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WO1999013840A1 - Composition d'un colorant capillaire - Google Patents

Composition d'un colorant capillaire Download PDF

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Publication number
WO1999013840A1
WO1999013840A1 PCT/JP1997/003264 JP9703264W WO9913840A1 WO 1999013840 A1 WO1999013840 A1 WO 1999013840A1 JP 9703264 W JP9703264 W JP 9703264W WO 9913840 A1 WO9913840 A1 WO 9913840A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
acid
dye
weight
red
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP1997/003264
Other languages
English (en)
Japanese (ja)
Inventor
Megumi Yoshimoto
Yuichi Nishida
Mutsumi Noguchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP8088806A priority Critical patent/JPH09249538A/ja
Application filed by Lion Corp filed Critical Lion Corp
Priority to PCT/JP1997/003264 priority patent/WO1999013840A1/fr
Publication of WO1999013840A1 publication Critical patent/WO1999013840A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair dye composition for hair dyeing, and more particularly, to a hair dyeing composition, which has little discoloration, has no migratory property, has a vivid hair dyeing color, and has a hair dyeing property and dyeing property.
  • the present invention relates to a hair dye composition excellent in suppleness and combability of hair after hair.
  • Hair dyes containing acid dyes and natural dyes are widely used at home and in beauty salons because they have less damage to hair than other hair dyes.
  • a hair dye composition that makes gray hair less noticeable by using it many times in a usage method such as a hair rinse, it contains an acid dye and an organic solvent, and has a pH of 2.0 to 4.5. Yes, compounded with salt of organic acid, etc. to provide buffer capacity of 0.0 :!
  • a hair dye composition having a composition of ⁇ 0.2 gram equivalent / 1 has been proposed (Japanese Patent Application Laid-Open No. 5-72882), but it is necessary to use the hair dye many times, The concrete containing sodium citrate and sodium lactate are not yet satisfactory in terms of transferability and texture.
  • the present invention eliminates the drawbacks of conventional hair dyes using acid dyes and natural dyes, significantly reduces the color of the shampoo washing solution at the time of hair dyeing, and also provides clothing, such as towels and pillow bars,
  • the present invention provides a hair dye composition that has no dye transferability, can obtain a vivid color tone, is excellent in dyeability, and has excellent flexibility and combability after dyeing hair. Aim. Disclosure of the invention
  • the inventor of the present invention has conducted intensive studies to solve the above-mentioned problems, and as a result, to prevent acid dyes and natural pigments from discoloring into a washing solution, and to eliminate transferability to clothes and the like, hair dyeing is performed. It has been found that this problem can be solved by blending a specific solution of glycolic acid, that is, ammonium glycolate, in the preparation, and in addition to such discoloration of the washing solution and suppression of the migration property, In order to obtain a vivid color tone even with black hair, they found that the problem could be solved by further blending hydrogen peroxide into the hair dye and bleaching the hair, thereby completing the present invention.
  • glycolic acid that is, ammonium glycolate
  • Examples of the acidic dye as the component (A) of the hair dye composition of the present invention include a nitro dye, an azo dye, a nitroso dye, a triphenylmethane dye, a xanthine dye, and a quinoline dye.
  • Dyes, anthraquinone dyes, indigo dyes, etc. Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106 No. 4, Yellow No. 4, Yellow No. 6, Green No. 3, Blue No. 1, Blue No. 2, Red No. 21, Red No. 2, No. 7, Red No. 2, No. 2, Red No. 2, No. 3, Red No. 2 3 1 No., Red No. 232, Orange No.
  • Examples of the natural dyes as the component (A) include carotenoids, anthraquinones, flavonoids (antocyanin, chalcone, flavonone), porphyrins, diketones, and betacyanines.
