WO1999013840A1 - Hair dye composition - Google Patents

Abstract

A hair dye composition which is excellent in dyeing properties, migration resistance, and softness and treatability of the dyed hair and can give a bright color tone, characterized by comprising the following components (A) to (C) and, if necessary, the component (D) and having a pH of 2.0 to 4.5: (A) 0.01 to 2 wt.% of an acid dye or natural pigment, (B) 0.5 to 50 wt.% of an organic solvent, (C) 0.1 to 20 wt.% of ammonium glycolate, and (D) 0.1 to 5 wt.% of hydrogen peroxide.

Description

 Specification

 Hair dye composition

Technical field

 TECHNICAL FIELD The present invention relates to a hair dye composition for hair dyeing, and more particularly, to a hair dyeing composition, which has little discoloration, has no migratory property, has a vivid hair dyeing color, and has a hair dyeing property and dyeing property. The present invention relates to a hair dye composition excellent in suppleness and combability of hair after hair.

Background art

 Hair dyes containing acid dyes and natural dyes are widely used at home and in beauty salons because they have less damage to hair than other hair dyes.

 However, when the acid dye hair dye is applied to the hair and washed off with a shampoo, the color of the wash is unpleasant and unpleasant, causing the dye to adhere to the towel or pillow cover after shampooing, It has the drawback that when hair is wet due to rain or rain, it is transferred to clothing. In addition, there is a disadvantage that a vivid color tone cannot be obtained particularly with black hair.

 In order to improve such drawbacks such as dyeing property and colorfastness, specific acid dyes are used, and glycolic acid and di- or pyrrolidone carboxylic acid and / or alkali metal salts or alkalis thereof are used. A hair dye composition using a combination of an earth metal salt and an amine salt has also been proposed (Japanese Unexamined Patent Publication No. Hei 6-29860), but it is still unsatisfactory in terms of transferability. .

Further, as a hair dye composition that makes gray hair less noticeable by using it many times in a usage method such as a hair rinse, it contains an acid dye and an organic solvent, and has a pH of 2.0 to 4.5. Yes, compounded with salt of organic acid, etc. to provide buffer capacity of 0.0 :! A hair dye composition having a composition of ~ 0.2 gram equivalent / 1 has been proposed (Japanese Patent Application Laid-Open No. 5-72882), but it is necessary to use the hair dye many times, The concrete containing sodium citrate and sodium lactate are not yet satisfactory in terms of transferability and texture.

 The present invention eliminates the drawbacks of conventional hair dyes using acid dyes and natural dyes, significantly reduces the color of the shampoo washing solution at the time of hair dyeing, and also provides clothing, such as towels and pillow bars, The present invention provides a hair dye composition that has no dye transferability, can obtain a vivid color tone, is excellent in dyeability, and has excellent flexibility and combability after dyeing hair. Aim. Disclosure of the invention

 The inventor of the present invention has conducted intensive studies to solve the above-mentioned problems, and as a result, to prevent acid dyes and natural pigments from discoloring into a washing solution, and to eliminate transferability to clothes and the like, hair dyeing is performed. It has been found that this problem can be solved by blending a specific solution of glycolic acid, that is, ammonium glycolate, in the preparation, and in addition to such discoloration of the washing solution and suppression of the migration property, In order to obtain a vivid color tone even with black hair, they found that the problem could be solved by further blending hydrogen peroxide into the hair dye and bleaching the hair, thereby completing the present invention.

 That is, according to the present invention,

 (A) 0.1 to 2% by weight of acid dye or natural pigment

 (B) Organic solvent 0.5 to 50% by weight

(C) Ammonium glycolate 0.:! To 2 0 weight ^_0/0

 And a pH of 2.0 to 4.5.

