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US20090088352A1 - Tractor hydraulic fluid compositions and preparation thereof - Google Patents

Tractor hydraulic fluid compositions and preparation thereof Download PDF

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Publication number
US20090088352A1
US20090088352A1 US11/930,685 US93068507A US2009088352A1 US 20090088352 A1 US20090088352 A1 US 20090088352A1 US 93068507 A US93068507 A US 93068507A US 2009088352 A1 US2009088352 A1 US 2009088352A1
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Prior art keywords
hydraulic fluid
fluid composition
tractor hydraulic
base oil
viscosity
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US11/930,685
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Inventor
John A. Zakarian
Angelito Tirona
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Chevron USA Inc
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Chevron USA Inc
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Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Priority to US11/930,685 priority Critical patent/US20090088352A1/en
Priority to PCT/US2008/075758 priority patent/WO2009042396A1/en
Priority to EP08799372.1A priority patent/EP2207868A4/en
Priority to BRPI0817476-8A priority patent/BRPI0817476A2/pt
Priority to JP2010527011A priority patent/JP2010540717A/ja
Priority to CN200880115864A priority patent/CN101855328A/zh
Priority to CA2700630A priority patent/CA2700630A1/en
Priority to MX2010003302A priority patent/MX2010003302A/es
Publication of US20090088352A1 publication Critical patent/US20090088352A1/en
Assigned to CHEVRON U.S.A. INC. reassignment CHEVRON U.S.A. INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: TIRONA, ANGELITO, ZAKARIAN, JOHN A.
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/002—Traction fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028—Overbased salts thereof
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • C—CHEMISTRY; METALLURGY
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbased sulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089—Overbased salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/065—Saturated Compounds
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature

Definitions

  • the invention relates generally to tractor hydraulic fluid compositions, and more specifically to tractor hydraulic fluid compositions having reduced levels of viscosity modifiers.
  • Tractor hydraulic fluids are multi-application lubricants that are used to lubricate the moving parts of off-highway mobile equipment, such as tractors, off-highway equipment, construction equipment, etc.
  • such fluids are designed to lubricate all of transmissions, differentials, final-drive planetary gears, wet-brakes, and hydraulic systems of such equipment, meeting specific manufacturer requirements.
  • Equipment manufacturers want lower viscosities at lower temperature (i.e., ⁇ 40° C.) while maintaining high temperature (i.e., 100° C.) thickening.
  • Tractor hydraulic fluid compositions in the prior art typically employ a Group I, II, III, IV (that is, a synthetic PAO (for poly ⁇ -olefin)), or mixtures thereof as a base oil stock.
  • the groups are broad categories of base stocks developed by the American Petroleum Institute (API) for the purpose of creating guidelines for base oils, Recent reforming processes have formed a new class of oil, e.g., Fischer-Tropsch base oil (FTBO), wherein the oil, fraction, or feed originates from or is produced at some stage by a Fischer-Tropsch process.
  • FTBO Fischer-Tropsch base oil
  • the Fischer-Tropsch synthesis products can be obtained by well-known processes such as, for example, the commercial SASOL® Slurry Phase Fischer-Tropsch technology, the commercial SHELL® Middle Distillate Synthesis (SMDS) Process, or by the non-commercial EXXON® Advanced Gas Conversion (AGC-21) process. Details of these processes and others are described in, for example, EP-A-776959, EP-A-668342; U.S. Pat. Nos. 4,943,672, 5,059,299, 5,733,839, and RE39073; and US Published Application No. 2005/0227866, WO-A-9934917, WO-A-9920720 and WO-A-05107935.
  • the Fischer-Tropsch synthesis product usually comprises hydrocarbons having 1 to 100, or even more than 100 carbon atoms, and typically includes paraffins, olefins and oxygenated products.
  • Fischer Tropsch is a viable process to generate clean alternative hydrocarbon products.
  • an intermediate feed or product may be fractionated by atmospheric or vacuum distillation.
  • the bottoms material collected from the vacuum distillation column comprises a mixture of high-boiling hydrocarbons.
  • U.S. Pat. No. 7,189,682 discloses a tractor hydraulic fluid using a mixture of viscosity modifier types of: 2 to 30 wt. % of a first viscosity modifier having a weight average molecular weight of 10,000 to 60,000; and 1 to 6 wt. % of a second viscosity modifier having a weight average molecular weight greater than that of the first viscosity modifier, and in the range of 50,000 to 200,000.
  • Suitable oils to be used in the tractor hydraulic fluid include those prepared by Fischer-Tropsch syntheses.
  • viscosity modifiers may reduce the shear stability of tractor hydraulic fluid in certain applications. There is a need for an improved tractor hydraulic fluid composition having reduced levels of viscosity index modifiers, while still meeting the target kinematic viscosity and Sow temperature Brookfield viscosity specifications for tractor equipment.
  • a tractor hydraulic fluid composition comprising (i) a lubricating base oil; (ii) from 0 to 10 wt % of a viscosity modifier; and (iii) 0-10 wt % of at least an additive package.
  • the lubricating base oil has consecutive numbers of carbon atoms and less than 7.5 wt % naphthene carbon by n-d-M
  • the tractor hydraulic fluid composition has a Brookfield viscosity of less than 70,000 mPa.s at ⁇ 35° C. and a kinematic viscosity of at least 7.0 mm 2 /s at 100° C.
  • a method for producing a tractor hydraulic fluid composition having a Brookfield viscosity of less than 70,000 mPa.s at ⁇ 35° C., a kinematic viscosity of at least 7.0 mm 2 /s at 100° C.
  • the method comprising blending (i) a lubricating base oil having consecutive numbers of carbon atoms and less than 7.5 wt % naphthenic carbon by n-d-M; with (ii) from 0 to 10 wt % of a viscosity modifier; and (iii) 0-10 wt % of at least an additive package.
  • a process for lubricating equipment comprising: supplying to a fluid reservoir of an off-highway mobile equipment a tractor hydraulic fluid composition comprising (i) a lubricating base oil; (ii) from 0 to 10 wt % of a viscosity modifier; and (iii) 0-10 wt % of at least an additive package; wherein the lubricating base oil consists essentially of at least an isomerized base oil having consecutive numbers of carbon atoms and less than 7.5 wt % naphthenic carbon by n-d-M; and the tractor hydraulic fluid composition has a Brookfield viscosity of less than 70,000 mPa.s at ⁇ 35° C. and a kinematic viscosity of at least 7.0 mm 2 /s. at 100° C.