  • azophylon-based pigments specifically, acane pigment, anato pigment, pubica pigment, gardenia yellow pigment, extracted carotene, cochineal pigment, lac pigment, red cabbage pigment, perilla pigment, purple corn pigment, Elderberry pigment, Boysen berry pigment, grape skin pigment, grape juice pigment, purple potato pigment, safflower yellow pigment, safflower red pigment, kolyan pigment, onion pigment, liquorice pigment, sandalwood pigment, spirulina blue pigment , Chlorofinole, konkon pigment, beaded, red yeast rice red pigment, red yeast rice yellow, cuticle Shi blue dye, mouth without red dye or the like is used.
  • akane dye from the viewpoint of the dyeing power, akane dye, pubica dye, cochineal dye, lac dye, kolyan dye, onion dye, cacao dye, sandalwood dye, gardenia blue dye, gardenia red dye, and the like are preferable.
  • These natural pigments can be used alone or as a mixture of two or more.
  • the amount of the acid dye 0 relative to the total weight hair dye composition. 0 1-2 by weight 0 /. However, from the viewpoint of hair dyeing power and cost, it is preferably from 0.02 to 1.0% by weight. If the amount of the acid dye is less than 0.01% by weight, the hair dyeing effect is not sufficiently exhibited, and if it exceeds 2% by weight, the degree of hair dyeing is good, but it is erroneously attached to skin or clothing. It is not preferable because it is difficult to remove when
  • the organic solvent as the component (B) of the hair dye composition of the present invention includes a compound represented by the following general formula (1), an N-alkylpyrrolidone represented by the following general formula (2) or Examples include alkylene carbonates having 1 to 4 carbon atoms.
  • R 1 is a hydrogen atom, a lower alkyl group or a group R3 ⁇ 4 ⁇ -R 3 —
  • R 2 is a hydrogen atom, a methyl group or a methoxy group
  • R 3 is a bond or a saturated or Y and Z each represent a hydrogen atom or a hydroxyl group
  • P, q and r each represent an integer of 0 to 5.
  • R 4 represents a substituted or branched alkyl group having 1 to 18 carbon atoms.
  • organic solvents include, for example, ethanol, isopropanol, n-propanol, n-butanol, isobutanol, ethylenglycol, propylene glycol, 1,3-butanediol, benzylinolenocone, cinnaminolenocone, phenetinolenocone p — anisyl alcohol, p —Methylbenzylanolekole, phenoxyethoxyethanol, 2-pendinoleoxyethanol, methylcarbitol, ethynole, potassium olebitone, propylcanolebitol, butylcanolebitol, trietix
  • examples include lenticular cornole monoethyl etherate, triethylene glycol corn monobutyl ether, glycerin, N
  • the compounding amount of the organic solvent as the component (B) is preferably 0.5 to 50% by weight, more preferably 5 to 20%, based on the total weight of the hair dye composition.
  • the hair dyeing effect is weak, and when the amount exceeds 50% by weight, a large amount of the organic solvent causes the once permeated color element to elute again. This is not preferred because the hair dyeing effect is reduced and skin irritation may occur.
  • ammonium glycolate as the component (C) of the hair dye composition of the present invention, those having a neutralization rate of 100% or various neutralization rates can be used.
  • the amount of the ammonium glycolate as the component (C) is preferably from 0.1 to 20% by weight, more preferably from 5 to 15% by weight, based on the total weight of the hair dye composition.
  • the amount is less than 0.1%, the effect of suppressing dye transfer is weak, and if it exceeds 20% by weight, skin irritation may appear, which is not preferable.
  • the compounding amount of hydrogen peroxide as the component (D) is preferably 0.1 to 5.0% by weight based on the total weight of the hair dye composition, and particularly 0.1 to 5.0 from the viewpoint of hair damage. 0% by weight is preferred.
  • chelating agents such as hydroxyethanediphosphonic acid, sodium edetate, sodium citrate, sodium metalate, dalconic acid, etc. Is preferably used in combination.
  • the hair dye composition of the present invention has a pH of 2.0 to 4.5. pH is If it is less than 2.0, there may be irritation when it adheres to the scalp, etc. If the pH is more than 4.5, the hair dyeing effect is impaired, and neither is preferred.
  • the pH can be adjusted using an organic acid, an inorganic acid or a salt thereof, or an alkali.
  • Examples of the organic acids include citric acid, succinic acid, tartaric acid, lactic acid, fumaric acid, linoleic acid, levulinic acid, butyric acid, valeric acid, oxalic acid, maleic acid, fumaric acid, and mandelic acid.
  • Examples of the inorganic acid include phosphoric acid, sulfuric acid, and nitric acid.
