UY24923A1 - Procedimiento para preparacion de pirazoles parasiticidas - Google Patents
Procedimiento para preparacion de pirazoles parasiticidasInfo
- Publication number
- UY24923A1 UY24923A1 UY24923A UY24923A UY24923A1 UY 24923 A1 UY24923 A1 UY 24923A1 UY 24923 A UY24923 A UY 24923A UY 24923 A UY24923 A UY 24923A UY 24923 A1 UY24923 A1 UY 24923A1
- Authority
- UY
- Uruguay
- Prior art keywords
- alkyl
- substituent
- alkoxy
- halogen
- independently selected
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000003217 pyrazoles Chemical class 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 7
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- -1 2,4,6-trisubstituted phenyl Chemical group 0.000 abstract 2
- 125000001246 bromo group Chemical group Br* 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000001153 fluoro group Chemical group F* 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- 125000004963 sulfonylalkyl group Chemical group 0.000 abstract 2
- SOWFJRRENUZFJD-UHFFFAOYSA-N 4-(2,2-dibromocyclopropyl)-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole-3-carbonitrile Chemical compound ClC1=CC(C(F)(F)F)=CC(Cl)=C1N1N=C(C#N)C(C2C(C2)(Br)Br)=C1 SOWFJRRENUZFJD-UHFFFAOYSA-N 0.000 abstract 1
- 125000001589 carboacyl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 230000000590 parasiticidal effect Effects 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/10—Anthelmintics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Pharmacology & Pharmacy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Animal Behavior & Ethology (AREA)
- Tropical Medicine & Parasitology (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyridine Compounds (AREA)
Abstract
La presente invención se refiere a un procedimiento para la preparación de compuestos derivados de 1-aril-4-ciclopropilpirazoles de fórmula (I), en la que: R1 es fenilo 2,4,6-trisustituido, en el que los sustituyentes en 2 y 6 se seleccionan independientemente entre halógeno, y el sustituyente 4 se selecciona entre alquilo, alcoxi, sulfonilalquilo; ó piridin-2-ilo 3,5-disustituido, en el que el sutituyente en 3 es halógeno y el sustituyente en 5 se selecciona entre alquilo, alcoxi, sulfonilalquilo; R3 es alquilo, ciano, alcanoílo o fenilo; R5 es H, alquilo, amino o halógeno; R2 y R4 se seleccionan cada uno, independientemente, entre H, alquilo, fluoro, cloro y bromo o, junto al átomo de carbono al que se encuentran unidos, forman un grupo cicloalquilo; R6 y R8 se seleccionan cada uno, independientemente, entre H, alquilo, fluoro, cloro y bromo; R7 es H, alquilo o alcoxi; o una de sus sales aceptables desde el punto de vista agrícola. Dichos compuestos poseen propiedades parasiticidas útiles en en el tratamiento de plantas. Ej. no limitante: 3-ciano-4-(2,2-dibromociclopropil)-1-(2,6-dicloro-4-trifluorometilfenil)pirazol.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9625290.3A GB9625290D0 (en) | 1996-12-05 | 1996-12-05 | Parasiticidal agents |
| GBGB9702235.4A GB9702235D0 (en) | 1997-02-04 | 1997-02-04 | Parasiticidal agents |
| GBGB9712045.5A GB9712045D0 (en) | 1997-06-10 | 1997-06-10 | Parasiticidal agents |
