TWI523279B - Light emitting diode device with full azimuth and its packaging method - Google Patents
Light emitting diode device with full azimuth and its packaging method Download PDFInfo
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- TWI523279B TWI523279B TW102123290A TW102123290A TWI523279B TW I523279 B TWI523279 B TW I523279B TW 102123290 A TW102123290 A TW 102123290A TW 102123290 A TW102123290 A TW 102123290A TW I523279 B TWI523279 B TW I523279B
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本發明是有關於一發光二極體及其封裝方法,特別是指一種可全方位發光之發光二極體裝置及其封裝方法。 The invention relates to a light-emitting diode and a packaging method thereof, in particular to a light-emitting diode device capable of omnidirectional illumination and a packaging method thereof.
隨著人類對於照明品質要求的提升,發光二極體(Light Emitting Diode,LED)以其低耗電、使用壽命長的優點,成為當前市場使用及研發的主流,並逐漸取代傳統燈泡,成為普遍的照明體。 With the improvement of lighting quality requirements, Light Emitting Diode (LED) has become the mainstream of current market use and R&D with its advantages of low power consumption and long service life, and has gradually replaced traditional light bulbs. Illumination body.
在許多場合中,發光二極體多是被要求設計成發散白光的特性,以符合不同的照明需求。而一般要製作白光發光二極體,都是以發黃光系列之釔鋁石榴石(Yttrium Aluminum Garnet;YAG)螢光粉配合發散藍光之發光二極體,兩者相配合後可發出白光。以此種技術製作的白光發光二極體,又可分為多晶片型白光發光二極體,及單晶片白光發光二極體兩種。 In many cases, LEDs are often designed to divergence white light to meet different lighting needs. Generally, white light-emitting diodes are required to be made of a yellow light-emitting Yttrium Aluminum Garnet (YAG) fluorescent powder with a diverging blue light emitting diode, which can be combined to emit white light. The white light emitting diode fabricated by the technology can be further divided into a multi-wafer type white light emitting diode and a single chip white light emitting diode.
請參照圖1,為一習知多晶片型白光發光二極體1,包含彼此相鄰設置的一紅光發光二極體11、一綠光發光二極體12,及一藍光發光二極體13。透過將該紅光發光二極體11、該綠光發光二極體12,及該藍光發光二極體13 所散發的光進行混成,即可產生白光。然而,習知多晶片型白光發光二極體1雖可視不同需求調整所欲發出之白光的光色,但需要同時使用多個不同顏色的發光二極體,故其製作成本較高。另外,不同顏色的發光二極體在驅動電壓上會有所差異,因此需要設計三組不同的電路分別控制驅動電壓,在製程上相當麻煩。此外,因不同顏色的發光二極體其晶片之衰減速率、溫度特性及壽命皆不盡相同,將導致該紅光發光二極體11、該綠光發光二極體12,及該藍光發光二極體13混成之白光光色會隨使用時間而產生變化,無法產生品質穩定的照明效果。 Referring to FIG. 1 , a conventional multi-wafer type white light emitting diode 1 includes a red light emitting diode 11 , a green light emitting diode 12 , and a blue light emitting diode 13 disposed adjacent to each other. . The red light emitting diode 11 , the green light emitting diode 12 , and the blue light emitting diode 13 The emitted light is mixed to produce white light. However, the conventional multi-wafer type white light-emitting diode 1 can adjust the light color of the white light to be emitted according to different needs, but it is necessary to use a plurality of light-emitting diodes of different colors at the same time, so that the manufacturing cost is high. In addition, the LEDs of different colors may have different driving voltages, so it is necessary to design three different circuits to separately control the driving voltage, which is quite troublesome in the manufacturing process. In addition, the light-emitting diodes of different colors have different decay rates, temperature characteristics and lifetimes of the wafer, which will result in the red light-emitting diode 11, the green light-emitting diode 12, and the blue light-emitting diode. The white light color of the polar body 13 will change with the use time, and it will not produce a stable lighting effect.
參照圖2及圖3,為一傳統單晶片型發光二極體2,包含一發光二極體21,及一被該發光二極體21所激發之螢光粉單元22。該傳統單晶片型發光二極體2主要可分為三種: Referring to FIG. 2 and FIG. 3, a conventional single-wafer type LED 2 includes a light-emitting diode 21 and a phosphor unit 22 excited by the light-emitting diode 21. The conventional single-wafer type light-emitting diode 2 can be mainly divided into three types:
一、藍光發光二極體21搭配黃色的螢光粉單元22。利用藍光發光二極體21激發可發出黃光之螢光粉單元22,該螢光粉單元22所發出之黃光與未被吸收之藍光混合,即可產生白光23。在此一類型中,所使用之螢光粉單元22主要為釔鋁石榴石結構之YAG螢光粉。 1. The blue light emitting diode 21 is matched with a yellow phosphor unit 22. The yellow light-emitting phosphor unit 22 is excited by the blue light-emitting diode 21, and the yellow light emitted by the phosphor powder unit 22 is mixed with the unabsorbed blue light to generate white light 23. In this type, the phosphor powder unit 22 used is mainly a YAG phosphor powder of a yttrium aluminum garnet structure.
二、藍光發光二極體21配合紅色與綠色的螢光粉單元22。利用藍光發光二極體21分別激發可發出紅光及綠光之螢光粉單元22,該 螢光粉單元22所產生之紅光、綠光,與未被吸收之藍光混合後,即可產生白光23。在此一類型中,所使用之螢光粉單元22主要是以含硫之螢光粉為主。 2. The blue light emitting diode 21 is combined with the red and green phosphor unit 22. The blue light emitting diode 21 is respectively used to excite the fluorescent powder unit 22 which can emit red light and green light, which The red light and the green light generated by the phosphor unit 22 are mixed with the unabsorbed blue light to generate white light 23. In this type, the phosphor unit 22 used is mainly a sulfur-containing phosphor.