  • FIG. 1 is a graph illustrating the effect of base oil viscosity on the Brookfield viscosity at ⁇ 35 ° C., comparing blends employing isomerized base oils with prior art blends containing API Group I and API Group II base oils.
  • Fischer-Tropsch derived means that the product, fraction, or feed originates from or is produced at some stage by a Fischer-Tropsch process.
  • Fischer-Tropsch base oil may be used interchangeably “with “FT base oil,” “FTBO,” “GTL base oil” (GTL: gas-to-liquid), or “Fischer-Tropsch derived base oil.”
  • isomerized base oil refers to a base oil made by isomerization of a waxy feed.
  • a “waxy feed” comprises at least 40 wt % n-paraffins. In one embodiment, the waxy feed comprises greater than 50 wt % n-paraffins. In another embodiment, greater than 75 wt % n-paraffins. In one embodiment, the waxy feed also has very low levels of nitrogen and sulphur, e.g., less than 25 ppm total combined nitrogen and sulfur, or in other embodiments less than 20 ppm. Examples of waxy feeds include slack waxes, deoiled slack waxes, refined foots oils, waxy lubricant raffinates.
  • n-paraffin waxes n-paraffin waxes, NAO waxes, waxes produced in chemical plant processes, deoiled petroleum derived waxes, microcrystalline waxes, Fischer-Tropsch waxes, and mixtures thereof.
  • the waxy feeds have a pour point of greater than 50° C. In another embodiment, greater than 60° C.
  • Pour Point Reducing Blend Component refers to an isomerized waxy product with relatively high molecular weights and a specified degree of alkyl branching in the molecule, such that it reduces the pour point of lubricating base oil blends containing it. Examples of a Pour Point Reducing Blend Component are disclosed,in U.S. Pat. Nos. 6,150,577 and 7,053,254, and Patent Publication No. US 2005-0247600 A1.
  • a Pour Point Reducing Blend Component can be: 1) an isomerized Fischer-Tropsch derived bottoms product; 2) a bottoms product prepared from art isomerized highly waxy mineral oil; or 3) an isomerized oil having a kinematic viscosity at 100° C. of at least about 8 mm 2 /s made from polyethylene plastic.
  • “Kinematic viscosity” is a measurement in mm 2 /s of the resistance to flow of a fluid under gravity* determined by ASTM D445-06,
  • Viscosity index (VI) is an empirical, unit-less number indicating the effect of temperature change on the kinematic viscosity of the oil. The higher the VI of an oil, the lower its tendency to change viscosity with temperature. Viscosity index is measured according to ASTM D 2270-04.
  • the boiling range distribution (SIMDIST TBP) of base oil, by wt %, is determined by simulated distillation according to ASTM D 6352-04, “Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 to 700° C. by Gas Chromatography.”
  • Noack volatility is defined as the mass of oil, expressed in weight %, which is lost when the oil is heated at 250° C. with a constant flow of air drawn through it for 60 min., measured according to ASTM D5800-05, Procedure B.
  • An alternative method to use is TGA Noack, by ASTM D6375-05. Where the TGA Noack is used, it is indicated.
  • Brookfield viscosity is used to determine the internal fluid-friction of a lubricant during cold temperature operation, which can be measured by ASTM D 2983-04.
  • Pul point is a measurement of the temperature at which a sample of base oil will begin to flow under certain carefully controlled conditions, which can be determined as described in ASTM D 5950-02.
  • consecutive numbers of carbon atoms means that the base oil has a distribution of hydrocarbon molecules over a range of carbon numbers, With every number of carbon numbers in-between.
  • the base oil may have hydrocarbon molecules ranging from C22 to C36 or from C30 to C60 with every carbon number in-between.
  • the hydrocarbon molecules of the base oil differ from each other by consecutive numbers of carbon atoms, as a consequence of the waxy feed also having consecutive numbers of carbon atoms.
  • the source of carbon atoms is CD and the hydrocarbon molecules are built up one carbon atom at a time. Petroleum-derived waxy feeds have consecutive numbers of carbon atoms.
  • PAO poly-alpha-olefin
  • the molecules of an isomerized base oil have a more linear structure, comprising a relatively long backbone with short branches.
  • the classic textbook description of a PAO is a star-shaped molecule, and in particular tridecane, which is illustrated as three decane molecules attached at a central point. While a star-shaped molecule is theoretical, nevertheless PAO molecules have fewer and longer branches than the hydrocarbon molecules that make up the isomerized base oil disclosed herein.
  • “Molecules with cycloparaffinic functionality” mean any molecule that is, or contains as one or more substituents, a monocyclic or a fused multicyclic saturated hydrocarbon group.
  • “Molecules with monocycloparaffinic functionality” mean any molecule that is a monocyclic saturated hydrocarbon group of three to seven ring carbons or any molecule that is substituted with a single monocyclic saturated hydrocarbon group of three to seven ring carbons.
  • “Molecules with multicycloparaffinic functionality” mean any molecule that is a fused multicyclic saturated hydrocarbon ring group of two or more fused rings, any molecule that is substituted with one or more fused multicyclic saturated hydrocarbon ring groups of two or more fused rings, or any molecule that is substituted with more than one monocyclic saturated hydrocarbon group of three to seven ring carbons.
  • Molecules with cycloparaffinic functionality, molecules with monocycloparaffinic functionality, and molecules with multicycloparaffinic functionality are reported as weight percent and are determined by a combination of Field Ionization Mass Spectroscopy (FIMS), HPLC-UV for aromatics, and Proton NMR for olefins, further fully described herein.
  • FIMS Field Ionization Mass Spectroscopy
  • Oxidator BN measures the response of a lubricating oil in a simulated application. High values, or long times to adsorb one liter of oxygen, indicate good stability. Oxidator BN can be measured via a Dornte-type oxygen absorption apparatus (R. W. Dornte “Oxidation of White Oils,” Industrial and Engineering Chemistry, Vol. 28, page 26, 1936). Using this apparatus, under 1 atmosphere of pure oxygen at 340° F., the time to absorb 1000 ml of O 2 by 100 g of oil is reported. In the Oxidator BN test, 0.8 ml of catalyst is used per 100 grams of oil.