| UY24798A UY24798A1 (es) | 1996-12-05 | 1997-12-03 | Pirazoles parasiticidas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UY24923A1 true UY24923A1 (es) | 1998-09-01 |
Family
ID=27268619
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UY24798A UY24798A1 (es) | 1996-12-05 | 1997-12-03 | Pirazoles parasiticidas |
| UY24923A UY24923A1 (es) | 1996-12-05 | 1998-03-12 | Procedimiento para preparacion de pirazoles parasiticidas |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UY24798A UY24798A1 (es) | 1996-12-05 | 1997-12-03 | Pirazoles parasiticidas |
Country Status (39)
| Country | Link |
|---|---|
| US (2) | US6075043A (es) |
| EP (1) | EP0946515B1 (es) |
| JP (2) | JP3950483B2 (es) |
| KR (1) | KR100354311B1 (es) |
| CN (1) | CN1106386C (es) |
| AR (1) | AR013879A1 (es) |
| AT (1) | ATE233736T1 (es) |
| AU (1) | AU720705B2 (es) |
| BG (1) | BG64127B1 (es) |
| BR (1) | BR9713565A (es) |
| CA (1) | CA2273951C (es) |
| CO (1) | CO5031251A1 (es) |
| CZ (1) | CZ295295B6 (es) |
| DE (1) | DE69719547T2 (es) |
| DK (1) | DK0946515T3 (es) |
| DZ (1) | DZ2360A1 (es) |
| EA (1) | EA002278B1 (es) |
| ES (1) | ES2191870T3 (es) |
| HR (1) | HRP970663B1 (es) |
| HU (1) | HUP0000544A3 (es) |
| ID (1) | ID21556A (es) |
| IL (1) | IL129866A (es) |
| IS (1) | IS1982B (es) |
| MA (1) | MA24414A1 (es) |
| MY (1) | MY117021A (es) |
| NO (2) | NO313518B1 (es) |
| NZ (1) | NZ335611A (es) |
| OA (1) | OA11055A (es) |
| PA (1) | PA8442101A1 (es) |
| PE (1) | PE20199A1 (es) |
| PL (1) | PL190926B1 (es) |
| PT (1) | PT946515E (es) |
| RS (1) | RS49720B (es) |
| SK (1) | SK285203B6 (es) |
| TN (1) | TNSN97197A1 (es) |
| TW (1) | TW524667B (es) |
| UA (1) | UA60321C2 (es) |
| UY (2) | UY24798A1 (es) |
| WO (1) | WO1998024767A1 (es) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW524667B (en) | 1996-12-05 | 2003-03-21 | Pfizer | Parasiticidal pyrazoles |
| GB9801851D0 (en) * | 1998-01-29 | 1998-03-25 | Pfizer Ltd | Parasiticidal agents |
| GB9810354D0 (en) * | 1998-05-14 | 1998-07-15 | Pfizer Ltd | Heterocycles |
| GB9811050D0 (en) * | 1998-05-22 | 1998-07-22 | Pfizer Ltd | Pyrazoles |
| AR021608A1 (es) * | 1998-12-11 | 2002-07-31 | Merial Ltd | Represion de artropodos en animales |
| US6531501B1 (en) | 1998-12-11 | 2003-03-11 | Aventis Cropscience, S.A. | Control of arthropods in animals |
| GB9916052D0 (en) * | 1999-07-08 | 1999-09-08 | Pfizer Ltd | Anthelmintic compositions |
| WO2001040195A2 (en) | 1999-12-02 | 2001-06-07 | Aventis Cropscience S.A. | Control of arthropods in animals |
| AU2003218758A1 (en) * | 2002-03-14 | 2003-09-22 | Syngenta Participations Ag | Derivatives of 1-phenyl-3-phenylpyrazole as herbicides |
| CH697663B1 (de) * | 2003-01-07 | 2009-01-15 | Lanxess Deutschland Gmbh | Pyrazolylalkine. |
| WO2005023773A1 (en) * | 2003-09-04 | 2005-03-17 | Pfizer Limited | Process for the preparation of substituted aryl pyrazoles |
| US7514464B2 (en) * | 2003-12-18 | 2009-04-07 | Pfizer Limited | Substituted arylpyrazoles |
| GB0329314D0 (en) * | 2003-12-18 | 2004-01-21 | Pfizer Ltd | Substituted arylpyrazoles |
| CA2560510C (en) | 2004-03-18 | 2009-10-13 | Pfizer Inc. | N-(1-arylpyrazol-4yl) sulfonamides and their use as parasiticides |
