[go: up one dir, main page]

WO2001060929A2 - Prepeintures et procedes de preparation de peintures de signalisation routiere a partir de ces prepeintures - Google Patents

Prepeintures et procedes de preparation de peintures de signalisation routiere a partir de ces prepeintures Download PDF

Info

Publication number
WO2001060929A2
WO2001060929A2 PCT/US2001/005101 US0105101W WO0160929A2 WO 2001060929 A2 WO2001060929 A2 WO 2001060929A2 US 0105101 W US0105101 W US 0105101W WO 0160929 A2 WO0160929 A2 WO 0160929A2
Authority
WO
WIPO (PCT)
Prior art keywords
prepaints
prepaint
binder
paint
opacifying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2001/005101
Other languages
English (en)
Other versions
WO2001060929A3 (fr
Inventor
John Michael Friel
John William Hook, Iii
Bernhard Helmut Lieser
Jerry William Washel
Dennis Paul Lorah
Donald Craig Schall
Ann Robertson Hermes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27391716&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2001060929(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Priority to AU43173/01A priority Critical patent/AU4317301A/en
Priority to EP01916111A priority patent/EP1257605A2/fr
Priority to JP2001560303A priority patent/JP2004500461A/ja
Priority to KR1020027010654A priority patent/KR20030032919A/ko
Priority to BR0108474-7A priority patent/BR0108474A/pt
Publication of WO2001060929A2 publication Critical patent/WO2001060929A2/fr
Publication of WO2001060929A3 publication Critical patent/WO2001060929A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80—Mixing plants; Combinations of mixers
    • B01F33/84—Mixing plants with mixing receptacles receiving material dispensed from several component receptacles, e.g. paint tins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80—Mixing plants; Combinations of mixers
    • B01F33/84—Mixing plants with mixing receptacles receiving material dispensed from several component receptacles, e.g. paint tins
    • B01F33/844—Mixing plants with mixing receptacles receiving material dispensed from several component receptacles, e.g. paint tins with means for customizing the mixture on the point of sale, e.g. by sensing, receiving or analysing information about the characteristics of the mixture to be made
    • B01F33/8442—Mixing plants with mixing receptacles receiving material dispensed from several component receptacles, e.g. paint tins with means for customizing the mixture on the point of sale, e.g. by sensing, receiving or analysing information about the characteristics of the mixture to be made using a computer for controlling information and converting it in a formula and a set of operation instructions, e.g. on the point of sale
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20—Measuring; Control or regulation
    • B01F35/22—Control or regulation
    • B01F35/2201—Control or regulation characterised by the type of control technique used
    • B01F35/2205—Controlling the mixing process from a remote server, e.g. by sending commands using radio, telephone, internet, local network, GPS or other means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D2/00—Special techniques in artistic painting or drawing, e.g. oil painting, water painting, pastel painting, relief painting
    • B44D2/002—Kits for drawing or painting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D3/00—Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
    • B44D3/003—Methods or devices for colour determination, selection or synthesis, e.g. use of colour tables
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D3/00—Accessories or implements for use in connection with painting or artistic drawing, not otherwise provided for; Methods or devices for colour determination, selection, or synthesis, e.g. use of colour tables
    • B44D3/06—Implements for stirring or mixing paints
    • B44D3/08—Implements for stirring or mixing paints for liquid or semi-liquid paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C09D17/007—Metal oxide
    • C09D17/008—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/30—Mixing paints or paint ingredients, e.g. pigments, dyes, colours, lacquers or enamel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/20—Measuring; Control or regulation