  • the catalyst is a mixture of soluble metal-naphthenates simulating the average metal analysis of used crankcase oil.
  • the additive package is 80 millimoles of zinc bispolypropylenephenyl-dithiophosphate per 100 grams of oil.
  • Molecular characterizations can be performed by methods known in the art, including Field Ionization Mass Spectroscopy (FIMS) and n-d-M analysis (ASTM D 3238-95 (Re-approved 2005) with normalization).
  • FIMS Field Ionization Mass Spectroscopy
  • ASTM D 3238-95 Re-approved 2005
  • the base oil is characterized as alkanes and molecules with different numbers of unsaturations.
  • the molecules with different numbers of unsaturations may be comprised of cycloparaffins, olefins, and aromatics. If aromatics are present in significant amount, they would be identified as 4-unsaturations. When olefins are present in significant amounts, they would be identified as 1-unsaturations.
  • the total of the 1-unsaturations, 2-unsaturations, 3-unsaturations, 4-unsaturations, 5-unsaturations, and 6-unsaturations from the FIMS analysis, minus the wt % olefins by proton NMR, and minus the wt % aromatics by HPLC-UV is the total weight percent of molecules with cycloparaffinic functionality. If the aromatics content was not measured, it was assumed to be less than 0.1 wt % and not included in the calculation for total weight percent of molecules with cycloparaffinic functionality.
  • the total weight percent of molecules with cycloparaffinic functionality is the sum of the weight percent of molecules with monocycloparaffinic functionality and the weight percent of molecules with multicycloparaffinic functionality.
  • Molecular weights are determined by ASTM D2503-92 (Reapproved 2002). The method uses thermoelectric measurement of vapour pressure (VPO). In circumstances where there is insufficient sample volume, an alternative method of ASTM D2502-04 may be used; and where this has been used it is indicated.
  • VPO vapour pressure
  • Density is determined by ASTM D4052-96 (Reapproved 2002). The sample is introduced into an oscillating sample tube and the change in oscillating frequency caused by the change in the mass of the tube is used in conjunction with calibration data to determine the density of the sample.
  • Weight percent olefins can be determined by proton-NMR according to the steps specified herein.
  • the olefins are conventional olefins, i.e. a distributed mixture of those olefin types having hydrogens attached to the double bond carbons such as: alpha, vinylidene, cis, trans, and tri-substituted, with a detectable allylic to olefin integral ratio between 1 and 2.5. When this ratio exceeds 3, it indicates a higher percentage of tri or tetra substituted olefins being present, thus other assumptions known in the analytical art can be made to calculate the number of double bonds in the sample.
  • the steps are as follows: A) Prepare a solution of 5-10% of the test hydrocarbon in deuterochloroform. B) Acquire a normal proton spectrum of at least 12 ppm spectral width and accurately reference the chemical shift (ppm) axis, with the instrument having sufficient gain range to acquire a signal without overloading the receiver/ADC, e.g., when a 30 degree pulse is applied, the instrument having a minimum signal digitization dynamic range of 65,000. In one embodiment, the instrument has a dynamic range of at least 260,000.
  • the wt % olefins by proton NMR 100 times the number of double bonds times the number of hydrogens in a typical olefin molecule divided by the number of hydrogens in a typical test substance molecule.
  • the wt % olefins by proton HMR calculation procedure, D works particularly well when the percent olefins result is low, less than 15 wt %.
  • Weight percent aromatics in one embodiment can be measured by HPLC-UV.
  • the test is conducted using a Hewlett Packard 1050 Series Quaternary Gradient High Performance Liquid Chromatography (HPLC) system, coupled with a HP 1050 Diode-Array UV-Vis detector interfaced to an HP Chern-station.
  • HPLC Hewlett Packard 1050 Series Quaternary Gradient High Performance Liquid Chromatography
  • Identification of the individual aromatic classes in the highly saturated base oil can be made on the basis of the UV spectral pattern and the elution time.
  • the amino column used for this analysis differentiates aromatic molecules largely on the basis of their ring-number (or double-bond number). Thus, the single ring aromatic containing molecules elute first, followed by the poly-cyclic aromatics in order of increasing double bond number per molecule.
  • Weight percent aromatic carbon (“Ca”), weight percent naphthenic carbon (“Cn”) and weight percent paraffinic carbon (“Cp”) in one embodiment can be measured by ASTM D3238-95 (Reapproved 2005) with normalization.
  • ASTM D3238-95 (Reapproved 2005) is the Standard Test Method for Calculation of Carbon Distribution and Structural Group Analysis of Petroleum Oils by the n-d-M Method. This method is for “olefin free” feedstocks which are assumed in this application to mean that that olefin content is 2 wt % or less.
  • the normalization process consists of the following: A) If the Ca value is less than zero, Ca is set to zero, and Cn and Cp are increased proportionally so that the sum is 100%, B) If the Cn value is less than zero, Cn is set to zero, and Ca and Cp arc increased proportionally so that the sum is 100%; and C) If both Cn and Ca are less than zero, Cn and Ca are set to zero, and Cp is set to 100%.
  • Extent of branching refers to the number of alkyl branches in hydrocarbons.
  • Branching and branching position can be determined using carbon-13 ( 13 C) NMR according to the following nine-step process: 1) Identify the CH branch centers and the CH 3 branch termination points using the DEPT Pulse sequence (Doddrell, D. T.; D. T. Pegg; M. R. Bendall, Journal of Magnetic Resonance 1982, 48, 323ff). 2) Verify the absence of carbons initiating multiple branches (quaternary carbons) using the APT pulse sequence (Pari, S. L.; J. N. Shoolery, Journal of Magnetic Resonance 1982, 46, 535ff.).
  • the 4-methyl branch fraction is calculated and tabulated, its contribution to the 4+methyls is subtracted to avoid double counting.
  • 5) Calculate the average carbon number. The average carbon number is determined by dividing the molecular weight of the sample by 14 (the formula weight of CH 2 ). 6) The number of branches per molecule is the sum of the branches found in step 4. 7) The number of alkyl branches per 100 carbon atoms is calculated from the number of branches per molecule (step 6) times 100/average carbon number.
  • the measurements can be performed using any Fourier Transform NMR spectrometer, e.g., one having a magnet of 7.0 T or greater.
