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TWI889040B - Semiconductor device - Google Patents

Semiconductor device Download PDF

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TWI889040B
TWI889040B TW112146454A TW112146454A TWI889040B TW I889040 B TWI889040 B TW I889040B TW 112146454 A TW112146454 A TW 112146454A TW 112146454 A TW112146454 A TW 112146454A TW I889040 B TWI889040 B TW I889040B
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metal layer
region
metal
type semiconductor
opening
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TW112146454A
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TW202414750A (en
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楊姿玲
林雅雯
廖庭德
顧浩民
陳世益
黃靖恩
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晶成半導體股份有限公司
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Abstract

The semiconductor element includes a first-type semiconductor structure, an active structure, a second-type semiconductor structure, an insulating structure, a first metal layer and a second metal layer. The first-type semiconductor structure includes a first region and a second region surrounding the first region, and a top surface in the first region. The active structure is on the second region, and there is no active structure on the first region. The second-type semiconductor structure is on the active structure. The insulating structure covers the first-type semiconductor structure and has a first opening in the first region. The first opening exposes the top surfaces. The first metal layer is in the first opening and in contact with the top surface. The first metal layer has an upper surface away from the top surface, and the upper surface does not contact the insulating structure. The second metal layer is on the first metal layer and has a metal material different from the first metal layer.

Description

半導體元件Semiconductor components

本揭露是關於半導體元件,特別是關於一種具有良好歐姆接觸的半導體元件。 The present disclosure relates to a semiconductor device, and more particularly to a semiconductor device having good ohmic contact.

半導體元件的用途十分廣泛,相關材料的開發研究也持續進行。舉例來說,包含III族及V族元素的III-V族半導體材料可應用於各種半導體元件如發光晶片(例如:發光二極體或雷射二極體)、吸光晶片(光電偵測器或太陽能電池)或不發光晶片(例如:開關或整流器的功率元件),能用於照明、醫療、顯示、通訊、感測、電源系統等領域。隨著科技的發展,現今對於半導體元件仍存在許多技術研發的需求。雖然現有的半導體元件大致上已經符合一般需求,但並非在各方面皆令人滿意,仍需要進一步的改良。 Semiconductor components are widely used, and the development and research of related materials are also ongoing. For example, III-V semiconductor materials containing group III and group V elements can be applied to various semiconductor components such as light-emitting chips (e.g., light-emitting diodes or laser diodes), light-absorbing chips (photodetectors or solar cells) or non-light-emitting chips (e.g., power components of switches or rectifiers), which can be used in lighting, medical, display, communication, sensing, power supply systems and other fields. With the development of technology, there are still many technical research and development needs for semiconductor components. Although existing semiconductor components generally meet general needs, they are not satisfactory in all aspects and still need further improvement.

本揭露實施例提供一種半導體元件。半導體元件包含第一型半導體結構、活性結構、第二型半導體結構、絕緣結構、第一金屬層及第二金屬層。第一型半導體結構包含第一區域及第二 區域圍繞第一區域、及頂表面位於第一區域。活性結構位於第二區域上,且第一區域上不具有活性結構。第二型半導體結構位於活性結構上。絕緣結構覆蓋第一型半導體結構且具有第一開口位於第一區域。第一開口露出上述頂表面。第一金屬層位於第一開口中且與此頂表面接觸。第一金屬層具有上表面遠離此頂表面,且此上表面未接觸絕緣結構。第二金屬層位於第一金屬層上且具有金屬材料不同於第一金屬層。 The disclosed embodiment provides a semiconductor element. The semiconductor element includes a first type semiconductor structure, an active structure, a second type semiconductor structure, an insulating structure, a first metal layer and a second metal layer. The first type semiconductor structure includes a first region and a second region surrounding the first region, and a top surface located in the first region. The active structure is located on the second region, and the first region does not have an active structure. The second type semiconductor structure is located on the active structure. The insulating structure covers the first type semiconductor structure and has a first opening located in the first region. The first opening exposes the above-mentioned top surface. The first metal layer is located in the first opening and contacts the top surface. The first metal layer has an upper surface away from the top surface, and the upper surface does not contact the insulating structure. The second metal layer is located on the first metal layer and has a metal material different from that of the first metal layer.

10、10’、10”:半導體元件 10, 10’, 10”: semiconductor components

100:基底 100: Base

102:第一型半導體結構 102: Type I semiconductor structure

104:活性結構 104: Active structure

106:第二型半導體結構 106: Type II semiconductor structure

108:絕緣結構 108: Insulation structure

112:第一開口 112: First opening

114:第二開口 114: Second opening

116:凹槽 116: Groove

118:第一金屬結構 118: First metal structure

119:第二金屬結構 119: Second metal structure

118a、119a:第一金屬層 118a, 119a: first metal layer

118b、119b:第二金屬層 118b, 119b: Second metal layer

118c、119c:第三金屬層 118c, 119c: The third metal layer

120:側壁 120: Side wall

121:第一頂表面 121: first top surface

122:第二頂表面 122: Second top surface

1081-1082:側壁 1081-1082: Side wall

110a1、110a2、110a3:第一區域 110a1, 110a2, 110a3: first area

110b1、110b2:第二區域 110b1, 110b2: Second area

20:半導體元件 20: Semiconductor components

θ1-θ2:傾斜角度 θ1-θ2: Tilt angle

Wa-Wc:寬度 Wa-Wc: Width

D:深度 D: Depth

T:厚度 T:Thickness

S1、S2:短邊 S1, S2: short side

L1、L2:長邊 L1, L2: long side

SC:短邊中心線 SC: Short side center line

LC:長邊中心線 LC: Long side center line

LL:左部長邊線 LL: Left long line

LR:右部長邊線 LR: Right long sideline

由以下的詳細敘述配合所附圖式,可最好地理解本揭露實施例。應注意的是,依據在業界的標準做法,各種特徵並未按照比例繪製且僅用於說明。事實上,可任意地放大或縮小各種元件的尺寸,以清楚地表現出本揭露實施例之特徵。 The present disclosed embodiments are best understood from the following detailed description in conjunction with the accompanying drawings. It should be noted that, in accordance with standard practice in the industry, various features are not drawn to scale and are used for illustration purposes only. In fact, the sizes of various components may be arbitrarily enlarged or reduced to clearly show the features of the present disclosed embodiments.

第1圖至第5圖是根據本揭露的一實施例,繪示出半導體元件的製程剖面示意圖。 Figures 1 to 5 are schematic cross-sectional views of the manufacturing process of a semiconductor device according to an embodiment of the present disclosure.

第6圖是根據本揭露的一實施例,繪示出半導體元件之上視示意圖。 FIG. 6 is a schematic top view of a semiconductor device according to an embodiment of the present disclosure.

第7圖是根據本揭露的另一實施例,繪示出半導體元件之剖面示意圖。 FIG. 7 is a schematic cross-sectional view of a semiconductor device according to another embodiment of the present disclosure.

第8圖是根據本揭露的又一實施例,繪示出半導體元件之剖面示意圖。 FIG. 8 is a schematic cross-sectional view of a semiconductor device according to another embodiment of the present disclosure.

第9圖是根據本揭露的另一實施例,繪示出半導體元件之上視示意圖。 FIG. 9 is a schematic top view of a semiconductor device according to another embodiment of the present disclosure.