  • Examples of the alkali include sodium hydroxide, potassium hydroxide, calcium hydroxide, monoethanolamine, diethanolamine, triethanolamine, and aminohydroxime. Tylpropanediol, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol and the like.
  • a basic amino acid such as arginine
  • these acids and alkalis can be used together, for example, as a sodium salt, a potassium salt, an ammonium salt, a triethanolamine salt or the like of the acid.
  • the hair dye composition of the present invention includes various surfactants, cationic polymers, oily components, thickeners such as hydroxyxetyl cellulose xanthan gum, and the like, as long as the effects of the present invention are not impaired.
  • Corn derivatives, fragrances, preservatives. UV absorbers, antioxidants, bactericides, etc. may be added.
  • surfactants include anionic surfactants such as olefin sulfonic acid, alkane sulfonic acid, fatty acid alkyl ether carboxylic acid, and N-acylamino acid; amide betaine, carbobetaine, and hydroxy sulfo. Any of amphoteric surfactants such as betaine; cationic surfactants such as mono- or dialkyl quaternary ammonium salts; and nonionic surfactants such as polyoxyalkylene alkyl ethers can be used.
  • Examples of the cationic polymer include cationized cellulose, cationized starch, cationized guar gum, diaryl quaternary ammonium salt polymer, diaryl quaternary ammonium salt Z-acrylamide copolymer, and hydroxche. Butylcellulose dimethyldiaryl quaternary ammonium copolymer and the like.
  • Examples of the oil component include fatty acid esters, linear or branched alkyl glyceryl ethers, and branched higher alcohols.
  • the hair dye composition of the present invention can be produced by a conventional method by mixing the above-mentioned components.
  • the method of using the composition is to apply it to the hair, leave it for 5 to 30 minutes, and then rinse it off with a shampoo.
  • the above-mentioned dyed hair bundle is measured with a color difference meter (SPECTRO manufactured by Nippon Denshoku Industries Co., Ltd.). L, a, and b values were measured with COLOR METERSE 2000), and the color difference ( ⁇ *) from undyed hair was determined to evaluate the dyeing. ⁇ * indicates that the larger the value is, the better the dyeing is.
  • Goat hair is dyed in the same manner as above, left to wash off with shampoo, put the hair bundle on a white towel, and apply a 500 g weight for 5 minutes.
  • the evaluation was performed and the results are shown in Table 1.
  • the evaluation criteria are as follows.
  • Goat hair is dyed in the same manner as above, left to stand, rinsed off with shampoo, air-dried, and evaluated for its texture and combability. The results are shown in Table 1.
  • Example 1 Example 2 Example 3 Example 4 Orange No. 205 No. 0.16 > Yellow No. 40 No. 1 (1) 0.04
  • Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Orange 205 -0.16-Yellow 403-1 (1)-0.04-Benzilano Recall 10 10 10 10 10 10 10 10 10 Glycomonoammonium 0.05 Glycolic acid 10
  • a cream having a pH of 3.0 was prepared from the composition shown below, and the hair bundle was treated in the same manner as in Examples 1 to 4. Hair dyeing properties, no discoloration during hair dyeing, migratory properties The hair feel, shampoo fastness and formulation stability were all good.
  • preparations were prepared with a pH of 3.0, using the agent A as a laying agent and the agent B as a foam setting agent.
  • LPG propellant
  • the hair bundles were subjected to A-agent treatment and B-agent treatment sequentially using these aerosol cans, and they showed hair dyeing properties, no discoloration during hair dyeing, dye transfer properties, hair feel, shampoo fastness, The drug product stability was all good.
  • a preparation having pH 3.0 was prepared as a tonic agent A, and a liquid B was prepared as a foam split-coat U.
  • the same experiment as in Example 6 was carried out except for using these A agent and B agent, and it was found that the hair dyeing property, the absence of discoloration during hair dyeing, the dye transfer property, the feel of hair, the shampoo fastness, The degree of no damage and the degree of damage repair were both good.
  • a gel agent having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4.
  • the hair dyeing performance was gradually dyed with the lapse of the treatment time. The hair effect was developed and good hair dyeing was obtained.No discoloration at the time of hair dyeing, transferability, hair feel, shampoo fastness, degree of no damage and damage repair were all good. .
