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US20060039882A1 - Hair care agents containing pregelatinized, cross-linked starch derivatives - Google Patents

Hair care agents containing pregelatinized, cross-linked starch derivatives Download PDF

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Publication number
US20060039882A1
US20060039882A1 US10/511,122 US51112205A US2006039882A1 US 20060039882 A1 US20060039882 A1 US 20060039882A1 US 51112205 A US51112205 A US 51112205A US 2006039882 A1 US2006039882 A1 US 2006039882A1
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United States
Prior art keywords
hair care
care agent
hair
derivatives
polymers
Prior art date
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Abandoned
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US10/511,122
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English (en)
Inventor
Michael Demitz
Horst Argembeaux
Stephan Ruppert
Ines Wallendszus
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Beiersdorf AG
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Individual
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Filing date
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Assigned to BEIERSDORF AG reassignment BEIERSDORF AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ARGEMBEAUX, HORST, WALLENDSZUS, INES, RUPPERT, STEPHEN, DEMITZ, MICHAEL
Publication of US20060039882A1 publication Critical patent/US20060039882A1/en
Abandoned legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the present invention relates to cosmetic haircare agents containing polymers.
  • the present invention relates in particular to haircare preparations or haircare agents containing substances and having especially improved combability and improved feel.
  • the hair consists of the hair shaft which protrudes freely from the skin—the keratinized (dead) section which represents the actual visible hair—and the hair root which sticks in the skin—the living section, in which the visible hair is continually renewed.
  • the hair shaft in turn is made up of three layers: a central section—the so-called hair marrow (medulla), which, however, in humans has retrogressed and is often missing altogether—also the marrow (cortex) and the external, horny layer up to ten layers thick (cuticle), which surrounds the entire hair.
  • the section of a hair in the vicinity of the scalp accordingly has a virtually closed horny layer.
  • the horny layer being the external sheath of the hair, but also the inner region below the cuticle, are exposed to particular stress by environmental influences.
  • UV-A and also UV-B radiation have a harmful effect on the hair, which is evident, for example, from the fact that certain amino acids, such as cystine and methionine are degraded or sulfur-sulfur bonds of keratin are cleaved, which in the worst case scenario can result in destruction of the hair.
  • hair and scalp represent parts of the body which, due to their position, are subjected to a considerable amount of UV radiation when outdoors.
  • One aim of hair care is to maintain the natural condition of freshly grown hair over the longest period possible and, if it is lost, to restore it.
  • Silky sheen, low porosity and a pleasant smooth feel are features of natural healthy hair.
  • hair care cosmetics which are, after they have worked, either intended to be washed out of the hair again, or which should remain on the hair.
  • the latter can be formulated such that they not only serve to care for the individual hair, but also improve the appearance of a hair style overall. Hair cared for in such a way is characterized by a pleasant feel, natural shine, increased body, suppleness and thus good stylability and strength and thus good hairstyle sit.
  • hair conditioning agents or conditioners Products which serve exclusively to care for the hair are generally referred to as hair conditioning agents or conditioners. After a longer or shorter residence time on the hair, these can be rinsed out (rinse-off products, e.g. rinses, hair treatments) or they remain following application to the hair (leave-on products).
  • the products can have various consistencies, meaning that they can be applied in very different ways. They may be emulsions or gels or low-viscosity solutions which are applied, for example, by means of spray applications, or foams, which are generated, for example, by suitable pressurized gas packings or special foam pumps during application. Creamy, opaque and clearly transparent products can be found on the market.
  • cosmetic haircare agents either containing one or more pregelatinized crosslinked starch derivatives and cationic polymers or containing one or more pregelatinized, crosslinked starch derivatives and nonionic, amphoteric and/or anionic polymers overcome the disadvantages of the prior art.
  • hair-treatment compositions with excellent care performances are obtained, where the combination of starch derivatives with cationic polymers improves the suppleness-improving care properties in a synergistic manner without weighing down the hair.
  • the combination of starch derivatives with nonionic, amphoteric and anionic polymers likewise synergistically improves the setting properties, which is associated with better hair volume. The hair is likewise given a pleasant feel sensation and can be styled easily.
  • pregelatinized, crosslinked starch derivatives used are hydroxypropylated starch phosphate esters, particularly preferably hydroxypropyl distarch phosphates.