 According to the present invention,

(A) 0.1 to 2% by weight of acid dye or natural pigment (B) Organic solvent 0.5 to 50% by weight

(C) glycol acid Anmoniumu 0.1:! ~ 2 0 weight ^_0/0

 (D) Hydrogen peroxide 0:! ~ 5% by weight

And a pH of 2.0 to 4.5. BEST MODE FOR CARRYING OUT THE INVENTION

Examples of the acidic dye as the component (A) of the hair dye composition of the present invention include a nitro dye, an azo dye, a nitroso dye, a triphenylmethane dye, a xanthine dye, and a quinoline dye. Dyes, anthraquinone dyes, indigo dyes, etc.Specifically, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106 No. 4, Yellow No. 4, Yellow No. 6, Green No. 3, Blue No. 1, Blue No. 2, Red No. 21, Red No. 2, No. 7, Red No. 2, No. 2, Red No. 2, No. 3, Red No. 2 3 1 No., Red No. 232, Orange No. 205, Orange No. 107, Yellow No. 202, Yellow No. 203, Green No. 201, Green No. 204, Green No. 206, Green No. 206, Blue 202, Blue 203, Blue 205, and Color 201, Red 401, Red 602, Red 503, Red 504, Red 504, Red 506, Orange 402, Yellow 402, Yellow 403, Yellow 406 No. 4, Yellow No. 4, Green No. 4, Green No. 4, Purple No. 4, Black No. 4, etc. are used. Of these, preferred acid dyes from the viewpoint of hair dyeing power are Yellow No. 4, Green No. 204, Red No. 2, Red No. 102, Green No. 3, Blue No. 1, Blue No. 205, Yellow No. 4 No. 03, Red No. 106, Red No. 201, Orange No. 205, Black No. 401, Green No. 201 or Purple No. 401, especially Black No. 410, Particular preference is given to purple # 401, orange # 205, yellow # 403 or red # 106. These acid dyes may be used alone or as a mixture of two or more. Can be

 Examples of the natural dyes as the component (A) include carotenoids, anthraquinones, flavonoids (antocyanin, chalcone, flavonone), porphyrins, diketones, and betacyanines. And azophylon-based pigments.Specifically, acane pigment, anato pigment, pubica pigment, gardenia yellow pigment, extracted carotene, cochineal pigment, lac pigment, red cabbage pigment, perilla pigment, purple corn pigment, Elderberry pigment, Boysen berry pigment, grape skin pigment, grape juice pigment, purple potato pigment, safflower yellow pigment, safflower red pigment, kolyan pigment, onion pigment, liquorice pigment, sandalwood pigment, spirulina blue pigment , Chlorofinole, konkon pigment, beaded, red yeast rice red pigment, red yeast rice yellow, cuticle Shi blue dye, mouth without red dye or the like is used. Among these, from the viewpoint of the dyeing power, akane dye, pubica dye, cochineal dye, lac dye, kolyan dye, onion dye, cacao dye, sandalwood dye, gardenia blue dye, gardenia red dye, and the like are preferable. These natural pigments can be used alone or as a mixture of two or more.

The amount of the acid dye, 0 relative to the total weight hair dye composition. 0 1-2 by weight ⁰ /. However, from the viewpoint of hair dyeing power and cost, it is preferably from 0.02 to 1.0% by weight. If the amount of the acid dye is less than 0.01% by weight, the hair dyeing effect is not sufficiently exhibited, and if it exceeds 2% by weight, the degree of hair dyeing is good, but it is erroneously attached to skin or clothing. It is not preferable because it is difficult to remove when

The organic solvent as the component (B) of the hair dye composition of the present invention includes a compound represented by the following general formula (1), an N-alkylpyrrolidone represented by the following general formula (2) or Examples include alkylene carbonates having 1 to 4 carbon atoms. R— (OCH ₂ CH ₂ ) p— (OCH ₂ CH) qZ

 (1)

(CH ₂ ) — Y

[Wherein, R ¹ is a hydrogen atom, a lower alkyl group or a group R¾ ^ -R ³ — (R ² is a hydrogen atom, a methyl group or a methoxy group, R ³ is a bond or a saturated or Y and Z each represent a hydrogen atom or a hydroxyl group, and P, q and r each represent an integer of 0 to 5. However, except when p = q = r = 0 and Z = H, and when p = q = r = 0 and Ι ^ = Η and 2 = ΟΗ)

N C O (2)

(In the formula, R ⁴ represents a substituted or branched alkyl group having 1 to 18 carbon atoms.) Specific examples of these organic solvents include, for example, ethanol, isopropanol, n-propanol, n-butanol, isobutanol, ethylenglycol, propylene glycol, 1,3-butanediol, benzylinolenocone, cinnaminolenocone, phenetinolenocone _p — anisyl alcohol, p —Methylbenzylanolekole, phenoxyethoxyethanol, 2-pendinoleoxyethanol, methylcarbitol, ethynole, potassium olebitone, propylcanolebitol, butylcanolebitol, trietix Examples include lenticular cornole monoethyl etherate, triethylene glycol corn monobutyl ether, glycerin, N-methylpyrrolidone, N-octylpyrrolidone, and N-laurylpyrrolidone.