三、紫外光發光二極體(UV-LED)21配合紅色、綠色與藍色三色的螢光粉單元22。利用該紫外光發光二極體21產生之紫外光的同時,激發三種或三種以上可分別產生紅、綠、與藍光之螢光粉單元22,螢光粉單元22產生之三色或三色以上的光即可混合成白光23。需注意的是,在此類型中,使用之發光二極體21除了是紫外光發光二極體21外,也可以是藍光發光二極體21。 3. The ultraviolet light emitting diode (UV-LED) 21 is combined with the phosphor powder unit 22 of three colors of red, green and blue. The ultraviolet light generated by the ultraviolet light emitting diode 21 is used to excite three or more kinds of phosphor powder units 22 which can respectively generate red, green and blue light, and the phosphor powder unit 22 generates three or more colors. The light can be mixed into white light 23. It should be noted that in this type, the light-emitting diode 21 used may be a blue light-emitting diode 21 in addition to the ultraviolet light-emitting diode 21.
參閱圖1及圖3,然而,無論是多晶片型白光發光二極體1,或是單晶片型發光二極體2,其所能發出白光的出光角度大約在90度至160度之間,因此使得該多晶片型白光發光二極體1或該單晶片型發光二極體2皆面臨發光角度不如傳統燈具來得全面的問題。雖然,該多晶片型白光發光二極體1或該單晶片型發光二極體2也可以如同傳統燈具一樣,加裝反射機構或是透鏡以改善燈具照明角度,但使用反射機構或利用透鏡增加出光角度都會造成該多晶片型白光發光二極體1或該單晶片型發光二極體2的發光效率降低。當然,使用者也可以利用設置兩倍以上數量的多晶片型白光發光二極體1或單晶片型發光二極體 2,以期達到360度照明角度的效果。但此一作法會大幅地增加設置成本,使發光二極體照明燈具售價提高。 Referring to FIG. 1 and FIG. 3, however, whether the multi-wafer type white light-emitting diode 1 or the single-wafer type light-emitting diode 2 has a white light emitting angle of about 90 to 160 degrees, Therefore, the multi-wafer type white light-emitting diode 1 or the single-wafer type light-emitting diode 2 faces a problem that the illumination angle is not as comprehensive as that of the conventional lamp. Although the multi-wafer type white light-emitting diode 1 or the single-wafer type light-emitting diode 2 can also be equipped with a reflection mechanism or a lens to improve the illumination angle of the lamp like a conventional lamp, the reflection mechanism or the lens is used to increase the angle. The light-emitting angle causes a decrease in luminous efficiency of the multi-wafer type white light-emitting diode 1 or the single-wafer type light-emitting diode 2. Of course, the user can also use a multi-wafer type white light-emitting diode 1 or a single-wafer type light-emitting diode that is more than twice the number. 2, in order to achieve the effect of 360 degree illumination angle. However, this practice will greatly increase the installation cost and increase the price of the LED lighting fixture.
因此,本發明之目的,即在提供一種兼顧成本與發光效率,且可全方位發光的發光二極體。 Therefore, an object of the present invention is to provide a light-emitting diode which can achieve both cost and luminous efficiency and can emit light in all directions.
本發明之另一目的,則在提供一種用以封裝出可全方位發光的發光二極體之封裝方法。 Another object of the present invention is to provide a packaging method for packaging a light-emitting diode capable of omnidirectional illumination.
於是,本發明全方位發光之發光二極體裝置,包含一燈板機構,及一覆設於該燈板機構之封裝體。該燈板機構包括一透明基板、一設置於該透明基板上之發光二極體晶片單元、一設置於該透明基板上並與該發光二極體晶片單元及一外界電源電連接之電性傳導單元,及一與該透明基板相固定的透明保護板。 Therefore, the omnidirectional light-emitting diode device of the present invention comprises a light-plate mechanism and a package covering the light-plate mechanism. The lamp board mechanism includes a transparent substrate, a light emitting diode chip unit disposed on the transparent substrate, and an electrical conduction disposed on the transparent substrate and electrically connected to the light emitting diode chip unit and an external power source. a unit and a transparent protective plate fixed to the transparent substrate.
另外,本發明全方位發光之發光二極體裝置之封裝方法,包含:一設置步驟,將該發光二極體晶片單元及該電性傳導單元設置於該透明基板上,並使該發光二極體晶片單元及該電性傳導單元能與外界電連接。 In addition, the method for packaging the omnidirectional light-emitting diode device of the present invention comprises: a setting step of disposing the light-emitting diode chip unit and the electrical conductive unit on the transparent substrate, and making the light-emitting diode The bulk wafer unit and the electrically conductive unit can be electrically connected to the outside.
一調配步驟,依照本發明所需的光色及色溫調配適合的封裝體。 A compounding step of formulating a suitable package in accordance with the desired color and color temperature of the present invention.
一結合步驟,透過一黏著劑單元將該透明保護板與該透明基板結合,使該透明基板、該發光二極體晶片單元、該電性傳導單元、該黏著劑單元及該透明保護板組成該燈板機構。 a bonding step of bonding the transparent protective plate to the transparent substrate through an adhesive unit, so that the transparent substrate, the light emitting diode wafer unit, the electrically conductive unit, the adhesive unit and the transparent protective plate constitute the Light board mechanism.
一封裝步驟,利用灌模及固化的方式,使該封裝體包覆並定型於該燈板機構外。 In a packaging step, the package is coated and shaped outside the lamp board by means of filling and curing.
本發明之功效在於:藉由該透明基板的設置,使該發光二極體晶片單元所發出的光可以360度全方位發射,並藉由該封裝體之調配,使該發光二極體晶片能調整出符合需求且品質穩定的光源,並保護該發光二極體晶片單元的設置。 The effect of the invention is that the light emitted by the LED unit can be emitted in 360 degrees by the arrangement of the transparent substrate, and the LED can be made by the package. Adjusting the light source that meets the requirements and is stable in quality, and protecting the setting of the LED unit.
