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WO2003037885A1 - Fluorosulfonyl compounds and process for production of compounds derived therefrom - Google Patents

Fluorosulfonyl compounds and process for production of compounds derived therefrom Download PDF

Info

Publication number
WO2003037885A1
WO2003037885A1 PCT/JP2002/011310 JP0211310W WO03037885A1 WO 2003037885 A1 WO2003037885 A1 WO 2003037885A1 JP 0211310 W JP0211310 W JP 0211310W WO 03037885 A1 WO03037885 A1 WO 03037885A1
Authority
WO
WIPO (PCT)
Prior art keywords
compounds
fluorosulfonyl
polymers
production
derived therefrom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2002/011310
Other languages
English (en)
French (fr)
Inventor
Takashi Okazoe
Atsushi Watakabe
Masahiro Ito
Kunio Watanabe
Takeshi Eriguchi
Kimiaki Kashiwagi
Shu-Zhong Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to EP02778016A priority Critical patent/EP1440971B1/en
Priority to DE60224554T priority patent/DE60224554T2/de
Priority to JP2003540166A priority patent/JP4492121B2/ja
Priority to CA2464643A priority patent/CA2464643C/en
Publication of WO2003037885A1 publication Critical patent/WO2003037885A1/ja
Priority to US10/830,140 priority patent/US7271229B2/en
Anticipated expiration legal-status Critical
Priority to US11/829,579 priority patent/US7709665B2/en
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F24/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18Radicals substituted by singly bound oxygen or sulfur atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18Radicals substituted by singly bound oxygen or sulfur atoms
    • C07D317/24Radicals substituted by singly bound oxygen or sulfur atoms esterified
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/42Halogen atoms or nitro radicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
PCT/JP2002/011310 2001-10-30 2002-10-30 Fluorosulfonyl compounds and process for production of compounds derived therefrom Ceased WO2003037885A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP02778016A EP1440971B1 (en) 2001-10-30 2002-10-30 Fluorosulfonyl compounds and process for production of compounds derived therefrom
DE60224554T DE60224554T2 (de) 2001-10-30 2002-10-30 Fluorsulfonylverbindungen und verfahren zur herstellung von davon abgeleiteten verbindungen
JP2003540166A JP4492121B2 (ja) 2001-10-30 2002-10-30 フルオロスルホニル基含有化合物および該化合物から誘導される化合物の製造方法
CA2464643A CA2464643C (en) 2001-10-30 2002-10-30 Processes for producing a fluorosulfonyl group-containing compound and a compound led from the fluorosulfonyl group-containing compound
US10/830,140 US7271229B2 (en) 2001-10-30 2004-04-23 Processes for producing a fluorosulfonyl group-containing compound and a compound led from the fluorosulfonyl group-containing compound
US11/829,579 US7709665B2 (en) 2001-10-30 2007-07-27 Processes for producing a fluorosulfonyl group-containing compound and a compound LED from the fluorosulfonyl group-containing compound

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001-332813 2001-10-30
JP2001332813 2001-10-30

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/830,140 Continuation US7271229B2 (en) 2001-10-30 2004-04-23 Processes for producing a fluorosulfonyl group-containing compound and a compound led from the fluorosulfonyl group-containing compound

Publications (1)

Publication Number Publication Date
WO2003037885A1 true WO2003037885A1 (en) 2003-05-08

Family

ID=19148179

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/011310 Ceased WO2003037885A1 (en) 2001-10-30 2002-10-30 Fluorosulfonyl compounds and process for production of compounds derived therefrom

Country Status (7)

Country Link
US (2) US7271229B2 (ja)
EP (1) EP1440971B1 (ja)
JP (2) JP4492121B2 (ja)
AT (1) ATE383352T1 (ja)
CA (1) CA2464643C (ja)
DE (1) DE60224554T2 (ja)
WO (1) WO2003037885A1 (ja)