以下揭露提供了許多的實施例或範例,用於實施所提供的標的物之不同元件。各元件和其配置的具體範例描述如下,以簡化本揭露實施例之說明。當然,這些僅僅是範例,並非用以限定本揭露實施例。舉例而言,敘述中若提及第一元件形成在第二元件之上,可能包含第一和第二元件直接接觸的實施例,也可能包含額外的元件形成在第一和第二元件之間,使得它們不直接接觸的實施例。此外,本揭露實施例可能在各種範例中重複參考數值以及/或字母。如此重複是為了簡明和清楚之目的,而非用以表示所討論的不同實施例及/或配置之間的關係。 The following disclosure provides a number of embodiments or examples for implementing different elements of the subject matter provided. Specific examples of each element and its configuration are described below to simplify the description of the disclosed embodiments. Of course, these are only examples and are not intended to limit the disclosed embodiments. For example, if the description refers to a first element formed on a second element, it may include an embodiment in which the first and second elements are directly in contact, and it may also include an embodiment in which an additional element is formed between the first and second elements so that they are not directly in contact. In addition, the disclosed embodiments may repeat reference values and/or letters in various examples. Such repetition is for the purpose of simplicity and clarity, and is not used to indicate the relationship between the different embodiments and/or configurations discussed.

再者,其中可能用到與空間相對用詞,例如「在……之下」、「下方」、「較低的」、「上方」、「較高的」等類似用詞,是為了便於描述圖式中一個(些)部件或特徵與另一個(些)部件或特徵之間的關係。空間相對用詞用以包括使用中或操作中的裝置之不同方位,以及圖式中所描述的方位。當裝置被轉向不同方位時(旋轉90度或其他方位),其中所使用的空間相對形容詞也將依轉向後的方位來解釋。 Furthermore, spatially relative terms such as "under", "below", "lower", "above", "higher" and the like may be used to facilitate the description of the relationship between one (or more) parts or features and another (or more) parts or features in the diagram. Spatially relative terms are used to include different orientations of the device in use or operation, as well as the orientations described in the diagram. When the device is turned to a different orientation (rotated 90 degrees or other orientations), the spatially relative adjectives used will also be interpreted according to the orientation after the rotation.

第1圖至第5圖係根據本揭露的一實施例,繪示出半導體元件10的製程剖面示意圖。在下方描述的各種示意圖和例示性實施例中,相似的元件符號用來表示相似的元件。本揭露之半導體元件10可包含發光晶片(例如,發光二極體或雷射二極體)、吸光 晶片(例如,光電偵測器或太陽能電池)、或者不發光晶片(例如,開關或整流器的功率元件)。在本揭露實施例中,半導體元件10之長度不大於150微米,較佳的範圍為10微米至150微米、或10微米至60微米、或60微米至150微米,以及寬度不大於100微米,較佳的範圍為5微米至100微米、或5微米至30微米、或30微米至75微米。 Figures 1 to 5 are schematic diagrams of the process cross-section of the semiconductor element 10 according to an embodiment of the present disclosure. In the various schematic diagrams and exemplary embodiments described below, similar element symbols are used to represent similar elements. The semiconductor element 10 of the present disclosure may include a light-emitting chip (e.g., a light-emitting diode or a laser diode), a light-absorbing chip (e.g., a photodetector or a solar cell), or a non-light-emitting chip (e.g., a power element of a switch or a rectifier). In the embodiment of the present disclosure, the length of the semiconductor element 10 is not greater than 150 microns, preferably in the range of 10 microns to 150 microns, or 10 microns to 60 microns, or 60 microns to 150 microns, and the width is not greater than 100 microns, preferably in the range of 5 microns to 100 microns, or 5 microns to 30 microns, or 30 microns to 75 microns.

請參照第1圖,提供基底100,且於基底100上依序形成第一型半導體結構102、活性結構104、第二型半導體結構106,並可藉由諸如乾式蝕刻製程、濕式蝕刻製程、或上述之組合來蝕刻部分的第一型半導體結構102、活性結構104、第二型半導體結構106,以露出一部分的第一型半導體結構102。如第1圖所示,第一型半導體結構102包含第一區域及第二區域。在本實施例中,於一剖面圖中,第一型半導體結構102包含三個第一區域110a1、110a2、110a3及二個第二區域110b1、110b2。第一區域110a1被第二區域110b1、110b2所圍繞且第一區域110a1位於另外兩個第一區域110a2、110a3之間。活性結構104及第二型半導體結構106位於第二區域110b1、110b2且未位於第一區域110a1、110a2、110a3。 Referring to FIG. 1 , a substrate 100 is provided, and a first type semiconductor structure 102, an active structure 104, and a second type semiconductor structure 106 are sequentially formed on the substrate 100. Parts of the first type semiconductor structure 102, the active structure 104, and the second type semiconductor structure 106 can be etched by, for example, a dry etching process, a wet etching process, or a combination thereof, to expose a portion of the first type semiconductor structure 102. As shown in FIG. 1 , the first type semiconductor structure 102 includes a first region and a second region. In this embodiment, in a cross-sectional view, the first type semiconductor structure 102 includes three first regions 110a1, 110a2, and 110a3 and two second regions 110b1 and 110b2. The first region 110a1 is surrounded by the second regions 110b1 and 110b2 and the first region 110a1 is located between the other two first regions 110a2 and 110a3. The active structure 104 and the second type semiconductor structure 106 are located in the second regions 110b1 and 110b2 and are not located in the first regions 110a1, 110a2, and 110a3.

在一些實施例中,基底100可包含絕緣材料、半導體材料或兩者。絕緣材料可包含例如下列材料:藍寶石(Sapphire)、金剛石、玻璃、石英、或AlN。半導體材料可包含例如下列材料:砷化鎵(GaAs)、磷化銦(InP)、碳化矽(SiC)、磷化鎵(GaP)、磷砷化鎵(GaAsP)、氧化鋅(ZnO)、硒化鋅(ZnSe)、氮化鎵(GaN)、氮化鋁(AlN)、鎵酸鋰(LiGaO2)、鋁酸鋰(LiAlO2)、鍺(Ge)或 矽(Si)。在一些實施例中,基底100為砷化鎵基底。在一些實施例中,基底100的厚度可介於50μm至1300μm之間。 In some embodiments, the substrate 100 may include an insulating material, a semiconductor material, or both. The insulating material may include, for example, the following materials: sapphire, diamond, glass, quartz, or AlN. The semiconductor material may include, for example, the following materials: gallium arsenide (GaAs), indium phosphide (InP), silicon carbide (SiC), gallium phosphide (GaP), gallium arsenide phosphide (GaAsP), zinc oxide (ZnO), zinc selenide (ZnSe), gallium nitride (GaN), aluminum nitride (AlN), lithium gallate (LiGaO 2 ), lithium aluminate (LiAlO 2 ), germanium (Ge), or silicon (Si). In some embodiments, the substrate 100 is a gallium arsenide substrate. In some embodiments, the thickness of the substrate 100 may be between 50 μm and 1300 μm.