 The compounding amount of the organic solvent as the component (B) is preferably 0.5 to 50% by weight, more preferably 5 to 20%, based on the total weight of the hair dye composition.

 When the amount of the organic solvent is less than 0.5% by weight, the hair dyeing effect is weak, and when the amount exceeds 50% by weight, a large amount of the organic solvent causes the once permeated color element to elute again. This is not preferred because the hair dyeing effect is reduced and skin irritation may occur.

 As the ammonium glycolate as the component (C) of the hair dye composition of the present invention, those having a neutralization rate of 100% or various neutralization rates can be used. A product having a neutralization rate of preferably from 10 to 70%, more preferably from 20 to 50%, exhibits good low color fading and low dye transferability.

 The amount of the ammonium glycolate as the component (C) is preferably from 0.1 to 20% by weight, more preferably from 5 to 15% by weight, based on the total weight of the hair dye composition.

 If the amount is less than 0.1%, the effect of suppressing dye transfer is weak, and if it exceeds 20% by weight, skin irritation may appear, which is not preferable.

 Further, the compounding amount of hydrogen peroxide as the component (D) is preferably 0.1 to 5.0% by weight based on the total weight of the hair dye composition, and particularly 0.1 to 5.0 from the viewpoint of hair damage. 0% by weight is preferred.

 As stabilizers for hydrogen peroxide, chelating agents such as hydroxyethanediphosphonic acid, sodium edetate, sodium citrate, sodium metalate, dalconic acid, etc. Is preferably used in combination.

The hair dye composition of the present invention has a pH of 2.0 to 4.5. pH is If it is less than 2.0, there may be irritation when it adheres to the scalp, etc. If the pH is more than 4.5, the hair dyeing effect is impaired, and neither is preferred. The pH can be adjusted using an organic acid, an inorganic acid or a salt thereof, or an alkali.

 Examples of the organic acids include citric acid, succinic acid, tartaric acid, lactic acid, fumaric acid, linoleic acid, levulinic acid, butyric acid, valeric acid, oxalic acid, maleic acid, fumaric acid, and mandelic acid. Examples of the inorganic acid include phosphoric acid, sulfuric acid, and nitric acid. Examples of the alkali include sodium hydroxide, potassium hydroxide, calcium hydroxide, monoethanolamine, diethanolamine, triethanolamine, and aminohydroxime. Tylpropanediol, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol and the like.

 In addition, it is also preferable to use a basic amino acid such as arginine.

 Furthermore, these acids and alkalis can be used together, for example, as a sodium salt, a potassium salt, an ammonium salt, a triethanolamine salt or the like of the acid.

 In addition, the hair dye composition of the present invention includes various surfactants, cationic polymers, oily components, thickeners such as hydroxyxetyl cellulose xanthan gum, and the like, as long as the effects of the present invention are not impaired. Corn derivatives, fragrances, preservatives. UV absorbers, antioxidants, bactericides, etc. may be added.

Here, surfactants include anionic surfactants such as olefin sulfonic acid, alkane sulfonic acid, fatty acid alkyl ether carboxylic acid, and N-acylamino acid; amide betaine, carbobetaine, and hydroxy sulfo. Any of amphoteric surfactants such as betaine; cationic surfactants such as mono- or dialkyl quaternary ammonium salts; and nonionic surfactants such as polyoxyalkylene alkyl ethers can be used. Examples of the cationic polymer include cationized cellulose, cationized starch, cationized guar gum, diaryl quaternary ammonium salt polymer, diaryl quaternary ammonium salt Z-acrylamide copolymer, and hydroxche. Butylcellulose dimethyldiaryl quaternary ammonium copolymer and the like. Examples of the oil component include fatty acid esters, linear or branched alkyl glyceryl ethers, and branched higher alcohols.