Definitions

  • This invention relates to sets of prepaints, a method of preparing road-marking paint lines from the sets of prepaints and to a method of preparing a range of road-marking paints from the sets of prepaints.
  • Paint formulation involves the process of selecting and admixing appropriate paint ingredients in the correct proportions to provide a paint with specific cost, processing and handling properties, as well as the desired final dry paint film properties.
  • the major ingredients of many paint formulations are a binder, an opacifying pigment, an optional pigment extender, and a fluid medium, e.g. , water if the paint is a water-borne paint such as a latex paint or a solvent if the paint is a solvent-borne paint such as an oil-based paint.
  • optional ingredients are included such as defoamers, coalescents, plasticizers, thickeners, non-thickening rheology modifiers, solvents, driers, anti-skinning agents, surfactants, mildewcides, biocides, and dispersants.
  • Formulating paints is complex. It is not simply a matter of mixing a few paint ingredients in different ratios. Rather, it involves the selection and mixing of different paint ingredients in different ratios depending on the type of paint desired. This requires paint manufacturers to store many different paint ingredients and change paint ingredients during manufacture depending on the sp cific paint type being prepared.
  • paints require those involved in the supply chain and, in particular, paint retailers to carry a large inventory of paints in order to offer a range of paints having various sheen levels, tint bases, particular end uses (i.e., exterior or interior), and various qualities. It would be desirable to make paints, either at a relatively large-scale industrial plants or on a relatively smaller-scale, at point-of-sale or at point-of-use locations using a limited number of paint ingredients to prepare all of these different paint formulations, thus minimizing the number and type of paint ingredients required to make a range of paints.
  • road-marking paint formulations are less complex than architectural paint formulations and typically are only tinted to a limited range of colors (white, yellow, light blue, red and black) rather than to the extremely wide palette of colors available for many architectural paint formulations.
  • a number of different ingredients must be combined to form the final road-marking paint.
  • Road-marking paint formulations may also require quick-setting which further complicates their formulation because the manufacturer, seller, or use must balance the advantages of quick-setting with the inherent limited pot-life that such paints exhibit.
  • road-marking paints may need to be applied, due to road safety requirements, under different conditions than are typically experienced when an architectural paint is applied.
  • road-marking paints may need to be applied over a temperatures range of from just above 0°C to greater than 40°C and in different humidities.
  • road-marking paints are exposed to rigorous conditions immediately after application, such as heavy traffic flow and deteriorating and unexpected weather conditions.
  • Paint manufacturers and retailers typically offer a range of paints, which includes at least two paint lines.
  • the range including at least two paint lines is meant that discrete elected levels of an observable property defining a first paint line are combined with discrete elected levels of an observable property defining a second paint line to define the paints in the range of paints.
  • paints including four paint lines it may be necessary to prepare paints encompassing four sheen levels, four tint bases, two use areas — interior use and exterior use, and three quality levels, and preferably all combinations thereof which means 96 different paint formulations (4 x 4 x 2 x 3) may be needed.
  • a range of paints in which certain of the defined paints, up to 10-60% of the total number of paints ⁇ are selected to be omitted, for example, for commercial reasons.
  • a "paint line,” as used herein, includes at least two different paints which offer dried film properties which differ materially from each other in at least one observable property such as color and outdoor durability.
  • prepaints are "mutually compatible" if the paints formed by admixing the prepaints do not evidence signs of colloidal instability such as fiocculation.
  • prepaints, as well as the paints formed from the prepaints exhibit less than 5 g of residue such as gel and grit per liter of paint when the paint is passed through a 200 mesh screen, more preferably less than 1 g of residue.
  • the present invention provides a set of different, but mutually compatible, fluid prepaints sufficient to formulate at least one paint line useful for road-marking applications.
  • the prepaints include at least one fluid prepaint including at least one opacifying pigment, at least one fluid prepaint including at least one extender pigment, and at least one fluid prepaint including at least one polymeric binder.
  • the number of prepaints is 3-15.
  • a method of forming a range of paints which range includes at least two paint lines useful for road-marking applications, which method comprises the steps of: (a) providing a set of different, but mutually compatible, fluid prepaints sufficient to formulate a range of road-making paints, which set comprises (i) at least one opacifying prepaint comprising at least one opacifying pigment; (ii) at least one extender prepaint comprising at least one extender pigment; (iii) at least one binder prepaint comprising at least one polymeric binder; and (iv) at least one additional different prepaint selected from the group consisting of prepaints (i), (ii), and (iii); and
  • the total number of prepaints is preferably 4-15.
  • the above methods may further include the step of mixing the prepaints before, while, or after they are dispensed into the containers or before or while they are dispensed into the applicators.
  • the above goal is achieved by employing a set of different, but mutually compatible, fluid prepaints sufficient to formulate at least one paint line useful for road- marking applications.
  • the set comprises (i) at least one opacifying/binder prepaint which comprises at least one opacifying pigment and at least one polymeric binder; and (ii) at least one extender pigment which comprises at least one extender pigment.
  • the number of prepaints is preferably 2-15, also provided is a method of forming at least one paint line useful for road- marking applications, comprises the steps of:
  • a method of forming a range of paints is provided.
  • the range includes at least two paint lines useful for road-marking applications.
  • the method comprises the steps of:
  • the above methods may further comprise the step of mixing the prepaints before, while, or after they are dispensed into the containers or before or while they are dispensed into the applicator(s).
  • the total number of prepaints is preferably 3-15.
  • the method may further include the step of adjusting the viscosity of the dispensed prepaints before, while, or after they are dispensed into the containers or before or while they are dispensed into the applicator(s) using a thickener, water, or mixtures thereof.
  • the methods may be carried out at a paint manufacturing facility, a point-of-sale or a point-of-use and may be controlled by a computer.
  • Additives may be used to enhance the application of the road making paints or final performance properties of the road-making paints.
  • at least one colorant typically white or yellow, may be added the dispensed prepaints.
  • the opacifying prepaint may further comprise at least one colorant.
  • the colorants are preferably white or yellow.
  • the prepaints may comprise a polymeric binder that is a latex polymer. They may further comprise at least one quick-setting fluid prepaint. Alternatively, the set of prepaints may contain a polymeric binder that is a quick-setting binder. Alternatively, the quick-setting component may be added as a separate ingredient. Furthermore, a combination of the above may be utilized.
  • a paint line includes two or more different paints whose dried films differ materially from each other in at least one observable property.
  • the complete paint line can be made from one each of the opacifying prepaint, (i) extender prepaint (ii) and binder prepaint (iii) or one each of opacifying/binder prepaint (I) and prepaint extender (II).
  • one key property e.g., sheen level, tint base, use type, or quality type
  • the complete paint line can be made from one each of the opacifying prepaint, (i) extender prepaint (ii) and binder prepaint (iii) or one each of opacifying/binder prepaint (I) and prepaint extender (II).
  • this range of paints may be made from: at least one each of the opacifying prepaint, (i) the extender prepaint, (ii) and the binder prepaint (iii) and at least one additional different prepaint selected from the group consisting of opacifying prepaint (i) extender prepaint (ii), and binder prepaint (iii); and opacifying/binder (I), at least one each of prepaint (I), extender prepaint (II) and at least one additional different prepaint selected from the group consisting of the opacifying/binder prepaint I and the extender prepaint II; and depending on which key properties are to be varied.
  • additional different prepaints selected from prepaints (i), (ii), and (iii) or “additional different prepaints” selected from prepaints (I) and (II) is meant a prepaint different from prepaint (i), (ii), and (iii) or (I) and (II), respectively, but otherwise meeting the limitations associated with prepaint (i), (ii), and (iii) or prepaints (I) and (II).
  • the range of paints can be made from at least one each of the opacifying prepaint (i) its extender prepaint (ii) and the binder prepaint (iii) and at least two additional different prepaints selected from the opacifying prepaint (i) the extender prepaint (ii), and the binder prepaint (iii); or at least one each of the opacifying/binder prepaint (I), the extender prepaint (II), and at least two additional prepaints selected from the group consisting of prepaints I and II; depending on which key properties are to be varied.
  • three key properties for example, three properties selected from sheen level, tint base, use type, and quality type
  • the complete range of paints can be made from at least one each of the opacifying prepaint (i), the extender prepaint (ii), the binder prepaint (iii) and at least three additional different prepaints selected from the group consisting of prepaints (i), (ii), and (iii) or at least one each of opacifying/binder prepaint (I), extender prepaint (II), and at least one additional prepaint selected from the group consisting of prepaints I and II; depending on which key properties are to be varied.
  • PVC pigment volume concentration
  • PVC (%) volume of pigment(s) + volume extender, s) x 100 volume of pigment(s) + volume extenders) + volume binder(s)
  • the prepaints are selected so they provide a wide formulation space so that the desired final paint properties lie within the blend space defined when the prepaints are at the extremes.
  • the prepaints will not by themselves be practical paints; however, by pushing the prepaints to these extremes one can maximize the blend space available for the paint line.
  • the prepaints, additives, and colorants are all fully compatible, they can be blended at the desired ratios to achieve the desired paint line(s) and range of paints without inducing colloidal instability.
  • This technique is similar to the design principles used in statistical experimental design and analysis of mixture component designs; however, instead of designing a mixture space to explore the response surface within it, one is designing the boundaries of the mixture space to maximize the flexibility of the paint system.
  • the key to success is to have mutual compatibility of the individual ingredients in each prepaint and of the prepaints across the mixture space.
  • Paint properties can be predicted in a number of ways.
  • One approach is to develop response surface models of the blend space using standard mixture component experimental design statistical tools. These simple statistical models can then be used by a linear optimization program, by a massive grid search, or by a graphical analysis tool.
  • Another approach is to simply use empirical methods to determine which blends are needed for specific paint lines, then incorporate those simple empirical recipes in the paint making machine software.
  • An extension of these techniques is to have the paint machine automatically pretest certain key properties (e.g., viscosity, drying speed, opacity or color) and make minor adjustments during the formulating of the paint from the prepaints. Having feedback loops in the paint machine can provide more precise matching of viscosity, drying speed, opacity, and color targets.
  • certain key properties e.g., viscosity, drying speed, opacity or color
