, SiO 2 , NSG (non-doped silicate glass), BPSG (boron / phosphorus / Silicate glass), PSG, BSG, AsSG, SbSG, PbSG, SOG (spin on glass), LTO (Low Temperature Oxide, low temperature CVD-SiO 2 ), low melting glass, glass paste, and other SiO X- based materials (silicon-based oxidation) Materials constituting the film); SiN-based materials including SiON-based materials; SiOC; SiOF; SiCN.
- inorganic insulating materials such as (Nb 2 O 5 ), tin oxide (SnO 2 ), and vanadium oxide (VO x ).
- fluorocarbon cycloperfluorocarbon polymer
- benzocyclobutene cyclic fluororesin, polytetrafluoroethylene, amorphous tetrafluoroethylene, polyaryl ether, fluorinated aryl ether, fluorinated Polyimide, amorphous carbon, parylene (polyparaxylylene), and fullerene fluoride
- Silk a trademark of The Dow Chemical Co., a coating type low dielectric constant interlayer insulating film material
- Flare Heneywell
- Polyallyl is a trademark of Electronic Materials Co. Ether and (PAE) type material
- Interlayer insulating layers and insulating films can be formed by various CVD methods, various coating methods, various PVD methods including sputtering and vacuum deposition methods, various printing methods such as screen printing methods, plating methods, electrodeposition methods, immersion methods, sol-gel methods. It can form based on well-known methods, such as.
- the organic EL display device preferably has a resonator structure in order to further improve the light extraction efficiency. Specifically, it is composed of a first interface constituted by an interface between a light reflecting layer provided below the first electrode and an interlayer insulating layer located thereon, and an interface between the second electrode and the organic layer. The light emitted from the light emitting layer is resonated with the second interface, and a part of the light is emitted from the second electrode.
- the distance from the maximum light emission position of the light emitting layer to the first interface is L 1
- the optical distance is OL 1
- the distance from the maximum light emission position of the light emitting layer to the second interface is L 2
- the optical distance is OL 2
- m When 1 and m 2 are integers, the following expressions (1-1), (1-2), (1-3), and (1-4) are satisfied.
- ⁇ Maximum peak wavelength of light spectrum generated in the light emitting layer (or a desired wavelength in the light generated in the light emitting layer)
- ⁇ 1 Phase shift amount of light reflected from the first interface (unit: radians)
- -2 ⁇ ⁇ 1 ⁇ 0 ⁇ 2 Phase shift amount of light reflected by the second interface (unit: radians)
- the distance L 1 from the maximum light emitting position of the light emitting layer to the first interface refers to the actual distance (physical distance) from the maximum light emitting position of the light emitting layer to the first interface, and from the maximum light emitting position of the light emitting layer.
- the distance L 2 to the second interface refers to the actual distance (physical distance) from the maximum light emission position of the light emitting layer to the second interface.
- the optical distance is also called an optical path length, and generally indicates n ⁇ L when a light beam passes through a medium having a refractive index n by a distance L. The same applies to the following.
- the average refractive index n ave is the sum of the products of the refractive index and the thickness of each layer constituting the organic layer and the interlayer insulating layer, and divided by the thickness of the organic layer and the interlayer insulating layer.
- the light reflecting layer and the second electrode absorb a part of the incident light and reflect the rest. Therefore, a phase shift occurs in the reflected light.
- the phase shift amounts ⁇ 1 and ⁇ 2 are calculated based on the values of the real part and the imaginary part of the complex refractive index of the material constituting the light reflecting layer and the second electrode, for example, using an ellipsometer. (See, for example, “Principles of Optic”, Max Born and Emil Wolf, 1974 (PERGAMON PRESS)).
- the refractive index of the organic layer, interlayer insulating layer, etc. can also be obtained by measuring using an ellipsometer.
- the red light emitting element configured by the white light emitting element including the red color filter actually resonates the red light emitted from the light emitting layer.
- reddish light (light having a light spectrum peak in the red region) is emitted from the second electrode.
- a green light-emitting element configured by providing a white light-emitting element with a green color filter resonates green light emitted from the light-emitting layer to produce greenish light (light having a light spectrum peak in the green region). ) Is emitted from the second electrode.
- the blue light emitting element configured by including the blue color filter in the white light emitting element resonates the blue light emitted from the light emitting layer, and has bluish light (having a peak of the light spectrum in the blue region).
- Light is emitted from the second electrode. That is, a desired wavelength ⁇ (specifically, a red wavelength, a green wavelength, and a blue wavelength) of the light generated in the light emitting layer is determined, and the equations (1-2) and (1-2) are determined. Based on the equations (1-3) and (1-4), various parameters such as OL 1 and OL 2 in the red light emitting device, the green light emitting device, and the blue light emitting device are obtained, and each light emitting device is designed. That's fine.
- paragraph number [0041] of Japanese Patent Application Laid-Open No. 2012-216495 discloses an organic EL element having a resonator structure in which a light emitting layer (organic layer) is a resonance part, and the distance from a light emitting point to a reflecting surface is disclosed. It is described that the thickness of the organic layer is preferably 80 nm or more and 500 nm or less, and more preferably 150 nm or more and 350 nm or less in order to enable appropriate adjustment.
- the thickness of the hole transport layer (hole supply layer) and the thickness of the electron transport layer (electron supply layer) are substantially equal.
- the electron transport layer (electron supply layer) may be thicker than the hole transport layer (hole supply layer), which is necessary for high efficiency with a low driving voltage and sufficient for the light emitting layer.
- Electronic supply is possible.
- the hole transport layer is disposed between the first electrode corresponding to the anode electrode and the light emitting layer, and the film is formed with a film thickness thinner than that of the electron transport layer, thereby increasing the supply of holes. It becomes possible.
- the display device can be used, for example, as a monitor device constituting a personal computer, or used as a monitor device incorporated in a television receiver, a mobile phone, a PDA (personal digital assistant), or a game machine. can do.
- the present invention can be applied to an electronic view finder (EVF) or a head mounted display (HMD).
- EVF electronic view finder
- HMD head mounted display
- electronic papers such as electronic books and electronic newspapers, bulletin boards such as signboards, posters, and blackboards, rewritable papers that replace printer paper, display units for home appliances, card display units such as point cards, images for electronic advertisements, and electronic POPs
- a display device can be configured.
- the display device of the present disclosure can be used as a light emitting device, and various lighting devices including a backlight device for a liquid crystal display device and a planar light source device can be configured.
- a head-mounted display is, for example, (A) a frame to be worn on the observer's head; and (B) an image display device attached to the frame; With The image display device (A) the display device of the present disclosure, and (B) an optical device that receives and emits light emitted from the display device of the present disclosure; With The optical device (B-1) A light guide plate that emits light incident from the display device of the present disclosure toward an observer after propagating inside by total reflection; (B-2) First deflecting means (for example, comprising a volume hologram diffraction grating film) for deflecting the light incident on the light guide plate so that the light incident on the light guide plate is totally reflected inside the light guide plate ,as well as, (B-3) Second deflection means for deflecting the light propagated in
- Example 1 relates to a display device of the present disclosure and a manufacturing method thereof.
- FIG. 1 is a schematic partial cross-sectional view of a display device of the present disclosure.
- the display device of Example 1 is specifically composed of an organic EL display device, and the light emitting element of Example 1 is specifically composed of an organic EL element.