 The hair dye composition of the present invention can be produced by a conventional method by mixing the above-mentioned components. The method of using the composition is to apply it to the hair, leave it for 5 to 30 minutes, and then rinse it off with a shampoo. Example

 The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples. Example:! ~ 4, Comparative Examples 1 ~ 9

Various compositions shown in Table 1 were prepared, and the degree of hair dyeing-migration, flexibility, and combability were evaluated according to the following evaluation criteria. The results are shown in Table 1 _c (degree of hair dyeing)

 After 1 g of each of the compositions shown in Table 1 was uniformly applied to 1 g of the dried goat hair bundle, the mixture was allowed to stand at room temperature for 15 minutes and shampooed. Thereafter, it was dried and evaluated for the degree of hair dyeing (ΔΕ *) according to the method described below.

The above-mentioned dyed hair bundle is measured with a color difference meter (SPECTRO manufactured by Nippon Denshoku Industries Co., Ltd.). L, a, and b values were measured with COLOR METERSE 2000), and the color difference (ΔΕ *) from undyed hair was determined to evaluate the dyeing. ΔΕ * indicates that the larger the value is, the better the dyeing is.

ΔΕ * = (Δβ *) ² + (Ab *) ² + (AL *) ²

(Migration)

 Goat hair is dyed in the same manner as above, left to wash off with shampoo, put the hair bundle on a white towel, and apply a 500 g weight for 5 minutes. The evaluation was performed and the results are shown in Table 1. The evaluation criteria are as follows.

 ◎ · · · Pure white

 染色 · · · If you look closely, you can see a faint stain

 △ · · · Stained, but light

 X · · · clearly stained, quite severe

 [Flexibility and combability]

 Goat hair is dyed in the same manner as above, left to stand, rinsed off with shampoo, air-dried, and evaluated for its texture and combability. The results are shown in Table 1.

 © · · · The texture is very supple and the comb is very good. 〇 · · · · The texture is supple and the comb is very good.

△ · · · The texture is not supple and the comb is not as good. X · · · The texture is not supple and the comb is not good. (1)

Example 1 Example 2 Example 3 Example 4 Orange No. 205 No. 0.16 _> Yellow No. 40 No. 1 (1) 0.04

Benzino Real Cornole 5 1 0 1 0 1 0 Ammonium glycolate 1 0 1 0 5 1 5 Queonic acid qs Purified water *

PH 3 3.5 5 3 3 Hair dyeing degree (Δ Ε) 2 5 3 5 3 8 4 0 Dye transferability ◎ ◎ O ◎ 'Good suppleness, good comb-through ◎ ◎ 〇 ◎

Table 1 — (2)

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Orange 205 -0.16-Yellow 403-1 (1)-0.04-Benzilano Recall 10 10 10 10 10 10 10 10 10 Glycomonoammonium 0.05 Glycolic acid 10

Sodium glycolate 10

Triethanolamine glycolate 10

Lactic acid 10

Sodium lactate 10

 Malic acid 10

Sodium citrate 10 Cunic acid-One suitable amount-Purified water

PH 3 3.5 3 3 3.5 5 3.5 3.5 3 3 Hair dyeing degree (ΔΕ) 40 40 40 35 30 35 40 31 40 Migrating properties Δ Δ Δ Δ △ Δ Δ X Δ Suppleness Good ◎ ◎ ◎ 〇 Δ 〇 XX Δ

Example 5

 A cream having a pH of 3.0 was prepared from the composition shown below, and the hair bundle was treated in the same manner as in Examples 1 to 4. Hair dyeing properties, no discoloration during hair dyeing, migratory properties The hair feel, shampoo fastness and formulation stability were all good.

 (% By weight: black 4 0 1 0 0.3 Screen 2 0 0 Montmoly mouth 10 0 Setostearyl alcohol 80

POE (30) stearyl ether 10 pyrendalcol 50 glycol ammonium olenoate 100 fragrance 0 4 ethanol 200 purified water Balance Example 6

Based on the composition shown below, preparations were prepared with a pH of 3.0, using the agent A as a laying agent and the agent B as a foam setting agent. Each of these agents A and B was filled in an aerosol can together with a propellant (LPG) (weight ratio of undiluted solution Z propellant = 92/8). The hair bundles were subjected to A-agent treatment and B-agent treatment sequentially using these aerosol cans, and they showed hair dyeing properties, no discoloration during hair dyeing, dye transfer properties, hair feel, shampoo fastness, The drug product stability was all good. (Agent A)