4‧‧‧發光二極體裝置 4‧‧‧Lighting diode device
40‧‧‧燈板機構 40‧‧‧Light board mechanism
41‧‧‧透明基板 41‧‧‧Transparent substrate
41’‧‧‧電路板 41’‧‧‧ boards
42‧‧‧發光二極體晶片單元 42‧‧‧LED Diode Wafer Unit
421‧‧‧發光二極體晶片 421‧‧‧Light Emitting Diode Wafer
43‧‧‧電性傳導單元 43‧‧‧Electrical Conduction Unit
431‧‧‧電性傳導部 431‧‧‧Electrical Conducting Department
44‧‧‧導線單元 44‧‧‧Wire unit
441‧‧‧導線 441‧‧‧ wire
45‧‧‧黏著劑單元 45‧‧‧Adhesive unit
451‧‧‧黏著部 451‧‧‧Adhesive
46‧‧‧透明保護板 46‧‧‧Transparent protection board
47‧‧‧封裝體 47‧‧‧Package
471‧‧‧螢光劑 471‧‧‧Fluorescent agent
48‧‧‧防潮膜 48‧‧‧Damp film
51‧‧‧設置步驟 51‧‧‧Setting steps
52‧‧‧調配步驟 52‧‧‧Provisioning steps
52’‧‧‧添加步驟 52’‧‧‧Addition steps
53‧‧‧結合步驟 53‧‧‧ Combination steps
54‧‧‧封裝步驟 54‧‧‧Packaging steps
本發明之其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中:圖1是一示意圖,說明一習知多晶片型白光發光二極體之使用態樣;圖2是一示意圖,說明一習知單晶片型發光二極體2;圖3是一示意圖,用以輔助說明圖2中虛線所示之部分的使用態樣;圖4是一立體圖,說明本發明全方位發光之發光二極體裝置的一第一較佳實施例;圖5是一立體分解圖,用以輔助說明圖4,為便於說明,圖5中省略部分構件未繪示;圖6是一俯視圖,說明該第一較佳實施例之另一使用態樣;圖7是一光譜圖,說明該第一較佳實施例使用之YAG:Ce螢光粉的激發光譜及發射光譜;圖8是一電子顯微鏡圖,說明該第一較佳實施例使用 之YAG:Ce螢光粉的顆粒;圖9是一流程圖,說明本發明全方位發光之發光二極體裝置之封裝方法的一第一較佳實施例;圖10是一頻譜圖,說明該全方位發光之發光二極體裝置之第一較佳實施例於使用時之頻譜狀態;圖11是一側視圖,說明本發明全方位發光之發光二極體裝置之一第二較佳實施例;圖12是一俯視示意圖,說明本發明全方位發光之發光二極體裝置之一第三較佳實施例,為便於說明,圖12中省略部分構件未繪示;圖13是一側視圖,用以輔助說明圖12;圖14是一側視圖,說明該第三較佳實施例之另一使用態樣;圖15是一流程圖,說明本發明全方位發光之發光二極體裝置之封裝方法的一第二較佳實施例;及圖16是一側視圖,說明本發明全方位發光之發光二極體裝置之一第四較佳實施例。 Other features and effects of the present invention will be apparent from the following description of the drawings. FIG. 1 is a schematic view showing a use of a conventional multi-wafer type white light emitting diode; FIG. 2 is a BRIEF DESCRIPTION OF THE DRAWINGS FIG. 3 is a schematic view for explaining the use of the portion shown by the broken line in FIG. 2; FIG. 4 is a perspective view showing the omnidirectional illumination of the present invention. FIG. 5 is an exploded perspective view for assisting in explaining FIG. 4. For convenience of explanation, parts omitted in FIG. 5 are not shown; FIG. 6 is a top view. Another use of the first preferred embodiment is illustrated; FIG. 7 is a spectrogram illustrating the excitation and emission spectra of the YAG:Ce phosphor used in the first preferred embodiment; FIG. 8 is an electron Microscope image illustrating the use of the first preferred embodiment FIG. 9 is a flow chart illustrating a first preferred embodiment of a method for packaging the omnidirectional illumination LED device of the present invention; FIG. 10 is a spectrogram illustrating The first preferred embodiment of the omnidirectional illumination LED device is in a spectrum state in use; FIG. 11 is a side view showing a second preferred embodiment of the omnidirectional illumination LED device of the present invention. FIG. 12 is a top plan view showing a third preferred embodiment of the omnidirectional illumination LED device of the present invention. For convenience of explanation, some of the components omitted in FIG. 12 are not shown; FIG. 13 is a side view. FIG. 14 is a side view showing another use mode of the third preferred embodiment; FIG. 15 is a flow chart illustrating the package of the omnidirectional illumination LED device of the present invention. A second preferred embodiment of the method; and FIG. 16 is a side elevational view of a fourth preferred embodiment of the omnidirectional illumination LED device of the present invention.
在本發明被詳細描述之前,要注意的是,在以下的說明內容中,類似的元件是以相同的編號來表示。 Before the present invention is described in detail, it is noted that in the following description, similar elements are denoted by the same reference numerals.
參閱圖4,為本發明全方位發光之發光二極體裝置4之一第一較佳實施例。該第一較佳實施例包含一燈板機構40,及一包覆於該燈板機構40外之封裝體47。其中,該燈板機構40包括一透明基板41、一設置於該透明基板 41上之發光二極體晶片單元42、一設置於該透明基板41上之電性傳導單元43、一電連接於該電性傳導單元43與該發光二極體晶片單元42間之導線單元44、一設置於該透明基板41上的黏著劑單元45,及一藉由該黏著劑單元45而與該透明基板41相固定的透明保護板46。 Referring to FIG. 4, a first preferred embodiment of the omnidirectional illumination LED device 4 of the present invention is shown. The first preferred embodiment includes a light panel mechanism 40 and a package body 47 that is wrapped around the light panel mechanism 40. The light board mechanism 40 includes a transparent substrate 41 and a transparent substrate. A light-emitting diode unit 42 on the 41, an electrical conduction unit 43 disposed on the transparent substrate 41, and a wire unit 44 electrically connected between the conductive unit 43 and the LED unit 42 An adhesive unit 45 disposed on the transparent substrate 41 and a transparent protective plate 46 fixed to the transparent substrate 41 by the adhesive unit 45.