在本揭露實施例中,第一型半導體結構102、第二型半導體結構106、活性結構104包含為單層或多層。第一型半導體結構102、第二型半導體結構106、活性結構104可分別包含III-V族半導體材料,例如鋁(Al)、鎵(Ga)、砷(As)、磷(P)、銦(In)、或氮(N)。具體而言,在本揭露實施例中,上述III-V族半導體材料可為二元化合物半導體(如GaAs、GaP、或GaN)、三元化合物半導體(如InGaAs、AlGaAs、InGaP、AlInP、InGaN、或AlGaN)、或四元化合物半導體(如AlGaInAs、AlGaInP、AlInGaN、InGaAsP、InGaAsN、或AlGaAsP)。在一些實施例中,第一型半導體結構102的厚度可介於1.5μm至4μm之間。在一些實施例中,第二型半導體結構106的厚度可介於0.1μm至2μm之間。在一些實施例中,活性結構104的厚度可介於0.01μm至1.0μm之間。第一型半導體結構102或第二型半導體結構106可包括布拉格反射結構(distributed bragg reflector structure;DBR),其由兩種以上具有不同折射率的半導體材料交替堆疊而形成。 In the disclosed embodiment, the first semiconductor structure 102, the second semiconductor structure 106, and the active structure 104 include a single layer or multiple layers. The first semiconductor structure 102, the second semiconductor structure 106, and the active structure 104 may include III-V semiconductor materials, such as aluminum (Al), gallium (Ga), arsenic (As), phosphorus (P), indium (In), or nitrogen (N). Specifically, in the disclosed embodiment, the III-V semiconductor material may be a binary compound semiconductor (such as GaAs, GaP, or GaN), a ternary compound semiconductor (such as InGaAs, AlGaAs, InGaP, AlInP, InGaN, or AlGaN), or a quaternary compound semiconductor (such as AlGaInAs, AlGaInP, AlInGaN, InGaAsP, InGaAsN, or AlGaAsP). In some embodiments, the thickness of the first type semiconductor structure 102 may be between 1.5 μm and 4 μm. In some embodiments, the thickness of the second type semiconductor structure 106 may be between 0.1 μm and 2 μm. In some embodiments, the thickness of the active structure 104 may be between 0.01 μm and 1.0 μm. The first type semiconductor structure 102 or the second type semiconductor structure 106 may include a Bragg reflector structure (DBR), which is formed by alternately stacking two or more semiconductor materials with different refractive indices.

在一些實施例中,可藉由下列磊晶成長製程來形成第一型半導體結構102、第二型半導體結構106及活性結構104,例如:金屬有機化學氣相沉積(metal-organic chemical vapor deposition,MOCVD)、氫化物氣相磊晶法(hydride vapor phase epitaxy,HVPE)、分子束磊晶(molecular beam epitaxy,MBE) 或液相磊晶法(liquid-phase epitaxy,LPE)、氣相磊晶(vapor phase epitaxy,VPE)、或前述之組合。 In some embodiments, the first type semiconductor structure 102, the second type semiconductor structure 106, and the active structure 104 can be formed by the following epitaxial growth processes, such as metal-organic chemical vapor deposition (MOCVD), hydride vapor phase epitaxy (HVPE), molecular beam epitaxy (MBE) or liquid-phase epitaxy (LPE), vapor phase epitaxy (VPE), or a combination thereof.

在一些實施例中,可藉由在磊晶成長期間原位(in-situ)摻雜及/或通過在磊晶成長之後使用摻質進行佈植(implanting)以進行第一型半導體結構102及第二型半導體結構106的摻雜。第一型半導體結構102可包含第一摻質使其具有第一導電型,第二型半導體結構106可包含第二摻質使其具有第二導電型。第一型半導體結構102及第二型半導體結構106具有不同的導電型,亦即第一導電型與第二導電型不同。第一導電型例如為p型及第二導電型例如為n型或第一導電型例如為n型及第二導電型例如為p型。當半導體元件10為發光元件時,第一型半導體結構102及第二型半導體結構106分別提供電洞及電子或,電子或電洞以於活性結構104中結合以發光。第一摻質或第二摻質可包含矽、碲、碳、鈹、鎂)。 In some embodiments, the doping of the first type semiconductor structure 102 and the second type semiconductor structure 106 can be performed by in-situ doping during epitaxial growth and/or by implanting the dopant after epitaxial growth. The first type semiconductor structure 102 can include a first dopant to have a first conductivity type, and the second type semiconductor structure 106 can include a second dopant to have a second conductivity type. The first type semiconductor structure 102 and the second type semiconductor structure 106 have different conductivity types, that is, the first conductivity type is different from the second conductivity type. The first conductivity type is, for example, p-type and the second conductivity type is, for example, n-type or the first conductivity type is, for example, n-type and the second conductivity type is, for example, p-type. When the semiconductor element 10 is a light-emitting element, the first type semiconductor structure 102 and the second type semiconductor structure 106 provide holes and electrons or electrons or holes to combine in the active structure 104 to emit light. The first dopant or the second dopant may include silicon, tellurium, carbon, curium, magnesium).

在一些實施例中,半導體元件10可包括多層量子井(multiple quantum well,MQW)、單一量子井(single-quantum well,SQW)、同質接面(homojunction)、異質接面(heterojunction)。 In some embodiments, the semiconductor element 10 may include multiple quantum wells (MQW), single-quantum wells (SQW), homojunctions, and heterojunctions.

當半導體元件10為發光元件且於半導體元件10操作時,活性結構104可發出光線。活性結構104所發出的光線包含可見光或不可見光。半導體元件10發出的光線的波長取決於活性結構104的材料組成。舉例來說,當活性結構104的材料包含InGaN系列 時,可發出峰值波長(peak wavelength)為400奈米至490奈米的藍光、深藍光,或是峰值波長為490奈米至550奈米的綠光;當活性結構104的材料包含AlGaN系列時,可發出峰值波長為250奈米至400奈米的紫外光;當活性結構104的材料包含InGaAs系列、InGaAsP系列、AlGaAs系列、或AlGaInAs系列時,可發出峰值波長為700奈米至1700奈米的紅外光;當活性結構104的材料包含InGaP系列或AlGaInP系列時,可發出峰值波長為610奈米至700奈米的紅光、或是峰值波長為530奈米至600奈米的黃光。 When the semiconductor device 10 is a light emitting device and the semiconductor device 10 is in operation, the active structure 104 can emit light. The light emitted by the active structure 104 includes visible light or invisible light. The wavelength of the light emitted by the semiconductor device 10 depends on the material composition of the active structure 104. For example, when the material of the active structure 104 includes the InGaN series, blue light or deep blue light with a peak wavelength of 400 nm to 490 nm or green light with a peak wavelength of 490 nm to 550 nm can be emitted; when the material of the active structure 104 includes the AlGaN series, ultraviolet light with a peak wavelength of 250 nm to 400 nm can be emitted; when the material of the active structure 104 includes the InGaAs series, InGaAsP series, AlGaAs series, or AlGaInAs series, infrared light with a peak wavelength of 700 nm to 1700 nm can be emitted; when the material of the active structure 104 includes the InGaP series or AlGaInP series, red light with a peak wavelength of 610 nm to 700 nm or yellow light with a peak wavelength of 530 nm to 600 nm can be emitted.