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004097851A1 (ja) * 2003-04-28 2004-11-11 Asahi Glass Company Limited 固体高分子電解質材料、製造方法及び固体高分子型燃料電池用膜電極接合体
WO2005037818A1 (ja) * 2003-10-16 2005-04-28 Asahi Glass Company, Limited 新規な含フッ素ジオキソラン化合物、および新規な含フッ素重合体
WO2005085303A1 (ja) * 2004-03-08 2005-09-15 Asahi Glass Company, Limited 硬化性組成物および含フッ素硬化物の製造方法
WO2005096422A1 (ja) * 2004-04-02 2005-10-13 Asahi Glass Company, Limited 固体高分子形燃料電池用電解質材料、電解質膜及び膜電極接合体
JP2005314388A (ja) * 2004-04-02 2005-11-10 Asahi Glass Co Ltd フルオロスルホニル基を含有する化合物、およびその重合体
WO2005121118A1 (ja) * 2004-06-11 2005-12-22 Asahi Glass Company, Limited ペルフルオロ(4-メチレン-1,3-ジオキソラン)構造を有する化合物、および新規な重合体
WO2006046620A1 (ja) * 2004-10-27 2006-05-04 Asahi Glass Company, Limited 電解質材料、電解質膜、及び固体高分子形燃料電池用膜電極接合体
JP2006143702A (ja) * 2004-11-22 2006-06-08 Japan Science & Technology Agency 含フッ素化合物の製造方法、含フッ素化合物、含フッ素ポリマー、及び含フッ素ポリマーを用いた光学材料若しくは電気材料
JP2006152249A (ja) * 2004-10-26 2006-06-15 Asahi Glass Co Ltd フルオロスルホニル基と1,3−ジオキソラン構造を有する重合体およびその用途
JP2006282619A (ja) * 2005-04-01 2006-10-19 Asahi Glass Co Ltd 新規な、ペルフルオロ(2,2−ジビニル−1,3−ジオキソラン)構造を有する化合物および含フッ素重合体
JP2006290864A (ja) * 2004-10-26 2006-10-26 Asahi Glass Co Ltd 新規な含フッ素エポキシ化合物およびその製造方法
JP2006290779A (ja) * 2005-04-08 2006-10-26 Asahi Glass Co Ltd 新規な、含フッ素化合物および含フッ素重合体
JP2007504125A (ja) * 2003-08-29 2007-03-01 独立行政法人科学技術振興機構 含フッ素1,3−ジオキソラン化合物の製造方法、含フッ素1,3−ジオキソラン化合物、含フッ素1,3−ジオキソラン化合物の含フッ素ポリマー、及び該ポリマーを用いた光学材料又は電気材料
EP1635412A4 (en) * 2003-05-13 2007-06-13 Asahi Glass Co Ltd ELECTROLYTE POLYMER FOR A FESTPOLYMER FUEL CELL, METHOD FOR ITS PREPARATION AND MEMBRANE ELECTRODE ASSEMBLY
JP2007154311A (ja) * 2005-11-10 2007-06-21 Asahi Glass Co Ltd 新規な含フッ素化合物の製造方法および新規化合物
JP2010095470A (ja) * 2008-10-16 2010-04-30 Asahi Glass Co Ltd フルオロスルホニル基を有する含フッ素化合物の製造方法
US7790817B2 (en) 2006-12-29 2010-09-07 Asahi Glass Company, Limited Process for producing fluoropolymer
WO2010137627A1 (ja) 2009-05-29 2010-12-02 旭硝子株式会社 電解質材料、液状組成物および固体高分子形燃料電池用膜電極接合体
WO2011013577A1 (ja) 2009-07-31 2011-02-03 旭硝子株式会社 電解質材料、液状組成物および固体高分子形燃料電池用膜電極接合体
JP2013075863A (ja) * 2011-09-30 2013-04-25 Asahi Glass Co Ltd 含フッ素化合物の製造方法
JP2013075861A (ja) * 2011-09-30 2013-04-25 Asahi Glass Co Ltd 含フッ素化合物の製造方法
WO2013115072A1 (ja) 2012-01-31 2013-08-08 旭硝子株式会社 含フッ素イオン交換樹脂液の製造方法
US8557474B2 (en) 2007-08-09 2013-10-15 Asahi Glass Company, Limited Fluorosulfonyl group-containing monomer and its polymer, and sulfonic acid group-containing polymer
WO2019221243A1 (ja) 2018-05-18 2019-11-21 Agc株式会社 含フッ素ポリマーの製造方法および含フッ素イオン交換ポリマーの製造方法
WO2020145287A1 (ja) 2019-01-08 2020-07-16 Agc株式会社 触媒層、触媒層形成用液および膜電極接合体
WO2021132475A1 (ja) 2019-12-27 2021-07-01 Agc株式会社 触媒層、触媒層形成用液および膜電極接合体
JP2021110951A (ja) * 2020-01-08 2021-08-02 ダイキン工業株式会社 ディスプレイ保護膜
WO2022075462A1 (ja) 2020-10-09 2022-04-14 Agc株式会社 膜電極接合体および固体高分子形燃料電池