  • the spectral width for the 13 C NMR studies can be limited to the saturated carbon region, 0-80 ppm vs. TMS (tetramethylsilane). Solutions of 25-50 wt. % in chloroform-dl are excited by 30 degrees pulses followed by a 1.3 seconds (sec.) acquisition time. In order to minimize non-uniform intensity data, the broadband proton inverse-gated decoupling is used during a 6 sec. delay prior to the excitation pulse and on during acquisition.
  • Samples are doped with 0.03 to 0.05 M Cr (acac) 3 (tris (acetylacetonato)-chromium (III)) as a relaxation agent to ensure full intensities are observed.
  • the DEPT and APT sequences can be carried out according to literature descriptions with minor deviations described in the Varian or Bruker operating manuals.
  • DEFT is Distortionless Enhancement by Polarization Transfer.
  • the DEPT 45 sequence gives a signal all carbons bonded to protons.
  • DEPT 90 shows CH carbons only.
  • DEPT 135 shows CH and CH 3 up and CH 2 180 degrees out of phase (down).
  • APT is attached proton test, known in the art. It allows all carbons to be seen, but if CH and CH 3 are up, then quaternaries and CH 2 are clown.
  • the branching properties of the sample can be determined by 13 C NMR using the assumption in the calculations that the entire sample was iso-paraffinic.
  • the unsaturates content may be measured using Field Ionization Mass
  • the tractor hydraulic fluid composition comprises a number of components, including optional additives, in a matrix of base oil,
  • the base oil (or blends thereof) comprises at least an isomerized base oil which the product itself, its fraction, or feed originates from or is produced at some stage by isomerization of a waxy Iced from a Fischer-Tropsch process (“Fischer-Tropsch derived base oils”).
  • the base oil comprises at least an isomerized base oil made from a substantially paraffinic wax feed (“waxy feed”).
  • Fischer-Tropsch derived base oils are disclosed in a number of patent publications, including for example U.S. Pat. Nos. 6,080,301, 6,090,989, and 6,165,949, and US Patent Publication No. US2004/0079678A1, US20050133409, US20060289337.
  • the Fischer-Tropsch process is a catalyzed chemical reaction in which carbon monoxide and hydrogen are converted into liquid hydrocarbons of various forms including a light reaction product and a waxy reaction product, with both being substantially paraffinic.
  • the isomerized base oil has consecutive numbers of carbon atoms and has less than 7.5-wt % naphthenie carbon by n-d-M with normalization. In another embodiment the isomerized base oil has consecutive numbers of carbon atoms and has less than 5 wt % naphthenie carbon by n-d-M with normalization. In one embodiment, the isomerized base oil made from a waxy feed has a kinematic viscosity at 100° C. between 1.5 and 3.5 mm 2 /s.
  • the isomerized base oil is made by a process in which the hydroisomerization dewaxing is performed at conditions sufficient for the base oil to have: a) a weight percent of all molecules with at least one aromatic functionality less than 0.30; b) a weight percent of all molecules with at least one cyeloparaffinic functionality greater than 10; c) a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality greater than 20 and d) a viscosity index greater than 28 ⁇ Ln (Kinematic viscosity at 100° C.)+80.
  • the isomerized base oil is made from a process in which the highly paraffinic wax is hydroisomerized using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, and under conditions of 600-750° F. (315-399° C.) In the process, the conditions for hydroisomerization are controlled such that the conversion of the compounds boiling above 700° F. (371° C.,) in the wax feed to compounds boiling below 700° F. (371 ° C.) is maintained between 10 wt % and 50 wt %.
  • a resulting isomerized base oil has a kinematic viscosity of between 1.0 and 15 mm 2 /s at 100° C. and a Noack volatility of less than 50 weight %.
  • the isomerized base oil has a Noack volatility less than an amount calculated by the following equation: 1000 ⁇ (Kinematic Viscosity at 100°C.) ⁇ 2.7 . In another embodiment, the isomerized base oil has a Noack volatility less than an amount calculated by the following equation: 900 ⁇ (Kinematic Viscosity at 100° C.) ⁇ 2.8 .
  • the isomerized base oil is made from a process in which the highly paraffinic waxy feed is hydroisomerized under conditions for the base oil to have a viscosity index of greater than 130.
  • the isomerized base oil has a traction coefficient of less than 0.023 (or less than 0.021) when measured at a kinematic viscosity of 15 mm 2 /s and at a slide to roll ratio of 40%.
  • the base oil comprises greater than 10 wt. % and less than 70 wt. % total molecules with cycloparaffinic functionality, and a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality greater than 15.
  • the isomerized base oil is obtained from a process in which the highly paraffinic wax is hydroisomerized at a hydrogen to feed ratio from 712.4 to 3562 liter H 2 /liter oil, for the base oil to have a total weight percent of molecules with cycloparaffinic functionality of greater than 10, and a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality of greater than 15.
  • the base oil has a viscosity index greater than an amount defined by the equation: 28 ⁇ Ln (Kinematic viscosity at 100° C.)+95,
  • the isomerized base oil contains between 2 and 7.5 wt % naphthenic carbon as measured by n-d-M.
  • the base oil has a kinematic viscosity of 1.5-3.0 mm 2 /s at 100° C. and 2-3 wt % naphthenic carbon.
  • the tractor hydraulic fluid composition employs a base oil that consists of at least one of the Isomerized base oils described above.
  • the composition consists essentially of at least a Fischer-Tropsch base oil.
  • the composition employs at least a Fischer-Tropsch base oil and optionally 5 to 95 wt. % of at least another type of oil, e.g., lubricant base oils selected from Group I, II, III, IV, and V lubricant base oils as defined in the API Interchange Guidelines, and mixtures thereof. Examples include conventionally used mineral oils, synthetic hydrocarbon oils or synthetic ester oils, or mixtures thereof depending on the application.
  • Mineral lubricating oil base stocks can be any conventionally refined base stocks derived from paraffinic, naphthenic and mixed base crudes.
  • Synthetic lubricating oils that can be used include esters of glycols and complex esters.
  • Other synthetic oils that can be used include synthetic hydrocarbons such as polyalphaolefins; alkyl benzenes, e.g., alkylate bottoms from the alkylation of benzene with tetrapropylene, or the copolymers of ethylene and propylene; silicone oils, e.g., ethyl phenyl polysiloxanes, methyl polysiloxanes, etc., polyglycol oils, e.g., those obtained by condensing butyl alcohol with propylene oxide; etc.