參照第2圖,絕緣結構108順應地覆蓋第1圖所示結構的上表面,換言之,絕緣結構108順應地覆蓋第一型半導體結構102、活性結構104及第二型半導體結構106上。雖然在圖中絕緣結構108僅繪示成一層,但絕緣結構108可為一層以上的膜層。在一些實施例中,絕緣結構108可以是非導電材料所形成,包含有機材料,例如苯并環丁烯(BCB)、過氟環丁烷(PFCB)、環氧樹脂(Epoxy)、丙烯酸樹脂(Acrylic Resin)、環烯烴聚合物(COC)、聚甲基丙烯酸甲酯(PMMA)、聚對苯二甲酸乙二酯(PET)、聚碳酸酯(PC)、聚醚醯亞胺(Polyetherimide)、氟碳聚合物(Fluorocarbon Polymer),或是無機材料,例如矽膠(Silicone)、玻璃(Glass),或是介電材料,例如氧化鋁(Al2O3)、氮化矽(SiNx)、氧化矽(SiOx)、氧化鈦(TiOx),或氟化鎂(MgFx)。在本揭露一實施例中,絕緣結構108為絕緣反射結構,使半導體元件10往基底100方向出光,以減少在電極側的光損耗,從而增加半導體元件10的光量輸出。在一實施例中,絕緣結 構108可包括布拉格反射結構(distributed bragg reflector structure;DBR),其由兩種以上具有不同折射率的絕緣材料交替堆疊而形成,例如,可通過層疊SiO2/TiO2、SiO2/Nb2O5等層來形成高反射率的絕緣反射層。 Referring to FIG. 2 , the insulating structure 108 covers the upper surface of the structure shown in FIG. 1 . In other words, the insulating structure 108 covers the first semiconductor structure 102, the active structure 104 and the second semiconductor structure 106 . Although the insulating structure 108 is shown as only one layer in the figure, the insulating structure 108 may be more than one film layer. In some embodiments, the insulating structure 108 may be formed of a non-conductive material, including an organic material, such as benzocyclobutene (BCB), perfluorocyclobutane (PFCB), epoxy, acrylic resin, cycloolefin polymer (COC), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), polycarbonate (PC), polyetherimide, fluorocarbon polymer, or an inorganic material, such as silicone, glass, or a dielectric material, such as aluminum oxide (Al 2 O 3 ), silicon nitride (SiN x ), silicon oxide (SiO x ), titanium oxide (TiO x ), or magnesium fluoride (MgF x ). In one embodiment of the present disclosure, the insulating structure 108 is an insulating reflective structure, which allows the semiconductor device 10 to emit light toward the substrate 100 to reduce light loss on the electrode side, thereby increasing the light output of the semiconductor device 10. In one embodiment, the insulating structure 108 may include a distributed bragg reflector structure (DBR), which is formed by alternately stacking two or more insulating materials with different refractive indices. For example, a high reflectivity insulating reflective layer may be formed by stacking layers of SiO2 / TiO2 , SiO2 / Nb2O5 , etc.

在一些實施例中,可利用沉積製程來形成絕緣結構108。上述沉積製程例如物理氣相沉積(physical vapor deposition,PVD)、化學氣相沉積(chemical vapor deposition,CVD)、金屬有機物化學氣相沉積(metal organic chemical vapor deposition;MOCVD)、原子層沉積(atomic layer deposition,ALD)或其組合。 In some embodiments, a deposition process may be used to form the insulating structure 108. The deposition process may be, for example, physical vapor deposition (PVD), chemical vapor deposition (CVD), metal organic chemical vapor deposition (MOCVD), atomic layer deposition (ALD), or a combination thereof.

參照第3圖,可藉由蝕刻製程來蝕刻位於第一區域110a1及第二區域110b1的絕緣結構108,以分別在第一區域110a1形成第一開口112及在第二區域110b1形成第二開口114,露出第一型半導體結構102及第二型半導體結構106。蝕刻絕緣結構108所使用的製程可包括乾式蝕刻製程、濕式蝕刻製程、或其組合。舉例而言,濕式蝕刻製程可採用酸性溶液或鹼性溶液。酸性溶液可包括氫氟酸、磷酸、硝酸、醋酸或前述之組合的溶液;鹼性溶液可包括含有氫氧化鉀、氨、過氧化氫或前述之組合的溶液。舉例而言,乾式蝕刻製程可包括電漿蝕刻(plasma etching,PE)、反應離子蝕刻(reactive ion etching,RIE)、感應耦合電漿活性離子蝕刻(inductively coupled plasma reactive ion etching,ICP-RIE)。上述蝕刻反應的氣體可包括含氧氣體、含氟氣體、含氯氣 體、含硼氣體、含氬氣體、及/或上述之組合。 Referring to FIG. 3 , the insulating structure 108 located in the first region 110a1 and the second region 110b1 can be etched by an etching process to form a first opening 112 in the first region 110a1 and a second opening 114 in the second region 110b1, respectively, to expose the first type semiconductor structure 102 and the second type semiconductor structure 106. The process used to etch the insulating structure 108 may include a dry etching process, a wet etching process, or a combination thereof. For example, the wet etching process may use an acidic solution or an alkaline solution. The acidic solution may include a solution of hydrofluoric acid, phosphoric acid, nitric acid, acetic acid, or a combination thereof; the alkaline solution may include a solution containing potassium hydroxide, ammonia, hydrogen peroxide, or a combination thereof. For example, the dry etching process may include plasma etching (PE), reactive ion etching (RIE), and inductively coupled plasma reactive ion etching (ICP-RIE). The gases in the above etching reactions may include oxygen-containing gas, fluorine-containing gas, chlorine-containing gas, boron-containing gas, argon-containing gas, and/or a combination thereof.

接著,參照第4圖,經由第一開口112進一步對第一區域110a1的第一型半導體結構102進行蝕刻,以形成凹槽116,凹槽係對應於第一開口的位置且與第一開口重疊。第一型半導體結構102具有第一頂表面121及一第二頂表面122。第一頂表面121係為凹槽之底部且位於第一區域110a1。第二頂表面122係被絕緣結構108所覆蓋。在一些實施例中,第一開口112露出第一頂表面121。第一頂表面121較第二頂表面122靠近基底100。在一實施例中,凹槽116具有一深度D可大於0.001μm或介於0.001μm及0.1μm之間。 Next, referring to FIG. 4 , the first type semiconductor structure 102 in the first region 110a1 is further etched through the first opening 112 to form a groove 116, which corresponds to the position of the first opening and overlaps with the first opening. The first type semiconductor structure 102 has a first top surface 121 and a second top surface 122. The first top surface 121 is the bottom of the groove and is located in the first region 110a1. The second top surface 122 is covered by the insulating structure 108. In some embodiments, the first opening 112 exposes the first top surface 121. The first top surface 121 is closer to the substrate 100 than the second top surface 122. In one embodiment, the groove 116 has a depth D that may be greater than 0.001 μm or between 0.001 μm and 0.1 μm.