  • colorants and optional additives are included in the prepaints to enhance specific paint properties and the additives and/or colorants are fully compatible, i.e., they can be blended at any ratio without inducing colloidal instability, then they can be blended in any combination falling within the formulation space needed to achieve the desired profile in the final paint. It is sufficient, however, for the colorants and optional additives to be compatible, i.e., they can be blended at desired ratios to achieve the desired property profile in the range of paints without inducing colloidal instability.
  • compatible paint ingredients may be combined in the various prepaints and the paints formed from the prepaints provide the properties characteristic of the amount of ingredient used.
  • all the fluid prepaints used in the methods of the present invention have the same or similar viscosities. This aids in mixing. Viscosity fluctuations in the final paints is expected to be reduced because of the prior equilibration of ingredients in the prepaints.
  • the prepaints are formulated to maximize the flexibility of paint manufacturing. Rather than purchasing individual paint ingredients, paint manufacturers, and even buyers at point-of- sale and point-of-use (paint stores, paint departments, and contractors) can purchase the set of prepaints required to prepare a desired range of paints. These prepaint sets will contain at least one each of the opacifying prepaint, the extender prepaint, and the binder prepaint and possibly additional prepaints depending upon the formulating flexibility desired. Optionally, the above prepaints are mixed with an additional prepaint which includes at least one colorant such as a colored pigment or dye.
  • the method of the present invention is not limited to preparing only latex paints per se but may also be extended to preparing any water-borne or solvent-borne coating, or related building product requiring mixing of ingredients, including, sealants, caulks, mastics, adhesives and other building-related products.
  • the prepaint is a fluid titanium dioxide prepaint which comprises at least one titanium dioxide opacifying pigment, at least one dispersant, at least one thickener, and water.
  • the prepaint ingredients and other optional paint ingredients are mutually compatible with each other and in the final paint.
  • the prepaint has a volume solids content of about 30% to about 80%, preferably about 40% to about 65%, and a Stormer viscosity of about 50 to about 250 KU, preferably about 60 to about 150 KU.
  • the prepaint is stable to sedimentation, i.e., the pigment does not settle out after 10 days at 25 °C.
  • the prepaint is a fluid titanium dioxide prepaint useful for formulating a one pack, pigmented latex paint containing other paint ingredients.
  • the prepaint includes at least one opacifying pigment, at least one dispersant, at least one thickener, at least one film-forming or nonfilm-forming polymeric binder, and water.
  • the prepaint ingredients are mutually compatible with each other and with other optional paint ingredients.
  • the prepaint has a volume solids content of about 30% to about 80%, preferably about 40% to about 65%, a PVC of about 35% to 100%, preferably about 45% to 100%, and a Stormer viscosity of about 50 to about 250 KU, preferably about 60 to about 150 KU.
  • the prepaint is stable to sedimentation, i.e., it does not settle out after 10 days at 25°C.
  • the polymeric binder is adsorbed onto the titanium dioxide opacifying pigment or other opacifier of present.
  • the pigment, the extender, the prepaint includes at least one mineral extender, at least one thickener, an optional polymeric binder and water.
  • the prepaint has a volume solids content of about 30% to about 80%, preferably about 40% to about 70%, a PVC of about 35% to 100%, preferably about 40% to 100%, and a Stormer viscosity of about 50 to about 250 KU, preferably about 60 to about 150 KU.
  • the prepaint ingredients are compatible with each other and with the ingredients of the other prepaints and should be compatible with ingredients of the other prepaints with which it will be used.
  • the fluid pigment extender prepaint includes at least one mineral extender, at least one thickener, a polymeric binder and water.
  • the prepaint has a volume solids content of about 30% to about 80%, preferably about 40%) to about 70%, a PVC of about 35%o to 100%, preferably about 40% to 100%), and a Stormer viscosity of about 50 to about 250 KU, preferably about 60 to about 150 KU.
  • the prepaint ingredients are compatible with each other and with the ingredients of the other prepaints and should be compatible with the ingredients of the other prepaints with which it will be used.
  • fluid latex polymer binder prepaint includes a water-borne latex polymer binder having a Tg of about -30°C to about 70°C, preferably about -10°C to about 60°C, and water.
  • the binder prepaint has a volume solids content of about 25% to about 70%, preferably about 30% to about 65%, and a Brookfield viscosity of less than about 100,000 centipoise, preferably about 100 to about 50,000 centipoise, at a shear rate of 1.25 reciprocal seconds.
  • the prepaint ingredients are compatible with each other and with the ingredients of the other prepaints that they will be used with.
  • prepaints I, II, i, ii, and iii are used, minor amounts, i.e., less than about 20% by weight, based on the total weight of the prepaint, of conventional paint additives an acid, a base, a defoamer, a coalescent, a cosolvent, a dispersing resins, a mildewcide, a biocide, an antifreeze agent, a durability enhancer (including water-miscible or emulsified epoxies, waterborne isocyanates and silanes), and the like may be included.
  • an acid, a base, a defoamer, a coalescent, a cosolvent, a dispersing resins, a mildewcide, a biocide, an antifreeze agent, a durability enhancer (including water-miscible or emulsified epoxies, waterborne isocyanates and silanes), and the like may be
  • the road-marking paint may have a pot-life of less than about 8 hours and thus would need to be applied in this time frame.
  • Opacifying pigments useful herein include white pigments which impart white scattering power to the paint across all visible wavelengths without a high degree of absorption.
  • Pigment extenders are inorganic solids or opaque polymers which do not impart the primary color or hiding power to the paint although they may have secondary influences on those properties.
  • the tint bases used for deep tone paints typically contain no or only very low levels of opacifying pigments.
  • Suitable opacifying pigments include titanium dioxide (TiO 2 ) or a combination of titanium dioxide and auxiliary hiding pigments such as voided latex polymer particles, zinc oxide, lead oxide, a synthetic polymer pigment, and mixtures thereof. Rutile and anatase grades of titanium dioxide are suitable for use herein. Rutile titanium dioxide is preferred. The surface of the titanium dioxides may be treated with various organic and/or inorganic surface treatments, e.g., as the oxides of silica, alumina, and zirconia. Fumed titanium oxide is also useful herein.
  • the voided latex particles useful herein have a particle size diameter of about 100 nm to about 2,500 nm, preferably about 500 nm to 1,100 nm and a void fraction of about 10% to about 15%.
  • the voided latex particles have at least one void but may have multiple voids, non- spherical voids, interconnected voids, voids having channels connected to the outside of the particles, and void structures described as vesiculated and sponge-like.
  • the voided latex particles have a single void.
  • the voided latex particles have a glass transition temperature (Tg), as measured by differential scanning calorimetry at a rate of 20°C/min, of at least about 20°C, preferably at least about 50°C.
  • Tg glass transition temperature
  • the voided latex particles may be prepared by conventional polymerization processes known in the art, such as those disclosed in US-A-3,784,391, US-A- 4,798,691, US-A-4,908,271, US-A-4,972,000, US-A-5,041,464, US-A-5, 157,084, US-A- 5,216,044 and US-6,020,435, as well as Japanese Patent Applications 60/223,873, 61/62510, 61/66710, 61/86941, 62/127336, 62/156387, 01/185311, and 02/140272.
  • the voided latex particles are prepared according to US-A-4,427,836, US-A-4,469,825, US-A-4,594,363, US-A-4,880,842, US-A-5,494,971 and US-A-6,020,435.
  • Extender pigments provide low cost volume, are not soluble in water, and have a low absorption number. Extender pigments used in road-marking paints are optimized for dispersion viscosities, brightness, and low cost. Suitable extender pigments include barium sulfate (about 1 to about 15 microns), Blanc Fixe (about 0.5 to about 5 microns), calcium carbonate (about 0.05 to about 35 microns), silica (about 0.001 to about 14 microns), magnesium silicate (about 0.5 to about 15 microns), aluminum silicate (about 0.2 to about 5 microns), mica, bentonite, magnesium alumino-silicate, fumed allumina, colloidal attapulgite, synthetic amorphous sodium alumino- silicate, sodium potassium alumino-silicate, and the like including combinations thereof. Glass, ceramic, polymeric beads or microspheres and combinations thereof may also be used.
  • Latex polymeric binders are polymers or prepolymers which form the primary film of the paint. Binders bind the pigment(s) and or extender(s), provide the required paint flow, and determine the durability and drying properties of the final paint film.
  • the binders selected for the prepaints will depend upon the final use of the formulated paints. It may be necessary and desirable to use binders which may be either quick-setting or non-quick-setting and which have the ability to achieve quick-setting times between the slowest and fastest setting times. For example, it may be desirable to include binders which are quicker setting when the paints are applied on a humid or rainy day, but not desirable from a cost perspective when the paints are applied on a dry day.
  • binders in the system by: (1) separating the component(s)/ingredient(s) that cause the quick-setting ("quick-setting component") from the component(s)/ingredient(s) that form the binder as a separate prepaint;
  • the quick-setting component is added as a separate component or prepaint, as described in Example 4 below.
  • the term "quick-setting,” means a coating that has a drying time of no greater than about 10 minutes as measured by a modified ASTM D1640 dry time test.
  • the test used is similar to ASTM D1640 which is a standard test for drying of organic coatings at room temperature in which the test films are applied on a non-porous substrate (e.g., a glass plate or metal panel) by a suitable means to give a wet film thickness of 0.012 +/- 0.001 inches.
  • the ASTM test method is modified in that only minimal thumb pressure is applied. The thumb is turned through an angle of 90° while in contact with the test film. The drying time at which this rotation does not break the film is recorded.
  • Suitable quick- setting systems include, but are not limited to:
  • an aqueous dispersion including an anionically-stabilized polymer having a Tg of at least about -10°C, a non-protonated or partially protonated polyamine functional polymer formed from either an amine or an imine monomer (quick-setting component), and a volatile base in an amount sufficient to deprotonate the conjugate acid of the polyamine functional polymer;
  • an aqueous dispersion including a polyamine functional polymer that is a latex polymer having pendant amine-functional groups and a Tg of at least about -10°C (i.e., quick-setting binder or component) and a volatile base in an amount sufficient to deprotonate the conjugate acid of the polyamine functional polymer;
  • an aqueous dispersion including a polyamine functional polymer that is a latex polymer having pendant amine-functional groups and pendant acid-functional groups where the ratio of amine-functional groups to acid-functional groups is greater than about 3 to 1 and where the polymer has a Tg of at least about -10°C and pendant acid-functional groups (i.e., quick-setting binder or component); and a volatile base in an amount sufficient to deprotonate the conjugate acid of the polyamine functional polymer;
  • an aqueous dispersion including a polyamine functional polymer having a Tg of at least about -10°C and that is a latex polymer having pendant amine-functional groups (i.e., quick- setting component), and a latex polymer that has a Tg of at least about -10°C pendant acid- functional groups (i.e., quick-setting component), and a volatile base in an amount sufficient to deprotonate the conjugate acid of the polyamine functional polymer;
  • an aqueous dispersion including an aqueous emulsion containing a polyamine functional polymer (i.e., quick-setting binder or component) having a Tg of at least about -10°C, formed from polymerizable monomers including (a) alkyl esters of acrylic or methacrylic acid where the alkyl ester is a C,-C 18 alkyl ester; (b) from about 0.1 to about 5% by weight, based on the acrylic or methacrylic film forming polymer of at least one secondary or tertiary aminoacrylate monomer, or secondary or tertiary aminomethacrylate monomer, and (c) from about 0.1 to about 5% by weight, based on the acrylic or methacrylic film forming polymer of a crosslinkable monomer selected from the group consisting of acrylamide, methacrylamide, and N-alkylol acrylamide; and said polyamine functional polymer having less than 3 percent by weight, based on said film forming poly