  • the cationic polymers used are polymeric quaternized ammonium salts of hydroxyethylcellulose which have been modified with a trimethylammonium-substituted epoxide, depolymerized and subsequently quaternized guar gum derivatives and/or quaternized guar derivatives.
  • the cationic polymers chosen are at least one from the group of cationic cellulose derivatives.
  • nonionic, amphoteric and/or anionic polymers used are PVP/VA copolymers, anionic acrylate copolymers and/or amphoteric amide/acrylate/methacrylate copolymers, particularly preferably PVP/VA copolymers.
  • the content of pregelatinized, crosslinked starch derivatives is particularly preferably 20 to 99.9% by weight, very particularly preferably 25 to 95% by weight, based on the total content of polymers.
  • the total content of polymers is preferably 0.1 to 3% by weight, particularly preferably 0.2 to 1.5% by weight, based on the total weight of the preparation. It is further preferred if further surfactants and/or cosmetic or dermatological auxiliaries, additives and/or active ingredients are additionally present.
  • the pregelatinized, crosslinked starch derivatives used are hydroxypropylated phosphate esters.
  • Very particular preference here is given to the use of a hydroxypropyl distarch phosphate, as is sold in the form of the product Structure® XL by National Starch.
  • starch derivatives (Structure XL) with a polymeric quaternized ammonium salt of hydroxyethylcellulose which is modified with a trimethylammonium-substituted epoxide (INCI: Polyquaternium-10) (Ucare Polymer JR 400 from Amerchol) or with a depolymerized guar gum derivative which has been quaternized (INCI: Guar Hydroxypropyl Trimonium Chloride) (Jaguar Excel from Rhodia) or with a quaternized guar derivative (Cosmedia Guar C 261 (Cognis)) or with a nonionic PVP/VA copolymer (Luviskol VA 64W, BASF) or with an anionic acrylate copolymer (Luviflex soft, BASF) or with an amphoteric amide/acrylate/methacrylate copolymer (Amphomer, National Starch) has proven to be particularly preferred.
  • the pregelatinized, crosslinked starch derivatives used are hydroxypropylated phosphate esters.
  • Very particular preference here is given to the use of a hydroxypropyl distarch phosphate, as is sold in the form of the product Structure® XL by National Starch.
  • Cosmetic and dermatological preparations according to the invention may be present in various forms.
  • they may be a solution, an anhydrous preparation, an emulsion or microemulsion of the water-in-oil (W/O) type or of the oil-in-water (O/W) type, a multiple emulsion, for example of the water-in-oil-in-water (W/O/W) type, a gel, a solid stick, an ointment or else an aerosol.
  • the haircare agents are topical preparations. They can have the customary composition and be used for the treatment and the care of the scalp and/or the hair or as a photoprotective preparation.
  • the preparations according to the invention are applied to the scalp and the hair in an adequate amount in the manner customary for cosmetics and haircare agents.
  • preparations for the purposes of the present invention may be in the form of a hair treatment or hair rinse.
  • compositions according to the invention can, for example, be in the form of preparations which are sprayable from aerosol containers, squeezable bottles or via a pump, spray or foaming device, but also in the form of a composition which can be applied from normal bottles and containers.
  • suitable propellants for cosmetic or dermatological preparations which are sprayable from aerosol containers are the customary known readily volatile liquefied propellants, for example dimethyl ether, hydrocarbons (propane, butane, isobutane), which can be used on their own or in a mixture with one another. Compressed air, nitrogen, nitrogen dioxide or carbon dioxide or mixtures of these substances are also used advantageously.
  • preparations according to the invention advantageously also comprise customary active substances, ingredients, additives and/or auxiliaries.
  • haircare agents A large number of products is referred to as haircare agents, the most important representatives of which are pretreatment agents, hair tonics and hair treatment agents.
  • the basic substances of haircare agents are, for example, fatty alcohols, waxes, paraffins, Vaseline, paraffin oil and solvents.
  • Fatty alcohols are, for example, straight- or branched-chain aliphatic monohydric alcohols having 6-22 carbon atoms in the molecule. In cosmetics, preference is given to using straight-chain fatty alcohols with a chain length of 12-18 carbon atoms. These fatty alcohols are soft, colorless masses, virtually nontoxic and well tolerated by the skin. Fatty alcohols are preferably used for the preparation of hair treatments and styling creams, with cetyl alcohol and stearyl alcohol being of particular importance.