在一些實施例中,如第3圖及第4圖所示,可採用二段式乾式蝕刻方法,先以第一段蝕刻製程形成第一開口112與第二開口114,再以第二段蝕刻製程形成凹槽116。詳言之,第一段蝕刻製程可為乾式蝕刻,對部分絕緣結構108進行蝕刻,以形成第一開口112及第二開口114。第二段蝕刻製程亦為乾式蝕刻,將部份的第一型半導體結構102及在第一段蝕刻製程中所產生的副產物進行蝕刻,以形成凹槽116。第一段蝕刻製程之反應氣體與第二段蝕刻製程之反應氣體不同。在其他實施例中,乾式蝕刻方法可包括一或多段製程,例如,三段或三段以上的蝕刻製程。 In some embodiments, as shown in FIG. 3 and FIG. 4, a two-stage dry etching method may be used, wherein the first etching process is used to form the first opening 112 and the second opening 114, and then the second etching process is used to form the groove 116. Specifically, the first etching process may be dry etching, in which a portion of the insulating structure 108 is etched to form the first opening 112 and the second opening 114. The second etching process is also dry etching, in which a portion of the first semiconductor structure 102 and the byproducts generated in the first etching process are etched to form the groove 116. The reaction gas of the first etching process is different from the reaction gas of the second etching process. In other embodiments, the dry etching method may include one or more processes, for example, three or more etching processes.

在一實施例中,一接觸層(未繪示)可形成於第二型半導體結構上106,接著,如第2圖所示,絕緣結構108覆蓋接觸層。接觸層可為透明且包含金屬氧化物(例如:ITO)或半導體材料(例如 是GaAs或InGaAs)。如第3圖所示,於進行蝕刻製程來蝕刻位於第一區域110a1及第二區域110b1的絕緣結構108以形成第一開口112及第二開口114的步驟中,部分接觸層會被蝕刻。 In one embodiment, a contact layer (not shown) may be formed on the second type semiconductor structure 106, and then, as shown in FIG. 2, an insulating structure 108 covers the contact layer. The contact layer may be transparent and include a metal oxide (e.g., ITO) or a semiconductor material (e.g., GaAs or InGaAs). As shown in FIG. 3, in the step of performing an etching process to etch the insulating structure 108 located in the first region 110a1 and the second region 110b1 to form the first opening 112 and the second opening 114, a portion of the contact layer is etched.

參照第5圖,於凹槽116及第一開口112中填入第一金屬結構118,並於第二開口114中填入第二金屬結構119。第6圖為半導體元件10之上視示意圖,第5圖為第6圖沿著I-I線之剖面示意圖。 Referring to FIG. 5, the first metal structure 118 is filled into the groove 116 and the first opening 112, and the second metal structure 119 is filled into the second opening 114. FIG. 6 is a schematic top view of the semiconductor element 10, and FIG. 5 is a schematic cross-sectional view of FIG. 6 along the I-I line.

如第5圖所示,第一金屬結構118及第二金屬結構119覆蓋絕緣結構108的部分頂表面。在一實施例中,第一金屬結構118以及第二金屬結構119各自可包含金屬材料,諸如鍺(Ge)、鈹(Be)、鋅(Zn)、鉻(Cr)、鎢(W)、金(Au)、鉑(Pt)、鈦(Ti)、鋁(Al)、銦(In)、錫(Sn)、鎳(Ni)、或銅(Cu)等金屬或上述材料之合金;第一金屬結構118以及第二金屬結構119可由多個層所組成,例如,可包括Cr/Au層、Cr/Cu層、Ni/Au層、Ti/Au層、Ti/Cu層、Cr/Pt/Au層、Ni/Pt/Au層、Ti/Pt/Au層、Cr/Ti/Pt/Au層、Au/Be層、Cr/Ti/Pt/Ni/Au/Sn層、Cr/Ti/Pt/Ni/Au/In層、Au/GeAu/Au層或Cr/Al/Ti/Ni/Au層。 As shown in FIG. 5 , the first metal structure 118 and the second metal structure 119 cover a portion of the top surface of the insulating structure 108. In one embodiment, the first metal structure 118 and the second metal structure 119 may each include a metal material, such as germanium (Ge), benzene (Be), zinc (Zn), chromium (Cr), tungsten (W), gold (Au), platinum (Pt), titanium (Ti), aluminum (Al), indium (In), tin (Sn), nickel (Ni), or copper (Cu) or an alloy of the above materials; the first metal structure 118 and the second metal structure 119 may be composed of multiple layers. For example, it may include a Cr/Au layer, a Cr/Cu layer, a Ni/Au layer, a Ti/Au layer, a Ti/Cu layer, a Cr/Pt/Au layer, a Ni/Pt/Au layer, a Ti/Pt/Au layer, a Cr/Ti/Pt/Au layer, an Au/Be layer, a Cr/Ti/Pt/Ni/Au/Sn layer, a Cr/Ti/Pt/Ni/Au/In layer, an Au/GeAu/Au layer, or a Cr/Al/Ti/Ni/Au layer.

如第5圖所示,絕緣結構108具有側壁1081及側壁1082,且側壁1081較側壁1082靠近凹槽116。第一型半導體結構102具有一側壁120,側壁120定義凹槽116且側壁1081定義第一開口112。第一型半導體結構102的側壁120及絕緣結構108的側壁1081分別具有第一傾斜角度θ1及第二傾斜角度θ2。在一些實施例 中,第一傾斜角度θ1不同於第二傾斜角度θ2,亦即,側壁120的第一斜率不同於側壁1081的第二斜率。在一些實施例中,第一傾斜角度θ1大於第二傾斜角度θ2(第一斜率大於第二斜率),如此可幫助第一金屬結構118在凹槽116的填充時與第一型半導體結構102之附著性及披覆性。在一實施例中,第一傾斜角度θ1的角度範圍可為20至80度。若第一傾斜角度θ1大於80度,可能使得第一金屬結構118在凹槽116內之披覆性較差,而使得半導體元件10於操作時,會有無法順利導通或元件信賴性失效問題;若第一傾斜角度θ1小於20度,則可能造成製程良率不佳。相反地,對第二傾斜角度θ2(第二斜率)而言,較小的第二傾斜角度θ2(即,較小的第二斜率)可使第一金屬結構118在第一開口112內具有較佳的附著性及披覆性。在一實施例中,第二傾斜角度θ2的角度範圍可為10至70度。若第二傾斜角度θ2小於10度,可能造成製程良率不佳;若第二傾斜角度θ2大於70,第一金屬結構118在第一開口112內與絕緣結構108有較差之披覆性,而使得半導體元件10於操作時,會有無法順利導通或元件信賴性失效問題。 As shown in FIG. 5 , the insulating structure 108 has a sidewall 1081 and a sidewall 1082, and the sidewall 1081 is closer to the groove 116 than the sidewall 1082. The first type semiconductor structure 102 has a sidewall 120, the sidewall 120 defines the groove 116 and the sidewall 1081 defines the first opening 112. The sidewall 120 of the first type semiconductor structure 102 and the sidewall 1081 of the insulating structure 108 have a first tilt angle θ1 and a second tilt angle θ2, respectively. In some embodiments, the first tilt angle θ1 is different from the second tilt angle θ2, that is, the first slope of the sidewall 120 is different from the second slope of the sidewall 1081. In some embodiments, the first tilt angle θ1 is greater than the second tilt angle θ2 (the first slope is greater than the second slope), which can help the first metal structure 118 to have good adhesion and coverage with the first type semiconductor structure 102 when the groove 116 is filled. In one embodiment, the first tilt angle θ1 can range from 20 to 80 degrees. If the first tilt angle θ1 is greater than 80 degrees, the coverage of the first metal structure 118 in the groove 116 may be poor, which may cause the semiconductor device 10 to fail to conduct smoothly or fail to have reliability problems during operation; if the first tilt angle θ1 is less than 20 degrees, it may cause poor process yield. On the contrary, for the second tilt angle θ2 (second slope), a smaller second tilt angle θ2 (i.e., a smaller second slope) can make the first metal structure 118 have better adhesion and coverage in the first opening 112. In one embodiment, the second tilt angle θ2 can range from 10 to 70 degrees. If the second tilt angle θ2 is less than 10 degrees, it may cause poor process yield; if the second tilt angle θ2 is greater than 70, the first metal structure 118 has poor coverage with the insulating structure 108 in the first opening 112, so that the semiconductor device 10 may not be turned on smoothly or the device reliability may fail during operation.