- the display device in Example 1 or the display device in the method for manufacturing the display device in Example 1 is: A plurality of pixels composed of the first light emitting element 10R, the second light emitting element 10G, and the third light emitting element 10B are arranged in a two-dimensional matrix,
- the pixel includes a lowermost layer / interlayer insulating layer 30, a first interlayer insulating layer 31 formed on the lowermost layer / interlayer insulating layer 30, a second interlayer insulating layer 32 formed on the first interlayer insulating layer 31, and It has an uppermost layer / interlayer insulating layer 33,
- Each light emitting element 10R, 10G, 10B A first electrode 51 formed on the uppermost layer / interlayer insulating layer 33;
- An insulating film 60 formed on at least the region of the uppermost layer / interlayer insulating layer 33 where the first electrode 51 is not formed;
- An organic layer 53 formed on the insulating film 60 from the first electrode 51 and having a light emitting layer made of an organic
- the uppermost layer / interlayer insulating layer 33 covers the lowermost layer / interlayer insulating layer 30, the first light reflecting layer 36R, the second light reflecting layer 36G, and the third light reflecting layer 36B,
- the portion of the first light emitting element 10R and the uppermost-interlayer insulating layer 33 located at the boundary region between the second light emitting element 10G is formed the first groove 42 1
- the portion of the uppermost-interlayer insulating layer 33 located at the boundary region between the second light emitting element 10G and the third light emitting element 10B is formed the second groove 42 2
- the portion of the uppermost-interlayer insulating layer 33 located at the boundary region between the first light emitting element 10R and the third light emitting element 10B are formed third groove 42 3.
- a light shielding layer 44 is formed inside the first groove part 42 1 , the second groove part 42 2 and the third groove part 42 3 ,
- the lowest portion and the third groove portion 42 3 lowest portion of the bottom 43 3 of the first groove 42 1 of the base portion 43 1 is located at a higher than the top surface of the first light reflecting layer 36R,
- the lowest part of the bottom part 43 2 of the second groove part 42 2 is located higher than the top surface of the second light reflecting layer 36G.
- the lowest portion of the bottom 43 1 of the first groove part 42 1, the lowest part of the bottom 43 of the second groove portion 42 2, and the third groove 42 3 bottom 43 3 lowest portion of the bottom layer - interlayer The portion closest to the insulating layer 30 is indicated.
- the lowest portion and lowest portion of the third groove 42 3 of the bottom 43 3 of the bottom 43 1 of the first groove 42 1 is located closer to the first light emitting element 10R than the third light emitting element 10B
- the lowest portion of the bottom portion 43 2 of the second groove portion 42 2 is located closer to the second light emitting element 10G than the third light emitting element 10B.
- the first interlayer insulating layer 31, the second interlayer insulating layer 32, and the uppermost layer / interlayer insulating layer 33 are collectively referred to as an interlayer insulating layer / laminated structure 34.
- the lowermost layer / interlayer insulating layer 30, the interlayer insulating layer / laminated structure 34, the organic layer 53, and the second electrode 52 are shared by a plurality of light emitting elements.
- the insulating film 60 extends to the edge of the first electrode 51.
- the display device of Example 1 includes the first substrate 11, the second substrate 12, and the image display unit 13 sandwiched between the first substrate 11 and the second substrate 12, In the image display unit 13, a plurality of light emitting elements 10R, 10G, and 10B of Example 1 are arranged in a two-dimensional matrix.
- a light emitting element is formed on the first substrate 11 side.
- the display device according to the first embodiment is a top emission type (upper surface light emission type) display device (upper surface light emission type display device) that emits light from the second substrate 12.
- color filters CF R , CF G , CF B and a black matrix layer BM are formed on the surface side of the second substrate 12 facing the first substrate 11.
- One light-emitting element constitutes one subpixel.
- One pixel includes three light emitting elements, a red light emitting element 10R, a green light emitting element 10G, and a blue light emitting element 10B.
- the second substrate 12 includes color filters CF R , CF G , and CF B.
- the organic EL element emits white light
- each of the light emitting elements 10R, 10G, and 10B includes a combination of a white light emitting element that emits white light and color filters CF R , CF G , and CF B. That is, the light emitting layer emits white light as a whole.
- a black matrix layer BM is provided between the color filters.
- the number of pixels is 1920 ⁇ 1080, for example, one light emitting element (display element) constitutes one subpixel, and the number of light emitting elements (specifically, organic EL elements) is three times the number of pixels.
- the first electrode 51 functions as an anode electrode
- the second electrode 52 functions as a cathode electrode.
- the first electrode 51 is made of a transparent conductive material such as ITO having a thickness of 0.01 ⁇ m to 0.1 ⁇ m
- the second electrode 52 is made of an Mg—Ag alloy having a thickness of 4 nm to 20 nm.
- the first electrode 51 is formed based on a combination of a vacuum deposition method and an etching method.
- the second electrode 52 is formed by a film forming method in which the energy of the film forming particles is low, such as vacuum deposition, and is not patterned.
- the organic layer 53 is also not patterned.
- the first light reflecting layer 36R, the second light reflecting layer 36G, and the third light reflecting layer 36B have a laminated structure of aluminum (Al) -copper (Cu) / titanium (Ti). Furthermore, the first substrate 11 is made of a silicon semiconductor substrate, and the second substrate 12 is made of a glass substrate.
- the light shielding layer 44 is made of tungsten (W), the lowermost layer / interlayer insulating layer 30 is made of SiO 2 , the first interlayer insulating layer 31 is made of SiN, and the second interlayer insulating layer 32 is made of SiO 2 , The upper layer / interlayer insulating layer 33 is made of SiO 2 and the insulating film 60 is made of SiON, but is not limited to these materials.
- the organic layer 53 includes a hole injection layer (HIL), a hole transport layer (HTL), a light emitting layer, an electron transport layer (ETL), and It has a laminated structure of an electron injection layer (EIL).
- the light emitting layer is composed of at least two light emitting layers that emit different colors, and the light emitted from the organic layer 53 is white.
- the light emitting layer has a structure in which three layers of a red light emitting layer that emits red light, a green light emitting layer that emits green light, and a blue light emitting layer that emits blue light are stacked.
- the light-emitting layer may have a structure in which two layers of a blue light-emitting layer that emits blue light and a yellow light-emitting layer that emits yellow light are stacked, a blue light-emitting layer that emits blue light, and an orange light-emitting layer.
- a structure in which two orange light-emitting layers are stacked can be employed.
- the red light emitting element 10R should display red is provided with a red color filter CF R
- the green light emitting element 10G to be displayed green is provided with a green color filter CF G
- blue to be displayed blue the light emitting element 10B is provided with a blue color filter CF B.
- the red light emitting element 10R, the green light emitting element 10G, and the blue light emitting element 10B have the same configuration and structure except for the position of the color filter and the light reflection layer.
- a black matrix layer BM is formed between the color filter CF and the color filter CF.
- the color filter CF and the black matrix layer BM are formed on the surface side of the second substrate 12 facing the first substrate 11. As a result, the distance between the light emitting layer and the color filter CF can be shortened, and light emitted from the light emitting layer can be prevented from entering the adjacent color filter CF and causing color mixing. .
- the hole injection layer is a layer that increases the hole injection efficiency and functions as a buffer layer that prevents leakage, and has a thickness of, for example, about 2 nm to 10 nm.
- the hole injection layer is made of, for example, a hexaazatriphenylene derivative represented by the following formula (A) or formula (B).
- R 1 to R 6 are each independently hydrogen, halogen, hydroxy group, amino group, arylamino group, substituted or unsubstituted carbonyl group having 20 or less carbon atoms, substituted or unsubstituted group having 20 or less carbon atoms.
- Substituted carbonyl ester group substituted or unsubstituted alkyl group having 20 or less carbon atoms, substituted or unsubstituted alkenyl group having 20 or less carbon atoms, substituted or unsubstituted alkoxy group having 20 or less carbon atoms, and having 30 or less carbon atoms
- X 1 to X 6 are each independently a carbon or nitrogen atom.