  • Waxes are fatty acid esters which occur in animal and vegetable products, but can also be prepared synthetically. Probably the best known naturally occurring wax is beeswax which comprises cerin and myricin as main constituents. However, wax is a generic term for a number of natural and synthetic substances which as a rule represent semisolid, white, odorless and water-insoluble masses.
  • Paraffins in the cosmetics sense are white, odorless masses of straight-chain high molecular weight hydrocarbons. Due to their properties comparable with those of waxes, they are also often referred to as petroleum waxes.
  • Vaseline is a mixture of branched-chain paraffins with a low content of cyclic paraffins. It is a soft, transparent and water-insoluble mass with a low intrinsic odor and is produced during the treatment of petroleum.
  • Paraffin oil is a mixture of saturated liquid hydrocarbons. It is insoluble in water, but miscible with fatty alcohols and waxes. It is used as additive in haircare agents for regulating the consistency.
  • haircare agents can be used in order to improve certain properties of the haircare agents, e.g. consistency, thermal stability and photo stability, appearance and odor, and to facilitate their preparation.
  • properties of the haircare agents e.g. consistency, thermal stability and photo stability, appearance and odor, and to facilitate their preparation.
  • the following are added as required:
  • the amount of the basic substances is, for example, 85 to 99.999% by weight, preferably 90 to 99.99% by weight, in each case based on the total weight of the preparation.
  • Quaternary ammonium compounds are an important group of the special active ingredients which are used to produce haircare agents. Haircare agents, in particular hair treatments, are given essential properties such as improvement of combability, and feel and prevention of static charging of the hair primarily by using quaternary ammonium compounds.
  • quaternary ammonium compounds are determined by the cationic group on the one hand and by the type of lipophilic radicals of this group on the other hand.
  • the compounds in which one to two radicals of longer-chain alkyl groups, such as lauryl, cetyl or stearyl groups, and the remaining radicals are methyl groups are suitable. Products of this type are preferably used as chlorides, bromides and methosulfates.
  • polymeric quaternary ammonium compounds macromolecules whose essential feature is the presence of two or more quaternary ammonium groups in the molecule. As a result, their ability to adhere to the hair is significantly increased.
  • Quaternary surfactants contain at least one N atom which is covalently bonded to 4 alkyl or aryl groups. Irrespective of the pH, this leads to a positive charge. Alkylbetaine, alkylamidopropylbetaine and alkylamidopropylhydroxysultaine are advantageous.
  • the cationic surfactants used according to the invention can also preferably be chosen from the group of quaternary ammonium compounds, in particular benzyltrialkylammonium chloride, and also alkyltrialkylammonium salts, for example cetyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chlorides or bromides, dialkyldimethylammonium chlorides or bromides, alkylamidoethyltriethylammonium ether sulfates, alkylpyridinium salts, for example lauryl- or cetylpyrimidinium chloride, imidazoline derivatives and compounds with cationic character, such as amine oxides, for example alkyldimethylamine oxides or alkylaminoethyldimethylamine oxides. Cetyltrimethylammonium salts in particular are to be used advantageously.
  • Monomeric or polymeric quaternary ammonium compounds are used widely in hair rinses and hair treatments, e.g. in concentrations of 0.5-5% by weight.
  • These include cetrimonium chloride, as is supplied under the name Dehyquart A by Henkel, or distearoylethyl hydroxethylmonium methosulfate, as is supplied under the name Dehyquart F 75 by Henkel.
  • the cosmetic or dermatological preparations are in the form of a lotion which is rinsed out and which is applied, for example, before or after bleaching, before or after shampooing, between two shampooing steps, before or after permanent-wave treatment, then they are, for example, emulsions which optionally comprise surface-active substances whose concentration can be between 0.1 and 10% by weight, preferably between 0.2 and 5% by weight.
  • a cosmetic preparation in the form of a lotion which is not rinsed out, in particular a lotion for arranging the hair, a lotion which is used while blow-drying the hair, a styling and treatment lotion is generally an emulsion and comprises the combinations according to the invention.
  • the lotion according to the invention is in the form of a microemulsion or an aqueous or aqueous-alcoholic solution.