  • a hair mousse having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4. Dyeing properties, hair feel, shampoo fastness, and formulation stability were all good.
  • Methylpolysiloxane (100,000) 45 Methylpolysiloxane (30 cs) 25 POE (30) Stearyl ether 04 Palm oil fatty acid diethanolamide 0 3 Yuka Former 310 009 Glycomonate ammonium 0 0 Fragrance 0
  • a hair having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4.Hair dyeing properties, no discoloration during hair dyeing, migratory properties The hair feel, shampoo fastness, and formulation stability were all good.
  • ⁇ L * is a value measured during the measurement of ⁇ *, and a smaller value indicates a more vivid color tone.
  • a cream having a pH of 3.0 was prepared from the composition shown below, and the hair bundle was treated in the same manner as in Examples 11 to 14.
  • the dye transfer properties, hair feel, shampoo fastness, and formulation stability were all excellent.
  • preparations were prepared with a pH of 3.0, using the agent A as a laying agent and the agent B as a foam setting agent.
  • LPG propellant
  • the hair bundles were subjected to A-agent treatment and B-agent treatment using these aerosol cans in order. Hair dyeing properties, no discoloration during hair dyeing, The transferability, hair feel, shampoo fastness, and formulation stability were all good.
  • a pH 3.0 formulation was prepared using the A agent as a tonic and the B solution as a foam split-coat agent.
  • the same experiment as in Example 6 was carried out except for using these A agent and B agent, and it was found that the hair dyeing property, the absence of discoloration during hair dyeing, the dye transfer property, the feel of hair, the shampoo fastness, The degree of no damage and the degree of damage repair were both good.
  • a pH 3.0 diel was prepared from the composition shown below, and the hair bundle was treated in the same manner as in Examples 1 to 4.
  • the hair dyeing performance was gradually increased with the elapse of the treatment time. The effect was exhibited and good hair dyeing was obtained, and no color fading at the time of hair dyeing, transferability, hair feel, shampoo fastness, degree of no damage, and degree of damage repair were all good.
  • a hair mousse having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4. Dyeing properties, hair feel, shampoo fastness, and formulation stability were all good.
  • Methylpolysiloxane (100,000) 45 Methylpolysiloxane (30 cs) 25 POE (30) Stearyl ether 04 Palm oil fatty acid diethanolamine 0 3 Yukaforma 3 0 1 0 9 Glycolic acid ammonium 1 0 0 Fragrance 0 Penzinole noreco 1 0 0 Ethanol 1 0 Gunoleconic acid 0 5 Cuenoic acid
  • a hair having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4. As a result, hair dyeing properties, no discoloration during hair dyeing, and dye transfer properties were observed. The hair feel, shampoo fastness and formulation stability are all good.
  • the hair dye composition according to claim 2 of the present invention further comprising hydrogen peroxide in addition to the hair dye composition containing ammonium glycolate according to claim 1 has the following effects. Gives a vivid color tone to black hair.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Veterinary Medicine (AREA)
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  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition d'un colorant capillaire qui confère d'excellentes qualités de teinture, de résistance à la migration, de douceur et de traitabilité aux cheveux teints, ainsi qu'un ton de couleur lumineux. Cette composition se caractérise en ce qu'elle comprend les éléments A) à C) et, éventuellement, l'élément D) et présente un pH compris entre 2,0 et 4,5. L'élément A) contient entre 0,01 et 2 % en poids d'un colorant acide ou d'un pigment naturel; l'élément B) contient entre 0,5 et 50 % en poids d'un solvant organique; l'élément C) contient entre 0,1 et 20 % en poids de glycolate d'ammonium; et l'élément D) contient entre 0,1 et 5 % en poids de peroxyde d'hydrogène.
PCT/JP1997/003264 1996-03-18 1997-09-16 Composition d'un colorant capillaire Ceased WO1999013840A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP8088806A JPH09249538A (ja) 1996-03-18 1996-03-18 染毛剤組成物
PCT/JP1997/003264 WO1999013840A1 (fr) 1996-03-18 1997-09-16 Composition d'un colorant capillaire

