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WO2008143247A1 - アミン系エポキシ樹脂硬化剤、これを含むガスバリア性エポキシ樹脂組成物、塗料及びラミネート用接着剤 - Google Patents

アミン系エポキシ樹脂硬化剤、これを含むガスバリア性エポキシ樹脂組成物、塗料及びラミネート用接着剤 Download PDF

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Publication number
WO2008143247A1
WO2008143247A1 PCT/JP2008/059213 JP2008059213W WO2008143247A1 WO 2008143247 A1 WO2008143247 A1 WO 2008143247A1 JP 2008059213 W JP2008059213 W JP 2008059213W WO 2008143247 A1 WO2008143247 A1 WO 2008143247A1
Authority
WO
WIPO (PCT)
Prior art keywords
epoxy resin
curing agent
agent
gas barrier
amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/059213
Other languages
English (en)
French (fr)
Other versions
WO2008143247A8 (ja
Inventor
Shinichi Yonehama
Shigeyuki Hirose
Shinichi Ayuba
Eiichi Honda
Masayoshi Takahashi
Kana Kumamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2007134137A external-priority patent/JP5217241B2/ja
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Priority to AU2008254045A priority Critical patent/AU2008254045B2/en
Priority to US12/600,114 priority patent/US8128782B2/en
Priority to CN2008800165952A priority patent/CN101679611B/zh
Priority to EP08764373.0A priority patent/EP2149586B1/en
Priority to HK10107558.7A priority patent/HK1141042B/xx
Priority to CA2687286A priority patent/CA2687286C/en
Publication of WO2008143247A1 publication Critical patent/WO2008143247A1/ja
Anticipated expiration legal-status Critical
Publication of WO2008143247A8 publication Critical patent/WO2008143247A8/ja
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Epoxy Resins (AREA)

Abstract

　本発明は、エポキシ樹脂に、エポキシ樹脂が従来有する優れた性能に加え、高いガスバリア性能と長いポットライフとを付与するアミン化合物を含むアミン系エポキシ樹脂硬化剤、及び該硬化剤を含む、高いガスバリア性能と長いポットライフとを有するエポキシ樹脂組成物を提供する。また、本発明は、該エポキシ樹脂組成物を主成分とした、各種ポリマー、紙、金属などに対する接着性に優れたラミネート用接着剤を提供する。 本発明のアミン系エポキシ樹脂硬化剤は、下記の（Ａ）と（Ｂ）と（Ｄ）との反応生成物、又は（Ａ）と（Ｂ）と（Ｃ）と（Ｄ）との反応生成物からなることを特徴とするものである。 （Ａ）メタキシリレンジアミン又はパラキシリレンジアミン、（Ｂ）ポリアミンとの反応によりアミド基部位を形成し、かつオリゴマーを形成し得る、少なくとも１つのアシル基を有する多官能性化合物、（Ｃ）炭素数１～８の一価カルボン酸及び／又はその誘導体、（Ｄ）ポリアミンとの反応により式（１）で示されるカーバメート部位を形成する、式（２）で示されるカーボネート部位を少なくとも１つ有する官能性化合物
PCT/JP2008/059213 2007-05-21 2008-05-20 アミン系エポキシ樹脂硬化剤、これを含むガスバリア性エポキシ樹脂組成物、塗料及びラミネート用接着剤 Ceased WO2008143247A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU2008254045A AU2008254045B2 (en) 2007-05-21 2008-05-20 Amine epoxy resin curing agent, gas barrier epoxy resin composition comprising the curing agent, coating agent, and adhesive agent for laminate
US12/600,114 US8128782B2 (en) 2007-05-21 2008-05-20 Amine epoxy resin curing agent, gas barrier epoxy resin composition comprising the curing agent, coating agent, and adhesive agent for laminate
CN2008800165952A CN101679611B (zh) 2007-05-21 2008-05-20 胺类环氧树脂固化剂、含有该固化剂的气体阻隔性环氧树脂组合物、涂料和层压用粘合剂
EP08764373.0A EP2149586B1 (en) 2007-05-21 2008-05-20 Amine epoxy resin curing agent, gas barrier epoxy resin composition comprising the curing agent, coating agent, and adhesive agent for laminate
HK10107558.7A HK1141042B (en) 2007-05-21 2008-05-20 Amine epoxy resin curing agent, gas barrier epoxy resin composition comprising the curing agent, coating agent, and adhesive agent for laminate
CA2687286A CA2687286C (en) 2007-05-21 2008-05-20 Amine epoxy resin curing agent, gas barrier epoxy resin composition comprising the curing agent, coating agent, and adhesive agent for laminate