在本實施例中,第一金屬結構118依序包括第一金屬層118a、第二金屬層118b、第三金屬層118c,且其各自平均寬度Wa<Wb<Wc。第一金屬層118a填入第一開口112的凹槽116,形成於第一型半導體結構102上並直接接觸凹槽116底部與側壁(即,直接接觸第一型半導體結構102的側壁120與第一頂表面121)。第二金屬層118b形成於第一金屬層118a上且填入第一開口112並與 絕緣結構108的側壁1081直接接觸。第三金屬層118c形成於第二金屬層118b上並與絕緣結構108的側壁1082直接接觸。在一些實施例中,第一金屬層118a的上表面遠離第一型半導體結構102的第一頂表面121並且未接觸絕緣結構108。凹槽116的設置可增加第一金屬層118a與第一型半導體結構102之間的接觸面積,從而降低順向電壓(forward voltage,Vf),改善元件性能。同樣地,第二金屬結構119可依序包括第一金屬層119a、第二金屬層119b、第三金屬層119c,如第5圖所示。在一些實施例中,第二金屬層119b的寬度大於第一金屬層119a的寬度並且第三金屬層119c的寬度大於第二金屬層119b的寬度,如第5圖所示。 In this embodiment, the first metal structure 118 includes a first metal layer 118a, a second metal layer 118b, and a third metal layer 118c in sequence, and their respective average widths Wa<Wb<Wc. The first metal layer 118a fills the groove 116 of the first opening 112, is formed on the first type semiconductor structure 102 and directly contacts the bottom and sidewall of the groove 116 (i.e., directly contacts the sidewall 120 and the first top surface 121 of the first type semiconductor structure 102). The second metal layer 118b is formed on the first metal layer 118a and fills the first opening 112 and directly contacts the sidewall 1081 of the insulating structure 108. The third metal layer 118c is formed on the second metal layer 118b and directly contacts the sidewall 1082 of the insulating structure 108. In some embodiments, the upper surface of the first metal layer 118a is away from the first top surface 121 of the first semiconductor structure 102 and does not contact the insulating structure 108. The provision of the groove 116 can increase the contact area between the first metal layer 118a and the first semiconductor structure 102, thereby reducing the forward voltage (Vf) and improving the device performance. Similarly, the second metal structure 119 can include a first metal layer 119a, a second metal layer 119b, and a third metal layer 119c in sequence, as shown in FIG. 5. In some embodiments, the width of the second metal layer 119b is greater than the width of the first metal layer 119a and the width of the third metal layer 119c is greater than the width of the second metal layer 119b, as shown in FIG. 5.

在一些實施例中,第一金屬層118a/119a、第二金屬層118b/119b及第三金屬層118c/119c各包括不相同的金屬材料。第一金屬層118a/119a可選用適合與半導體形成歐姆接觸的材料,例如Cr、Ti、Ni、BeAu、GeAu。第二金屬層118b/119b可選用金屬材料且具有反射功能,例如Pt、Al、Ti、Ni、TiW、Au。第三金屬層118c/119c可選用適合作為外部連接的導電材料,例如Au、AuSn、Sn、Sn合金、In、Cu、Ni。在一實施例中,第一金屬結構118與第二金屬結構119各自可由Cr/Pt/Au層所組成的三層結構。但應可理解的是,在其他實施例中,第一金屬結構118及第二金屬結構119可各自為單層結構、雙層結構或三層以上的多層結構,其各膜層的材料可選自上述第一金屬層、第二金屬層與第三金屬層所使用的材料或其組合。 In some embodiments, the first metal layer 118a/119a, the second metal layer 118b/119b, and the third metal layer 118c/119c each include different metal materials. The first metal layer 118a/119a can be selected from materials suitable for forming ohmic contact with semiconductors, such as Cr, Ti, Ni, BeAu, GeAu. The second metal layer 118b/119b can be selected from metal materials with a reflective function, such as Pt, Al, Ti, Ni, TiW, Au. The third metal layer 118c/119c can be selected from conductive materials suitable for external connections, such as Au, AuSn, Sn, Sn alloy, In, Cu, Ni. In one embodiment, the first metal structure 118 and the second metal structure 119 may each be a three-layer structure composed of Cr/Pt/Au layers. However, it should be understood that in other embodiments, the first metal structure 118 and the second metal structure 119 may each be a single-layer structure, a double-layer structure, or a multi-layer structure of more than three layers, and the material of each film layer may be selected from the materials used for the first metal layer, the second metal layer, and the third metal layer or a combination thereof.

在一實施例中第二金屬結構119可與第一金屬結構118在相同或不同的沉積製程中分別填入第一開口112及第二開口114。在一些實施例中,第一金屬層118a的厚度T可介於50Å至500Å之間。第二金屬層118b的厚度可介於50Å至1000Å之間。第三金屬層118c的厚度可介於0.1μm至3μm之間。在一些實施例中,第一金屬層119a的厚度可介於50Å至500Å之間。第二金屬層119b的厚度可介於50Å至1000Å之間。第三金屬層119c的厚度可介於0.1μm至3μm之間。在一實施例中,第一金屬層118a的厚度T小於第二金屬層118b,第二金屬層118b的厚度小於第三金屬層118c。詳言之,第一金屬層118a、119a具有較薄的厚度,可增加第一金屬層118a、119a之透光性,且活性結構104所發出的光線可透過第一金屬層118a、119a且被第二金屬層118b、119b反射。由於第二金屬層118b、119b係作為反射層,其需具有一定厚度且具有大於第一金屬層118a、119a之厚度。第三金屬層118c、119c係用於與外部電路連接,若具有較厚的厚度可增加半導體元件10與外部電路連接之接合良率,以提升半導體元件10之光電特性。 In one embodiment, the second metal structure 119 and the first metal structure 118 may be respectively filled into the first opening 112 and the second opening 114 in the same or different deposition process. In some embodiments, the thickness T of the first metal layer 118a may be between 50Å and 500Å. The thickness of the second metal layer 118b may be between 50Å and 1000Å. The thickness of the third metal layer 118c may be between 0.1μm and 3μm. In some embodiments, the thickness of the first metal layer 119a may be between 50Å and 500Å. The thickness of the second metal layer 119b may be between 50Å and 1000Å. The thickness of the third metal layer 119c may be between 0.1μm and 3μm. In one embodiment, the thickness T of the first metal layer 118a is smaller than that of the second metal layer 118b, and the thickness of the second metal layer 118b is smaller than that of the third metal layer 118c. In detail, the first metal layers 118a and 119a have a thinner thickness, which can increase the light transmittance of the first metal layers 118a and 119a, and the light emitted by the active structure 104 can pass through the first metal layers 118a and 119a and be reflected by the second metal layers 118b and 119b. Since the second metal layers 118b and 119b are used as reflective layers, they need to have a certain thickness and have a thickness greater than that of the first metal layers 118a and 119a. The third metal layers 118c and 119c are used to connect to external circuits. If they are thicker, the bonding yield of the semiconductor element 10 and the external circuit can be increased to improve the optoelectronic properties of the semiconductor element 10.