  • composition including an aqueous dispersion including a polymer having a Tg of at least about -10°C pendant strong cationic groups (i.e., quick-setting component); an aqueous dispersion including a polymer having a Tg equal to or greater than about -10°C pendant weak acid groups;
  • Suitable polymeric binders include, but are not limited to, latex polymers such as homopolymers, copolymers, or terpolymers such as acrylic and/or methacrylic, polyvinyl acetate, styrene-acrylic, styrene-butadiene, vinyl acetate-acrylic, ethylene-vinyl acetate, vinyl acetate- vinyl versatate, vinyl acetate-vinyl maleate, vinyl acetate-vinyl chloride-acrylic, ethylene-vinyl acetate-acrylic, and urethane polymers, optionally containing up to 1 % by weight of functional monomers such as carboxylic acid, phosphate, sulfate, sulfonate, amide and like functional monomers and combinations thereof.
  • functional monomers such as carboxylic acid, phosphate, sulfate, sulfonate, amide and like functional monomers and combinations thereof.
  • Polymeric binders optionally incorporated in opacifying prepaint (i) and extender prepaint (ii) and the different prepaints selected from (i) and (ii), prepaints, or other prepaints may be the same as or different from the polymeric binder incorporated in binder prepaint (iii).
  • polymeric binders incorporated in opacifying/binder prepaint I and extender prepaint II and the different prepaints selected from I and II, or other prepaints may be the same as or different from each other.
  • Other binders such as alkyds and their blends with chlorinated rubber, solvent-borne thermoplastic acrylics, unsaturated polyesters, two-part epoxies and the like may be included in the prepaints.
  • Thickener is a general term which includes any material added to a paint to modify its rheological profile.
  • Preferred thickeners for use herein are associative thickeners. Suitable thickeners for use herein include polyvinyl alcohol (PVA), hydrophobically-modified, alkali soluble emulsions known in the art as HASE emulsions, alkali-soluble or alkali-swellable emulsions known in the art as ASE emulsions, hydrophobically-modified ethylene oxide- urethane polymers known in the art as HEUR thickeners, and cellulosic thickeners such as hydroxymethyl cellulose (HMC), hydroxyethyl cellulose (HEC), hydrophobically-modified hydroxy ethyl cellulose (HMHEC), sodium carboxymethyl cellulose (SCMC), sodium carboxymethyl 2-hydroxyethyl cellulose, 2-hydroxypropyl methyl cellulose, 2-hydroxyethyl methyl cellulose, 2-hydroxybut
  • Suitable dispersants for use herein include non-ionic, anionic, and cationic dispersants such as 2-amino 2-methyl 1-propanol (AMP), dimethyl amino ethanol (DMAE), potassium tripolyphosphate (KTPP), trisodium polyphosphate (TSPP), citric acid and other carboxylic acids, and the like.
  • AMP 2-amino 2-methyl 1-propanol
  • DMAE dimethyl amino ethanol
  • KTPP potassium tripolyphosphate
  • TSPP trisodium polyphosphate
  • citric acid and other carboxylic acids and the like.
  • Anionic polymers such as homopolymers and copolymers based on polycarboxylic acids, including those that have been hydrophobically- or hydrophilically- modified, e.g., polyacrylic acid or polymethacrylic acid or maleic anhydride with various monomers such as styrene, acrylate or methacrylate esters, diisobutylene, and other hydrophilic or hydrophobic comonomers. Also, included are salts of the aforementioned polymers, as well as mixtures of these dispersants.
  • Suitable defoamers include silicone-based and mineral oil-based defoamers, and the like.
  • Coalescents are not necessary if solvent-free latex polymeric binders are used in the binder prepaints. Solvent-free binders typically have a low Tg and low minimum film-forming temperature so that they are film-forming at ambient temperatures, such as about 20°C. If a coalescent is required, preferably it is incorporated in each of binder prepaint (iii) and any other prepaints containing latex polymeric binders.
  • Suitable coalescents, plasticizers, and other optional solvents include ethylene glycol, propylene glycol, hexylene glycol, 2,2,4-trimethyl-l,3- pentanediol monoisobutyrate (TEXANOLTM), glycol ethers, mineral spirits, methyl carbitol, butyl carbitol, phthalates, adipates, and the like.
  • Suitable mildewcides and biocides include zinc oxide, isothiazolones, triazoles, and the like.
  • Suitable surfactants include cationic, anionic, and non-ionic surfactants.
  • the term "road” is used as a generic term and includes any indoor or outdoor solid surface which is or may be exposed to pedestrians, moving vehicles, tractors, or aircrafts constantly or intermittently.
  • Some non-limiting examples of a “road” include highways, streets, driveways, sidewalks, runways, taxiing areas, tarmac areas, parking lots, rooftops, indoor floors (such as in factories or shopping malls), and like surfaces.
  • the surface material may be masonry, tar, asphalt, resins, concrete, cement, plaster, stone, stucco, tiles, wood, polymeric materials, metals such as aluminum, stainless steel, or carbon steel), and combinations thereof. All of the substrates may already have one or more layers of existing coating or paint which may be fresh or aged.
  • the road-marking paint may be applied to the surface by a number of ways known to those having ordinary skill in the art, including, but not limited to, spraying, rolling, brushing, extrusion, and combinations thereof.
  • any of the prepaints may optionally contain absorbers that accelerate the drying of the road-marking paint, provided that the absorbers are added to the prepaint in a time frame that will permit the application of the paint.
  • the addition of an absorber to a prepaint will cause a rapid increase in viscosity that may make it difficult or impossible to apply.
  • the absorber may need to be added immediately prior to application to the road surface.
  • the absorbers may be added separately.
  • Suitable absorbers include organic superabsorbent polymers, ion- exchange resins, hollow sphere polymers, molecular sieves, talcs, inorganic absorbers such as inorganic superabsorbent gels and Sumica gel, porous and non-porous carbonaceous materials, encapsulated, alkali-swellable polymers, and mixtures thereof.
  • the level of absorber used is in the range of from about 0.01 % by weight to about 90% by weight, preferably from about 0.1% by weight to about 70% by weight, more preferably from about 1% by weight to about 30% by weight, based on the total weight of the latex polymer in the final paint.
  • Postponement of road-marking paint production can be particularly advantageous when techniques are used to accelerate the drying of the paint.
  • Such techniques include the addition of optional additives, such as absorbers that accelerate the drying of the road-marking paint, or the use of reactive ingredients that crosslink/cure or "quick-set," as defined herein. Because such systems have a limited pot-life and must be utilized soon after preparation, formulating the road- marking paint at the point-of-use provides an improved manufacturing technique. It becomes much more practical to utilize such techniques because the paint is used shortly after it is formulated.
  • Such techniques are further enhanced by producing the road-marking paint in the applicator(s) itself, shortly before or while the road-marking paint is applied.
  • Crosslinking of water-borne road-marking paint may be achieved by adding water- miscible or emulsified epoxies, water-borne isocyanates, silanes and the like.
  • Quick-setting binder systems as described herein, also represent a type of crosslinking or curing (i.e., ionic) and their use also benefits from postponement of the paint manufacture to the paint-of-use. This allows the use of quick-setting components that would have very limited pot life in the road- making paint. For example, a polyamine with a pKa that results in a protonated amine with very little loss of the volatile base which will deprotonate it, will have poor stability, but dry very rapidly on the road.
  • Such quick-setting and crosslinking systems benefit from postponing preparation of the paint up to and including preparation of the paint in the applicator(s) because of their short pot life.
  • the prepaints herein permit the production of the final road-marking paint at many locations beyond the conventional paint manufacturing facility and may include production at the point-of-use, such as in an on-line painting vehicle or on the job site, at a distributor, at a government transportation facility, and at point-of-sale (for example, manufacturer's retail store or large retail building-products facility).
  • the following ingredients are mixed to form a white opacifying prepaint which should have PVC of 50.8%, a VS of 57.43%, and a weight solids of 79.0%:
  • Acrylic Emulsion Polymer Binder 50% solids (Rhoplex AC-630, 532.7
  • the prepaint is prepared using a laboratory mixer having a 45° pitch stirring blade.
  • the binder, water, dispersant, wetting aid, and defoamer are combined and mixed.
  • the titanium dioxide is slowly added and the mixture is stirred for 15-20 minutes.
  • the coalescent, thickener, ammonium hydroxide, and additional water, if necessary, are then added.
  • the following ingredients are mixed to form a yellow opacifying pigment prepaint which should have a PVC of 51.7%, a VS of 57.7%, and a weight solids of 67.5%:
  • the prepaint is prepared using a laboratory mixer having a 45° pitch stirring blade.
  • the binder, water, dispersant, wetting aid and defoamer, are combined and mixed.
  • the titanium dioxide and yellow pigment are slowly added and the mixture is stirred for 15-20 minutes.
  • the coalescent, thickener, ammonium hydroxide, and additional water, if necessary, are then added.
  • Example 3 The following ingredients are mixed to form an extender pigment prepaint which should have a PVC of 61.0%, a VS of 61.4%, and a weight solids of 77.4%:
  • the prepaint is prepared using a laboratory mixer having a 45° pitch stirring blade.
  • the binder, water, dispersant, wetting aid and defoamer are combined and mixed.
  • the extender pigment is slowly added and the mixture is stirred for 15-20 minutes.
  • the methanol, coalescent, thickener, ammonium hydroxide, and additional water, if necessary, are then added.
  • polyamine prepaint which should be quick- setting. It should have a PVC of 0%, a VS of 27.4%, and a weight solids of 28.8%:
  • White road-marking paints are formed by combining the prepaints described above in the following manner:
  • the resulting paints should have the following properties:
  • Paint No. 5-1 is a slower dry white traffic paint. Paint No. 5-2 is a lower cost, slower dry white traffic paint. Paint No. 5-3 is a fast dry white traffic paint. Paint No. 5-4 is a lower cost, fast dry white traffic paint. Paint No. 5-5 is a faster dry, white traffic paint. Paint No. 5-6 is a lower cost, faster dry white traffic paint.
  • Yellow road-marking paints may be formed by combining the prepaints described above in the following manner
  • the resulting paints should have the following properties: Paint
  • Paint No. 6-1 is a slower dry yellow traffic paint. Paint No. 6-2 is a lower cost, slower dry yellow traffic paint. Paint No. 6-3 is a fast dry yellow traffic paint. Paint No. 6-4 is a lower cost, fast dry yellow traffic paint. Paint No. 6-5 is a faster dry, yellow traffic paint; and Paint No. 6-6 is a lower cost, faster dry yellow traffic paint.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Radar, Positioning & Navigation (AREA)
  • Analytical Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Road Signs Or Road Markings (AREA)
  • Road Repair (AREA)
  • Paper (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des ensembles de prépeintures servant à réaliser une ligne de peinture de signalisation routière. L'invention concerne également des procédés permettant à la personne appliquant la peinture de signalisation routière de modifier les propriétés de la peinture de signalisation routière au niveau du point d'application, de manière à les adapter aux conditions ambiantes telles que la température, l'humidité, la circulation routière et similaires.
PCT/US2001/005101 2000-02-18 2001-02-16 Prepeintures et procedes de preparation de peintures de signalisation routiere a partir de ces prepeintures Ceased WO2001060929A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU43173/01A AU4317301A (en) 2000-02-18 2001-02-16 Prepaints and method of preparing road-marking paints from prepaints
EP01916111A EP1257605A2 (fr) 2000-02-18 2001-02-16 Prepeintures et procedes de preparation de peintures de signalisation routiere a partir de ces prepeintures
JP2001560303A JP2004500461A (ja) 2000-02-18 2001-02-16 プレペイントおよびプレペイントから路面標識ペイントを製造する方法
KR1020027010654A KR20030032919A (ko) 2000-02-18 2001-02-16 예비도료 및 예비도료로 부터 도로 표시용 도료의 제조방법
BR0108474-7A BR0108474A (pt) 2000-02-18 2001-02-16 Conjunto de pré-tintas aquosas fluidas diferentes, porém mutuamente compatìveis, processos de formação de pelo menos uma linha de tinta de marcação de rodovias,de formação de uma série de tintas de marcação de rodovias,e, de formulação de pelo menos uma tinta de marcação de rodovias, dispositivo, e, veìculo