參閱圖5,該透明基板41之材料可為玻璃、陶瓷、塑膠或高分子聚合物,而該發光二極體晶片單元42則具有多個固定於該透明基板41上且可發出藍光的發光二極體晶片421。該電性傳導單元43具有兩個分別與外界電源相連接之電性傳導部431,該導線單元44則具有多個使該等電性傳導部431與該等發光二極體晶片421電連接之導線441。需特別說明的是,在本較佳實施例中,該等電性傳導部431分別連接外接電源的正極與負極,且由20 mA的電流驅動。另外,每一發光二極體晶片421的面積可為10 x 30 mil2的n倍(n=1,2,3...),以透過面積的增大來提升發光效果。 Referring to FIG. 5, the material of the transparent substrate 41 may be glass, ceramic, plastic or high molecular polymer, and the LED unit 42 has a plurality of light-emitting diodes fixed on the transparent substrate 41 and emitting blue light. The polar body wafer 421. The electrically conductive unit 43 has two electrically conductive portions 431 respectively connected to the external power source. The lead unit 44 has a plurality of electrically conductive portions 431 electrically connected to the LEDs 421 . Wire 441. It should be noted that, in the preferred embodiment, the electrically conductive portions 431 are respectively connected to the positive and negative terminals of the external power source, and are driven by a current of 20 mA. In addition, the area of each of the light-emitting diode wafers 421 may be n times (n = 1, 2, 3, ...) of 10 x 30 mil 2 to increase the light-emitting effect by increasing the transmission area.
該黏著劑單元45具有二間隔設置於該透明基板41上的黏著部451。當然,該黏著劑單元45也可以僅具有一黏著部451,只要其設置位置能使該透明保護板46穩固地結合於該透明基板41上即可。如同該透明基板41一般,該透明保護板46的材質也可以玻璃、陶瓷、塑膠或高分子聚合物等透明板材。此外,該等發光二極體晶片421、該等電性傳導部431、該等導線441的數量也不以圖式中所繪示的樣子為限。在本較佳實施例中,該發光二極體晶片單元 42是具有15片彼此串聯之發光二極體晶片421,實際運用上也可以是以如圖6之方式,以並聯的方式使該等發光二極體晶片421彼此電連接。另外,該發光二極體晶片單元42也可僅具有一發光二極體晶片421,只要適當地藉由該導線單元44及該電性傳導單元43的配置而與外界電源連接,一樣可以達到本發明欲達成之功效。 The adhesive unit 45 has two adhesive portions 451 which are spaced apart from each other on the transparent substrate 41. Of course, the adhesive unit 45 may have only one adhesive portion 451 as long as it is disposed at a position such that the transparent protective plate 46 can be firmly bonded to the transparent substrate 41. As the transparent substrate 41, the transparent protective plate 46 may be made of a transparent plate such as glass, ceramic, plastic or polymer. In addition, the number of the LEDs 421, the electrically conductive portions 431, and the wires 441 are not limited to those shown in the drawings. In the preferred embodiment, the LED chip unit 42 is a light-emitting diode wafer 421 having 15 chips connected in series, and in practice, the light-emitting diode chips 421 may be electrically connected to each other in parallel as shown in FIG. In addition, the LED unit 42 may have only one LED chip 421, and may be connected to the external power source as appropriate by the arrangement of the wire unit 44 and the electrical conduction unit 43. The effect that the invention wants to achieve.
復參閱圖4,該封裝體47是由粉狀的螢光劑471、固化劑、硅膠、矽烷(siline coupling)及擴散劑,混合均勻並經固化而成。其中,該粉狀之螢光劑471的組成是取自各種自普通的稀土元素激發的黃色、綠色和紅色的螢光粉,再將各種螢光粉依不同的比例調製成不同的螢光體後,以不同的螢光體進行本發明所使用之螢光劑471的調製。 Referring to FIG. 4, the package body 47 is formed by a powdery phosphor 471, a curing agent, a silica gel, a siline coupling, and a diffusing agent, which are uniformly mixed and cured. The composition of the powdery phosphor 471 is obtained from various yellow, green and red phosphors excited by common rare earth elements, and various phosphors are prepared into different phosphors according to different ratios. Thereafter, the modulation of the phosphor 471 used in the present invention is carried out with different phosphors.
進一步說明,在本較佳實施例中,是選用YAG螢光粉、LuAG螢光粉及SSN螢光粉三種螢光粉來進行調配。其中,黃色的YAG螢光粉,其分子式為Y3Al5O12:Ce,是採用高溫固相法制成,並能提供540 nm至580 nm附近的黃色發射光;綠色的LuAG螢光粉之分子式為Lu3Al5O12:Ce,也是採用高溫固相法制成,並可提供500 nm至540 nm附近的綠色發射光;而氮化物紅色的SSN螢光粉之分子式則為Sr2Si5N8:Eu,同樣是採用高溫固相法制成,並可提供620 nm至660 nm附近的紅色發射光。 Further, in the preferred embodiment, three kinds of phosphor powders, YAG phosphor powder, LuAG phosphor powder and SSN phosphor powder, are used for the preparation. Among them, the yellow YAG phosphor powder has a molecular formula of Y 3 Al 5 O 12 :Ce, which is prepared by high-temperature solid phase method and can provide yellow emission light near 540 nm to 580 nm; green LuAG phosphor powder The molecular formula is Lu 3 Al 5 O 12 :Ce, which is also made by high temperature solid phase method and can provide green emission light around 500 nm to 540 nm; while the molecular formula of nitride red SSN phosphor powder is Sr 2 Si 5 N 8 :Eu is also made by high temperature solid phase method and provides red emission near 620 nm to 660 nm.