 (Wt%) ammonium glycolate 10.0

 POE (30) Stearyl ether 0 4 Amidoamine 0 2 Cation Idori Senorerose 0 3 Soprengry cone 0 Fragrance 0 3 Ethanol 0 200 Purified water balance (B agent)

 (Wt%) acane dye 5.0

P〇 E (27) glyceryl ether 100 POE (30) stearyl ether 0 3 stearyl trimethylammonium chloride 0 2 cationized senorelose 0 3 polymetaryl ester 0 3 fragrance 0 2 Penzinole noreco 3 0 Ethanore 2 0 0 Purified water Balance Example 7

 From the composition shown below, a preparation having pH 3.0 was prepared as a tonic agent A, and a liquid B was prepared as a foam split-coat U. The same experiment as in Example 6 was carried out except for using these A agent and B agent, and it was found that the hair dyeing property, the absence of discoloration during hair dyeing, the dye transfer property, the feel of hair, the shampoo fastness, The degree of no damage and the degree of damage repair were both good.

 (Agent A)

 (weight%)

P C A—N a 3.0 Cuenoic acid 0 3

1-Men Tonore 0 1 Isopro Pinole Metinolenophenol 0 Fragrance 0 3 Hexylene glycol Cornole 20 Ethanore 30 0 Purified Water Balance (B)

 (% By weight) Gardenia blue pigment 3.0 Palm oil fatty acid diethanolamine 0 3 Dimethyl silicon (SH200-30CS) 70 Dimethylsilicon (SH200-0-100, OOOCS) 30

POE (30) stearyl ether 0 3 stearyl chloride trimethylammonium 0 2 ammonium glycolate ammonium 50 Perfume 0 2 Black 4 0 1 0 0 0 3 Purple 4 0 1 0 0 0 1 Glycerin 0 5 Penzinoleanolole 5 0 Ethanol 2 0 0 Purified water Balance Example 8

 A gel agent having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4.The hair dyeing performance was gradually dyed with the lapse of the treatment time. The hair effect was developed and good hair dyeing was obtained.No discoloration at the time of hair dyeing, transferability, hair feel, shampoo fastness, degree of no damage and damage repair were all good. .

(Weight. /.) Glycine 3.0 Red No. 106 No. 02 Hydroxypropinoresolenorose 10 0 Cation Dino senorelose 0 3 Dipropylene Glyconore 20 0 Yuka Former 210 1 110 Cuenoic acid 0 2 Benzyla Noreco nore 1 0 0 Echinorea noreco no 5 0 0 Fragrance 0.5 Purified water balance Example 9

 A hair mousse having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4. Dyeing properties, hair feel, shampoo fastness, and formulation stability were all good.

 (Wt%) orange 2 0 5 0.2 0.2 feniralanine 5

 Hekino Lenguri Cornole 2

 Promoise E

 Promoise W

 Methylpolysiloxane (100,000) 45 Methylpolysiloxane (30 cs) 25 POE (30) Stearyl ether 04 Palm oil fatty acid diethanolamide 0 3 Yuka Former 310 009 Glycomonate ammonium 0 0 Fragrance 0

 Penzino Lea Nore 0 0 Eta Nore 0

 Cuenoic acid

Purified water balance Example 1 o

 A hair having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4.Hair dyeing properties, no discoloration during hair dyeing, migratory properties The hair feel, shampoo fastness, and formulation stability were all good.

 (Wt%) Black 4 0 1 0 1 Purple 4 0 1 0

 Pyridoxine hydrochloride 5

 Hydroxypro pinoresenorelose 0 5 Hydroxypro pinoreme tinoresenorelose 0 5 Ammonium dalicholate 100 0 0 Carbopol 9 4 0 0 5 Cuenoic acid

 Diethylene Gri Cornore

 Benzylanole 5

 Ethanore 2 0

 Methyl paraben 0

 Purified water Example 11-: 14, Comparative example 10-: 12, Reference example

Various compositions shown in Table 2 were prepared, and in the same manner as in Examples 1 to 4, the hair dyeing degree and the migratory property were evaluated, and the vividness (AL *) was measured. The results are shown in Table 2. However, instead of 1 g of goat hair bundle used in Examples 1 to 4 above, human hair black hair 10 cmlg was used as the material to be dyed used for measuring the hair dyeing degree. Was.