  • cosmetic preparations for the treatment and care of the hair can be in the form of gels which comprise organic thickeners, e.g. gum arabic, xanthan gum, sodium alginate, cellulose derivatives, preferably methylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose or inorganic thickeners, e.g. aluminum silicates, such as, for example, bentonite, or a mixture of polyethylene glycol and polyethylene glycol stearate or distearate.
  • the thickener is present in the gel, for example, in an amount between 0.1 and 30% by weight, preferably between 0.5 and 15% by weight.
  • the preparations according to the invention can comprise cosmetic auxiliaries as are customarily used in such preparations, e.g. preservatives, perfumes, substances for preventing foaming, foam stabilizers, dyes, pigments which have a coloring effect, thickeners, surface-active substances, emulsifiers, softening, moisturizing and/or humectant substances, refatting agents, fats, oils, waxes, alcohols, polyols and their toxicological compatible ethers and esters, branched and/or unbranched hydrocarbons, further antioxidants, stabilizers, pH regulators, bodying agents, bactericides, deodorants, antimicrobial substances, antistats, UV absorbers, complexing and sequestering agents, pearlizing agents, polymers, electrolytes, organic solvents, silicone derivatives, plant extracts, vitamins and/or other active ingredients or other customary constituents of a cosmetic or dermatological formulation.
  • Solubility promoters e.g. for incorporating hydrophobic components, such
  • the total amount of the auxiliaries is, for example, 0.001 to 15% by weight, preferably 0.01 to 10% by weight, in each case based on the total weight of the preparation.
  • the amount of thickeners is, for example, 0.05 to 5.0% by weight, preferably 0.1 to 3.0% by weight, in particular 0.15 to 2.0% by weight, in each case based on the total weight of the preparation.
  • the water content of the preparations is, for example, 60 to 95% by weight, preferably 75 to 95% by weight, in particular 80 to 90% by weight, in each case based on the total weight of the preparation.
  • Antioxidants which may additionally be used according to the invention are all antioxidants customary or suitable for cosmetic and/or dermatological applications.
  • the total amount of the antioxidants is, for example, 0.000.001 to 2% by weight, preferably 0.001 to 1% by weight, in each case based on the total weight of the preparation.
  • antioxidants are advantageously chosen from the group consisting of amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and derivatives thereof, imidazoles (e.g. urocanic acid) and derivatives thereof, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and derivatives thereof (e.g. anserine), carotenoids, carotenes (e.g. ⁇ -carotene, ⁇ -carotene, lycopene) and derivatives thereof, chlorogenic acid and derivatives thereof, lipoic acid and derivatives thereof (e.g.
  • amino acids e.g. glycine, histidine, tyrosine, tryptophan
  • imidazoles e.g. urocanic acid
  • peptides such as D,L-carnosine, D-carnosine, L-carnosine and derivatives thereof (e.g. anserine)
  • thiols e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and the glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, ⁇ -linoleyl, cholesteryl and glyceryl esters thereof
  • salts thereof dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and derivatives thereof (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (e.g.
  • buthionine sulfoximines in very low tolerated doses (e.g. pmol to ⁇ mol/kg), also (metal) chelating agents (e.g. ⁇ -hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), ⁇ -hydroxy acids (e.g.
  • citric acid citric acid, lactic acid, malic acid
  • humic acid bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and derivatives thereof
  • unsaturated fatty acids and derivatives thereof e.g. ⁇ -linolenic acid, linoleic acid, oleic acid
  • folic acid and derivatives thereof vitamin C and derivatives (e.g. ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g.
  • vitamin E acetate
  • vitamin A and derivatives vitamin A palmitate
  • coniferyl benzoate of benzoin resin rutinic acid and derivatives thereof, ⁇ -glycosylrutin, ferulic acid, furfurylideneglucitol, carnosine, butylhydroxytoluene, butylhydroxyanisol, nordihydroguaiacic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and derivatives thereof, mannose and derivatives thereof, zinc and derivatives thereof (e.g. ZnO, ZnSO 4 ), selenium and derivatives thereof (e.g. selenomethionine), stilbenes and derivatives thereof (e.g. stilbene oxide, trans-stilbene oxide) and the derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of the specified active ingredients which are suitable according to the invention.
  • Preparations according to the invention may advantageously also comprise substances which absorb UV radiation in the UV-B region, where the total amount of the filter substances is, for example, 0.001% by weight to 30% by weight, preferably 0.05 to 10% by weight, in particular 0.1 to 1.0% by weight, based on the total weight of the preparations, in order to provide cosmetic preparations which protect the hair and/or the skin from the entire range of ultraviolet radiation. They can also serve as sunscreens for the hair or the skin, in particular the scalp.