- the hole transport layer is a layer that increases the efficiency of transporting holes to the light emitting layer. In the light emitting layer, when an electric field is applied, recombination of electrons and holes occurs to generate light.
- the electron transport layer is a layer that increases the efficiency of electron transport to the light emitting layer
- the electron injection layer is a layer that increases the efficiency of electron injection to the light emitting layer.
- the hole transport layer is made of, for example, 4,4 ′, 4 ′′ -tris (3-methylphenylphenylamino) triphenylamine ⁇ m-MTDATA> or ⁇ -naphthylphenyldiamine ⁇ NPD> having a thickness of about 40 nm. .
- the light-emitting layer is a light-emitting layer that generates white light by mixing colors, and is formed by stacking, for example, a red light-emitting layer, a green light-emitting layer, and a blue light-emitting layer as described above.
- red light emitting layer when an electric field is applied, a part of holes injected from the first electrode 51 and a part of electrons injected from the second electrode 52 are recombined to generate red light. To do.
- a red light emitting layer includes, for example, at least one material among a red light emitting material, a hole transporting material, an electron transporting material, and a charge transporting material.
- the red light emitting material may be a fluorescent material or a phosphorescent material.
- a red light-emitting layer having a thickness of about 5 nm can be formed by, for example, using 4,4-bis (2,2-diphenylvinyl) biphenyl ⁇ DPVBi> and 2,6-bis [(4′-methoxydiphenylamino) styryl] -1 , 5-dicyanonaphthalene ⁇ BSN> mixed with 30% by mass.
- Such a green light emitting layer when an electric field is applied, a part of holes injected from the first electrode 51 and a part of electrons injected from the second electrode 52 are recombined to generate green light. To do.
- a green light emitting layer contains, for example, at least one material among a green light emitting material, a hole transporting material, an electron transporting material, and a charge transporting material.
- the green light emitting material may be a fluorescent material or a phosphorescent material.
- the green light emitting layer having a thickness of about 10 nm is made of, for example, DPVBi mixed with 5% by mass of coumarin 6.
- Such a blue light emitting layer when an electric field is applied, a part of holes injected from the first electrode 51 and a part of electrons injected from the second electrode 52 are recombined to generate blue light. To do.
- a blue light emitting layer contains, for example, at least one material among a blue light emitting material, a hole transporting material, an electron transporting material, and a charge transporting material.
- the blue light emitting material may be a fluorescent material or a phosphorescent material.
- the blue light-emitting layer having a thickness of about 30 nm is, for example, 2.5% by mass of 4,4′-bis [2- ⁇ 4- (N, N-diphenylamino) phenyl ⁇ vinyl] biphenyl ⁇ DPAVBi> in DPVBi. Consists of a mixture.
- the electron transport layer having a thickness of about 20 nm is made of, for example, 8-hydroxyquinoline aluminum ⁇ Alq3>.
- the electron injection layer having a thickness of about 0.3 nm is made of, for example, LiF or Li 2 O.
- An insulating or conductive protective film 14 (specifically, for example, made of SiN, ITO, IGZO, or IZO) is provided above the second electrode 52 for the purpose of preventing moisture from reaching the organic layer 53. It has been.
- the protective film 14 and the second substrate 12 are bonded via a resin layer (sealing resin layer) 15 made of, for example, an epoxy adhesive.
- the lowermost layer / interlayer insulating layer 30, the interlayer insulating layer / laminated structure 34, the organic layer 53, and the second electrode 52 are shared by a plurality of light emitting elements. That is, the lowermost layer / interlayer insulating layer 30, the interlayer insulating layer / laminated structure 34, the organic layer 53, and the second electrode 52 are not patterned and are in a so-called solid film state.
- the angle of view is several inches or less, A small and high-resolution display device having a pixel pitch of several tens of micrometers or less can also be supported.
- the light emitting element has a resonator structure in which the organic layer 53 is a resonance part.
- the thickness of the organic layer 53 is adjusted. Is preferably 8 ⁇ 10 ⁇ 8 m or more and 5 ⁇ 10 ⁇ 7 m or less, more preferably 1.5 ⁇ 10 ⁇ 7 m or more and 3.5 ⁇ 10 ⁇ 7 m or less.
- the red light emitting element 10R actually resonates the red light emitted from the light emitting layer to produce reddish light (the peak of the light spectrum in the red region). ) From the second electrode 52.
- the green light emitting element 10 ⁇ / b> G resonates green light emitted from the light emitting layer and emits greenish light (light having a light spectrum peak in a green region) from the second electrode 52.
- the blue light emitting element 10 ⁇ / b> B resonates the blue light emitted from the light emitting layer and emits bluish light (light having a light spectrum peak in a blue region) from the second electrode 52.
- Example 1 a transistor (specifically, for example, a MOSFET) 20 formed on a silicon semiconductor substrate (first substrate 11) is provided below the lowermost layer / interlayer insulating layer 30.
- the first electrode 51 and the transistor 20 formed on the silicon semiconductor substrate (first substrate 11) are contact holes (contact plugs) formed in the lowermost layer / interlayer insulating layer 30 and the interlayer insulating layer / stacked structure 34. ) Is connected through.
- the contact hole is not shown.
- the transistor 20 made of a MOSFET is composed of a gate electrode 21, a gate insulating layer 22, a channel formation region 23, and a source / drain region 24, and an element isolation region 25 is formed between the transistors 20. Thereby, the transistors 20 are isolated from each other.
- FIGS. 2A, 2B, 2C, 3A, 3B, 4A, 4B, 5A, 5B, and 6 which are schematic partial end views of the lowermost layer and the interlayer insulating layer, etc. A method for manufacturing the display device according to the first embodiment will be described.
- a light emitting element driving unit is formed on a silicon semiconductor substrate (first substrate 11) based on a known MOSFET manufacturing process.
- a lowermost layer / interlayer insulating layer 30, a patterned first interlayer insulating layer 31, and a patterned second interlayer insulating layer 32 are formed. Specifically, after the lowermost layer / interlayer insulating layer 30 is formed on the entire surface based on the CVD method, the first interlayer insulating layer 31 and the second interlayer insulating layer 32 are formed on the lowermost layer / interlayer insulating layer 30 based on the CVD method. Are sequentially formed. Then, based on the well-known RIE method, the second interlayer insulating layer 32 is patterned, and further, the first interlayer insulating layer 31 is patterned. In this way, the structure shown in FIG. 2A can be obtained.
- Step-120 Then, after forming the light reflection layer 35 on the entire surface based on the sputtering method (see FIG. 2B), the resist layer 37 is formed based on the photolithography technique. In this way, the structure shown in FIG. 2C can be obtained.
- the light reflection layer 35 is patterned based on a well-known RIE method.
- the first light reflecting layer 36R is formed on the lowermost layer / interlayer insulating layer 30 region where the first light emitting element 10R is to be formed, and the first light emitting element 10G is formed on the first interlayer insulating layer 31 region.
- the second light reflecting layer 36G can be formed, and the third light reflecting layer 36B can be formed on the region of the second interlayer insulating layer 32 where the third light emitting element 10B is to be formed (see FIG. 3A).
- Step-130 Thereafter, at least a portion of the first interlayer insulating layer 31 located in the boundary region between the first light emitting element 10R and the second light emitting element 10G (specifically, in Example 1, the first light emitting element 10R and the first light emitting element 10R
- the first recess 41 1 is formed by etching the lowermost layer / interlayer insulating layer 30 and the first interlayer insulating layer 31) located in the boundary region with the two light emitting elements 10G.