  • the tractor hydraulic fluid composition comprises a reduced level of viscosity modifiers, while still meeting the target kinematic viscosity and low temperature Brookfield viscosity specifications for mobile equipment.
  • this reduced level is in the range of 0 to 10 wt. %.
  • this reduced level ranges from 0.5 to 5 wt. %,
  • the reduced level ranges from 1-3 wt. %.
  • the reduced level is between 0.5 to 2 wt. %.
  • the reduced amount of viscosity modifiers used is a mixture of modifiers selected from polyacrylate or polymethacrylate and polymers comprising vinyl aromatic units and esterified carboxyl-containing units.
  • the first viscosity modifier is a polyacrylate or polymethacrylate having an average molecular weight of 10,000 to 60,000.
  • the second viscosity modifier comprises vinyl aromatic units and esterified carboxyl-containing units, having an average molecular weight of 100,000 to 200,000.
  • the reduced amount of viscosity modifiers comprises a blend of a polymethacrylate viscosity modifier having a weight average molecular weight of 25,000 to 150,000 and a shear stability index less than 5 and a polymethacrylate viscosity modifier having a weight average molecular weight of 500,000 to 1,000,000 and a shear stability index of 25 to 60.
  • the viscosity modifier is selected from the group consisting of ethylene propylene copolymers; styrene-isoprene copolymers; hydrated styrene isoprene copolymers; poly alkyl (meth) acrylates; functionalized poly alkyl (meth) acrylates; and mixtures thereof.
  • the tractor hydraulic fluid comprises at least an additive package.
  • An “additive package” is a mixture of chemical substances designed to impart specific performance properties to the tractor hydraulic fluid.
  • the additive package comprises at least a surfactant, or also known as a dispersant, which can be generally classified as anionic, cationic, zwitterionic, or non-ionic.
  • a dispersant may be used alone or in combination of one or more species or types of dispersants. Examples include an oil-soluble dispersant selected from the group consisting of succinimide dispersants, succinic ester dispersants, succinic ester-amide dispersant, Mannich base dispersant, phosphorylated forms thereof, and boronated forms thereof.
  • the dispersants may be capped with acidic molecules capable of reacting with secondary amino groups.
  • the molecular weight of the hydrocarbyl groups may range from 600 to 3000 for example from 750 to 2500, and as a further example from 900 to 1500.
  • the dispersant is selected from the group of alkenyl succinimide. alkenyl succinimides modified with other organic compounds, alkenyl succinimides modified by post-treatment with ethylene carbonate or boric acid, pentaerythritols, phenate-salicylates and their post-treated analogs, polyamide ashless dispersants, and mixtures thereof.
  • the ashless dispersant may include the products of the reaction of a polyethylene polyamine, e.g., triethylene tetramine or tetraethykne pentamine, with a hydrocarbon substituted carboxylic acid or anhydride made by reaction of a polyolefin, such as polyisobutene, of suitable molecular weight, with an unsaturated polycarboxylic acid or anhydride, e.g., maleic anhydride, maleic acid, fumaric acid, or the like, including mixtures of two or more such substances.
  • the ashless dispersant is a borated dispersant.
  • Borated dispersants maybe formed by boronating (borating) an ashless dispersant having basic nitrogen and/or at least one hydroxyl group in the molecule, such as a succinimide dispersant, succinamide dispersant, succinic ester dispersant, succinic ester-amide dispersant, Mannich base dispersant, or hydrocarbyl amine or polyamine dispersant.
  • the additive package further comprises one or more metallic detergents, which are the metal salts of organic acids.
  • the acids, or mixtures thereof are reacted with inorganic bases such as metal oxides, metal hydroxides, and/or metal carbonates.
  • metallic detergent include an oil-soluble neutral or overbased salt of alkali or alkaline earth metal with one or more of the following acidic substances (or mixtures thereof): (1) a sulfonic acid, (2) a carboxylic acid, (3) a salicylic acid, (4) an alkyl phenol, (5) a sulfurized alkyl phenol, and (6) an organic phosphorus acid characterized by at least one direct carbon-to-phosphorus linkage, such as a phosphonate.
  • Such an organic phosphorus acid may include those prepared by the treatment of an olefin polymer (e.g., polyisobutylene having a molecular weight of 1,000) with a phosphorizing agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulfide, phosphorus trichloride and sulfur, white phosphorus and a sulfur halide, or phosphorothioic chloride.
  • an olefin polymer e.g., polyisobutylene having a molecular weight of 1,000
  • a phosphorizing agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulfide, phosphorus trichloride and sulfur, white phosphorus and a sulfur halide, or phosphorothioic chloride.
  • the metallic detergent is selected from the group of sulfurized or unsulfurized alkyl or alkenyl phenates, alkyl or alkenyl aromatic sulfonates, borated sulfonates, sulfurized or unsulfurized metal salts of multi-hydroxy alkyl or alkenyl aromatic compounds, alkyl or alkenyl hydroxy aromatic sulfonates, sulfurized or unsulfurized alkyl or alkenyl naphthenates, metal salts of alkanoic acids, metal salts of an alkyl or alkenyl multiacid, and chemical and physical mixtures thereof.
  • the additive package further comprises at least a corrosion inhibitor selected from thiazoles, triazoles, and thiadiazoles.
  • a corrosion inhibitor selected from thiazoles, triazoles, and thiadiazoles.
  • examples of such compounds include benzotriazole, tolyltriazole, octyltriazole, decyltriazole, dodecyitriazole, 2-mercapto benzothiazole, 2,5-dimercapto-1,3,4-thiadiazole, 2-mercapto-5-hydrocarbylthio-1,3,4-thiadiazoless 2-mercapto-5-hydrocarbyldithio-1,3,4-thiadiazoles, 2,5-bis(hydrocarbylthio)-1,3,4-thiadiazoles, and 2,5-bis(hydrocarbyldithio)-1,3,4-thiadiazoles.
  • Suitable compounds include the 1,3,4-thiadiazoles, a number of which are available as articles of commerce, and also combinations of triazoles such as tolyltriazole with a 1,3,5-thiadiazole such as a 2,5-bis(alkyldithio)-1,3,4-thiadiazoIe.