  • the emulsions according to the invention comprise UV-B filter substances, these may advantageously be water-soluble.
  • Advantageous water-soluble UV-B filters are, for example:
  • UV-A filters which are hitherto customarily present in cosmetic preparations. It is possible to use the amounts used for the UV-B combination.
  • the preparations according to the invention can be prepared in the customary manner by mixing the individual constituents.
  • the active ingredients of the combinations according to the invention or else the premixed constituents of the combinations according to the invention may be added in the mixing operation.
  • the pH of the preparations can be adjusted in a known manner by adding acids or bases, preferably by adding buffer mixtures, e.g. based on citric acid/citrate or phosphoric acid phosphate buffer mixtures.
  • buffer mixtures e.g. based on citric acid/citrate or phosphoric acid phosphate buffer mixtures.
  • the pH is below 10, e.g. in the range from 2-7, in particular in the range from 3-5.
  • Hair treatment 1 2 3 Hydroxypropylmethylcellulose 0.5 0.5 0.5 0.5 Cetrimonium bromide 1.0 1.0 1.0 Glycerol 3.0 3.0 3.0 Cetearyl alcohol 2.5 2.5 2.5 Glyceryl stearate 2.0 2.0 2.0 Hydroxypropyl starch phosphate ester 0.2 0.5 0.8 (Structure XL) Polyquaternium-10 0.1 — — Guar hydroxypropyl trimonium — 0.2 — chloride PVP/VA copolymer — — 0.1 Preservative, perfume, pH adjustment q.s. q.s. q.s. Water, demin. (demineralized) ad 100.0 ad 100.0 ad 100.0 The pH is adjusted to 3.5.
  • Spray conditioners 7 8 9 Benzophenone-4 0.05 0.03 0.04 Hydrolyzed keratin 0.5 1.0 0.2 Polyquaternium-10 0.5 — 1.0 PVP/VA copolymer — 0.7 — Hydroxypropyl starch phosphate ester 0.2 0.5 0.8 (Structure XL) Cetrimonium chloride 0.2 0.8 0.1 Preservative, perfume, pH adjustment q.s. q.s. q.s. Water, demin. ad 100.0 ad 100.0 ad 100.0 The pH is adjusted to 5.5.
  • Leave-on conditioner 10 11 12 Cetyl alcohol 1.5 1.8 2.0 C12-13 alkyl lactate 2.0 1.0 1.5 Cetrimonium chloride 0.3 0.2 0.2 Acrylates/C10-30 alkyl acrylates 0.5 0.3 0.2 crosspolymer Polyquaternium-10 — 0.2 0.5 PVP/VA copolymer 0.4 — — Hydroxypropyl starch phosphate ester 0.2 0.5 0.8 (Structure XL) Preservative, perfume, pH adjustment q.s. q.s. q.s. Water, demin. ad 100.0 ad 100.0 ad 100.0 ad 100.0

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
US10/511,122 2002-04-11 2003-04-09 Hair care agents containing pregelatinized, cross-linked starch derivatives Abandoned US20060039882A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10216500.9 2002-04-11
DE10216500A DE10216500A1 (de) 2002-04-11 2002-04-11 Haarpflegemittel
PCT/EP2003/003677 WO2003084487A1 (de) 2002-04-11 2003-04-09 Haarpflegemittel vorgelatinisierte, quervernetzte stärkederivate enthaltend

Publications (1)

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US20060039882A1 true US20060039882A1 (en) 2006-02-23

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US (1) US20060039882A1 (de)
EP (1) EP1496842A1 (de)
DE (1) DE10216500A1 (de)
WO (1) WO2003084487A1 (de)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070160555A1 (en) * 2006-01-09 2007-07-12 Staudigel James A Personal care compositions containing cationically modified starch and an anionic surfactant system
US20090176675A1 (en) * 2006-01-09 2009-07-09 Marjorie Mossman Peffly Personal Care Compositions Containing Cationically Modified Starch and an Anionic Surfactant System
US8828368B2 (en) 2010-12-21 2014-09-09 L'oreal Cosmetic composition comprising a particular zinc salt and a starch
US20150065580A1 (en) * 2011-12-07 2015-03-05 Shandong Runze Pharmaceuticals Co., Ltd. Application of fluoxetine to treatment of depigmentation diseases
US9375393B2 (en) 2010-12-21 2016-06-28 L'oreal Composition comprising a non-nitrogenous zinc salt and a particular cationic surfactant
US9833424B2 (en) 2011-12-07 2017-12-05 Shandong Runze Pharmaceuticals Co., Ltd. Application of fluoxetine to treatment of depigmentation diseases
US20180133135A1 (en) * 2016-11-17 2018-05-17 Henkel Ag & Co. Kgaa Hair cleansing conditioner

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20022746A1 (it) * 2002-12-23 2004-06-24 Natu Raw Ltd Composizioni per uso topico a base di un diamido.