在本較佳實施例中,藉由黃色的YAG螢光粉,LuAG螢光粉及SSN螢光粉三種螢光粉來調配出H3000、 H4500、H6000及Y-003四種螢光體。各種不同螢光體及所使用的螢光粉重量克配比規格如下: In the preferred embodiment, the H3000 is prepared by yellow YAG phosphor powder, LuAG phosphor powder and SSN phosphor powder. H4500, H6000 and Y-003 four kinds of phosphors. The specifications of the various phosphors and the phosphor powder used are as follows:
一、H3000螢光體,色溫為3000±300K:YAG:LuAG:SSN=0.2:0.40:0.10~0.15 1. H3000 phosphor, color temperature is 3000±300K: YAG: LuAG: SSN=0.2: 0.40: 0.10~0.15
二、H4500螢光體,色溫為4500±300K:YAG:LuAG:SSN=0.2:0.40:0.05~0.10 Second, H4500 phosphor, color temperature is 4500 ± 300K: YAG: LuAG: SSN = 0.2: 0.40: 0.05 ~ 0.10
三、H6000螢光體,色溫為6000±300K:YAG:LuAG:SSN=0.2:0.40:0.01~0.05 Third, H6000 phosphor, color temperature is 6000 ± 300K: YAG: LuAG: SSN = 0.2: 0.40: 0.01 ~ 0.05
四、Y-003螢光體:YAG=100% Fourth, Y-003 phosphor: YAG=100%
當然,上述黃色的YAG螢光粉也可以採用氮氧化物黃色螢光粉,分子式為β-SiAlON,上述綠色的LuAG螢光粉也可以為氮化物綠色螢光粉,分子式為BaAlON,而上述的紅色的SSN螢光粉也可以為氮化物紅色螢光粉SASN,分子式為SrAlSiN8:Eu。使用者可以根據需要加入第四種或者以上種類的螢光粉。 Of course, the yellow YAG phosphor powder may also be a yellow oxide yellow phosphor powder, the molecular formula is β-SiAlON, and the green LuAG phosphor powder may also be a nitride green phosphor powder, and the molecular formula is BaAlON, and the above The red SSN phosphor can also be a nitride red phosphor SASN with a molecular formula of SrAlSiN 8 :Eu. The user can add a fourth or more kinds of phosphor powder as needed.
需特別說明的是,在本較佳實施例中所使用之螢光劑471,可以是選自上述四種螢光體的組合,也可以是選用上述四種螢光體的其中一種,只要注意調配出來的粉狀螢光劑471需符合以下要求: It should be noted that the phosphor 471 used in the preferred embodiment may be selected from the combination of the above four kinds of phosphors, or one of the above four kinds of phosphors may be selected. The formulated powdered phosphor 471 must meet the following requirements:
一、螢光劑471的激發光譜應與該等發光二極體晶片421所發出的藍光(波長440 nm至470nm)發射光譜相匹配。 1. The excitation spectrum of the phosphor 471 should match the emission spectrum of the blue light (wavelength 440 nm to 470 nm) emitted by the LED chips 421.
二、被藍光激發後,該螢光劑471能產生高效 的可見光發射,其發射光譜滿足白光要求,且光能轉換率高、流明效率高,並具備優良的溫度猝滅特性。 2. After being excited by blue light, the fluorescent agent 471 can produce high efficiency. The visible light emission has an emission spectrum that satisfies the requirements of white light, high light energy conversion rate, high lumen efficiency, and excellent temperature quenching characteristics.
三、材料的物理化學性質穩定,且具有抗潮的功用,不會與半導體芯片或封裝材料相互反應。 Third, the material is stable in physical and chemical properties, and has a moisture-resistant function and does not react with semiconductor chips or packaging materials.
四、要能耐紫外光子長期轟擊,性能安定。 Fourth, to be able to withstand long-term bombardment of ultraviolet photons, performance stability.
五、螢光劑471的顆粒要細,粒徑需在8μm以下。 5. The particles of the phosphor 471 should be fine, and the particle size should be below 8 μm.
六、要求合成螢光劑471的設備簡單,且所使用的原料價格低廉。 6. The equipment for synthesizing the phosphor 471 is simple, and the raw materials used are inexpensive.
參閱圖7,為本發明自製配方Y-003螢光體(黃色YAG:Ce螢光粉)的測試的頻譜。從激發光譜獲得的波長有342 nm和460 nm,其中460 nm剛好和發光二極體晶片421所發射的藍光發射光譜(440 nm至470 nm)相匹配。從圖7中可知透過該Y-003螢光體可獲得的發射光譜550 nm左右的波長,若再調整其使用比例,則可以進一步調節波長的範圍。 Referring to Fig. 7, the spectrum of the test of the self-made formula Y-003 phosphor (yellow YAG: Ce phosphor) of the present invention is shown. The wavelengths obtained from the excitation spectrum are 342 nm and 460 nm, of which 460 nm coincides with the blue emission spectrum (440 nm to 470 nm) emitted by the LED 421. As can be seen from Fig. 7, the wavelength of the emission spectrum obtained by the Y-003 phosphor is about 550 nm, and if the ratio of use is adjusted, the wavelength range can be further adjusted.
圖8則為本發明自製配方Y-003螢光體的YAG:Ce的顆粒電鏡照片。螢光粉粒度參數(Granularity Parameters):D10=9.74μm,顯示出本發明所使用之螢光粉顆粒接近螢光劑471所要求的粒徑。 Fig. 8 is a particle electron micrograph of YAG:Ce of the self-made formula Y-003 phosphor of the present invention. The Granularity Parameters: D10 = 9.74 μm, showing that the phosphor particles used in the present invention are close to the particle size required for the phosphor 471.
另外,由於該螢光劑471是無機化合物,而硅膠則是有機化合物,因此兩者在混合上常會發生無法均勻 混合的情況,進而在固化的過程中產生縫隙。該等縫隙中所被封存的空氣在高溫下會使其中的氫原子及氧原子產生化學反應,進而形成黑斑或造成光斑。因此,藉由該擴散劑及矽烷(siline coupling)的添加,可使無機的螢光劑471及有機的硅膠均勻混合,避免因混合不均而產生縫隙影響封裝後的照明品質。在本較佳實施例中,所使用之擴散劑為喬越所出產的型號115或120之擴散劑,其內所含的成分為二氧化硅,而所使用之矽烷可選用任一市售產品。 In addition, since the phosphor 471 is an inorganic compound and the silica gel is an organic compound, the two often fail to be uniform in mixing. In the case of mixing, a gap is created during the curing process. The air sealed in the gaps causes a chemical reaction between hydrogen atoms and oxygen atoms in the high temperature, thereby forming dark spots or causing spots. Therefore, by the addition of the diffusing agent and the silane coupling, the inorganic phosphor 471 and the organic silica gel can be uniformly mixed to prevent the gap from being affected by the unevenness of the mixing and affecting the lighting quality after the package. In the preferred embodiment, the diffusing agent used is a type 115 or 120 diffusing agent produced by Qiao Yue, the component contained therein is silica, and the decane used may be any commercially available product. .