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US18365600P 2000-02-18 2000-02-18
US18365500P 2000-02-18 2000-02-18
US60/183,655 2000-02-18
US60/183,656 2000-02-18
US24763900P 2000-11-10 2000-11-10
US60/247,639 2000-11-10

Publications (2)

Publication Number Publication Date
WO2001060929A2 true WO2001060929A2 (fr) 2001-08-23
WO2001060929A3 WO2001060929A3 (fr) 2002-02-28

Family

ID=27391716

Family Applications (5)

Application Number Title Priority Date Filing Date
PCT/US2001/005110 Ceased WO2001060930A2 (fr) 2000-02-18 2001-02-16 Precurseurs de peintures et procedes pour preparer des peintures a partir de precurseurs de peintures
PCT/US2001/005308 Ceased WO2001060936A2 (fr) 2000-02-18 2001-02-16 Premix et procedes de preparation d"adhesifs et de pates a partir de ces premix
PCT/US2001/005307 Ceased WO2001060925A2 (fr) 2000-02-18 2001-02-16 Melanges stables contenant des pigments opacifiants
PCT/US2001/005205 Ceased WO2001060931A2 (fr) 2000-02-18 2001-02-16 Prepeintures et procedes de preparation de peintures a partir desdites prepeintures
PCT/US2001/005101 Ceased WO2001060929A2 (fr) 2000-02-18 2001-02-16 Prepeintures et procedes de preparation de peintures de signalisation routiere a partir de ces prepeintures

Family Applications Before (4)

Application Number Title Priority Date Filing Date
PCT/US2001/005110 Ceased WO2001060930A2 (fr) 2000-02-18 2001-02-16 Precurseurs de peintures et procedes pour preparer des peintures a partir de precurseurs de peintures
PCT/US2001/005308 Ceased WO2001060936A2 (fr) 2000-02-18 2001-02-16 Premix et procedes de preparation d"adhesifs et de pates a partir de ces premix
PCT/US2001/005307 Ceased WO2001060925A2 (fr) 2000-02-18 2001-02-16 Melanges stables contenant des pigments opacifiants
PCT/US2001/005205 Ceased WO2001060931A2 (fr) 2000-02-18 2001-02-16 Prepeintures et procedes de preparation de peintures a partir desdites prepeintures

Country Status (15)

Country Link
US (5) US20020016405A1 (fr)
EP (4) EP1268683A2 (fr)
JP (4) JP2003523443A (fr)
KR (4) KR20030032919A (fr)
CN (4) CN1416455A (fr)
AR (1) AR029800A1 (fr)
AT (1) ATE299921T1 (fr)
AU (5) AU2001238426A1 (fr)
BR (4) BR0108475A (fr)
DE (1) DE60112060T2 (fr)
ES (1) ES2244589T3 (fr)
MX (3) MXPA01001665A (fr)
PL (3) PL366299A1 (fr)
TW (3) TW583293B (fr)
WO (5) WO2001060930A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2135902A1 (fr) 2008-06-20 2009-12-23 Colas Produits de marquage routier à propriétés photocatalytiques, autonettoyantes et à surface hyperhydrophile renouvelable
IT201700004305A1 (it) * 2017-01-17 2018-07-17 Alfa Srl Prodotti semilavorati per la realizzazione estemporanea di prodotti fluidi coprenti, ottenuti individuando e ricomponendo i componenti di un prodotto fluido coprente bianco
US10793722B2 (en) 2017-08-09 2020-10-06 Pidilite Industries Limited Organic-inorganic hybrid polymer latex for high durable traffic marking paint