DE102004010718A1 (de) * 2004-03-03 2005-09-22 Beiersdorf Ag Haarpflegemittel mit Kreatin
US8623341B2 (en) 2004-07-02 2014-01-07 The Procter & Gamble Company Personal care compositions containing cationically modified starch and an anionic surfactant system
FR2881954B1 (fr) * 2005-02-11 2007-03-30 Oreal Composition cosmetique comprenant un cation, un polymere cationique, un compose solide et un amidon et procede de traitement cosmetique

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4508705A (en) * 1980-07-02 1985-04-02 Lever Brothers Company Skin treatment composition
US5520200A (en) * 1993-12-22 1996-05-28 L'oreal Process for the non-lasting reshaping of keratinous fibres
US5653988A (en) * 1994-07-09 1997-08-05 Beiersdorf Aktiengesellschaft Shower oil
US5869070A (en) * 1994-12-06 1999-02-09 The Procter & Gamble Company Shelf stable skin cleansing liquid with gel forming polymer and lipid
US5871756A (en) * 1995-01-18 1999-02-16 National Starch And Chemical Investment Holding Corporation Cosmetics containing thermally-inhibited starches
US5900241A (en) * 1995-05-29 1999-05-04 L'oreal Use in cosmetics of an expanded solid composition which has a matrix containing an alveolar network made from a natural product or from a derivative of a natural product capable of being expanded
US5925380A (en) * 1995-05-29 1999-07-20 L'oreal Expanded solid composition whose matrix comprises a starch-based cellular network and which contains expanded thermoplastic hollow particles and its uses in topical application
US5997886A (en) * 1997-11-05 1999-12-07 The Procter & Gamble Company Personal care compositions
US6248338B1 (en) * 1996-07-08 2001-06-19 National Starch And Chemical Investment Holding Corporation Starchy cleaning and cosmetic care preparations
US20010007655A1 (en) * 1998-04-09 2001-07-12 Charles W. Paul Aerosol hair cosmetic compositions containing non-ionically derivatized starches
US20010018046A1 (en) * 1998-04-09 2001-08-30 Melissa J. Vitale Use of stabilized starches in low voc, polyacrylic acid-containing hair cosmetic compositions
US6294180B1 (en) * 1998-11-06 2001-09-25 L'oreal Cosmetic and/or dermatological powder, process for its preparation and its uses
US6322818B1 (en) * 1999-07-24 2001-11-27 Cerestar Holding B.V. Starch granulation
US6413505B1 (en) * 1998-04-09 2002-07-02 Nationa L Starch And Chemical Investment Holding Corporation Nonionically derivatized starches and their use in non-aerosol, low VOC hair cosmetic compositions
US20030035783A1 (en) * 2000-04-19 2003-02-20 Susanne Birkel Cosmetic agent in the form of a gel
US20030147834A1 (en) * 2001-12-20 2003-08-07 Isabelle Rollat Reshapable hair styling rinse composition comprising (meth)acrylic copolymers

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US18046A (en) * 1857-08-25 Method of rendering the mouths of trunks
CA2268693A1 (en) * 1998-04-09 1999-10-09 National Starch And Chemical Investment Holding Corporation Nonionically derivatized starches and their use in low voc, polyacrylic acid-containing hair cosmetic compositions
DE69931990T2 (de) * 1998-04-09 2007-01-11 National Starch And Chemical Investment Holding Corp., Wilmington Nicht-ionisch modifizierte Stärke und deren Verwendung in Aerosolzusammensetzungen zur Haarfestigung
US6299907B1 (en) * 1998-06-12 2001-10-09 Kansas State University Research Foundation Reversibly swellable starch products
FR2779648B1 (fr) * 1998-06-15 2001-07-20 Oreal Composition cosmetique ou pharmaceutique se presentant sous forme de solide et pouvant etre deformable
EP1128846A4 (de) * 1999-09-15 2002-10-25 Avebe America Inc Durch scherkräfte vorverkleisterte stärke