在一些實施例中,第一金屬層118a厚度T與凹槽116深度D的比值介於0.5-2之間。在一實施例中,如第5圖所示,第一金屬層118a的厚度T大於凹槽116的深度D。在一實施例中,第一金屬層118a厚度T與凹槽116深度D的比值大於1.0且小於或等於2.0。在此實施例中,第一金屬層118a填入凹槽116,與第一型半導體結構102的側壁120直接接觸,並覆蓋絕緣結構108一部分的側壁 1081,但未覆蓋側壁1082。 In some embodiments, the ratio of the thickness T of the first metal layer 118a to the depth D of the groove 116 is between 0.5 and 2. In one embodiment, as shown in FIG. 5, the thickness T of the first metal layer 118a is greater than the depth D of the groove 116. In one embodiment, the ratio of the thickness T of the first metal layer 118a to the depth D of the groove 116 is greater than 1.0 and less than or equal to 2.0. In this embodiment, the first metal layer 118a fills the groove 116, directly contacts the sidewall 120 of the first semiconductor structure 102, and covers a portion of the sidewall 1081 of the insulating structure 108, but does not cover the sidewall 1082.

第7圖是根據本揭露另一實施例的半導體元件10’之剖面示意圖,其與第5圖的主要差別在於第一金屬層118a的厚度T等於凹槽116的深度D,且第一金屬層118a僅填入凹槽116,亦即,第一金屬層118a厚度T與凹槽116深度D的比值等於1.0。 FIG. 7 is a schematic cross-sectional view of a semiconductor device 10' according to another embodiment of the present disclosure. The main difference between FIG. 7 and FIG. 5 is that the thickness T of the first metal layer 118a is equal to the depth D of the groove 116, and the first metal layer 118a only fills the groove 116, that is, the ratio of the thickness T of the first metal layer 118a to the depth D of the groove 116 is equal to 1.0.

第8圖是根據本揭露又一實施例的半導體元件10”之剖面示意圖,其與第5圖的主要差別在於第一金屬層118a的厚度T小於凹槽116的深度D,且第二金屬層118b填入凹槽116並與側壁120直接接觸。亦即,第一金屬層118a厚度T與凹槽116深度D的比值大於或等於0.5,且小於1.0。 FIG. 8 is a cross-sectional schematic diagram of a semiconductor device 10" according to another embodiment of the present disclosure. The main difference between FIG. 8 and FIG. 5 is that the thickness T of the first metal layer 118a is less than the depth D of the groove 116, and the second metal layer 118b fills the groove 116 and directly contacts the sidewall 120. That is, the ratio of the thickness T of the first metal layer 118a to the depth D of the groove 116 is greater than or equal to 0.5 and less than 1.0.

第9圖是根據本揭露另一實施例之半導體元件20之上視示意圖。半導體元件20與半導體元件10具有類似的結構。在本實施例中,半導體元件20之形狀可為方形或長方形且包含二短邊S1、S2及二長邊L1、L2。一短邊中心線SC通過二短邊S1、S2的中心,以將半導體元件20分成上半部與下半部;一長邊中心線LC通過二長邊L1、L2的中心,以將半導體元件20分成左半部與右半部。一左部長邊線LL位於長邊中心線LC及短邊S1之間,且將左半部分成兩等分;一右部長邊線LR位於長邊中心線LC及短邊S2之間,且將右半部分成兩等分。第一開口112、凹槽116與第一金屬結構118設置在半導體元件20之左半部,以及第二開口114與第二金屬結構119設置在半導體元件20之右半部。當第一開口112、凹槽116或第一金屬結構118之上視形狀為圓形或方形時,其圓心或中心設置在 短邊中心線SC或/且左部長邊線LL,換言之,第一開口112、凹槽116或第一金屬結構118之圓心或中心與短邊中心線SC或/且左部長邊線LL重疊。當第二開口114或第二金屬結構119之形狀為圓形或方形時,其圓心或中心,設置在短邊中心線SC或/且右部長邊線LR上,換言之,第二開口114或第二金屬結構119之圓心或中心與短邊中心線SC或/且右部長邊線LR重疊。第一開口112或第一金屬結構118的圓心或中心係相對於長邊中心線LC分別與第二開口114或第二金屬結構119的圓心或中心對稱或鏡射。在一實施例中,左部長邊線LL、長邊中心線LC及右部長邊線LR將長邊分成相等的四等分。 FIG. 9 is a schematic top view of a semiconductor element 20 according to another embodiment of the present disclosure. The semiconductor element 20 has a similar structure to the semiconductor element 10. In the present embodiment, the shape of the semiconductor element 20 may be square or rectangular and include two short sides S1, S2 and two long sides L1, L2. A short side center line SC passes through the centers of the two short sides S1, S2 to divide the semiconductor element 20 into an upper half and a lower half; a long side center line LC passes through the centers of the two long sides L1, L2 to divide the semiconductor element 20 into a left half and a right half. A left long side line LL is located between the long side center line LC and the short side S1 and divides the left half into two equal parts; a right long side line LR is located between the long side center line LC and the short side S2 and divides the right half into two equal parts. The first opening 112, the groove 116 and the first metal structure 118 are arranged on the left half of the semiconductor element 20, and the second opening 114 and the second metal structure 119 are arranged on the right half of the semiconductor element 20. When the first opening 112, the groove 116 or the first metal structure 118 is circular or square, the center or center thereof is arranged on the short side center line SC or/and the left long side line LL. In other words, the center or center of the first opening 112, the groove 116 or the first metal structure 118 overlaps with the short side center line SC or/and the left long side line LL. When the second opening 114 or the second metal structure 119 is circular or square, its center is set on the short side centerline SC or/and the right long sideline LR. In other words, the center of the second opening 114 or the second metal structure 119 overlaps with the short side centerline SC or/and the right long sideline LR. The center of the first opening 112 or the first metal structure 118 is symmetrical or mirrored with the center of the second opening 114 or the second metal structure 119 relative to the long side centerline LC. In one embodiment, the left long sideline LL, the long side centerline LC and the right long sideline LR divide the long side into four equal parts.