 Note that ΔL * is a value measured during the measurement of ΔΕ *, and a smaller value indicates a more vivid color tone.

 As is evident from Table 2, in the case of black hair dyeing, as is clear from the comparison between Examples 11 to 14 and Comparative Examples 10 to 12 and Reference Example, hydrogen peroxide was used in combination. The hair can be dyed in vivid colors. Table 2

Example Comparative example Reference example

11 12 13 14 10 11 12 Orange 205 No. <-0.16-> 0.16 Yellow No. 40 3 <-0.04-> 0.04 Benzinoleanoreconore 10 10 10 15 15 10 10 10 10 Ammonium glycolate 5 10 5 5 5 5 5

Eta ₂ 0 ₂ Water (35% solution) 1 1 2 1 1 1 1 Ethanol <20> Kuen acid or

 Sodium hydroxide <— -—— appropriate amount -—>

Ρ Η 3 2.5 3 3 3 6 3 3 Hair coloring (Δ Ε *) 42 42 47 44 30 28 22 0.3 Vividness (AL *) -12 -12 -15 -13-12-10-10 0.6 ◎ ◎ ◎ ◎ mm ◎ ◎ ◎ Example 15

 A cream having a pH of 3.0 was prepared from the composition shown below, and the hair bundle was treated in the same manner as in Examples 11 to 14. The dye transfer properties, hair feel, shampoo fastness, and formulation stability were all excellent.

 (weight%)

H ₂ 〇 _dihydrate (35%) 2.0 Black 4 0 1 No. 0 3 disk Waran 2 0 0 Monmori port Nai DOO 0 cell Tosute allyl § Bruno L'Ecole 8 0 POE (3 0) stearyl E over § Honoré 0 Propylene Gly Cornole 5 0 Dali cholic acid ammonium 1 0 0 Fragrance 0 4

E D T A 0 5 Ethanol 20 0 Purified water Balance Example 16

Based on the composition shown below, preparations were prepared with a pH of 3.0, using the agent A as a laying agent and the agent B as a foam setting agent. Each of these agents A and B was filled in an aerosol can together with a propellant (LPG) (weight ratio of undiluted solution Z propellant = 92/8). The hair bundles were subjected to A-agent treatment and B-agent treatment using these aerosol cans in order. Hair dyeing properties, no discoloration during hair dyeing, The transferability, hair feel, shampoo fastness, and formulation stability were all good.

 (Agent A)

 (weight%)

H ₂ 〇 _dihydrate (35%) 1.0 glycol acid Anmoniumu 1 0.0 Kuen acid

 POE (30) Stearyl ether 0 4 Amidoamine 0 2 Cation Idenzanorelose 0 3 Sopreng glycol 1 0

E D T A 0 5 Fragrance 0 3 Ethanor 20 0 Purified water Balance (B agent)

 (Wt%) acane dye 2.0

POE (27) Glyceryl ether 0 0 P〇 E (30) Stearyl ether 0 3 Stearyl trimethylammonium chloride 0 2 Loose 0 3 Polymethacrylic acid ester 0 3 Fragrance 0 2 Pendinoleano Recono 3 0 Ethanore 20.0 Purified water balance Example 17

 From the compositions shown below, a pH 3.0 formulation was prepared using the A agent as a tonic and the B solution as a foam split-coat agent. The same experiment as in Example 6 was carried out except for using these A agent and B agent, and it was found that the hair dyeing property, the absence of discoloration during hair dyeing, the dye transfer property, the feel of hair, the shampoo fastness, The degree of no damage and the degree of damage repair were both good.