Families Citing this family (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7919546B2 (en) * 1998-12-23 2011-04-05 Microblend Technologies, Inc. Color integrated and mobile paint systems for producing paint from a plurality of prepaint components
US8014885B2 (en) 1998-12-23 2011-09-06 Microblend Technologies, Inc. Mobile paint system utilizing slider attribute prompts and reflectance memory storage
US20090099695A1 (en) * 1998-12-23 2009-04-16 Microblend Technologies, Inc. Color integrated and mobile paint systems for producing paint from a plurality of prepaint components
US7339000B1 (en) 1998-12-23 2008-03-04 Coatings Management Systems Inc. Method and apparatus for producing an aqueous paint composition from a plurality of premixed compositions
MXPA01001665A (es) * 2000-02-18 2002-04-01 John Michael Friel Pinturas para el marcado de caminos,preparadas a partir de prepinturas; metodo y aparato para formar zonas y lineas marcadas en los caminos, con dichas pinturas y dispositivo para aplicar dichas pinturas
US7250464B2 (en) * 2000-02-18 2007-07-31 Rohm And Haas Company Distributed paint manufacturing system
US7113919B1 (en) * 2000-02-29 2006-09-26 Chemdomain, Inc. System and method for configuring products over a communications network
US7812079B2 (en) 2001-02-22 2010-10-12 Valspar Sourcing, Inc. Coating compositions containing low VOC compounds
ZA200205980B (en) * 2001-08-15 2003-04-01 Edwin Hugh Nungesser Stable mixtures containing extender pigments.
US7288616B2 (en) * 2002-01-18 2007-10-30 Lubrizol Advanced Materials, Inc. Multi-purpose polymers, methods and compositions
US7166667B2 (en) * 2002-06-12 2007-01-23 Rohm And Haas Company Methods of preparing paints from prepaints
DE10232908A1 (de) 2002-07-19 2004-01-29 Goldschmidt Ag Verwendung organfunktionell modifizierter, Phenylderivate enthaltender Polysiloxane als Dispergier- und Netzmittel für Füllstoffe und Pigmente in wässrigen Pigmentpasten und Farb- oder Lackformulierungen
US20040121082A1 (en) * 2002-10-22 2004-06-24 Jack Dunnous Method and apparatus for producing multi-color concrete
AU2002301894B2 (en) 2002-11-07 2007-07-05 Nawkaw Holdings B. V. A masonry staining composition, a method of coating a masonry structure and a method of producing a masonry structure, a method of producing a masonry unit
US7402627B2 (en) * 2003-08-18 2008-07-22 Columbia Insurance Company Precursor colorant composition for latex paint
US9139676B2 (en) * 2003-08-18 2015-09-22 Benjamin Moore & Co. Environmentally friendly colorant compositions and latex paints/coatings
US8329807B2 (en) * 2003-08-18 2012-12-11 Columbia Insurance Company Latex paint film resistant to adverse effects of water, and compositions and methods for making same
US20050193668A1 (en) * 2004-02-23 2005-09-08 Hamilton Coatings, Llc Drywall joint construction and method
EP1609830A1 (fr) * 2004-06-24 2005-12-28 Rohm and Haas Company Compositions aqueuses contenant des ions de métaux polyvalent et polymères dispersés
DE102004037118A1 (de) * 2004-07-30 2006-03-23 Degussa Ag Titandioxid enthaltende Dispersion
US20060165885A1 (en) * 2004-12-28 2006-07-27 Fay Ralph M Method of insulating cavities in a structure using a spray-on method and resultant insulation
EP1910476A1 (fr) * 2005-07-11 2008-04-16 Akzo Nobel Coatings International BV Methode de preparation d'une composition de revetement en poudre
US20090136737A1 (en) * 2005-07-11 2009-05-28 John Ring Powder coating materials
EP1920022B1 (fr) * 2005-08-02 2013-10-09 Rory E. Brennan Compositions et procedes d'adherence
WO2007027037A1 (fr) * 2005-08-31 2007-03-08 Lg Chem, Ltd. Latex inodore pour le couchage du papier et composition de couchage du papier contenant ledit latex
EP1931742A2 (fr) * 2005-09-07 2008-06-18 Elementis Specialties, Inc. Compositions de peinture ameliorees renfermant un additif permettant de reduire l'effet de perte de viscosite provoque par l'addition de colorants
US20070059508A1 (en) * 2005-09-13 2007-03-15 Building Materials Investment Corporation Fiber mat and process of making same
US7498377B2 (en) * 2005-10-24 2009-03-03 Unimin Corporation Fluoride based composite material and method for making the same
US7582157B2 (en) * 2005-10-24 2009-09-01 The Unimin Corporation Pigment composition for paint
US20090211492A1 (en) * 2005-12-10 2009-08-27 Hawes Charles L Composition for thinning of oil-based paint
US20070135325A1 (en) * 2005-12-10 2007-06-14 Hawes Charles L Composition for thinning and cleanup of paint
US7803864B2 (en) * 2006-01-05 2010-09-28 Rohm And Haas Company Associative thickener compositions and methods of use
KR100757048B1 (ko) * 2006-01-10 2007-09-07 주식회사 유상실업 금속 및 귀금속 콜로이드 비전해 도금 용액 및 섬유에 도금방법
CA2651424A1 (fr) * 2006-06-07 2007-12-21 Elementis Specialties, Inc. Formules de peinture ameliorees contenant un adjuvant destine a reduire l'effet d'une perte de viscosite provoquee par l'ajout de colorants
US20080015104A1 (en) 2006-07-13 2008-01-17 Unimin Corporation Ultrafine nepheline syenite
US20080040980A1 (en) * 2006-07-13 2008-02-21 Unimin Corporation Method of processing nepheline syenite
US8858699B2 (en) 2006-07-13 2014-10-14 Unimin Corporation Ultra fine nepheline syenite powder and products for using same
ATE467671T1 (de) * 2006-09-01 2010-05-15 Cedric Sheridan Zwischenprodukt für die herstellung für schleif- oder schneidwerkzeuge
IL178698A0 (en) * 2006-10-17 2007-02-11 Rami Rotenberg A coating and method of preparing same
ES2403031T3 (es) * 2007-01-05 2013-05-13 Basf Se Molienda conjunta de pigmentos orgánicos con sílice pirógena
TW200846637A (en) 2007-01-16 2008-12-01 Rohm & Haas System and method for making paints from prepaints
US7757976B2 (en) * 2007-02-07 2010-07-20 Unimin Corporation Method of processing nepheline syenite powder to produce an ultra-fine grain size product
DE102007023994B4 (de) * 2007-05-23 2014-10-30 Continental Reifen Deutschland Gmbh Verfahren zum Herstellen eines lösungsmittelfreien Reifendichtmittels auf polymerer Basis
JP2008291165A (ja) * 2007-05-28 2008-12-04 Gantsu Kasei Kk 路面表示用水性塗料組成物
CN101680192B (zh) * 2007-06-18 2012-07-11 欧美诺华解决方案公司 纸涂布组合物、涂布纸和方法
CA2691830C (fr) * 2007-07-09 2014-07-29 Unimin Corporation Poudre de syenite nephelinique ayant une taille de particules regulee et son nouveau procede de fabrication
US20090088516A1 (en) * 2007-10-01 2009-04-02 Chunzhao Li Method to improve the color acceptance of viscosity stabilized latex paints
US20090156718A1 (en) * 2007-11-20 2009-06-18 Hinton John R Caulking Bead Agent and Method of Creating an Improved Caulking Bead
US20090149591A1 (en) * 2007-12-07 2009-06-11 Yong Yang Paint Compositions With Low- or Zero-VOC Coalescence Aids and Nano-Particle Pigments
US20090151601A1 (en) * 2007-12-17 2009-06-18 Elementis Specialties, Inc. Low voc waterbased coatings with efflorescence resistance
EP2080789B1 (fr) * 2007-12-17 2011-03-30 Merck Patent GmbH Pigments de charge
US20120141785A1 (en) * 2008-01-11 2012-06-07 Hugh Winters Lowrey Process for application of durable fast drying multi-coat organic coating system
US7966588B1 (en) 2008-01-26 2011-06-21 National Semiconductor Corporation Optimization of electrical circuits
US9087164B2 (en) * 2008-01-26 2015-07-21 National Semiconductor Corporation Visualization of tradeoffs between circuit designs
US8100296B2 (en) * 2008-03-24 2012-01-24 Sashco, Inc. System and method of providing individual quantities of custom colored sealing compound
EP2107086B1 (fr) 2008-04-02 2012-05-02 Evonik Degussa GmbH Dispersion comprenant des particules de dioxyde de silicium hydrophobes
CN104262683B (zh) 2008-04-17 2017-05-03 尤尼明公司 由矿物或岩石材料形成的具有受控的粒度分布的阻热膜用粉末
US9181718B2 (en) * 2008-05-08 2015-11-10 Wellington Investment Corporation System and method for installation of molding
US8141599B2 (en) * 2008-06-17 2012-03-27 Valspar Sourcing, Inc. Expanded color space architectural paint and stain tinting system
US8009276B1 (en) 2008-06-23 2011-08-30 Hrl Laboratories, Llc System and method of surface wave imaging to map pressure on a surface
US7931858B1 (en) 2008-06-23 2011-04-26 Hrl Laboratories, Llc System and method for surface decontamination using electromagnetic surface waves
US7719694B1 (en) 2008-06-23 2010-05-18 Hrl Laboratories, Llc System and method of surface wave imaging to detect ice on a surface or damage to a surface
US8124013B1 (en) 2008-06-23 2012-02-28 Hrl Laboratories, Llc System and method for large scale atmospheric plasma generation
US8333829B2 (en) * 2008-08-18 2012-12-18 Robert Richard Liversage Sprayable liquid emulsion polymer coating compositions
KR101641158B1 (ko) * 2008-08-27 2016-07-21 썬 케미칼 코포레이션 단색들 및 톤들의 자동 잉크 색 매칭
US20100151198A1 (en) * 2008-12-12 2010-06-17 Khan Amir G Roofing Material
DE102009038146A1 (de) * 2009-08-21 2011-03-03 Heubach Gmbh Abtönsystem zur Herstellung einer definierten Anzahl von Farbtönen einer gebrauchsfertigen Anstrichfarbe, einschliesslich dazugehöriger Komponenten
IT1395469B1 (it) * 2009-07-31 2012-09-21 Panettieri Substrato patinato per la stampa e relativo metodo di produzione
JP5442577B2 (ja) * 2009-11-18 2014-03-12 ローム アンド ハース カンパニー 水性コーティング組成物
JP5351190B2 (ja) * 2010-03-16 2013-11-27 ローム アンド ハース カンパニー 多価金属カチオンおよび分散されたポリマーを含む水性組成物
US9309435B2 (en) * 2010-03-29 2016-04-12 The Clorox Company Precursor polyelectrolyte complexes compositions comprising oxidants
US8712741B2 (en) 2010-06-28 2014-04-29 National Semiconductor Corporation Power supply architecture system designer
CN101974262B (zh) * 2010-11-16 2012-07-11 天津市万畅建材有限公司 一种具有柔韧性的中性耐水腻子膏及其制备方法
JP5349562B2 (ja) 2010-11-19 2013-11-20 ローム アンド ハース カンパニー 疎水的変性アルキレンオキシドウレタンポリマー
US9625187B2 (en) * 2010-12-15 2017-04-18 Mitsubishi Electric Corporation Combined air-conditioning and hot-water supply system
US9511566B2 (en) 2011-05-13 2016-12-06 Polyglass Usa, Inc. Building construction material with high solar reflectivity
EP2578647B1 (fr) * 2011-10-03 2017-06-14 Rohm and Haas Company Composition de revêtement avec des particules de polymère opaque à haute teneur en pigment et particules de dioxide de titane encapsulées dans un polymère
WO2013074117A1 (fr) 2011-11-18 2013-05-23 Hewlett-Packard Development Company, L.P. Matériau d'enregistrement à jet d'encre
CA2867164C (fr) 2012-04-20 2020-04-14 Valspar Sourcing, Inc. Dispersion de poudre de pigment de dioxyde de titane et peinture
CN104245856B (zh) 2012-04-20 2016-08-24 威士伯采购公司 制备二氧化钛颜料研磨分散体和油漆的方法
JP2014051651A (ja) * 2012-08-24 2014-03-20 Rohm & Haas Co ヒンダードアルキルアミンポリマー
US9041408B2 (en) 2013-01-16 2015-05-26 Hrl Laboratories, Llc Removable surface-wave networks for in-situ material health monitoring
WO2014111292A1 (fr) 2013-01-18 2014-07-24 Basf Se Compositions de revêtement à base de dispersion acrylique
US9203835B2 (en) 2013-03-01 2015-12-01 Paypal, Inc. Systems and methods for authenticating a user based on a biometric model associated with the user
US9606098B2 (en) * 2013-03-29 2017-03-28 Weyerhaeuser Nr Company Moisture indicator for wood substrates
KR101364323B1 (ko) * 2013-06-20 2014-02-19 주식회사 쌍 곰 건조시간이 빠르며 미끄럼 저항성이 우수한 일액형 폴리싱 타일접착제
CN104405853A (zh) * 2014-12-12 2015-03-11 常熟市明瑞针纺织有限公司 纺织设备用凸轮
JP6467220B2 (ja) * 2014-12-22 2019-02-06 ダイハツ工業株式会社 塗装方法
TWI644702B (zh) * 2015-08-26 2018-12-21 美商愛康運動與健康公司 力量運動機械裝置
US9994722B2 (en) 2015-09-25 2018-06-12 Columbia Insurance Company Reduced point of sale bases for multi-finish paint line and methods for same
KR101675488B1 (ko) * 2016-01-29 2016-11-14 태정산업개발(주) 밀착성과 부착력이 향상된 방수제의 실내외 시공방법
US10407586B2 (en) * 2016-07-28 2019-09-10 Michelman, Inc. Seed coating compositions including ethylene copolymer and lubricant
CN106433524B (zh) * 2016-08-30 2018-07-06 泰兴联创绝缘材料有限公司 一种丙烯酸乳液共混剥离力连续可调压敏胶配方、制备方法
WO2018067829A1 (fr) * 2016-10-05 2018-04-12 Valspar Sourcing, Inc. Dispersion pigmentaire contenant une substance coalescente
CN106752269A (zh) * 2016-12-30 2017-05-31 安徽真信涂料有限公司 一种铝型材粉末涂料装饰性颜料分散剂
JP6839585B2 (ja) * 2017-03-30 2021-03-10 花王株式会社 印刷インキ用分散剤組成物
US10849843B2 (en) 2018-02-01 2020-12-01 The Procter & Gamble Company Stable cosmetic ink composition
US10716873B2 (en) 2018-02-01 2020-07-21 The Procter & Gamble Company System and method for dispensing material
US10813857B2 (en) 2018-02-01 2020-10-27 The Procter & Gamble Company Heterogenous cosmetic ink composition for inkjet printing applications
US10610471B2 (en) 2018-02-01 2020-04-07 The Procter & Gamble Company Cosmetic ink composition comprising a surface tension modifier
MX2021002423A (es) 2018-08-28 2021-04-28 Consorcio Comex S A De C V Sistema de recubrimiento configurable.
US11518893B2 (en) * 2018-11-20 2022-12-06 Columbia Insurance Company Manufacturing method for multi paint finishes and a multi-finish extender grind
EP4007786A4 (fr) * 2019-08-02 2023-08-30 Bmic Llc Revêtements acryliques résistants à l'eau
US12110410B2 (en) 2019-08-02 2024-10-08 Bmic Llc Water-resistant acrylic coatings
CN111286290A (zh) * 2019-12-12 2020-06-16 西安中科贝昂环保科技有限公司 一种环保美缝剂及制备方法
US12371584B2 (en) * 2020-02-27 2025-07-29 The Pittsburgh Paints Co. Coating system
EP4168497A1 (fr) * 2020-06-22 2023-04-26 Rohm and Haas Company Procédé pour l'ajustement de la brillance dans des formulations de peinture
US20240198717A1 (en) * 2021-05-14 2024-06-20 Rohm And Haas Company In-line process for preparing paint
US11697872B2 (en) * 2021-06-23 2023-07-11 GM Global Technology Operations LLC Multi-layered coating system for a substrate and method of making the same
MX2023015189A (es) * 2021-07-13 2024-01-23 Rohm & Haas Proceso en linea para preparar pintura.
JP2023082766A (ja) * 2021-12-03 2023-06-15 株式会社日本触媒 酸化チタン分散体
JP7756400B2 (ja) * 2022-09-27 2025-10-20 株式会社和光 ラインマーキング剤組成物及びその原液並びにラインマーク方法
WO2025006029A1 (fr) * 2023-06-28 2025-01-02 Dow Global Technologies Llc Composition adhésive