整體來說,在本較佳實施例中,該螢光劑471佔封裝體47之重量百分比60%至70%,該擴散劑及矽烷的添加量分別佔該封裝體47的重量百分比2%及0.1%以下,剩餘的則為硅膠與固化劑依1:4的重量比例調合而成。 In general, in the preferred embodiment, the phosphor 471 accounts for 60% to 70% by weight of the package 47, and the amount of the diffusing agent and decane is 2% by weight of the package 47, respectively. 0.1% or less, the remainder is a blend of silica gel and curing agent in a weight ratio of 1:4.
參閱圖5及圖9,本發明全方位發光之發光二極體裝置之封裝方法是包含一設置步驟51、一調配步驟52、一結合步驟53,及一封裝步驟54。 Referring to FIG. 5 and FIG. 9 , the packaging method of the omnidirectional light emitting diode device of the present invention comprises a setting step 51 , a compounding step 52 , a combining step 53 , and a packaging step 54 .
首先,該設置步驟51是用以將該等發光二極體晶片421及該等電性傳導部431設置於該透明基板41上,並使該等發光二極體晶片421及該等電性傳導部431能與一外界電源電連接。 First, the setting step 51 is for disposing the LEDs 421 and the electrically conductive portions 431 on the transparent substrate 41, and the LEDs 421 and the electrically conductive electrodes. The portion 431 can be electrically connected to an external power source.
詳細地說,是先於該透明基板41上,以透明度較高的膠材如矽膠等作為固定晶片的黏膠,並依照產品所需的發光二極體晶片421的串、並個數進行固晶排列,並在該透明基板41上設置該等與該外部電源電連接的電性傳導部431。接著,利用傳統發光二極體焊線(wire bond)的方 式,將該等導線441焊在該等發光二極體晶片421及該等電性傳導部431之間,使該等發光二極體晶片421與外界電源電連接。 In detail, prior to the transparent substrate 41, a highly transparent adhesive such as silicone or the like is used as a glue for fixing the wafer, and the number of the LEDs 421 required for the product is solidified. The crystal array is arranged, and the electrically conductive portion 431 electrically connected to the external power source is disposed on the transparent substrate 41. Then, using the square of the conventional light-emitting diode wire bond The wires 441 are soldered between the LEDs 421 and the electrically conductive portions 431 to electrically connect the LEDs 421 to an external power source.
需特別說明的是,為使得本發明之使用年限及耐用性可以維持在良好的狀態,在該設置步驟51中,要特別注意該等發光二極體晶片421在進行焊線時,焊線強度是否足夠,而該等電性傳導部431與該透明基板41間的結合強度也需要特別注意。 It should be particularly noted that in order to maintain the useful life and durability of the present invention in a good state, in the setting step 51, special attention should be paid to the wire bonding strength of the light-emitting diode wafer 421 when the bonding wire is being processed. Whether or not it is sufficient, and the bonding strength between the electrically conductive portion 431 and the transparent substrate 41 also requires special attention.
參閱圖4及圖9,該調配步驟52是依照本發明所需的光色及色溫調配適合的封裝體47。進一步說明,是將螢光劑471、固化劑、硅膠、矽烷及擴散劑,按比例調配混合攪拌10至30分鐘後,使該呈粉狀的螢光劑471均勻地分散於該封裝體47中,並除去氣泡備用。由於螢光劑471的分佈影響了與其所能吸收或被激發的光線發射之角度,因此螢光劑471是否均勻分散於該封裝體47內,即成為該調配步驟52中非常重要的一環。 Referring to Figures 4 and 9, the blending step 52 is a suitable package 47 in accordance with the desired color and color temperature of the present invention. Further, the phosphor 471, the curing agent, the silica gel, the decane, and the diffusing agent are mixed and stirred for 10 to 30 minutes, and the powdery phosphor 471 is uniformly dispersed in the package 47. Medium, and remove the bubble spare. Since the distribution of the phosphor 471 affects the angle of emission of light that it can absorb or be excited, whether or not the phosphor 471 is uniformly dispersed in the package 47 becomes a very important part of the compounding step 52.
該結合步驟53是透過該等黏著部451將該透明保護板46與該透明基板41相結合,即完成該燈板機構40的設置。 The bonding step 53 combines the transparent protective plate 46 with the transparent substrate 41 through the adhesive portions 451, that is, the installation of the light plate mechanism 40 is completed.
接著進行該封裝步驟54。該封裝步驟54是利用灌模及固化的方式,使該封裝體47包覆並定型於該燈板機構40外。進一步說明,該封裝步驟54是透過一柱狀外型的模具(圖未示)包覆該燈板機構40,並使用灌模的方式,將調配好的封裝體47灌入該模具中以包覆該燈板機構 40。接著,使用固化的方式,使該封裝體47定型,再拆離該模具後,即完成本發明該全方位發光之發光二極體裝置4的設置。需特別注意的是,在該封裝步驟54中,封裝體47所固化成型的柱狀體厚度是否均勻,會影響該發光二極體裝置4是否能均勻出光,因此在該封裝步驟54中務必仔細確認該封裝體47固化的結果。 This encapsulation step 54 is then performed. The encapsulation step 54 is to cover and shape the package body 47 outside the lamp panel mechanism 40 by means of filling and curing. Further, the encapsulating step 54 is to cover the lamp panel mechanism 40 through a cylindrical outer mold (not shown), and fill the prepared package body 47 into the mold by using a filling method. Covering the light board mechanism 40. Next, the package body 47 is shaped by curing, and after the mold is detached, the installation of the omnidirectional light-emitting diode device 4 of the present invention is completed. It should be noted that, in the packaging step 54, whether the thickness of the column body formed by the package 47 is uniform, whether the light-emitting diode device 4 can uniformly emit light, and therefore must be carefully in the packaging step 54. The result of curing of the package 47 was confirmed.
復參閱圖4,使用時,該等發光二極體晶片421所射出之藍光波長在碰到該螢光劑471後,會混成符合預設品質的白光色溫射出。由於該第一較佳實施例之燈板機構40中,所使用的透明基板41及透明保護板46皆為透明或具有良好的光穿透率,因此並不會因為該透明基板41或該透明保護板46的設置而遮擋了該等發光二極體晶片421的發光角度。換言之,即便以該封裝體47以柱狀之形態包覆該燈板機構40,其柱狀結構外觀各面仍可均勻發出白光。 Referring to FIG. 4, in use, the wavelength of the blue light emitted by the LED chips 421 is mixed with the white light color temperature of the preset quality after the phosphor 471 is touched. In the lamp panel mechanism 40 of the first preferred embodiment, the transparent substrate 41 and the transparent protective plate 46 are transparent or have good light transmittance, and therefore are not transparent to the transparent substrate 41 or the transparent substrate 41. The arrangement of the protective plates 46 blocks the light-emitting angle of the light-emitting diode wafers 421. In other words, even if the package body 47 is covered with the lamp body 40 in the form of a column, the white surface of the columnar structure can uniformly emit white light.