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Publication number Priority date Publication date Assignee Title
EP1126537B1 (en) * 2000-02-15 2010-12-15 Asahi Glass Company Ltd. Block polymer, process for producing a polymer, and polymer electrolyte fuel cell
AU2002218492A1 (en) 2000-11-28 2002-06-11 Asahi Glass Company, Limited Process for producing fluorosulfonyl fluoride compound
WO2003037885A1 (en) 2001-10-30 2003-05-08 Asahi Glass Company, Limited Fluorosulfonyl compounds and process for production of compounds derived therefrom
WO2004066426A1 (ja) * 2003-01-20 2004-08-05 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質材料の製造方法及び固体高分子型燃料電池用膜電極接合体
US20050037265A1 (en) * 2003-08-14 2005-02-17 Asahi Glass Company, Limited Polymer electrolyte fuel cell, electrolyte material therefore and method for its production
DE602004026317D1 (de) 2003-08-29 2010-05-12 Japan Science & Tech Agency Verfahren zur herstellung von fluorierten 1,3-doxolanverbindingen, fluorierten 1,3-dioxolaneverbindungen, fluorierte polymere von den fluorierten 1,3-dioxolane, und von optischen und elektrischen materialien unter verwendung von diesen polymeren
EP1836231B1 (en) 2003-12-01 2009-04-22 Japan Science and Technology Agency Fluorinated polymers, method for producing the fluorinated compounds and polymers
US8415070B2 (en) * 2006-12-21 2013-04-09 E I Du Pont De Nemours And Company Partially fluorinated cyclic ionic polymers and membranes
US8906572B2 (en) 2012-11-30 2014-12-09 General Electric Company Polymer-electrolyte membrane, electrochemical fuel cell, and related method
JP6028177B1 (ja) * 2015-12-25 2016-11-16 株式会社野田スクリーン 光源装置
WO2019165636A1 (zh) * 2018-03-02 2019-09-06 博容新材料(深圳)有限公司 含氟1,3-二氧环烷类烯烃的制备方法