DE10032118B9 (de) * 2000-07-01 2006-12-07 Wella Ag Antithixotropes kosmetisches Mittel

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4508705A (en) * 1980-07-02 1985-04-02 Lever Brothers Company Skin treatment composition
US5520200A (en) * 1993-12-22 1996-05-28 L'oreal Process for the non-lasting reshaping of keratinous fibres
US5653988A (en) * 1994-07-09 1997-08-05 Beiersdorf Aktiengesellschaft Shower oil
US6033680A (en) * 1994-12-06 2000-03-07 The Procter & Gamble Company Shelf stable skin cleansing liquid with gel forming polymer and lipid
US5869070A (en) * 1994-12-06 1999-02-09 The Procter & Gamble Company Shelf stable skin cleansing liquid with gel forming polymer and lipid
US5871756A (en) * 1995-01-18 1999-02-16 National Starch And Chemical Investment Holding Corporation Cosmetics containing thermally-inhibited starches
US5925380A (en) * 1995-05-29 1999-07-20 L'oreal Expanded solid composition whose matrix comprises a starch-based cellular network and which contains expanded thermoplastic hollow particles and its uses in topical application
US5900241A (en) * 1995-05-29 1999-05-04 L'oreal Use in cosmetics of an expanded solid composition which has a matrix containing an alveolar network made from a natural product or from a derivative of a natural product capable of being expanded
US6248338B1 (en) * 1996-07-08 2001-06-19 National Starch And Chemical Investment Holding Corporation Starchy cleaning and cosmetic care preparations
US5997886A (en) * 1997-11-05 1999-12-07 The Procter & Gamble Company Personal care compositions
US20010007655A1 (en) * 1998-04-09 2001-07-12 Charles W. Paul Aerosol hair cosmetic compositions containing non-ionically derivatized starches
US20010018046A1 (en) * 1998-04-09 2001-08-30 Melissa J. Vitale Use of stabilized starches in low voc, polyacrylic acid-containing hair cosmetic compositions
US6413505B1 (en) * 1998-04-09 2002-07-02 Nationa L Starch And Chemical Investment Holding Corporation Nonionically derivatized starches and their use in non-aerosol, low VOC hair cosmetic compositions
US6294180B1 (en) * 1998-11-06 2001-09-25 L'oreal Cosmetic and/or dermatological powder, process for its preparation and its uses
US6322818B1 (en) * 1999-07-24 2001-11-27 Cerestar Holding B.V. Starch granulation
US20030035783A1 (en) * 2000-04-19 2003-02-20 Susanne Birkel Cosmetic agent in the form of a gel
US20030147834A1 (en) * 2001-12-20 2003-08-07 Isabelle Rollat Reshapable hair styling rinse composition comprising (meth)acrylic copolymers

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070160555A1 (en) * 2006-01-09 2007-07-12 Staudigel James A Personal care compositions containing cationically modified starch and an anionic surfactant system
US20090176675A1 (en) * 2006-01-09 2009-07-09 Marjorie Mossman Peffly Personal Care Compositions Containing Cationically Modified Starch and an Anionic Surfactant System
US8828368B2 (en) 2010-12-21 2014-09-09 L'oreal Cosmetic composition comprising a particular zinc salt and a starch
US9375393B2 (en) 2010-12-21 2016-06-28 L'oreal Composition comprising a non-nitrogenous zinc salt and a particular cationic surfactant
US20150065580A1 (en) * 2011-12-07 2015-03-05 Shandong Runze Pharmaceuticals Co., Ltd. Application of fluoxetine to treatment of depigmentation diseases
US9833424B2 (en) 2011-12-07 2017-12-05 Shandong Runze Pharmaceuticals Co., Ltd. Application of fluoxetine to treatment of depigmentation diseases
US20180133135A1 (en) * 2016-11-17 2018-05-17 Henkel Ag & Co. Kgaa Hair cleansing conditioner

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