- the second interlayer insulating layer 32 located in the boundary region between the second light emitting element 10G and the third light emitting element 10B (specifically, in Example 1, the second light emitting element 10G and third forming the light-emitting element 10B and the first interlayer insulating layer 31 portion and the second concave portion 41 2 parts) by etching the second interlayer insulating layer 32 located in the boundary region.
- the first interlayer insulating layer 31 and a portion of the second interlayer insulating layer 32 located in the boundary region between the first light emitting element 10R and the third light emitting element 10B (specifically, in Example 1, Includes a lowermost layer / interlayer insulating layer 30 part, a first interlayer insulating layer 31 part, and a second interlayer insulating layer 32 part) located in the boundary region between the first light emitting element 10R and the third light emitting element 10B).
- Etching forms the third recess 41 3 . See FIG. 3B and FIG. 4A for the above process.
- the resist layer 37 is removed. In this way, the structure shown in FIG. 4B can be obtained.
- the uppermost layer / interlayer insulating layer 33 is planarized based on the CMP method.
- the first groove portion 42 1 and the second groove portion 42 are formed in the uppermost layer / interlayer insulating layer 33 above the first recess portion 41 1 , the second recess portion 41 2 and the third recess portion 41 3. forming the second and third grooves 42 3.
- These groove portions 42 1 , 42 2 , and 42 3 are formed by a self-alignment method.
- the light shielding layer 44 is formed inside the first groove portion 42 1 , the second groove portion 42 2, and the third groove portion 42 3 .
- a tungsten layer is formed on the entire surface based on the tungsten CVD method, and the tungsten layer on the uppermost layer / interlayer insulating layer 33 is removed based on the CMP method. In this way, the structure shown in FIG. 6 can be obtained.
- the lowest portion and the third groove portion 42 3 lowest portion of the bottom 43 3 of the first groove 42 1 of the base portion 43 1 is located at a higher than the top surface of the first light reflecting layer 36R
- the second groove 42 the lowest portion of the second bottom section 43 3 is located at a higher than the top surface of the second light reflecting layer 36G.
- the lowest portion and the third groove 42 3 lowest portion of the bottom 43 3 of the bottom 43 1 of the first groove 42 1, than the third light emitting element 10B is located closer to the first light emitting element 10R
- the lowest portion of the bottom portion 43 2 of the second groove portion 42 2 is located closer to the second light emitting element 10G than the third light emitting element 10B.
- a connection hole is formed in the lowermost layer / interlayer insulating layer 30 and the interlayer insulating layer / stacked structure 34 located above one source / drain region of the transistor 20 based on the photolithography technique and the etching technique. .
- a metal layer is formed on the uppermost layer / interlayer insulating layer 33 including the connection hole based on, for example, a sputtering method, and then the metal layer is patterned based on a photolithography technique and an etching technique, thereby forming the uppermost layer /
- the first electrode 51 can be formed on the interlayer insulating layer 33. The first electrode 51 is separated for each light emitting element.
- a contact hole (contact plug) (not shown) that electrically connects the first electrode 51 and the transistor 20 can be formed in the connection hole.
- Step-170 for example, after forming the insulating film 60 on the entire surface based on the CVD method, the opening 61 is formed in a part of the insulating film 60 on the first electrode 51 based on the photolithography technique and the etching technique. The first electrode 51 is exposed at the bottom of the opening 61.
- the organic layer 53 is formed on the first electrode 51 and the insulating film 60 by, for example, a PVD method such as a vacuum deposition method or a sputtering method, a coating method such as a spin coating method or a die coating method.
- the second electrode 52 is formed on the entire surface of the organic layer 53 based on, for example, a vacuum deposition method or the like. In this manner, the organic layer 53 and the second electrode 52 can be continuously formed on the first electrode 51, for example, in a vacuum atmosphere.
- the protective film 14 is formed on the entire surface by, eg, CVD or PVD. Finally, the protective film 14 and the second substrate 12 are bonded together via the resin layer (sealing resin layer) 15.
- color filters CF R , CF G , CF B , and a black matrix layer BM are formed on the second substrate 12 in advance.
- the surface on which the color filter CF is formed is used as a bonding surface.
- the organic EL display device shown in FIG. 1 can be obtained.
- the uppermost layer / interlayer insulating layer 33 is formed on the entire surface, and then the uppermost layer / interlayer insulating layer 33 is subjected to a planarization process, whereby the first groove portion 42 1 and the second groove portion 42 2 are formed. and since the third groove 42 3 can be formed by a so-called self-alignment manner, it is possible to cope with the miniaturization of the light emitting element. Furthermore, since the height relationship between the lowest portions of the bottom portions 43 1 , 43 2 , and 43 3 of the groove portions and the top surfaces of the light reflecting layers 36R, 36G, and 36B is defined, the groove portions 42 1 , 42 2 , and 42 3 are defined. And the light reflecting layers 36R, 36G, and 36B can be reliably prevented from coming into contact with each other, and the occurrence of a problem that the emission color varies can be avoided.
- the second embodiment is a modification of the first embodiment.
- the insulating film 62 made of SiON or SiO 2 or polyimide resin is a region of the uppermost layer / interlayer insulating layer 33 where the first electrode 51 is not formed. Is formed on top.
- the organic layer 53 is formed on the flat first electrode 51 and the insulating film 62 as a whole, and the organic layer 53 is also flat. As described above, by forming the organic layer 53 on the first flat electrode 51 and the insulating film 62 as a whole, it is possible to prevent a problem such as abnormal light emission at the end of the opening of the insulating film. .
- the insulating film 62 is formed on the entire surface based on the CVD method, and then planarization is performed.
- the insulating film 62 may be left on the region of the uppermost layer / interlayer insulating layer 33 where the first electrode 51 is not formed.
- the light-emitting element and display device of Example 2 can be configured and structured in the same manner as the light-emitting element and display device of Example 1, and thus detailed description thereof is omitted.
- Example 3 is also a modification of Example 1.
- Example 3 when the organic layer 53 is formed, at least a part of the organic layer 53 (specifically, for example, a hole injection layer) is used as an insulating film.
- the edge portion of the opening 61 provided in the insulating film 60 is in a discontinuous state.
- the hole injection layer is increased in resistance, and the first electrode in a certain light emitting element and the second light emitting element constituting the adjacent light emitting element are formed. Occurrence of a phenomenon such as leakage current flowing between the electrodes can be reliably prevented.
- a second insulating film having an end portion (a bowl-shaped end portion) protruding from the opening 61 is formed on the insulating film 60 to form the second insulation.
- At least a part of the hole injection layer may be discontinuous at the protruding end of the film.
- a kind of sacrificial layer is formed on the entire surface.
- the insulating film 60 is formed, and the opening 61 is formed in a part of the insulating film 60.
- the sacrificial layer is exposed at the bottom of the opening 61.
- a sacrificial layer formed in the uppermost layer / interlayer insulating layer 33 located between the first electrode 51 and the first electrode 51 is covered with an insulating film 60. Then, the portion of the sacrificial layer exposed at the bottom of the opening 61 is removed.
- a gap is generated between the first electrode 51 and the portion of the insulating film 60 located above the first electrode 51 by removing the sacrificial layer. That is, the portion of the insulating film 60 located above the first electrode 51 is a kind of bowl. Therefore, if the hole injection layer is formed in this state, at least a part of the hole injection layer can be in a discontinuous state.
- the present disclosure has been described based on the preferred embodiments, the present disclosure is not limited to these embodiments.
- the configuration of the display device (organic EL display device) and the light emitting element (organic EL element) described in the embodiments and the configuration of the structure are examples, and can be changed as appropriate.
- the method for manufacturing the display device is also an example. It can be changed as appropriate.
- one pixel is composed of three subpixels exclusively from a combination of a white light emitting element and a color filter.