為確保本發明確實能在維持發光品質的前提下達到全方位發光的功效,以如圖5所示之規格,並搭配由不同比例的H3000、H4500、H6000及Y-003螢光體所製成的螢光劑471,逐一針對其光電特性進行檢測。需特別說明的是,在本檢測實驗中,實驗分為初期光電特性(點燈時間t=0)及壽命測試(點燈時間t=60分),且所有的實驗均在驅動電流為20 mA的室溫下進行。實驗結果如下表1及表2及圖10。 In order to ensure that the present invention can achieve the omnidirectional illuminating effect under the premise of maintaining the illuminating quality, it is made of the specifications shown in FIG. 5 and matched with different proportions of H3000, H4500, H6000 and Y-003 phosphors. The phosphor 471 is detected one by one for its photoelectric characteristics. In particular, in this test, the experiment is divided into initial photoelectric characteristics (lighting time t = 0) and life test (lighting time t = 60 minutes), and all experiments are driven at 20 mA. It is carried out at room temperature. The experimental results are shown in Tables 1 and 2 and Figure 10 below.
從實驗結果來看,理論上色溫較低時亮度也會較低,但本發明在高色溫與低色溫時所呈現之亮度相差不 多,應為螢光劑471的貢獻。此外,在演色性的檢測上也都有接近80%的表現。 From the experimental results, the brightness will be lower when the theoretical color temperature is lower, but the brightness difference between the present invention at high color temperature and low color temperature is not More, it should be the contribution of the fluorescent agent 471. In addition, there are nearly 80% performance in the detection of color rendering.
進一步,在20mA條件下白光與黃光在5分鐘內光衰會到達穩定值,而白光的光衰程度較低,只有3%,黃光較高有7%。彩色座標(CIE)變化與色溫變化的幅度不大,大約都在5分鐘內可到達穩定值。 Further, under 20 mA, white light and yellow light will reach a stable value within 5 minutes, while white light has a low light attenuation of only 3%, and yellow light has a higher 7%. The color coordinate (CIE) change and the color temperature change are not large, and the stable value can be reached in about 5 minutes.
藉由以上所述之結構設計,本發明之第一較佳實施例於實際使用時具有以下所述優點: With the structural design described above, the first preferred embodiment of the present invention has the following advantages in practical use:
(1)全方位出光:透過該透明基板41的設置,使得本發明之發光二極體晶片單元42的出光方向不 會受到遮擋,加上包覆於該燈板機構40外圍的封裝體47也是透明的態樣,因此可以平均地達到360度的出光的效果。 (1) Omnidirectional light output: the light emitting direction of the light emitting diode wafer unit 42 of the present invention is not transmitted through the arrangement of the transparent substrate 41 It is shielded, and the package 47 wrapped around the periphery of the lamp mechanism 40 is also transparent, so that an effect of 360 degrees of light can be achieved on average.
(2)光電特性穩定:透過本發明特殊配置的螢光劑471,不但使本發明所發出之白光品質穩定,且無論是高色溫或低色溫時皆能呈現差不多的亮度。另外,在演色性及光衰上,皆能有穩定良好的表現。 (2) Photoelectric characteristics are stable: The fluorescent agent 471 specially configured by the present invention not only stabilizes the white light quality emitted by the present invention, but also exhibits similar brightness regardless of high color temperature or low color temperature. In addition, in terms of color rendering and light decay, it can have a stable and good performance.
(3)使用壽命長:本發明除了有該透明基板41保護該等發光二極體晶片421外,還有該封裝體47包覆該燈板機構40,因此外界的水分或施力不易直接對該等發光二極體晶片421造成危害,可有效延長使用壽命。 (3) Long service life: In addition to the transparent substrate 41 protecting the light-emitting diode chips 421, the package body 47 covers the light-plate assembly 40, so that the external moisture or force is not easy to directly The LED chips 421 cause damage and can effectively extend the service life.
(4)維持發光品質:該封裝體47透過該擴散劑及矽烷的添加,使得無機的螢光劑471與有機的矽膠得以均勻混合,因此該封裝體47中不易因混合不勻而產生縫隙,故能避免封裝不良而造成光點的產生。 (4) Maintaining the illuminating quality: the encapsulating body 47 is uniformly mixed with the organic phthalocyanine by the addition of the diffusing agent and decane, so that the package 47 is less likely to have a gap due to uneven mixing. Therefore, it is possible to avoid the occurrence of light spots caused by poor packaging.
參閱圖11,為本發明之第二較佳實施例,為了避免本發明所揭示之封裝體47被外界侵透的水分毀損,該發光二極體裝置4還可用一種特殊的防潮膜48,以熱積壓 器(Laminator)積壓並包覆該全方位發光之發光二極體裝置4全體。如此一來,不但可以達到如同該第一較佳實施例之功效,經過信賴性實驗(Ref.SAE Technical Paper Series 850144,Thin film A.C.Electroluminescence for Automobile Instruments,March 1 1985)後,也已證明此法確實能使本發明的使用壽命增長。 Referring to FIG. 11, in order to avoid damage to the moisture of the package 47 disclosed by the present invention, the light-emitting diode device 4 can also be provided with a special moisture-proof film 48, in accordance with the second preferred embodiment of the present invention. Heat backlog The Laminator accumulates and covers the entire illuminating LED device 4 in all directions. In this way, not only can the effect as in the first preferred embodiment be achieved, but also after the reliability test (Ref. SAE Technical Paper Series 850144, Thin Film AC Electroluminescence for Automobile Instruments, March 1 1985). It is indeed possible to increase the service life of the present invention.