 (Agent A)

 (weight%)

H ₂ 〇 ₂ water (35%) 2

 P C A-N a 3 0 Cuenoic acid 0 3

1 Menthol 0 Isopropylmethylphenol 0 Fragrance 0 3 Sodium citrate 0 5 Hexylene glycol 20 0 Ethanol 30 0 Purified water balance (B agent)

(% By weight) Gardenia blue pigment 2.0 Palm oil fatty acid diethanolamide 0.3 Dimethyl silicon (SH200—30CS) 7.0 Dimethylsilicon (SH200—100,000 CS3.0

POE (30) Stearyl ether 0.3 Stearyl trimethylammonium chloride 0.2 Ammonium glycoconoleate 5.0 Perfume 0.2 Black 4 0 1 0 0.03 Purple 4 0 1 0 0 0 1 Glycerin 0.5 Penzinoleanorecone 5.0 Ethanore 20.0 Purified water Balance

Example 18

 A pH 3.0 diel was prepared from the composition shown below, and the hair bundle was treated in the same manner as in Examples 1 to 4.The hair dyeing performance was gradually increased with the elapse of the treatment time. The effect was exhibited and good hair dyeing was obtained, and no color fading at the time of hair dyeing, transferability, hair feel, shampoo fastness, degree of no damage, and degree of damage repair were all good.

 (weight%)

H ₂ 〇 ₂ water (3 5%) 1 glycine 3.0 Kuen Sanna Application Benefits um 0.5 red 1 0 6 No. 0.2 hydroxycarboxylic pro Pinot receptacle Honoré loin 1.0 Cationi Dani Senorerose 0 3 Dipropylene glycol 2.0 0 Yukaformer 2 0 1 0 Cuenoic acid 0 2 Benzinorealo alcohol 1 0 0 Etinorealo alcohol 500 0 0 Ammonium glycolate 1 0 0 Fragrance 0 5 Purified water Balance Example 1 9

 A hair mousse having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4. Dyeing properties, hair feel, shampoo fastness, and formulation stability were all good.

 (weight%)

H ₂ 〇 ₂ water (35%)

 Orange 2 0 5 0 2 Phenylamine 5

 Hexylene glycol cone 2

 Promoise E

 Promoise W

Methylpolysiloxane (100,000) 45 Methylpolysiloxane (30 cs) 25 POE (30) Stearyl ether 04 Palm oil fatty acid diethanolamine 0 3 Yukaforma 3 0 1 0 9 Glycolic acid ammonium 1 0 0 Fragrance 0 Penzinole noreco 1 0 0 Ethanol 1 0 Gunoleconic acid 0 5 Cuenoic acid

 Purified water balance Example 20

 A hair having a pH of 3.0 was prepared from the composition shown below, and the hair tresses were treated in the same manner as in Examples 1 to 4. As a result, hair dyeing properties, no discoloration during hair dyeing, and dye transfer properties were observed. The hair feel, shampoo fastness and formulation stability are all good.

 (weight%)

H ₂ 〇 ₂ water (3 5%) 2 Black 4 0 1 No. 0 Purple 4 0 1 No. 0 5 hydrochloride pyridinium Dokishin 5 arsenide Dorokishipuro Pinot receptacle Honoré loin 0 5 arsenide Dorokishipuro Pinot Leme Chino receptacle Honoré port scan 0 5 glycol acid Ammonium 0 0 Carbopol 9 4 0 0 5 Cuenoic acid Sodium methyl methacrylate 0.5 Diethylene glycol cornole 1 Penzinoleanol cornole 5 Ethanol 20 Methyl paraben 0.1 Purified water residue Hair dye containing the ammonium dalicholate according to claim 1 of the present invention The composition has good hair dyeing properties, has little discoloration during shampooing, has no transferability to clothing, skin, etc., and has suppleness and excellent combability to hair after dyeing. Attach

 Further, the hair dye composition according to claim 2 of the present invention further comprising hydrogen peroxide in addition to the hair dye composition containing ammonium glycolate according to claim 1 has the following effects. Gives a vivid color tone to black hair.

Claims

The scope of the claims 1. (A) 0.01 to 2% by weight of acid dye or natural pigment  (B) Organic solvent 0.5 to 50% by weight  (C) Ammonium glycolate 0:: ~ 20% by weight Wherein ρ 2. is 2.0 to 4.5: a hair dye composition characterized by: 2. (Α) Acidic dye or natural pigment at 0.0 1-2% by weight  (Β) Organic solvent 0.5 to 50% by weight (C) ammonium glycolate 0.1 to 20 weight ⁰ /.  (D) Hydrogen peroxide 0:! ~ 5 wt% A hair dye composition, characterized in that ρ 2. is 2.0 to 4.5,