- one pixel is composed of four subpixels including a light emitting element that emits white light. May be.
- the light emitting element driving unit is configured by a MOSFET, but may be configured by a TFT.
- the lowermost layer / interlayer insulating layer, the patterned first interlayer insulating layer, and the patterned second interlayer insulating layer are formed, and then the light reflecting layer is formed on the entire surface, and then the light reflecting layer is formed.
- the first light reflection layer, the second light reflection layer, and the third light reflection layer were formed by patterning, and then the first recess, the second recess, and the third recess were formed. Steps (A), (B), and (C) in the method for manufacturing a display device have been performed.
- [Step-A] forming a first light reflecting layer on the region of the lowermost layer / interlayer insulating layer where the first light emitting element is to be formed; [Step-B] After forming the first interlayer insulating layer on the lowermost layer / interlayer insulating layer, forming the second light reflecting layer on the first interlayer insulating layer, and then [Step-C] After forming the second interlayer insulating layer on the first interlayer insulating layer, forming the third light reflecting layer on the second interlayer insulating layer, [Step-D] The desired regions of the second interlayer insulating layer, the first interlayer insulating layer, and the lowermost layer / interlayer insulating layer are removed by etching, At least in the first interlayer insulating layer portion (specifically, for example, the lowermost layer / interlayer insulating layer portion and the first interlayer insulating layer portion) located in the boundary region between the first light emitting element and the second light emitting element.
- this indication can also take the following structures.
- a plurality of pixels composed of the first light emitting element, the second light emitting element, and the third light emitting element are arranged in a two-dimensional matrix,
- the pixel includes a lowermost layer / interlayer insulation layer, a first interlayer insulation layer formed on the lowermost layer / interlayer insulation layer, a second interlayer insulation layer formed on the first interlayer insulation layer, and an uppermost layer / interlayer insulation.
- Each light emitting element A first electrode formed on the uppermost layer / interlayer insulating layer; An insulating film formed on a region of the uppermost layer / interlayer insulating layer where at least the first electrode is not formed; An organic layer formed on the insulating film from the first electrode and having a light emitting layer made of an organic light emitting material; and A second electrode formed on the organic layer;
- the first light emitting element includes a first light reflecting layer formed on the lowermost layer / interlayer insulating layer
- the second light emitting element includes a second light reflecting layer formed on the first interlayer insulating layer
- the third light emitting element is a method of manufacturing a display device including a third light reflecting layer formed on the second interlayer insulating layer, (A) forming a lowermost layer / interlayer insulating layer, a patterned first interlayer insulating layer, and a patterned second interlayer insulating layer; (B) After forming the light reflecting layer on the entire surface, the light reflecting layer is patterned
- step (C) Etching the lowermost layer / interlayer insulating layer part and the first interlayer insulating layer part located in the boundary region between the first light emitting element and the second light emitting element to form the first recess, Etching the portion of the first interlayer insulating layer and the portion of the second interlayer insulating layer located in the boundary region between the second light emitting element and the third light emitting element to form a second recess,
- the bottom layer / interlayer insulating layer portion, the first interlayer insulating layer portion, and the second interlayer insulating layer portion located in the boundary region between the first light emitting device and the third light emitting device are etched to form a third recess.
- the lowest part of the bottom of the first groove and the lowest part of the bottom of the third groove are located higher than the top surface of the first light reflecting layer, The method for manufacturing a display device according to [A01] or [A02], wherein the lowest portion of the bottom of the second groove is located higher than the top surface of the second light reflecting layer.