| US20070149464A1 (en) * | 2005-06-15 | 2007-06-28 | Pfizer Inc. | Combination |
| CN101228134A (zh) | 2005-06-15 | 2008-07-23 | 辉瑞有限公司 | 用作杀寄生虫剂的取代芳基吡唑 |
| US7645786B2 (en) | 2005-06-15 | 2010-01-12 | Pfizer Inc. | Substituted arylpyrazoles |
| US20080176865A1 (en) * | 2005-06-15 | 2008-07-24 | Pfizer Limited | Substituted arylpyrazoles |
| US20080146643A1 (en) * | 2005-06-15 | 2008-06-19 | Pfizer Limited | Combination |
| CA2614282A1 (en) | 2005-07-06 | 2007-01-11 | Sepracor Inc. | Combinations of eszopiclone and trans 4-(3,4-dichlorophenyl)-1,2,3,4-tetrahydro-n-methyl-1-napthalenamine or trans 4-(3,4-dichlorophenyl)-1,2,3,4-tetrahydro-1-napthalenamine, and methods of treatment of menopause and mood, anxiety, and cognitive disorders |
| EP1783114A1 (en) * | 2005-11-03 | 2007-05-09 | Novartis AG | N-(hetero)aryl indole derivatives as pesticides |
| DE102006061537A1 (de) * | 2006-12-27 | 2008-07-03 | Bayer Healthcare Ag | Mittel zur Bekämpfung von Parasiten an Tieren |
| DE102006061538A1 (de) | 2006-12-27 | 2008-07-03 | Bayer Healthcare Ag | Kombinationsprodukt zur Bekämpfung von Parasiten an Tieren |
| JP2013523805A (ja) | 2010-04-08 | 2013-06-17 | ゾエティス・エルエルシー | 殺虫剤および殺ダニ剤としての置換３，５−ジフェニル−イソオキサゾリン誘導体 |
| CN103270036B (zh) | 2010-08-05 | 2015-11-25 | 佐蒂斯有限责任公司 | 作为抗寄生物剂的异噁唑啉衍生物 |
| BR112013006686A2 (pt) | 2010-09-24 | 2017-11-14 | Zoetis Llc | isoxazolina oximas como agentes antiparasitários |
| WO2012120399A1 (en) | 2011-03-10 | 2012-09-13 | Pfizer Inc. | Spirocyclic isoxazoline derivatives as antiparasitic agents |
| WO2012127347A1 (en) | 2011-03-22 | 2012-09-27 | Pfizer Inc. | Isoxazoline derivatives as antiparasitic agents |
| ES2609005T3 (es) | 2011-06-30 | 2017-04-18 | Agente para combatir parásitos en animales | |
| BR112014018650A8 (pt) | 2012-02-03 | 2017-07-11 | Zoetis Llc | Derivados azetidina de dihidrofurano como agentes antiparasitários |
| JO3626B1 (ar) | 2012-02-23 | 2020-08-27 | Merial Inc | تركيبات موضعية تحتوي على فيبرونيل و بيرميثرين و طرق استخدامها |
| MX336431B (es) | 2012-05-09 | 2016-01-18 | Zoetis Services Llc | Derivados de azetidina como agentes antiparasitarios. |
| MX363173B (es) | 2012-12-12 | 2019-03-12 | Zoetis Services Llc | Composiciones inyectables de fenilpirazol. |
| MX2020001525A (es) | 2017-08-24 | 2020-03-20 | Novo Nordisk As | Composiciones de peptido similar al glucagon tipo 1 (glp-1) y sus usos. |
| CN111116478B (zh) * | 2019-12-18 | 2021-10-26 | 浙江金伯士药业有限公司 | 一种兽用抗生素维吉霉素中间体的制备方法 |
| IL294521A (en) | 2020-02-18 | 2022-09-01 | Novo Nordisk As | glp-1 compounds and their uses |
| CN115894374A (zh) * | 2023-02-16 | 2023-04-04 | 广州佳途科技股份有限公司 | 一种氟甲腈的制备方法及其应用 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2658725A1 (de) * | 1976-12-24 | 1978-07-06 | Bayer Ag | Mittel zur bekaempfung von tierischen ektoparasiten mit stark ausgepraegter residualwirkung |
| US4479968A (en) | 1980-10-17 | 1984-10-30 | The Wellcome Foundation Ltd. | Control of ectoparasitic infestations of pigs |
| GB2086302A (en) * | 1980-10-24 | 1982-05-12 | Bone Cravens Ltd | Prefill Valve System |
| US5547974A (en) * | 1985-12-20 | 1996-08-20 | Rhone-Poulenc Agriculture Ltd. | Derivatives of N-phenylpyrazoles |