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WO2000056694A1 (en) * 1999-03-23 2000-09-28 Asahi Glass Company, Limited Process for producing fluorine compound through liquid-phase fluorination
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JPWO2004097851A1 (ja) * 2003-04-28 2006-07-13 旭硝子株式会社 固体高分子電解質材料、製造方法及び固体高分子型燃料電池用膜電極接合体
JP4774988B2 (ja) * 2003-04-28 2011-09-21 旭硝子株式会社 固体高分子電解質材料、製造方法及び固体高分子型燃料電池用膜電極接合体
WO2004097851A1 (ja) * 2003-04-28 2004-11-11 Asahi Glass Company Limited 固体高分子電解質材料、製造方法及び固体高分子型燃料電池用膜電極接合体
US7429428B2 (en) 2003-04-28 2008-09-30 Asahi Glass Company, Limited Polymer electrolyte material, production method thereof and membrane electrode assembly for polymer electrolyte fuel cell
EP2916377A1 (en) * 2003-05-13 2015-09-09 Asahi Glass Company, Limited Process for the production of a membrane-electrode assembly
US7488788B2 (en) 2003-05-13 2009-02-10 Asahi Glass Company, Limited Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly
EP1635412A4 (en) * 2003-05-13 2007-06-13 Asahi Glass Co Ltd ELECTROLYTE POLYMER FOR A FESTPOLYMER FUEL CELL, METHOD FOR ITS PREPARATION AND MEMBRANE ELECTRODE ASSEMBLY
JP2007504125A (ja) * 2003-08-29 2007-03-01 独立行政法人科学技術振興機構 含フッ素1,3−ジオキソラン化合物の製造方法、含フッ素1,3−ジオキソラン化合物、含フッ素1,3−ジオキソラン化合物の含フッ素ポリマー、及び該ポリマーを用いた光学材料又は電気材料
JP4776536B2 (ja) * 2003-08-29 2011-09-21 独立行政法人科学技術振興機構 含フッ素1,3−ジオキソラン化合物の製造方法
CN100412072C (zh) * 2003-10-16 2008-08-20 旭硝子株式会社 含氟二氧戊环化合物及新型含氟聚合物
WO2005037818A1 (ja) * 2003-10-16 2005-04-28 Asahi Glass Company, Limited 新規な含フッ素ジオキソラン化合物、および新規な含フッ素重合体
JP4696914B2 (ja) * 2003-10-16 2011-06-08 旭硝子株式会社 新規な含フッ素ジオキソラン化合物、および新規な含フッ素重合体
JPWO2005037818A1 (ja) * 2003-10-16 2006-12-28 旭硝子株式会社 新規な含フッ素ジオキソラン化合物、および新規な含フッ素重合体
US7252886B2 (en) 2004-03-08 2007-08-07 Asahi Glass Company, Limited Curable composition and process for producing cured fluorinated product
WO2005085303A1 (ja) * 2004-03-08 2005-09-15 Asahi Glass Company, Limited 硬化性組成物および含フッ素硬化物の製造方法
JP4997968B2 (ja) * 2004-04-02 2012-08-15 旭硝子株式会社 固体高分子形燃料電池用電解質材料、電解質膜及び膜電極接合体
WO2005096422A1 (ja) * 2004-04-02 2005-10-13 Asahi Glass Company, Limited 固体高分子形燃料電池用電解質材料、電解質膜及び膜電極接合体
US7799468B2 (en) 2004-04-02 2010-09-21 Asahi Glass Company, Limited Electrolyte material for polymer electrolyte fuel cells, electrolyte membrane and membrane-electrode assembly
JP2012109259A (ja) * 2004-04-02 2012-06-07 Asahi Glass Co Ltd 固体高分子形燃料電池用電解質材料、電解質膜及び膜電極接合体
JP2005314388A (ja) * 2004-04-02 2005-11-10 Asahi Glass Co Ltd フルオロスルホニル基を含有する化合物、およびその重合体
WO2005121118A1 (ja) * 2004-06-11 2005-12-22 Asahi Glass Company, Limited ペルフルオロ(4-メチレン-1,3-ジオキソラン)構造を有する化合物、および新規な重合体
JP2006152249A (ja) * 2004-10-26 2006-06-15 Asahi Glass Co Ltd フルオロスルホニル基と1,3−ジオキソラン構造を有する重合体およびその用途