  • the 1,3,4-thiadiazoles are generally synthesized from hydrazine and carbon disulfide by known procedures. See, for example, U.S. Pat. Nos. 2,765,289; 2,749,311; 2,760,933; 2,850,453; 2,910,439; 3,663,561; 3,862,798; and 3,840,549.
  • the additive package further includes rust or corrosion inhibitors selected from the group of monocarboxylic acids and polycarboxy lie acids.
  • suitable monocarboxylic acids are octanoic acid, decanoic acid and dodecanoic acid.
  • Suitable polycarboxylic acids include dimer and trimer acids such as are produced from such acids as tall oil fatty acids, oleic acid, linoleic acid, or the like.
  • rust Inhibitor may comprise alkenyl succinic acid and alkenyl succinic anhydride corrosion inhibitors such as, for example, tetrapropenylsuccinic acid, tetrapropenylsuccinic anhydride, tetradecenylsuccinic acid, tetradecenylsuccinic anhydride, hexadecenylsuceinic acid, hexadecenylsuccinic anhydride, and the like.
  • alkenyl succinic acid and alkenyl succinic anhydride corrosion inhibitors such as, for example, tetrapropenylsuccinic acid, tetrapropenylsuccinic anhydride, tetradecenylsuccinic acid, tetradecenylsuccinic anhydride, hexadecenylsuceinic acid, hexadecenylsuccinic anhydr
  • Suitable rust or corrosion inhibitors include ether amines; acid phosphates; amines; polyethoxylated compounds such as ethoxylated amines, ethoxylated phenols, and ethoxylated alcohols; imidazolines; aminosuccinic acids or derivatives thereof, and the like. Mixtures of such rust or corrosion inhibitors can be used.
  • Other examples of rust inhibitors include a polyethoxylated phenol, neutral calcium sulfonate and basic calcium sulfonate.
  • the additive package further comprises at least a friction modifier selected from the group of succinimide, a bis-succinimide, an alkylated fatty amine, an ethoxylated fatty amine, an amide, a glycerol ester, an imidazoline, fatty alcohol, fatty acid, amine, borated ester, other esters, phosphates, phosphites, phosphonates, and mixtures thereof.
  • a friction modifier selected from the group of succinimide, a bis-succinimide, an alkylated fatty amine, an ethoxylated fatty amine, an amide, a glycerol ester, an imidazoline, fatty alcohol, fatty acid, amine, borated ester, other esters, phosphates, phosphites, phosphonates, and mixtures thereof.
  • the additive package further comprises at least an antiwear additive.
  • antiwear additive examples include, but are not limited to, phosphates, carbamates, esters, alkali metal or mixed alkali metal borates, alkaline earth metal borates, dispersions of hydrated alkali metal borates, dispersions of alkaline-earth metal borates, molybdenum complexes, and mixtures thereof.
  • the antiwear additive is selected from the group of a zinc dialkyl dithio phosphate (ZDDP), an alkyl phosphite, a trialkyl phosphite, and amine salts of dialkyl and mono-alkyl phosphoric acid.
  • the additive package may further comprise at least an antioxidant selected from the group of phenolic antioxidants, aromatic amine antioxidants, sulfurized phenolic antioxidants, and organic phosphites, among others.
  • phenolic antioxidants include 2,6-di-tert-butylphenol, liquid mixtures of tertiary butylated phenols, 2,6-di-tert-butyl-4-methylphenol, 4,4′-methylenebis(2,6-di-tert-butylphenol), 2,2′-methylenebis(4-methyl6-tert-butylphenol)3 mixed methylene-bridged polyalkyl phenols, 4,4′-thiobis(2-methyl-6-tert-butylphenol), 4,4′-butylidene-bis(3-methyl-6-tert-butylphenol), 4,4′-isopropylidene-bis(2,6-di-tert-butylphenol), 2,2′-methylene-bis(4-methyl-6-nony
  • the antioxidant is an organic phosphonate having at least one direct carbon-to-phosphorus linkage.
  • Diphenylamine-type oxidation inhibitors include, but are not limited to, alkylated diphenylamine, phenyl-alpha-naphthylamine, and alkylated-alpha-naphthylamine.
  • Other types of oxidation inhibitors include metal dithiocarbamate (e.g., zinc dithiocarbamate), and 15-methylenebis(dibutyldithiocarbamate).
  • the additive package comprises at least an extreme pressure anti-wear agent (EP/AW Agent).
  • EP/AW Agent extreme pressure anti-wear agent
  • examples include zinc dialky-1-dithiophosphate (primary alkyl, secondary alkyl, and aryl type), diphenyl sulfide, methyl trichlorostearate, chlorinated naphthalene, fluoroalkylpolysiloxane, lead naphthenate, neutralized phosphates, dithiophosphates, and sulfur-free phosphates.
  • the additive package may also include conventional additives in addition to those described above.
  • additives include but are not limited to seal swell agents, colorants, antifoam and defoamer additives such as alkyl methacrylate polymers and dimethyl silicone polymers, and/or air expulsion additives.
  • seal swell agents such as seal swell agents, colorants, antifoam and defoamer additives such as alkyl methacrylate polymers and dimethyl silicone polymers, and/or air expulsion additives.
  • colorants such as alkyl methacrylate polymers and dimethyl silicone polymers
  • air expulsion additives such as alkyl methacrylate polymers and dimethyl silicone polymers
  • Such additives may be added to provide, for example, multiple functionality.
  • the additional components are added as a fully formulated additive package, fully formulated to meet an original equipment manufacturer's requirements for a tractor hydraulic fluid, e.g., giving the fluid the capacity to meet bench and dynamometer tests.
  • the package to be used depends in part on the requirements of the specific equipment to receive the lubricant composition. Examples of additives and additive packages that have been used in tractor hydraulic fluids are disclosed in U.S. Pat. Nos. 5,635,459 and 5,843,873.
  • Other examples of additive packages for use in tractor hydraulic fluid include but are not limited to those commercially available from the Lubrizol Corporation such as the Lubrizol 9990 series, Universal Tractor Transmission Oil (UTTO) package and Super Tractor Oil Universal (STOU) package.