| GB8531485D0 (en) * | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
| US5232940A (en) * | 1985-12-20 | 1993-08-03 | Hatton Leslie R | Derivatives of N-phenylpyrazoles |
| GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
| GB8713769D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
| GB8613914D0 (en) * | 1986-06-07 | 1986-07-09 | Coopers Animal Health | Liquid formulations |
| ATE65013T1 (de) * | 1986-12-05 | 1991-07-15 | Ciba Geigy Ag | Ektoparasitizide nicht-waessrige pour-onfl¨ssigformulierung. |
| DE3706993A1 (de) * | 1987-03-05 | 1988-09-15 | Bayer Ag | 5-amino-3-halogenalkyl-1-aryl-pyrazole |
| SE455750B (sv) | 1987-06-11 | 1988-08-01 | Ericsson Telefon Ab L M | Digitalt tidsmultiplext mobiltelefonisystem med ett effektivt utnyttjande av varje tidsram |
| GB9120641D0 (en) * | 1991-09-27 | 1991-11-06 | Ici Plc | Heterocyclic compounds |
| ZA94170B (en) * | 1993-01-20 | 1995-03-15 | Soltec Res Pty Ltd | Ectoparasiticidal formulation |
| AUPM437194A0 (en) * | 1994-03-11 | 1994-03-31 | Commonwealth Scientific And Industrial Research Organisation | Pesticide formulation |
| WO1997007202A1 (en) | 1995-08-11 | 1997-02-27 | Novo Nordisk A/S | Novel lipolytic enzymes |
| GB9601128D0 (en) * | 1995-08-11 | 1996-03-20 | Pfizer Ltd | Parasiticidal compounds |
| JPH0987111A (ja) * | 1995-09-27 | 1997-03-31 | Sumitomo Chem Co Ltd | 害虫駆除用毒餌剤 |
| FR2739255B1 (fr) * | 1995-09-29 | 1998-09-04 | Rhone Merieux | Composition antiparasitaire pour le traitement et la protection des animaux de compagnie |
| ES2191076T3 (es) * | 1995-12-19 | 2003-09-01 | Bayer Cropscience Sa | Nuevos derivados de 1-aril-pirazol y su empleo como plaguicidas. |
| GR1002899B (el) * | 1996-03-29 | 1998-05-11 | Rhone Merieux | Περιλαιμιο κατα ψυλλων και κροτωνων για σκυλους και γατες, με βαση ν-φαινυλπυραζολη |
| IE80657B1 (en) * | 1996-03-29 | 1998-11-04 | Merial Sas | Insecticidal combination to control mammal fleas in particular fleas on cats and dogs |
| GR970100096A (el) * | 1996-03-29 | 1997-11-28 | Merial | Εξωτερικη διαταξη κατα των παρασιτων για βοοειδη με βαση τη ν-φαινυλπυραζολη, ειδικα σκουλαρικια. |
| IE970215A1 (en) * | 1996-03-29 | 1997-10-08 | Rhone Merieux | Direct pour-on skin solution for antiparasitic use in cattle¹and sheep |
| TW524667B (en) | 1996-12-05 | 2003-03-21 | Pfizer | Parasiticidal pyrazoles |
| US7100379B2 (en) * | 2003-08-14 | 2006-09-05 | Samsung Electronics Co., Ltd. | Water supply control apparatus and method for ice maker |
-
1997
- 1997-10-24 TW TW086115810A patent/TW524667B/zh not_active IP Right Cessation
- 1997-11-25 BR BR9713565-8A patent/BR9713565A/pt not_active Application Discontinuation
- 1997-11-25 AU AU54859/98A patent/AU720705B2/en not_active Ceased
- 1997-11-25 DK DK97951271T patent/DK0946515T3/da active
- 1997-11-25 EP EP97951271A patent/EP0946515B1/en not_active Expired - Lifetime
- 1997-11-25 ES ES97951271T patent/ES2191870T3/es not_active Expired - Lifetime
- 1997-11-25 PT PT97951271T patent/PT946515E/pt unknown
- 1997-11-25 ID IDW990469A patent/ID21556A/id unknown
- 1997-11-25 PL PL333922A patent/PL190926B1/pl not_active IP Right Cessation
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Effective date: 20180312 |