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US183655A (en) 1876-10-24 Improvement in harness-saddles
US62510A (en) 1867-02-26 Improved railway-switch
US86941A (en) 1869-02-16 Improvement in corn-planter
US185311A (en) 1876-12-12 Improvement in paint-staffs for millstones
US183656A (en) 1876-10-24 Improvement in grain-separators
US247639A (en) 1881-09-27 hawley
US223873A (en) 1880-01-27 Process of autographic printing
US66710A (en) 1867-07-16 William f
US140272A (en) 1873-06-24 Improvement in ruling-pens
US127336A (en) 1872-05-28 Improvement in devices for locking nuts
US156387A (en) 1874-10-27 Improvement in cotton-presses
DE2027737C3 (de) * 1969-07-08 1975-11-20 Ncr Corp., Dayton, Ohio (V.St.A.) Härtbare Klebstoff- oder Vergußmasse auf Basis von Epoxidharz und ungesättigtem Polyesterharz
US3868263A (en) * 1970-06-22 1975-02-25 Kenneth E Mcconnaughay Method of making a paving composition
CA935255A (en) * 1971-02-12 1973-10-16 Canadian Titanium Pigments Limited High-solids tio2 pigment and method for making same
US3784391A (en) 1971-12-27 1974-01-08 Nl Industries Inc Finely divided hollow microcapsules of polymeric resins
US4243430A (en) 1977-09-21 1981-01-06 Rohm And Haas Company Pigment dispersant for aqueous paints
US4170485A (en) 1978-08-22 1979-10-09 American Cyanamid Company Titanium dioxide slurries from recycle material
US4427836A (en) 1980-06-12 1984-01-24 Rohm And Haas Company Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent
JPS5874757A (ja) 1981-10-29 1983-05-06 Toa Paint Kk 道路標示用塗料
US4403866A (en) 1982-05-07 1983-09-13 E. I. Du Pont De Nemours And Company Process for making paints
US4469825A (en) 1983-03-09 1984-09-04 Rohm And Haas Company Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as an opacifying agent
JPS6187734A (ja) 1984-10-03 1986-05-06 Japan Synthetic Rubber Co Ltd 中空ポリマ−粒子の製造方法
US4594363A (en) 1985-01-11 1986-06-10 Rohm And Haas Company Production of core-sheath polymer particles containing voids, resulting product and use
GB8705482D0 (en) 1987-03-09 1987-04-15 Ici Plc Dispensing apparatus
CA1303437C (fr) 1988-02-29 1992-06-16 Nobuo Kawahashi Particules polymeres creuses, procede de production et utilisation comme pigment
JP2591050B2 (ja) 1988-03-31 1997-03-19 日産自動車株式会社 アンチスキッド制御装置
US4880842A (en) 1988-05-20 1989-11-14 Rohm & Haas Company Multi-stage opacifying polymer particles containing non-polymeric acid absorbed therein
JP2728910B2 (ja) 1988-12-27 1998-03-18 三井東圧化学株式会社 小孔を有する合成樹脂粒子の製造法
DE3910742A1 (de) 1989-04-03 1990-10-04 Aqualon Gmbh Verwendung von hydrophobierten, nicht-ionogenen celluloseethern in dispersionsfarben und so erhaltene dispersionsfarben
US5078302A (en) 1989-07-17 1992-01-07 Fluid Management Limited Partnership Paint dispensing apparatus
CA2020629C (fr) 1989-07-21 2000-02-01 Frank Landy Revetement aqueux de longue conservation a cure rapide
JP2872710B2 (ja) 1989-10-27 1999-03-24 三井化学株式会社 合成樹脂エマルション及びその製造方法
US5114630A (en) * 1990-09-21 1992-05-19 The United Of America As Represented By The Secretary Of The Navy Continuous manufacture and casting
US5157084A (en) 1990-10-12 1992-10-20 The Dow Chemical Company Process of making hollow polymer latex particles
AU2930992A (en) 1991-10-31 1993-06-07 E.I. Du Pont De Nemours And Company Dispersant treated pigments
DE69324953T2 (de) 1992-03-26 1999-09-16 Aqualon Co., Wilmington Fluidisierte Polymer-Suspension für die kontinuierliche Herstellung eines Überzugsmittels
DE4301991A1 (de) * 1993-01-26 1994-07-28 Herberts Gmbh Modulsystem und dessen Verwendung bei Verfahren zur Herstellung von wäßrigen Überzugsmitteln
DE4307498A1 (de) 1993-03-10 1994-09-15 Herberts Gmbh Modulsystem und dessen Verwendung bei Verfahren zur Herstellung von wäßrigen Überzugsmitteln
WO1994025238A1 (fr) 1993-05-05 1994-11-10 E.I. Du Pont De Nemours And Company Dispositif de precision servant a l'apport de liquides
US5823670A (en) 1993-11-17 1998-10-20 Calgon Corporation Chemical delivery and on-site blending system for producing multiple products
DE4415292A1 (de) 1994-04-30 1995-11-02 Herberts Gmbh Modulsystem und Verfahren zur Herstellung wäßriger Überzugsmittel
US5494971A (en) 1994-08-12 1996-02-27 Rohm And Haas Company Encapsulated hydrophilic polymers and their preparation
IE73467B1 (en) 1994-08-26 1997-06-04 Gen Paints Intellectual Proper Paint manufacture
AU709278B2 (en) 1996-03-06 1999-08-26 Rohm And Haas Company Quick-drying aqueous coating compositions
IT1283307B1 (it) 1996-03-27 1998-04-16 Corob Srl Dispositivo umidificatore di ugelli di erogazione di fluidi di una macchina dispensatrice.
US5989331A (en) 1996-05-28 1999-11-23 Southern Clay Products, Inc. TiO2 slurry stabilization
MY115083A (en) 1996-06-07 2003-03-31 Rohm & Haas Waterborne traffic paints having improved fast dry characteristic and method of producing traffic markings therefrom
IT1287957B1 (it) 1996-08-06 1998-08-26 Corob Spa Macchina dispensatrice di prodotti allo stato fluido, in particolare di coloranti ed affini per la formulazione di vernici e simili.
DE19714577A1 (de) 1997-04-09 1998-10-15 Basf Coatings Ag Mischsystem zur Herstellung wasserverdünnbarer Überzugsmittel
US6020435A (en) 1997-11-05 2000-02-01 Rohm And Haas Company Process for preparing polymer core shell type emulsions and polymers formed therefrom
US6073055A (en) * 1997-11-10 2000-06-06 Basf Corporation Computerized virtual paint manufacturing and application system
IT1305253B1 (it) 1998-02-23 2001-04-19 Colorificio Adriatico S R L Metodo di preparazione istantanea di vernici e pitture.
US6221145B1 (en) 1998-12-23 2001-04-24 Coating Management Systems, Inc. Method of producing and aqueous paint composition from a plurality of premixed components
DE19904330A1 (de) 1999-01-28 2000-08-10 Basf Coatings Ag Wäßriger Beschichtungsstoff und Modulsystem zu seiner Herstellung
EP1057522B1 (fr) 1999-05-31 2004-07-21 Kikusui Chemical Industries Co., Ltd., Kozuka Bldg. Procédé pour la fabrication/manipulation de composants fluides emballés, code de données pour l'instruction de fabrication/manipulation utilisé dans ce procédé et emballages de composants fluides pourvues de ce code de données pour l'instruction de fabrication/manipulation
US20020007867A1 (en) 1999-07-07 2002-01-24 Kikusui Chemical Industries Co., Ltd. Method for manufacturing/handling fluid component packaged goods, manufacture/handling instructing data code for use in this method and fluid component packaged goods affixed by this manufacture/handling instructing data code
EP1094096A1 (fr) * 1999-10-22 2001-04-25 Nickolas Bizzio Procédé pour réaliser des peintures en mélangeant des quantités prédéterminées de produits fluides
US6689824B2 (en) * 2000-02-18 2004-02-10 Rohm And Haas Company Prepaints and method of preparing road-marking paints from prepaints
US7250464B2 (en) * 2000-02-18 2007-07-31 Rohm And Haas Company Distributed paint manufacturing system
MXPA01001665A (es) * 2000-02-18 2002-04-01 John Michael Friel Pinturas para el marcado de caminos,preparadas a partir de prepinturas; metodo y aparato para formar zonas y lineas marcadas en los caminos, con dichas pinturas y dispositivo para aplicar dichas pinturas