  • the additive comprises a material having the following characteristics: viscosity of 208 mm 2 /s at 25° C.; 107 at 40° C.; 17.8 at 100° C.; a pour point of ⁇ 40° C., and a flash point of 180° C.
  • the additive package comprises among other materials, metal-containing detergents, such as 1-2% (e.g.
  • a calclum-overbased sulfonate detergent such as 1-2% (e.g., 1.69%) of a zinc diaikyldithiophosphate; 0.5 to 2% (e.g. 1.03%) of friction modifiers; and 0.1 to 2% (e.g., 0.25%) of a nitrogen-containing dispersant such as succinimide dispersants.
  • antioxidants or anti-wear agents such as 1-2% (e.g., 1.69%) of a zinc diaikyldithiophosphate; 0.5 to 2% (e.g. 1.03%) of friction modifiers; and 0.1 to 2% (e.g., 0.25%) of a nitrogen-containing dispersant such as succinimide dispersants.
  • a nitrogen-containing dispersant such as succinimide dispersants.
  • Other conventional components may also be present, if desired.
  • the tractor hydraulic fluid comprises a sufficient amount of pour point depressant so that the pour point of the tractor hydraulic fluid blend is at least 3° C. below the pour point of a blend that does not have the pour point depressant.
  • Pour point depressants are known in the art and include, but are not limited to, esters of maleic anhydride-styrene copolymers, polymethacrylates, polyacrylates, polyacrylamides, condensation products of haloparaffin waxes and aromatic compounds, vinyl carboxylate polymers, and terpolymers of dialkylfumarates, vinyl esters of fatty acids, ethylene-vinyl acetate copolymers, alkyl phenol formaldehyde condensation resins, alkyl vinyl ethers, olefin copolymers, and mixtures thereof.
  • the lubricating base oil contains a Pour Point Reducing Blend Component.
  • the Pour Point Reducing Blend Component is an isomerized Fischer-Tropsch derived vacuum distillation bottoms product, which is a high boiling syncrude fraction which has been isomerized under controlled conditions to give a specified degree of alkyl branching in the molecule.
  • Syncrude prepared from the Fischer-Tropsch process comprises a mixture of various solid, liquid, and gaseous hydrocarbons.
  • the Fischer-Tropsch waxes are converted into Fischer-Tropsch base oils by various processes, such as by hydroprocessing and distillation, the base oils produced fall into different narrow-cut viscosity ranges.
  • the bottoms that remains after recovering the lubricating base oil cuts from the vacuum column is generally unsuitable for use as a lubricating base oil itself and is usually recycled to a hydrocracking unit for conversion to lower molecular weight products.
  • the pour Point Reducing Blend Component is an isomerized Fischer-Tropsch derived vacuum distillation bottoms product having an average molecular weight between 600 and 1100 and an average degree of branching In the molecules between 6.5 and 10 alkyl branches per 100 carbon atoms.
  • the higher molecular weight hydrocarbons are more effective as Pour Point Reducing Blend Components than the lower molecular weight hydrocarbons.
  • a higher cut point in a vacuum distillation unit which results in a higher boiling bottoms material is used to prepare the Pour Point Reducing Blend Component. The higher cut point also has the advantage of resulting in a higher yield of the distillate base oil fractions.
  • the Pour Point Reducing Blend Component is an isomerized Fischer-Tropsch derived vacuum distillation bottoms product having a pour point that is at least 3° C. higher than the pour point of the distillate base oil it is blended with.
  • the pour Point Reducing Blend Component is an isomerized petroleum derived base oil containing material having a boiling range above about 1050° F.
  • the isomerized bottoms material is solvent dewaxed prior to being used as a pour point reducing blend component. The waxy product further separated during solvent dewaxing from the pour point reducing blend 5 component was found to display excellent improved pour point depressing properties compared to the oily product recovered after the solvent dewaxing.
  • the pour Point Reducing Blend Component has an average degree of branching in the molecules within the range of from 6.5 to 10 alkyl branches per 100 carbon atoms. In another embodiment, the Pour Point Reducing Blend Component has an average molecular weight between 600-1100. In a third embodiment, between 700-1000.
  • the pour Point Reducing Blend Component is an isomerized oil having a kinematic viscosity at 100° C. of at least about 8 mm 2 /s made from polyethylene plastic.
  • the Pour Point Reducing Blend Component is made from waste plastic
  • the Pour Point Reducing Blend Component is made from a process comprising: pyrolysis of polyethylene plastic, separating out a heavy fraction, hydrotreating the heavy fraction, catalytic isomerizing the hydrotreated heavy fraction, and collecting the Pour Point Reducing Blend Component having a kinematic viscosity at 100° C. of at least about 8 mm 2 /s.
  • the Pour Point Reducing Blend Component derived from polyethylene plastic has a boiling range above 1050° F. (555° C.), or even a boiling range above 1200° F. (649° C.).
  • Additives used in formulating the compositions can be blended into the base oil matrix individually or in various sub-combinations. In one embodiment, all of the components are blended concurrently using an additive concentrate (i.e., additives plus a diluent, such as a hydrocarbon solvent).
  • an additive concentrate i.e., additives plus a diluent, such as a hydrocarbon solvent.
  • the use of an additive concentrate takes advantage of the mutual compatibility afforded by the combination of ingredients when in the form of an additive concentrate.
  • the tractor hydraulic fluid composition is prepared by mixing the base oil matrix with the separate additives or additive package(s) at an appropriate temperature, such as approximately 60° C., until homogeneous.
  • the tractor hydraulic fluid composition in one embodiment is characterized as having an excellent shear stability, with an unsheared kinematic viscosity at 100° C. of at least 9.1 mm 2 /s, a sheared kinematic viscosity at 100° C. of at least 7.1 mm 2 /s, and a Brookfield viscosity at ⁇ 40° C. of less than 20,000 mPa.s.
  • Shear stability can be expressed by a shear stability index (SSI), which is a measure of the tendency of tractor hydraulic fluid compositions to degrade and lose their ability to thicken and maintain viscosity, when subjected to shearing. Shearing can occur in pumps, gears, engines, etc.
  • SSI shear stability index
  • the tractor hydraulic fluid exhibits a Brookfield viscosity at ⁇ 35° C. of less than 70,000 mPa.s.
  • the Brookfield viscosity at ⁇ 35° C. is less than 50,000 mPa.s.