- the lowest portion of the bottom of the first groove and the lowest portion of the bottom of the third groove are located closer to the first light emitting element than the third light emitting element, The method for manufacturing a display device according to any one of [A01] to [A03], wherein the lowest portion of the bottom of the second groove is located closer to the second light emitting element than the third light emitting element.
- a display device in which a plurality of pixels composed of a first light emitting element, a second light emitting element, and a third light emitting element are arranged in a two-dimensional matrix,
- the pixel includes a lowermost layer / interlayer insulation layer, a first interlayer insulation layer formed on the lowermost layer / interlayer insulation layer, a second interlayer insulation layer formed on the first interlayer insulation layer, and an uppermost layer / interlayer insulation.
- Each light emitting element A first electrode formed on the uppermost layer / interlayer insulating layer; An insulating film formed on a region of the uppermost layer / interlayer insulating layer where at least the first electrode is not formed; An organic layer formed on the insulating film from the first electrode and having a light emitting layer made of an organic light emitting material; and A second electrode formed on the organic layer;
- the first light emitting element includes a first light reflecting layer formed on the lowermost layer / interlayer insulating layer
- the second light emitting element includes a second light reflecting layer formed on the first interlayer insulating layer
- the third light emitting element includes a third light reflecting layer formed on the second interlayer insulating layer,
- the uppermost layer / interlayer insulating layer covers the lowermost layer / interlayer insulating layer, the first light reflecting layer, the second light reflecting layer, and the third light reflecting layer,
- a first groove is formed in a portion of the uppermost layer / interlayer insulating layer located in the boundary region between
- 10R ... 1st light emitting element red light emitting element
- 10G ... 2nd light emitting element green light emitting element
- 10B ... 3rd light emitting element blue light emitting element
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Abstract
Description
第1発光素子、第2発光素子及び第3発光素子から構成された画素が、複数、2次元マトリクス状に配列されて成り、
画素は、最下層・層間絶縁層、最下層・層間絶縁層上に形成された第1層間絶縁層、第1層間絶縁層上に形成された第2層間絶縁層、及び、最上層・層間絶縁層を有しており、
各発光素子は、
最上層・層間絶縁層上に形成された第1電極、
少なくとも第1電極が形成されていない最上層・層間絶縁層の領域の上に形成された絶縁膜、
第1電極上から絶縁膜上に亙り形成され、有機発光材料から成る発光層を有する有機層、並びに、
有機層上に形成された第2電極、
を備えており、
第1発光素子は、最下層・層間絶縁層上に形成された第1光反射層を備えており、
第2発光素子は、第1層間絶縁層上に形成された第2光反射層を備えており、
第3発光素子は、第2層間絶縁層上に形成された第3光反射層を備えている表示装置の製造方法であって、
(A)最下層・層間絶縁層、パターニングされた第1層間絶縁層、及び、パターニングされた第2層間絶縁層を形成し、その後、
(B)全面に光反射層を形成した後、光反射層をパターニングすることで、第1発光素子を形成すべき最下層・層間絶縁層の領域上に第1光反射層を形成し、第2発光素子を形成すべき第1層間絶縁層の領域上に第2光反射層を形成し、第3発光素子を形成すべき第2層間絶縁層の領域上に第3光反射層を形成し、次いで、
(C)第1発光素子と第2発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分をエッチングして第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する少なくとも第2層間絶縁層の部分をエッチングして第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第3凹部を形成した後、
(D)全面に最上層・層間絶縁層を形成し、次いで、最上層・層間絶縁層に平坦化処理を施すことで、第1凹部、第2凹部及び第3凹部の上方の最上層・層間絶縁層の部分に、第1溝部、第2溝部及び第3溝部を形成し、その後、
(E)第1溝部、第2溝部及び第3溝部の内部に遮光層を形成する、
各工程から成る。
画素は、最下層・層間絶縁層、最下層・層間絶縁層上に形成された第1層間絶縁層、第1層間絶縁層上に形成された第2層間絶縁層、及び、最上層・層間絶縁層を有しており、
各発光素子は、
最上層・層間絶縁層上に形成された第1電極、
少なくとも第1電極が形成されていない最上層・層間絶縁層の領域の上に形成された絶縁膜、
第1電極上から絶縁膜上に亙り形成され、有機発光材料から成る発光層を有する有機層、並びに、
有機層上に形成された第2電極、
を備えており、
第1発光素子は、最下層・層間絶縁層上に形成された第1光反射層を備えており、
第2発光素子は、第1層間絶縁層上に形成された第2光反射層を備えており、
第3発光素子は、第2層間絶縁層上に形成された第3光反射層を備えており、
最上層・層間絶縁層は、最下層・層間絶縁層、第1光反射層、第2光反射層及び第3光反射層を覆っており、
第1発光素子と第2発光素子との境界領域に位置する最上層・層間絶縁層の部分には第1溝部が形成されており、
第2発光素子と第3発光素子との境界領域に位置する最上層・層間絶縁層の部分には第2溝部が形成されており、
第1発光素子と第3発光素子との境界領域に位置する最上層・層間絶縁層の部分には第3溝部が形成されており、
第1溝部、第2溝部及び第3溝部の内部には遮光層が形成されており、
第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第1光反射層の頂面よりも高い所に位置し、
第2溝部の底部の最も低い部分は、第2光反射層の頂面よりも高い所に位置する。
1.本開示の表示装置及びその製造方法、全般に関する説明
2.実施例1(本開示の表示装置及びその製造方法)
3.実施例2(実施例1の変形)
4.実施例3(実施例1の変形)
5.その他
以下の説明において、第1層間絶縁層、第2層間絶縁層及び最上層・層間絶縁層の積層構造を、便宜上、『層間絶縁層・積層構造体』と呼ぶ場合がある。
第1発光素子と第2発光素子との境界領域に位置する最下層・層間絶縁層の部分及び第1層間絶縁層の部分をエッチングして第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する最下層・層間絶縁層の部分、第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第3凹部を形成する形態とすることができる。
第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第1光反射層の頂面よりも高い所に位置し、
第2溝部の底部の最も低い部分は、第2光反射層の頂面よりも高い所に位置する形態とすることができる。
第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第3発光素子よりも第1発光素子に近い所に位置し、
第2溝部の底部の最も低い部分は、第3発光素子よりも第2発光素子に近い所に位置する形態とすることができる。
0.7{-Φ2/(2π)+m2}≦2×OL2/λ≦1.2{-Φ2/(2π)+m2} (1-2)
L1<L2 (1-3)
m1<m2 (1-4)
ここで、
λ :発光層で発生した光のスペクトルの最大ピーク波長(あるいは又、発光層で発生し た光の内の所望の波長)
Φ1:第1界面で反射される光の位相シフト量(単位:ラジアン)
但し、-2π<Φ1≦0
Φ2:第2界面で反射される光の位相シフト量(単位:ラジアン)
但し、-2π<Φ2≦0
である。
OL1=L1×nave
OL2=L2×nave
の関係がある。ここで、平均屈折率naveとは、有機層及び層間絶縁層を構成する各層の屈折率と厚さの積を合計し、有機層及び層間絶縁層の厚さで除したものである。
(イ)観察者の頭部に装着されるフレーム、及び、
(ロ)フレームに取り付けられた画像表示装置、
を備えており、
画像表示装置は、
(A)本開示の表示装置、及び、