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2135902A1 (fr) 2008-06-20 2009-12-23 Colas Produits de marquage routier à propriétés photocatalytiques, autonettoyantes et à surface hyperhydrophile renouvelable
US8183308B2 (en) 2008-06-20 2012-05-22 Colas Road marking products with self-cleaning photocatalytic properties and with a renewable hyperhydrophilic surface
IT201700004305A1 (it) * 2017-01-17 2018-07-17 Alfa Srl Prodotti semilavorati per la realizzazione estemporanea di prodotti fluidi coprenti, ottenuti individuando e ricomponendo i componenti di un prodotto fluido coprente bianco
WO2018134749A1 (fr) * 2017-01-17 2018-07-26 Alfa S.R.L. Produits semi-traités pour la production extemporanée de produits fluides de recouvrement qui sont obtenus par identification et recombinaison des composants d'un produit fluide de recouvrement blanc
US10793722B2 (en) 2017-08-09 2020-10-06 Pidilite Industries Limited Organic-inorganic hybrid polymer latex for high durable traffic marking paint
US11236236B2 (en) 2017-08-09 2022-02-01 Pidilite Industries Limited Organic-inorganic hybrid polymer latex for high durable traffic marking paint

Also Published As

Publication number Publication date
PL357302A1 (en) 2004-07-26
AU2001238426A1 (en) 2001-08-27
ES2244589T3 (es) 2005-12-16
TW583292B (en) 2004-04-11
WO2001060930A3 (fr) 2002-03-21
US20020016405A1 (en) 2002-02-07
CN1404513A (zh) 2003-03-19
MX248298B (es) 2007-08-22
TW583293B (en) 2004-04-11
US6919400B2 (en) 2005-07-19
KR20030032919A (ko) 2003-04-26
US20020004551A1 (en) 2002-01-10
EP1268683A2 (fr) 2003-01-02
US6531537B2 (en) 2003-03-11
AR029800A1 (es) 2003-07-16
US6613832B2 (en) 2003-09-02
CN1404515A (zh) 2003-03-19
BR0108474A (pt) 2003-04-22
EP1265970A2 (fr) 2002-12-18
JP2003523443A (ja) 2003-08-05
WO2001060931A2 (fr) 2001-08-23
DE60112060T2 (de) 2006-04-20
KR20020093811A (ko) 2002-12-16
JP2004500461A (ja) 2004-01-08
EP1268689B1 (fr) 2005-07-20
WO2001060930A2 (fr) 2001-08-23
BR0108470A (pt) 2003-04-22
WO2001060936A3 (fr) 2002-05-02
MX235121B (es) 2006-03-22
EP1268689A2 (fr) 2003-01-02
AU781472B2 (en) 2005-05-26
PL365175A1 (en) 2004-12-27
JP2003523440A (ja) 2003-08-05
CN1404518A (zh) 2003-03-19
DE60112060D1 (de) 2005-08-25
ATE299921T1 (de) 2005-08-15
AU4157201A (en) 2001-08-27
KR20020086541A (ko) 2002-11-18
PL366299A1 (en) 2005-01-24
WO2001060931A3 (fr) 2002-03-21
WO2001060929A3 (fr) 2002-02-28
AU3979001A (en) 2001-08-27
WO2001060925A2 (fr) 2001-08-23
MXPA02007926A (es) 2004-09-10
AU783738B2 (en) 2005-12-01
BR0108475A (pt) 2003-04-22
MXPA01001665A (es) 2002-04-01
CN1208407C (zh) 2005-06-29
WO2001060925A3 (fr) 2001-12-20
CN1416455A (zh) 2003-05-07
KR100810949B1 (ko) 2008-03-10
US20040030035A1 (en) 2004-02-12
TWI283698B (en) 2007-07-11
BR0108468A (pt) 2002-12-03
KR20030076924A (ko) 2003-09-29
AU4317301A (en) 2001-08-27
MXPA02007924A (es) 2004-09-10
US20020013401A1 (en) 2002-01-31
EP1257605A2 (fr) 2002-11-20
AU3850901A (en) 2001-08-27
US20020002934A1 (en) 2002-01-10
WO2001060936A2 (fr) 2001-08-23
CN1188478C (zh) 2005-02-09
KR100754939B1 (ko) 2007-09-04
JP2003523442A (ja) 2003-08-05

Similar Documents

Publication Publication Date Title
US6689824B2 (en) Prepaints and method of preparing road-marking paints from prepaints
EP1257605A2 (fr) Prepeintures et procedes de preparation de peintures de signalisation routiere a partir de ces prepeintures
ZA200205921B (en) Prepaints and method of preparing road-making paints from prepaints.
EP1371691B1 (fr) Prepeintures et procedes de preparation de peintures a partir de prepeintures
US20050143505A1 (en) Paint with color change additive and method of application and painted substrate
JP2008284550A (ja) 速乾性多成分水性コーティングを製造する方法
CA2597951C (fr) Revetement superficiel decoratif reflechissant et systeme de revetement superficiel a l'eau decoratif comportant au moins une couche d'appret
US6337106B1 (en) Method of producing a two-pack fast-setting waterborne paint composition and the paint composition therefrom
JP2001288415A (ja) 水系艶消しコーティング組成物及び艶消しコーティング方法
US20210079228A1 (en) Substrate marking system
RU2278880C2 (ru) Полуфабрикаты красок и способы приготовления красок из полуфабрикатов красок

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 2002/05921

Country of ref document: ZA

Ref document number: 200205921

Country of ref document: ZA

WWE Wipo information: entry into national phase

Ref document number: 43173/01

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2001916111

Country of ref document: EP

ENP Entry into the national phase

Ref country code: JP

Ref document number: 2001 560303

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 1020027010654

Country of ref document: KR

Ref document number: 018052088

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2001916111

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 1020027010654

Country of ref document: KR

WWW Wipo information: withdrawn in national office

Ref document number: 2001916111

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 43173/01

Country of ref document: AU