JP2006290864A (ja) * 2004-10-26 2006-10-26 Asahi Glass Co Ltd 新規な含フッ素エポキシ化合物およびその製造方法
WO2006046620A1 (ja) * 2004-10-27 2006-05-04 Asahi Glass Company, Limited 電解質材料、電解質膜、及び固体高分子形燃料電池用膜電極接合体
JP5261937B2 (ja) * 2004-10-27 2013-08-14 旭硝子株式会社 電解質膜の製造方法
US7910236B2 (en) 2004-10-27 2011-03-22 Asahi Glass Company, Limited Electrolyte material, electrolyte membrane and membrane-electrolyte assembly for polymer electrolyte fuel cells
JP2006143702A (ja) * 2004-11-22 2006-06-08 Japan Science & Technology Agency 含フッ素化合物の製造方法、含フッ素化合物、含フッ素ポリマー、及び含フッ素ポリマーを用いた光学材料若しくは電気材料
JP2006282619A (ja) * 2005-04-01 2006-10-19 Asahi Glass Co Ltd 新規な、ペルフルオロ(2,2−ジビニル−1,3−ジオキソラン)構造を有する化合物および含フッ素重合体
JP2006290779A (ja) * 2005-04-08 2006-10-26 Asahi Glass Co Ltd 新規な、含フッ素化合物および含フッ素重合体
JP2007154311A (ja) * 2005-11-10 2007-06-21 Asahi Glass Co Ltd 新規な含フッ素化合物の製造方法および新規化合物
US7790817B2 (en) 2006-12-29 2010-09-07 Asahi Glass Company, Limited Process for producing fluoropolymer
US8557474B2 (en) 2007-08-09 2013-10-15 Asahi Glass Company, Limited Fluorosulfonyl group-containing monomer and its polymer, and sulfonic acid group-containing polymer
JP2010095470A (ja) * 2008-10-16 2010-04-30 Asahi Glass Co Ltd フルオロスルホニル基を有する含フッ素化合物の製造方法
US9508463B2 (en) 2009-05-29 2016-11-29 Asahi Glass Company, Limited Electrolyte material, liquid composition and membrane/electrode assembly for polymer electrolyte fuel cell
WO2010137627A1 (ja) 2009-05-29 2010-12-02 旭硝子株式会社 電解質材料、液状組成物および固体高分子形燃料電池用膜電極接合体
JP5565410B2 (ja) * 2009-05-29 2014-08-06 旭硝子株式会社 電解質材料、液状組成物および固体高分子形燃料電池用膜電極接合体
WO2011013577A1 (ja) 2009-07-31 2011-02-03 旭硝子株式会社 電解質材料、液状組成物および固体高分子形燃料電池用膜電極接合体
JP2013075863A (ja) * 2011-09-30 2013-04-25 Asahi Glass Co Ltd 含フッ素化合物の製造方法
JP2013075861A (ja) * 2011-09-30 2013-04-25 Asahi Glass Co Ltd 含フッ素化合物の製造方法
WO2013115072A1 (ja) 2012-01-31 2013-08-08 旭硝子株式会社 含フッ素イオン交換樹脂液の製造方法
WO2019221243A1 (ja) 2018-05-18 2019-11-21 Agc株式会社 含フッ素ポリマーの製造方法および含フッ素イオン交換ポリマーの製造方法
WO2020145287A1 (ja) 2019-01-08 2020-07-16 Agc株式会社 触媒層、触媒層形成用液および膜電極接合体
WO2021132475A1 (ja) 2019-12-27 2021-07-01 Agc株式会社 触媒層、触媒層形成用液および膜電極接合体
JP2021110951A (ja) * 2020-01-08 2021-08-02 ダイキン工業株式会社 ディスプレイ保護膜
CN114981689A (zh) * 2020-01-08 2022-08-30 大金工业株式会社 显示器保护膜
WO2022075462A1 (ja) 2020-10-09 2022-04-14 Agc株式会社 膜電極接合体および固体高分子形燃料電池

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JP4492121B2 (ja) 2010-06-30
EP1440971B1 (en) 2008-01-09
JP5040982B2 (ja) 2012-10-03
US7709665B2 (en) 2010-05-04
US20080287694A1 (en) 2008-11-20
US7271229B2 (en) 2007-09-18
CA2464643C (en) 2011-06-07
JPWO2003037885A1 (ja) 2005-02-17
EP1440971A4 (en) 2005-01-26
EP1440971A1 (en) 2004-07-28
US20040230018A1 (en) 2004-11-18
ATE383352T1 (de) 2008-01-15
CA2464643A1 (en) 2003-05-08
DE60224554D1 (de) 2008-02-21

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