(B)本開示の表示装置から出射された光が入射され、出射される光学装置、
を備えており、
光学装置は、
(B-1)本開示の表示装置から入射された光が内部を全反射により伝播した後、観察者に向けて出射される導光板、
(B-2)導光板に入射された光が導光板の内部で全反射されるように、導光板に入射された光を偏向させる第1偏向手段(例えば、体積ホログラム回折格子膜から成る)、及び、
(B-3)導光板の内部を全反射により伝播した光を導光板から出射させるために、導光板の内部を全反射により伝播した光を複数回に亙り偏向させる第2偏向手段(例えば、体積ホログラム回折格子膜から成る)、
から成る。
第1発光素子10R、第2発光素子10G及び第3発光素子10Bから構成された画素が、複数、2次元マトリクス状に配列されて成り、
画素は、最下層・層間絶縁層30、最下層・層間絶縁層30上に形成された第1層間絶縁層31、第1層間絶縁層31上に形成された第2層間絶縁層32、及び、最上層・層間絶縁層33を有しており、
各発光素子10R,10G,10Bは、
最上層・層間絶縁層33上に形成された第1電極51、
少なくとも第1電極51が形成されていない最上層・層間絶縁層33の領域の上に形成された絶縁膜60、
第1電極51上から絶縁膜60上に亙り形成され、有機発光材料から成る発光層を有する有機層53、並びに、
有機層53上に形成された第2電極52、
を備えており、
第1発光素子10Rは、最下層・層間絶縁層30上に形成された第1光反射層36Rを備えており、
第2発光素子10Gは、第1層間絶縁層31上に形成された第2光反射層36Gを備えており、
第3発光素子10Bは、第2層間絶縁層32上に形成された第3光反射層36Bを備えている。
最上層・層間絶縁層33は、最下層・層間絶縁層30、第1光反射層36R、第2光反射層36G及び第3光反射層36Bを覆っており、
第1発光素子10Rと第2発光素子10Gとの境界領域に位置する最上層・層間絶縁層33の部分には第1溝部421が形成されており、
第2発光素子10Gと第3発光素子10Bとの境界領域に位置する最上層・層間絶縁層33の部分には第2溝部422が形成されており、
第1発光素子10Rと第3発光素子10Bとの境界領域に位置する最上層・層間絶縁層33の部分には第3溝部423が形成されている。そして、
第1溝部421、第2溝部422及び第3溝部423の内部には遮光層44が形成されており、
第1溝部421の底部431の最も低い部分及び第3溝部423の底部433の最も低い部分は、第1光反射層36Rの頂面よりも高い所に位置し、
第2溝部422の底部432の最も低い部分は、第2光反射層36Gの頂面よりも高い所に位置する。
先ず、シリコン半導体基板(第1基板11)に発光素子駆動部を公知のMOSFET製造プロセスに基づき形成する。
次いで、最下層・層間絶縁層30、パターニングされた第1層間絶縁層31、及び、パターニングされた第2層間絶縁層32を形成する。具体的には、CVD法に基づき全面に最下層・層間絶縁層30を形成した後、最下層・層間絶縁層30上に、CVD法に基づき第1層間絶縁層31及び第2層間絶縁層32を、順次、形成する。そして、周知のRIE法に基づき、第2層間絶縁層32をパターニングし、更に、第1層間絶縁層31をパターニングする。こうして、図2Aに示す構造を得ることができる。
その後、スパッタリング法に基づき全面に光反射層35を形成した後(図2B参照)、フォトリソグラフィ技術に基づきレジスト層37を形成する。こうして、図2Cに示す構造を得ることができる。
その後、第1発光素子10Rと第2発光素子10Gとの境界領域に位置する少なくとも第1層間絶縁層31の部分(実施例1にあっては、具体的には、第1発光素子10Rと第2発光素子10Gとの境界領域に位置する最下層・層間絶縁層30の部分及び第1層間絶縁層31の部分)をエッチングして第1凹部411を形成する。併せて、第2発光素子10Gと第3発光素子10Bとの境界領域に位置する少なくとも第2層間絶縁層32の部分(実施例1にあっては、具体的には、第2発光素子10Gと第3発光素子10Bとの境界領域に位置する第1層間絶縁層31の部分及び第2層間絶縁層32の部分)をエッチングして第2凹部412を形成する。併せて、第1発光素子10Rと第3発光素子10Bとの境界領域に位置する少なくとも第1層間絶縁層31の部分及び第2層間絶縁層32の部分(実施例1にあっては、具体的には、第1発光素子10Rと第3発光素子10Bとの境界領域に位置する最下層・層間絶縁層30の部分、第1層間絶縁層31の部分及び第2層間絶縁層32の部分)をエッチングして第3凹部413を形成する。以上の工程に関しては、図3B及び図4Aを参照のこと。そして、レジスト層37を除去する。こうして、図4Bに示す構造を得ることができる。
次に、プラズマCVD法に基づき、全面に最上層・層間絶縁層33を形成した後(図5A参照)、CMP法に基づき、最上層・層間絶縁層33に平坦化処理を施す。こうして、図5Bに示すように、第1凹部411、第2凹部412及び第3凹部413の上方の最上層・層間絶縁層33の部分に、第1溝部421、第2溝部422及び第3溝部423を形成する。これらの溝部421,422,423はセルフ・アライン方式で形成される。
その後、第1溝部421、第2溝部422及び第3溝部423の内部に遮光層44を形成する。具体的には、タングステンCVD法に基づき全面にタングステン層を形成し、CMP法に基づき最上層・層間絶縁層33上のタングステン層を除去する。こうして、図6に示す構造を得ることができる。
次に、トランジスタ20の一方のソース/ドレイン領域の上方に位置する最下層・層間絶縁層30及び層間絶縁層・積層構造体34の部分に、フォトリソグラフィ技術及びエッチング技術に基づき接続孔を形成する。その後、接続孔を含む最上層・層間絶縁層33の上に金属層を、例えば、スパッタリング法に基づき形成し、次いで、フォトリソグラフィ技術及びエッチング技術に基づき金属層をパターニングすることで、最上層・層間絶縁層33の上に第1電極51を形成することができる。第1電極51は、各発光素子毎に分離されている。併せて、接続孔内に第1電極51とトランジスタ20とを電気的に接続する図示しないコンタクトホール(コンタクトプラグ)を形成することができる。尚、第1溝部421、第2溝部422及び第3溝部423の内部に遮光層44を形成すると同時に、コンタクトホールを形成してもよい。
次に、例えば、CVD法に基づき、全面に絶縁膜60を形成した後、フォトリソグラフィ技術及びエッチング技術に基づき、第1電極51上の絶縁膜60の一部に開口部61を形成する。開口部61の底部に第1電極51が露出している。
その後、第1電極51及び絶縁膜60の上に、有機層53を、例えば、真空蒸着法やスパッタリング法といったPVD法、スピンコート法やダイコート法等のコーティング法等によって成膜する。次いで、例えば真空蒸着法等に基づき、有機層53の全面に第2電極52を形成する。このようにして、第1電極51上に、有機層53及び第2電極52を、例えば、真空雰囲気において連続して成膜することができる。その後、例えばCVD法又はPVD法によって、全面に保護膜14を形成する。最後に、樹脂層(封止樹脂層)15を介して保護膜14と第2基板12とを貼り合わせる。尚、第2基板12には、予めカラーフィルタCFR,CFG,CFB、及び、ブラックマトリクス層BMを形成しておく。そして、カラーフィルタCFが形成された面を貼り合わせ面とする。こうして、図1に示した有機EL表示装置を得ることができる。
[工程-A]第1発光素子を形成すべき最下層・層間絶縁層の領域上に第1光反射層を形成し、次いで、
[工程-B]最下層・層間絶縁層の上に第1層間絶縁層を形成した後、第1層間絶縁層上に第2光反射層を形成し、その後、
[工程-C]第1層間絶縁層の上に第2層間絶縁層を形成した後、第2層間絶縁層上に第3光反射層を形成し、次いで、
[工程-D]第2層間絶縁層、第1層間絶縁層及び最下層・層間絶縁層の所望の領域をエッチングによって除去し、
第1発光素子と第2発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分(具体的には、例えば、最下層・層間絶縁層の部分及び第1層間絶縁層の部分)に、第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する少なくとも第2層間絶縁層の部分(具体的には、例えば、第1層間絶縁層の部分及び第2層間絶縁層の部分)に、第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分及び第2層間絶縁層の部分(具体的には、例えば、最下層・層間絶縁層の部分、第1層間絶縁層の部分及び第2層間絶縁層の部分)に、第3凹部を形成する、
といった工程を採用してもよい。
[A01]《表示装置の製造方法》
第1発光素子、第2発光素子及び第3発光素子から構成された画素が、複数、2次元マトリクス状に配列されて成り、
画素は、最下層・層間絶縁層、最下層・層間絶縁層上に形成された第1層間絶縁層、第1層間絶縁層上に形成された第2層間絶縁層、及び、最上層・層間絶縁層を有しており、
各発光素子は、
最上層・層間絶縁層上に形成された第1電極、
少なくとも第1電極が形成されていない最上層・層間絶縁層の領域の上に形成された絶縁膜、
第1電極上から絶縁膜上に亙り形成され、有機発光材料から成る発光層を有する有機層、並びに、
有機層上に形成された第2電極、
を備えており、
第1発光素子は、最下層・層間絶縁層上に形成された第1光反射層を備えており、
第2発光素子は、第1層間絶縁層上に形成された第2光反射層を備えており、
第3発光素子は、第2層間絶縁層上に形成された第3光反射層を備えている表示装置の製造方法であって、
(A)最下層・層間絶縁層、パターニングされた第1層間絶縁層、及び、パターニングされた第2層間絶縁層を形成し、その後、
(B)全面に光反射層を形成した後、光反射層をパターニングすることで、第1発光素子を形成すべき最下層・層間絶縁層の領域上に第1光反射層を形成し、第2発光素子を形成すべき第1層間絶縁層の領域上に第2光反射層を形成し、第3発光素子を形成すべき第2層間絶縁層の領域上に第3光反射層を形成し、次いで、
(C)第1発光素子と第2発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分をエッチングして第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する少なくとも第2層間絶縁層の部分をエッチングして第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第3凹部を形成した後、
(D)全面に最上層・層間絶縁層を形成し、次いで、最上層・層間絶縁層に平坦化処理を施すことで、第1凹部、第2凹部及び第3凹部の上方の最上層・層間絶縁層の部分に、第1溝部、第2溝部及び第3溝部を形成し、その後、
(E)第1溝部、第2溝部及び第3溝部の内部に遮光層を形成する、
各工程から成る表示装置の製造方法。
[A02]工程(C)において、