需特別說明的是,在本較佳實施例中所使用的防潮膜48是選用Aclar Film,即Nitoflon-4820N日東電工相當品。而實際使用時,並不以此種防潮膜48為限。 It should be particularly noted that the moisture-proof film 48 used in the preferred embodiment is an Aclar Film, that is, Nitoflon-4820N Nitto Denko equivalent. In actual use, it is not limited to such a moisture-proof film 48.
參閱圖12與圖13,為本發明之一第三較佳實施例。該第三較佳實施例與該第一較佳實施例大致相同,其不同的地方僅在於:該第三較佳實施例是直接使用一透明的電路板41’(PCB板)做為透明基板41(見圖11),而將該等發光二極體晶片421以ITO製程的方式直接固設於該電路板41’上。透過此一方式,該較佳實施例不需要再設置該等導線441(見圖11),而可直接將電路形成於該電路板41’上,能降低本發明因為焊線強度不足而產生的不良率。 Referring to Figures 12 and 13, a third preferred embodiment of the present invention is shown. The third preferred embodiment is substantially the same as the first preferred embodiment except that the third preferred embodiment directly uses a transparent circuit board 41' (PCB board) as a transparent substrate. 41 (see FIG. 11), and the LED chips 421 are directly fixed on the circuit board 41' by an ITO process. In this way, the preferred embodiment does not need to provide the wires 441 (see FIG. 11), and the circuit can be directly formed on the circuit board 41', which can reduce the invention because of insufficient strength of the wire. Bad rate.
此外,參閱圖14,在該第三較佳實施例中,由於該等發光二極體晶片421是可設置於該透明或不透明的電路板41’的兩相反側,因此能使得本發明所欲達到全方位發光之功效更加顯著。 In addition, referring to FIG. 14, in the third preferred embodiment, since the LED chips 421 are disposed on opposite sides of the transparent or opaque circuit board 41', the present invention can be made. The effect of achieving all-round illumination is more remarkable.
參閱圖15及圖16,為本發明之第四較佳實施例。該第四較佳實施例與該第一較佳實施例大致相同,其不同之處在於:在完成該調配步驟52後,即先進行一添加 步驟52’。該添加步驟52’是直接將該調配步驟52中調配好的封裝體47先覆蓋於未與該透明保護板46結合的透明基板41、該發光二極體晶片單元42及該導線單元44上,之後再進行該結合步驟53,利用該黏著劑單元45將該透明保護板46黏著於該透明基板41上。藉此,該封裝體47及其內含的螢光粉會位於該透明基板41及該透明保護板46之間,讓該螢光劑471的作用效果更好。而在此較佳實施例中,最後進行該封裝步驟54時,該封裝體47無論是否包覆該透明保護板46,都可以達到本發明所欲達到之功效。 Referring to Figures 15 and 16, a fourth preferred embodiment of the present invention is shown. The fourth preferred embodiment is substantially the same as the first preferred embodiment, except that after the configuration step 52 is completed, an addition is performed first. Step 52'. The adding step 52 ′ directly covers the transparent package 41 disposed in the matching step 52 on the transparent substrate 41 , the light emitting diode wafer unit 42 , and the wire unit 44 that are not combined with the transparent protective plate 46 . Thereafter, the bonding step 53 is performed, and the transparent protective sheet 46 is adhered to the transparent substrate 41 by the adhesive unit 45. Thereby, the package body 47 and the phosphor powder contained therein are located between the transparent substrate 41 and the transparent protection plate 46, so that the effect of the phosphor 471 is better. In the preferred embodiment, when the encapsulation step 54 is performed, the package 47 can achieve the effect of the present invention regardless of whether the transparent protection plate 46 is coated or not.
綜上所述,本發明透過該透明基板41的設置,搭配該封裝體47中特殊調配的螢光劑471,不但能使得該發光二極體晶片單元42可以全方位發光,且能擁有穩定且良好的發光品質及光電特性。此外,該擴散劑的添加也可以有助於降低封裝過程中因為各原料混合效果不佳產生的光點,故確實能達成本發明之目的。 In summary, the present invention, through the arrangement of the transparent substrate 41, and the specially-configured phosphor 471 in the package 47, can not only enable the LED unit 42 to emit light in all directions, but also has stable and Good luminescence quality and photoelectric properties. In addition, the addition of the diffusing agent can also contribute to the reduction of the spot caused by the poor mixing effect of the raw materials in the packaging process, so that the object of the present invention can be achieved.
惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及發明說明內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。 The above is only the preferred embodiment of the present invention, and the scope of the invention is not limited thereto, that is, the simple equivalent changes and modifications made by the scope of the invention and the description of the invention are All remain within the scope of the invention patent.
4‧‧‧發光二極體裝置 4‧‧‧Lighting diode device
40‧‧‧燈板機構 40‧‧‧Light board mechanism
41‧‧‧透明基板 41‧‧‧Transparent substrate
42‧‧‧發光二極體晶片單元 42‧‧‧LED Diode Wafer Unit
421‧‧‧發光二極體晶片 421‧‧‧Light Emitting Diode Wafer
43‧‧‧電性傳導單元 43‧‧‧Electrical Conduction Unit
431‧‧‧電性傳導部 431‧‧‧Electrical Conducting Department
44‧‧‧導線單元 44‧‧‧Wire unit
441‧‧‧導線 441‧‧‧ wire
45‧‧‧黏著劑單元 45‧‧‧Adhesive unit
451‧‧‧黏著部 451‧‧‧Adhesive
46‧‧‧透明保護板 46‧‧‧Transparent protection board
47‧‧‧封裝體 47‧‧‧Package
471‧‧‧螢光劑 471‧‧‧Fluorescent agent
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| CN201310354672.8A CN104253121A (en) | 2013-06-28 | 2013-08-14 | Omni-directional light-emitting diode device and packaging method thereof |
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| CN107507900A (en) * | 2017-10-03 | 2017-12-22 | 浙江中宙光电股份有限公司 | A kind of LED lamp bead of injection molding packaging and preparation method thereof |
| CN107863002A (en) * | 2017-12-13 | 2018-03-30 | 武汉华星光电半导体显示技术有限公司 | Flexible display and preparation method thereof, display device |
| CN111816745A (en) * | 2020-07-27 | 2020-10-23 | 江西新正耀光学研究院有限公司 | Structure and manufacturing method of ultraviolet light emitting diode element |
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