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP8088806A JPH09249538A (ja) 1996-03-18 1996-03-18 染毛剤組成物
PCT/JP1997/003264 WO1999013840A1 (fr) 1996-03-18 1997-09-16 Composition d'un colorant capillaire

Publications (1)

Publication Number Publication Date
WO1999013840A1 true WO1999013840A1 (fr) 1999-03-25

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PCT/JP1997/003264 Ceased WO1999013840A1 (fr) 1996-03-18 1997-09-16 Composition d'un colorant capillaire

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JP (1) JPH09249538A (fr)
WO (1) WO1999013840A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3427719A1 (fr) * 2017-07-14 2019-01-16 Kao Germany GmbH Blanchiment aqueuse et composition de teinture pour fibres kératiniques, procédé, kit et utilisation de celui-ci

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09249538A (ja) * 1996-03-18 1997-09-22 Lion Corp 染毛剤組成物
JP3394716B2 (ja) * 1998-10-12 2003-04-07 花王株式会社 染毛剤組成物
JP2000226319A (ja) * 1999-02-04 2000-08-15 Pola Chem Ind Inc 染毛料
JP3544137B2 (ja) * 1999-02-25 2004-07-21 花王株式会社 染毛方法
JP2002265339A (ja) * 2001-03-06 2002-09-18 Takara Belmont Co Ltd 染毛剤組成物及び染毛方法
JP6930994B2 (ja) 2015-11-24 2021-09-01 ロレアル 毛髪をトリートメントするための組成物
RU2771234C2 (ru) * 2015-11-24 2022-04-28 Л'Ореаль Композиции для обработки волос
US11090249B2 (en) 2018-10-31 2021-08-17 L'oreal Hair treatment compositions, methods, and kits for treating hair

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0578228A (ja) * 1991-09-20 1993-03-30 Kao Corp 染毛剤組成物
JPH06298630A (ja) * 1993-04-14 1994-10-25 Yamahatsu Sangyo Kk 頭髪用酸性染毛料組成物
JPH09249538A (ja) * 1996-03-18 1997-09-22 Lion Corp 染毛剤組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0578228A (ja) * 1991-09-20 1993-03-30 Kao Corp 染毛剤組成物
JPH06298630A (ja) * 1993-04-14 1994-10-25 Yamahatsu Sangyo Kk 頭髪用酸性染毛料組成物
JPH09249538A (ja) * 1996-03-18 1997-09-22 Lion Corp 染毛剤組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3427719A1 (fr) * 2017-07-14 2019-01-16 Kao Germany GmbH Blanchiment aqueuse et composition de teinture pour fibres kératiniques, procédé, kit et utilisation de celui-ci

Also Published As

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