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2007-134137 2007-05-21
JP2007134137A JP5217241B2 (ja) 2007-05-21 2007-05-21 ガスバリア性エポキシ樹脂硬化剤およびエポキシ樹脂組成物
JP2007-236991 2007-09-12
JP2007236991 2007-09-12
JP2007330689 2007-12-21
JP2007-330689 2007-12-21

Publications (2)

Publication Number Publication Date
WO2008143247A1 true WO2008143247A1 (ja) 2008-11-27
WO2008143247A8 WO2008143247A8 (ja) 2010-07-08

Family

ID=40031944

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/059213 Ceased WO2008143247A1 (ja) 2007-05-21 2008-05-20 アミン系エポキシ樹脂硬化剤、これを含むガスバリア性エポキシ樹脂組成物、塗料及びラミネート用接着剤

Country Status (8)

Country Link
US (1) US8128782B2 (ja)
EP (1) EP2149586B1 (ja)
KR (1) KR101475096B1 (ja)
CN (1) CN101679611B (ja)
AU (1) AU2008254045B2 (ja)
CA (1) CA2687286C (ja)
TW (1) TWI425022B (ja)
WO (1) WO2008143247A1 (ja)

Cited By (6)

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JP2013528685A (ja) * 2010-06-15 2013-07-11 ビーエーエスエフ ソシエタス・ヨーロピア エポキシ樹脂組成物中での環状カーボネートの使用
US8586653B2 (en) * 2011-09-19 2013-11-19 Basf Se Curing of epoxy resin compositions comprising cyclic carbonates using mixtures of amino hardeners
US8741988B2 (en) * 2010-06-15 2014-06-03 Basf Se Use of cyclic carbonates in epoxy resin compositions
US8877837B2 (en) * 2011-09-21 2014-11-04 Basf Se Curing of epoxy resin compositions comprising cyclic carbonates using mixtures of amino hardeners and catalysts
WO2016208344A1 (ja) * 2015-06-26 2016-12-29 三菱瓦斯化学株式会社 耐薬品性を有する塗膜
US11472167B2 (en) 2017-07-31 2022-10-18 Dow Global Technologies Llc All-polyethylene laminate film structures having barrier adhesive layer

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WO2011115020A1 (ja) 2010-03-16 2011-09-22 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物及びラミネート用接着剤
JP5641043B2 (ja) 2010-04-21 2014-12-17 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物及びラミネート用接着剤
US9960646B2 (en) * 2010-09-02 2018-05-01 Sumitomo Bakelite Co., Ltd. Fixing resin composition for use in rotor
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JP6241674B2 (ja) * 2012-04-27 2017-12-06 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物、及びガスバリア性接着剤、並びにガスバリア性積層体
JP6137502B2 (ja) * 2012-04-27 2017-05-31 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物、及びガスバリア性接着剤、並びにガスバリア性積層体
JP5766352B2 (ja) * 2012-06-15 2015-08-19 三菱電機株式会社 回転電機固定子コイル絶縁用液状熱硬化性樹脂組成物、それを用いた回転電機及びその製造方法
DE102013018088B4 (de) 2013-02-10 2017-01-26 Karim El Kudsi Beschichtungen auf Epoxydharzbasis und ein Verfahren zu ihrer Herstellung und ihre Verwendungen
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CN104945599B (zh) * 2015-06-18 2017-03-01 常州大学 一种潜伏性环氧树脂固化‑发泡剂及其制备方法
WO2017179513A1 (ja) * 2016-04-11 2017-10-19 凸版印刷株式会社 バリアフィルム積層体及びその製造方法、波長変換シート、バックライトユニット、並びにエレクトロルミネッセンス発光ユニット
CN110012670B (zh) * 2016-11-02 2020-02-07 大日精化工业株式会社 水分散体及其制造方法和用途、水分散体组合物和其用途
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CN110240693B (zh) * 2019-07-10 2021-12-17 深圳市前海博扬研究院有限公司 多胺固化剂及制备方法和环氧树脂组合物
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US8128782B2 (en) 2012-03-06
EP2149586A4 (en) 2014-07-23
HK1141042A1 (en) 2010-10-29
CA2687286A1 (en) 2008-11-27
CA2687286C (en) 2015-03-24
EP2149586A1 (en) 2010-02-03
AU2008254045A1 (en) 2008-11-27
EP2149586B1 (en) 2018-01-03
WO2008143247A8 (ja) 2010-07-08
KR101475096B1 (ko) 2014-12-22
TWI425022B (zh) 2014-02-01
AU2008254045B2 (en) 2013-02-14
TW200911868A (en) 2009-03-16

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