綜上所述,本揭露實施例藉由對部份半導體層做進一步蝕刻以形成凹槽的設置,使金屬結構直接與於凹槽中露出的半導體層側壁接觸,可改善金屬與半導體之間的電性接觸,從而改善元件電壓異常的情形,以維持產品的性能。應理解的是,並非全部的優點皆已必然在此討論,也非所有實施例都需要具備特定的優點,且其他實施例可提供不同的優點。 In summary, the disclosed embodiment further etches a portion of the semiconductor layer to form a groove, so that the metal structure directly contacts the sidewall of the semiconductor layer exposed in the groove, which can improve the electrical contact between the metal and the semiconductor, thereby improving the abnormal voltage of the device to maintain the performance of the product. It should be understood that not all advantages are necessarily discussed here, and not all embodiments need to have specific advantages, and other embodiments can provide different advantages.

以上概述數個實施例之部件,以便在本發明所屬技術領域中具有通常知識者可更易理解本揭露實施例的觀點。在本發明所屬技術領域中具有通常知識者應理解,他們能以本揭露實施例為基礎,設計或修改其他製程和結構,以達到與在此介紹的實施例相同之目的及/或優勢。在本發明所屬技術領域中具有通常知識者也應理解到,此類等效的製程和結構並無悖離本發明的精神與範圍, 且他們能在不違背本發明之精神和範圍之下,做各式各樣的改變、取代和替換。 The above summarizes the components of several embodiments so that those with ordinary knowledge in the art to which the present invention belongs can more easily understand the viewpoints of the disclosed embodiments. Those with ordinary knowledge in the art to which the present invention belongs should understand that they can design or modify other processes and structures based on the disclosed embodiments to achieve the same purpose and/or advantages as the embodiments introduced herein. Those with ordinary knowledge in the art to which the present invention belongs should also understand that such equivalent processes and structures do not violate the spirit and scope of the present invention, and they can make various changes, substitutions and replacements without violating the spirit and scope of the present invention.

104:活性結構 106:第二型半導體結構 110a1、110a2、110a3:第一區域 110b1、110b2:第二區域 112第一開口 116:凹槽 118:第一金屬結構 119:第二金屬結構 118a,119a:第一金屬層 118b,119b:第二金屬層 118c,119c:第三金屬層 120:側壁 121:第一頂表面 122:第二頂表面 1081、1082:側壁 θ1-θ2:傾斜角度 Wa-Wc:寬度 D:深度 T:厚度 104: active structure 106: second type semiconductor structure 110a1, 110a2, 110a3: first region 110b1, 110b2: second region 112 first opening 116: groove 118: first metal structure 119: second metal structure 118a, 119a: first metal layer 118b, 119b: second metal layer 118c, 119c: third metal layer 120: side wall 121: first top surface 122: second top surface 1081, 1082: side wall θ1-θ2: tilt angle Wa-Wc: width D: depth T: thickness

Claims (10)

一種半導體元件,包含: 一第一型半導體結構,包含一第一區域及一第二區域圍繞該第一區域,且該第一型半導體結構包含一頂表面位於該第一區域; 一活性結構,位於該第二區域上,且該第一區域上不具有該活性結構; 一第二型半導體結構,位於該活性結構上; 一絕緣結構,覆蓋該第一型半導體結構且具有一第一開口位於該第一區域,該第一開口露出該頂表面; 一第一金屬層,位於該第一開口中且與該頂表面接觸,該第一金屬層具有一上表面遠離該頂表面,且該上表面未接觸該絕緣結構;以及 一第二金屬層,位於第一金屬層上,該第二金屬層與該第一金屬層具有不同的金屬材料。 A semiconductor element comprises: A first-type semiconductor structure comprising a first region and a second region surrounding the first region, and the first-type semiconductor structure comprises a top surface located in the first region; An active structure located on the second region, and the first region does not have the active structure; A second-type semiconductor structure located on the active structure; An insulating structure covering the first-type semiconductor structure and having a first opening located in the first region, the first opening exposing the top surface; A first metal layer located in the first opening and in contact with the top surface, the first metal layer having an upper surface away from the top surface, and the upper surface does not contact the insulating structure; and A second metal layer is located on the first metal layer, and the second metal layer has a different metal material from the first metal layer. 如請求項1之半導體元件,其中該第一金屬層具有一第一寬度,該第二金屬層具有一第二寬度大於該第一寬度。A semiconductor device as claimed in claim 1, wherein the first metal layer has a first width and the second metal layer has a second width greater than the first width. 如請求項1之半導體元件,其中,該第一金屬層的材料為Cr、Ti、Ni、BeAu或GeAu。A semiconductor device as claimed in claim 1, wherein the material of the first metal layer is Cr, Ti, Ni, BeAu or GeAu. 如請求項1之半導體元件,其中該絕緣結構具有一側壁,該第一金屬層接觸該側壁。A semiconductor device as claimed in claim 1, wherein the insulating structure has a side wall and the first metal layer contacts the side wall. 如請求項4之半導體元件,其中第二金屬層接觸該側壁。A semiconductor device as claimed in claim 4, wherein the second metal layer contacts the side wall. 如請求項1之半導體元件,其中,該第二金屬層的材料為Pt、Al、Ti、Ni、TiW或Au。A semiconductor device as claimed in claim 1, wherein the material of the second metal layer is Pt, Al, Ti, Ni, TiW or Au. 如請求項1之半導體元件,其中,該絕緣結構覆蓋該第二型半導體結構且具有一第二開口位於該第二區域。A semiconductor device as claimed in claim 1, wherein the insulating structure covers the second type semiconductor structure and has a second opening located in the second region. 如請求項7之半導體元件,更包含一第三金屬層位於該第二開口中且與該第二型半導體結構接觸、以及一第四金屬層位於該第二開口中且與該第三金屬層接觸,該第三金屬層具有一第三寬度且該第四金屬層具有一第四寬度大於該第三寬度。The semiconductor element of claim 7 further includes a third metal layer located in the second opening and in contact with the second type semiconductor structure, and a fourth metal layer located in the second opening and in contact with the third metal layer, the third metal layer has a third width and the fourth metal layer has a fourth width greater than the third width. 如請求項1之半導體元件,其中該絕緣結構包括布拉格反射結構。A semiconductor device as claimed in claim 1, wherein the insulating structure includes a Bragg reflection structure. 如請求項1之半導體元件,其中,該第一金屬層具有一第一厚度,該第二金屬層具有一第二厚度大於該第一厚度。A semiconductor device as claimed in claim 1, wherein the first metal layer has a first thickness, and the second metal layer has a second thickness greater than the first thickness.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW202029521A (en) * 2019-01-25 2020-08-01 晶元光電股份有限公司 Light-emitting device
TW202137581A (en) * 2020-03-17 2021-10-01 晶元光電股份有限公司 Semiconductor light-emitting device
TW202147639A (en) * 2020-05-13 2021-12-16 日商日機裝股份有限公司 Semiconductor light-emitting element and method of manufacturing semiconductor light-emitting element

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW202029521A (en) * 2019-01-25 2020-08-01 晶元光電股份有限公司 Light-emitting device
TW202137581A (en) * 2020-03-17 2021-10-01 晶元光電股份有限公司 Semiconductor light-emitting device
TW202147639A (en) * 2020-05-13 2021-12-16 日商日機裝股份有限公司 Semiconductor light-emitting element and method of manufacturing semiconductor light-emitting element

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