第1発光素子と第2発光素子との境界領域に位置する最下層・層間絶縁層の部分及び第1層間絶縁層の部分をエッチングして第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する最下層・層間絶縁層の部分、第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第3凹部を形成する[A01]に記載の表示装置の製造方法。
[A03]第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第1光反射層の頂面よりも高い所に位置し、
第2溝部の底部の最も低い部分は、第2光反射層の頂面よりも高い所に位置する[A01]又は[A02]に記載の表示装置の製造方法。
[A04]第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第3発光素子よりも第1発光素子に近い所に位置し、
第2溝部の底部の最も低い部分は、第3発光素子よりも第2発光素子に近い所に位置する[A01]乃至[A03]のいずれか1項に記載の表示装置の製造方法。
[B01]《表示装置》
第1発光素子、第2発光素子及び第3発光素子から構成された画素が、複数、2次元マトリクス状に配列されて成る表示装置であって、
画素は、最下層・層間絶縁層、最下層・層間絶縁層上に形成された第1層間絶縁層、第1層間絶縁層上に形成された第2層間絶縁層、及び、最上層・層間絶縁層を有しており、
各発光素子は、
最上層・層間絶縁層上に形成された第1電極、
少なくとも第1電極が形成されていない最上層・層間絶縁層の領域の上に形成された絶縁膜、
第1電極上から絶縁膜上に亙り形成され、有機発光材料から成る発光層を有する有機層、並びに、
有機層上に形成された第2電極、
を備えており、
第1発光素子は、最下層・層間絶縁層上に形成された第1光反射層を備えており、
第2発光素子は、第1層間絶縁層上に形成された第2光反射層を備えており、
第3発光素子は、第2層間絶縁層上に形成された第3光反射層を備えており、
最上層・層間絶縁層は、最下層・層間絶縁層、第1光反射層、第2光反射層及び第3光反射層を覆っており、
第1発光素子と第2発光素子との境界領域に位置する最上層・層間絶縁層の部分には第1溝部が形成されており、
第2発光素子と第3発光素子との境界領域に位置する最上層・層間絶縁層の部分には第2溝部が形成されており、
第1発光素子と第3発光素子との境界領域に位置する最上層・層間絶縁層の部分には第3溝部が形成されており、
第1溝部、第2溝部及び第3溝部の内部には遮光層が形成されており、
第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第1光反射層の頂面よりも高い所に位置し、
第2溝部の底部の最も低い部分は、第2光反射層の頂面よりも高い所に位置する表示装置。
[B02]第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第3発光素子よりも第1発光素子に近い所に位置し、
第2溝部の底部の最も低い部分は、第3発光素子よりも第2発光素子に近い所に位置する[B01]に記載の表示装置。
Claims (6)
- 第1発光素子、第2発光素子及び第3発光素子から構成された画素が、複数、2次元マトリクス状に配列されて成り、
画素は、最下層・層間絶縁層、最下層・層間絶縁層上に形成された第1層間絶縁層、第1層間絶縁層上に形成された第2層間絶縁層、及び、最上層・層間絶縁層を有しており、
各発光素子は、
最上層・層間絶縁層上に形成された第1電極、
少なくとも第1電極が形成されていない最上層・層間絶縁層の領域の上に形成された絶縁膜、
第1電極上から絶縁膜上に亙り形成され、有機発光材料から成る発光層を有する有機層、並びに、
有機層上に形成された第2電極、
を備えており、
第1発光素子は、最下層・層間絶縁層上に形成された第1光反射層を備えており、
第2発光素子は、第1層間絶縁層上に形成された第2光反射層を備えており、
第3発光素子は、第2層間絶縁層上に形成された第3光反射層を備えている表示装置の製造方法であって、
(A)最下層・層間絶縁層、パターニングされた第1層間絶縁層、及び、パターニングされた第2層間絶縁層を形成し、その後、
(B)全面に光反射層を形成した後、光反射層をパターニングすることで、第1発光素子を形成すべき最下層・層間絶縁層の領域上に第1光反射層を形成し、第2発光素子を形成すべき第1層間絶縁層の領域上に第2光反射層を形成し、第3発光素子を形成すべき第2層間絶縁層の領域上に第3光反射層を形成し、次いで、
(C)第1発光素子と第2発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分をエッチングして第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する少なくとも第2層間絶縁層の部分をエッチングして第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する少なくとも第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第3凹部を形成した後、
(D)全面に最上層・層間絶縁層を形成し、次いで、最上層・層間絶縁層に平坦化処理を施すことで、第1凹部、第2凹部及び第3凹部の上方の最上層・層間絶縁層の部分に、第1溝部、第2溝部及び第3溝部を形成し、その後、
(E)第1溝部、第2溝部及び第3溝部の内部に遮光層を形成する、
各工程から成る表示装置の製造方法。 - 工程(C)において、
第1発光素子と第2発光素子との境界領域に位置する最下層・層間絶縁層の部分及び第1層間絶縁層の部分をエッチングして第1凹部を形成し、併せて、
第2発光素子と第3発光素子との境界領域に位置する第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第2凹部を形成し、併せて、
第1発光素子と第3発光素子との境界領域に位置する最下層・層間絶縁層の部分、第1層間絶縁層の部分及び第2層間絶縁層の部分をエッチングして第3凹部を形成する請求項1に記載の表示装置の製造方法。 - 第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第1光反射層の頂面よりも高い所に位置し、
第2溝部の底部の最も低い部分は、第2光反射層の頂面よりも高い所に位置する請求項1に記載の表示装置の製造方法。 - 第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第3発光素子よりも第1発光素子に近い所に位置し、
第2溝部の底部の最も低い部分は、第3発光素子よりも第2発光素子に近い所に位置する請求項3に記載の表示装置の製造方法。 - 第1発光素子、第2発光素子及び第3発光素子から構成された画素が、複数、2次元マトリクス状に配列されて成る表示装置であって、
画素は、最下層・層間絶縁層、最下層・層間絶縁層上に形成された第1層間絶縁層、第1層間絶縁層上に形成された第2層間絶縁層、及び、最上層・層間絶縁層を有しており、
各発光素子は、
最上層・層間絶縁層上に形成された第1電極、
少なくとも第1電極が形成されていない最上層・層間絶縁層の領域の上に形成された絶縁膜、
第1電極上から絶縁膜上に亙り形成され、有機発光材料から成る発光層を有する有機層、並びに、
有機層上に形成された第2電極、
を備えており、
第1発光素子は、最下層・層間絶縁層上に形成された第1光反射層を備えており、
第2発光素子は、第1層間絶縁層上に形成された第2光反射層を備えており、
第3発光素子は、第2層間絶縁層上に形成された第3光反射層を備えており、
最上層・層間絶縁層は、最下層・層間絶縁層、第1光反射層、第2光反射層及び第3光反射層を覆っており、
第1発光素子と第2発光素子との境界領域に位置する最上層・層間絶縁層の部分には第1溝部が形成されており、
第2発光素子と第3発光素子との境界領域に位置する最上層・層間絶縁層の部分には第2溝部が形成されており、
第1発光素子と第3発光素子との境界領域に位置する最上層・層間絶縁層の部分には第3溝部が形成されており、
第1溝部、第2溝部及び第3溝部の内部には遮光層が形成されており、
第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第1光反射層の頂面よりも高い所に位置し、
第2溝部の底部の最も低い部分は、第2光反射層の頂面よりも高い所に位置する表示装置。 - 第1溝部の底部の最も低い部分及び第3溝部の底部の最も低い部分は、第3発光素子よりも第1発光素子に近い所に位置し、
第2溝部の底部の最も低い部分は、第3発光素子よりも第2発光素子に近い所に位置する請求項5に記載の表示装置。
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| US15/761,170 US10381424B2 (en) | 2015-09-25 | 2016-08-05 | Display device and method for manufacturing the same |
| CN201680053737.7A CN108029175B (zh) | 2015-09-25 | 2016-08-05 | 显示装置以及用于制造其的方法 |
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Also Published As
| Publication number | Publication date |
|---|---|
| KR102653050B1 (ko) | 2024-04-01 |
| US20200258962A1 (en) | 2020-08-13 |
| CN111200003A (zh) | 2020-05-26 |
| CN108029175B (zh) | 2020-02-21 |
| JP2017062941A (ja) | 2017-03-30 |
| US10580844B2 (en) | 2020-03-03 |
| CN111200003B (zh) | 2024-09-13 |
| KR20240044541A (ko) | 2024-04-04 |
| US10381424B2 (en) | 2019-08-13 |
| KR102698040B1 (ko) | 2024-08-23 |
| KR20180056646A (ko) | 2018-05-29 |
| US11145701B2 (en) | 2021-10-12 |
| CN111276625A (zh) | 2020-06-12 |
| US20180269267A1 (en) | 2018-09-20 |
| US20190333975A1 (en) | 2019-10-31 |
| KR102528609B1 (ko) | 2023-05-04 |
| KR20230062890A (ko) | 2023-05-09 |
| CN108029175A (zh) | 2018-05-11 |
| CN111276625B (zh) | 2023-04-07 |
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