  • the Brookfield viscosity at ⁇ 35° C. is less than 22,000 mPa.s.
  • the Brookfield viscosity at ⁇ 35° C. is less than 18,000 mPa.s.
  • the tractor hydraulic fluid composition is supplied to the fluid reservoir of the equipment to be lubricated, and thence to the moving parts of the equipment itself including but not limited to tractors and/or off-highway mobile equipment, Moving parts include a transmission, a hydrostatic transmission, a gearbox, a final drive, a hydraulic system, etc.
  • the Examples are prepared by mixing the components in the amounts indicated in the tables. Mixing is accomplished in a beaker or a reactor vessel with mechanical stirring. Unless specified otherwise, the components in the examples are as follows:
  • FT base oil s are from Chevron Corporation of S an Ramon, Calif., indicated as FTBO-XL, FTBO-L, FTBO-M, and FTBO-H.
  • the properties of the FTBO base oils used in the examples are shown in Tables 2 and 5.
  • Chevron UCBO 4R and UCBO 7R are API Group III base oils from Chevron Corporation.
  • ViscoplexTM 1-604 and ViscoplexTM 1-3006 are pour point depressants from Degussa of Germany.
  • ViscoplexTM 8-220 and ViscoplexTM 8-944 are viscosity modifiers from Degussa.
  • 218-3 is a foam inhibitor.
  • OLOATM A, OLOATM B, and OLOATM C are additive packages from Chevron Oronite Company LLC of San Ramon, Calif.
  • Table 1 lists the components and results of formulated blends employing different FT base oils (with the properties as shown in Table 2) as examples 1-6.
  • the samples were tested against John Deere J20C specification.
  • the John Deere J20C specification for tractor hydraulic fluid requires a Brookfield viscosity of less than 70,000 cP at ⁇ 35° C. and a kinematic viscosity of at least 9.1 mm 2 /s at 100° C.
  • the J20C requirements are easily achieved with the addition of 3 wt % viscosity modifier.
  • the base oil viscosity can be increased thereby requiring less viscosity modifier (1.5 wt %), while still meeting the J20C requirements.
  • Example 3 shows that a blend without viscosity modifier did not meet the Brookfield viscosity requirements.
  • Examples 4-6 are duplicates of Examples 1-3, except that the blends in Examples 4-6 are made with a combination of FTBO-L and FTBO-H, whereas the blends in Examples 1-3 are made with a combination of FTBO-M and FTBO-H.
  • FIG. 1 is a graph comparing the Brookfield viscosity at ⁇ 35 ° C. versus the base oil viscosity at 100° C. used in the blend.
  • the graph compares typical data for API Group I and API Group II base oils with results from Examples 1-6, formulated tractor hydraulic fluid blends containing embodiments of isomerized base oils (“FTBO”).
  • FTBO isomerized base oils
  • Table 3 lists the components and results of a low viscosity blend prepared to meet the John Deere J20D specification, namely a Brookfield viscosity of less than 20,000 cP at ⁇ 40° C. and a kinematic viscosity of at least 7.0 mm 2 /s at 100° C.
  • Table 4 lists the components and results of formulated blends comparing blends made with prior art base oils with blends containing FT base oils (with the properties as shown in Table 5) as examples 8-10.
  • the blends containing FT base oils meet the requirements of both John Deere J20C and J20D specifications, thus allowing the blends to be used in a very wide range of ambient temperatures because of their exceptional viscosities at both low ( ⁇ 40° C.) and high (100° C.) temperatures.
  • These types of tractor hydraulic fluids are referred to as “all season” or “all weather” fluids.
  • Example 8 shows an “all weather” fluid made with commercial Group III base oil.
  • Examples 9 and 10 show that the use of FT base oils has allowed a higher base oil viscosity for the blend, 5.2 mm 2 /s versus 5.0 mm 2 /s for Example 8 (prior art base oils).
  • the higher base oil viscosity results in the use of less viscosity modifier because less thickening is needed to achieve the final product blend viscosity of about 9.4 mm 2 /s at 100° C.
  • Less viscosity modifier will result in a more shear stable product because the viscosity modifier is the component in the blend which exhibits poor stability against sheardown.
  • Example 10 Components, wt % in blend FTBO L — 47.50 30.40 FTBO M — 35.90 43.00 FTBO XL — — 10.00 Chevron UCBO 4R 53.28 — — Chevron UCBO 7R 29.85 — — Oloa C 7.80 7.80 7.80 Viscoplex 8-944 3.00 3.00 3.00 Viscoplex 8-220 5.87 5.60 5.60 Viscoplex 1-3006 0.20 0.20 0.20 Total wt % in blend 100.00 100.00 100.00 100.00 Blend Properties Base oil visc. at 100° C. 5.0 5.2 5.2 Visc. mm 2 /s. 40° C. 45.13 42.22 42.45 Visc.

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US11/930,685 2007-09-27 2007-10-31 Tractor hydraulic fluid compositions and preparation thereof Abandoned US20090088352A1 (en)

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US11/930,685 US20090088352A1 (en) 2007-09-27 2007-10-31 Tractor hydraulic fluid compositions and preparation thereof
PCT/US2008/075758 WO2009042396A1 (en) 2007-09-27 2008-09-10 Tractor hydraulic fluid compositions and preparation thereof
EP08799372.1A EP2207868A4 (en) 2007-09-27 2008-09-10 HYDRAULIC FLUID COMPOSITIONS FOR TRACTOR AND PREPARATION THEREOF
BRPI0817476-8A BRPI0817476A2 (pt) 2007-09-27 2008-09-10 Composição de fluído hidráulico para trator, e, método para produzir a mesma.
JP2010527011A JP2010540717A (ja) 2007-09-27 2008-09-10 トラクター用油圧流体組成物及びそれの調製
CN200880115864A CN101855328A (zh) 2007-09-27 2008-09-10 拖拉机液压油组合物及其制备
CA2700630A CA2700630A1 (en) 2007-09-27 2008-09-10 Tractor hydraulic fluid compositions and preparation thereof
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CN104789310A (zh) * 2015-04-21 2015-07-22 苏州劲元油压机械有限公司 一种高粘度低温液压油及其制备工艺
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EP2207868A4 (en) 2014-08-27
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EP2207868A1 (en) 2010-07-21
BRPI0817476A2 (pt) 2015-07-14

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