TWI432894B - 間隔物形成用感放射線性樹脂組成物、間隔物、間隔物的形成方法及液晶顯示元件 - Google Patents
間隔物形成用感放射線性樹脂組成物、間隔物、間隔物的形成方法及液晶顯示元件 Download PDFInfo
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- TWI432894B TWI432894B TW97143985A TW97143985A TWI432894B TW I432894 B TWI432894 B TW I432894B TW 97143985 A TW97143985 A TW 97143985A TW 97143985 A TW97143985 A TW 97143985A TW I432894 B TWI432894 B TW I432894B
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- VSMKVYMEPNUODT-UHFFFAOYSA-N benzenecarboximidamide;benzoic acid Chemical compound NC(=[NH2+])C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 VSMKVYMEPNUODT-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
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- 238000004132 cross linking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940113088 dimethylacetamide Drugs 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
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- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- OYOOQSUZHNTBOR-UHFFFAOYSA-N ethyl 4-[2-(2,4-dichlorophenyl)-2-[2-(2,4-dichlorophenyl)-4,5-bis(4-ethoxycarbonylphenyl)imidazol-2-yl]-5-(4-ethoxycarbonylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OCC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OCC)C=2C=CC(=CC=2)C(=O)OCC)C=2C(=CC(Cl)=CC=2)Cl)(C=2C(=CC(Cl)=CC=2)Cl)N=C1C1=CC=C(C(=O)OCC)C=C1 OYOOQSUZHNTBOR-UHFFFAOYSA-N 0.000 description 1
- RUBLKNMXKTZIJC-UHFFFAOYSA-N ethyl 4-[2-(2-chlorophenyl)-2-[2-(2-chlorophenyl)-4,5-bis(4-ethoxycarbonylphenyl)imidazol-2-yl]-5-(4-ethoxycarbonylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OCC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OCC)C=2C=CC(=CC=2)C(=O)OCC)C=2C(=CC=CC=2)Cl)(C=2C(=CC=CC=2)Cl)N=C1C1=CC=C(C(=O)OCC)C=C1 RUBLKNMXKTZIJC-UHFFFAOYSA-N 0.000 description 1
- QFIGRVQAPIHBKZ-UHFFFAOYSA-N ethyl 4-[2-(2-cyanophenyl)-2-[2-(2-cyanophenyl)-4,5-bis(4-ethoxycarbonylphenyl)imidazol-2-yl]-5-(4-ethoxycarbonylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OCC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OCC)C=2C=CC(=CC=2)C(=O)OCC)C=2C(=CC=CC=2)C#N)(C=2C(=CC=CC=2)C#N)N=C1C1=CC=C(C(=O)OCC)C=C1 QFIGRVQAPIHBKZ-UHFFFAOYSA-N 0.000 description 1
- LVUYILZRQXJFAO-UHFFFAOYSA-N ethyl 4-[2-[4,5-bis(4-ethoxycarbonylphenyl)-2-(2,4,6-trichlorophenyl)imidazol-2-yl]-5-(4-ethoxycarbonylphenyl)-2-(2,4,6-trichlorophenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OCC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OCC)C=2C=CC(=CC=2)C(=O)OCC)C=2C(=CC(Cl)=CC=2Cl)Cl)(C=2C(=CC(Cl)=CC=2Cl)Cl)N=C1C1=CC=C(C(=O)OCC)C=C1 LVUYILZRQXJFAO-UHFFFAOYSA-N 0.000 description 1
- LBGPFUQYTWXMCD-UHFFFAOYSA-N ethyl 4-[2-[4,5-bis(4-ethoxycarbonylphenyl)-2-(2-ethylphenyl)imidazol-2-yl]-5-(4-ethoxycarbonylphenyl)-2-(2-ethylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OCC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OCC)C=2C=CC(=CC=2)C(=O)OCC)C=2C(=CC=CC=2)CC)(C=2C(=CC=CC=2)CC)N=C1C1=CC=C(C(=O)OCC)C=C1 LBGPFUQYTWXMCD-UHFFFAOYSA-N 0.000 description 1
- FOGQWALXMBGLOR-UHFFFAOYSA-N ethyl 4-[2-[4,5-bis(4-ethoxycarbonylphenyl)-2-(2-methylphenyl)imidazol-2-yl]-5-(4-ethoxycarbonylphenyl)-2-(2-methylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OCC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OCC)C=2C=CC(=CC=2)C(=O)OCC)C=2C(=CC=CC=2)C)(C=2C(=CC=CC=2)C)N=C1C1=CC=C(C(=O)OCC)C=C1 FOGQWALXMBGLOR-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
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- 239000000945 filler Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
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- 238000007756 gravure coating Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
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- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 description 1
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- 208000013469 light sensitivity Diseases 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
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- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
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- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- MDYBVSPVYNBZEY-UHFFFAOYSA-N methyl 4-[2-[4,5-bis(4-methoxycarbonylphenyl)-2-(2-methylphenyl)imidazol-2-yl]-5-(4-methoxycarbonylphenyl)-2-(2-methylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OC)C=2C=CC(=CC=2)C(=O)OC)C=2C(=CC=CC=2)C)(C=2C(=CC=CC=2)C)N=C1C1=CC=C(C(=O)OC)C=C1 MDYBVSPVYNBZEY-UHFFFAOYSA-N 0.000 description 1
- CXKMRVPMSQOROU-UHFFFAOYSA-N methyl 4-[2-[4,5-bis(4-methoxycarbonylphenyl)-2-(2-phenylphenyl)imidazol-2-yl]-5-(4-methoxycarbonylphenyl)-2-(2-phenylphenyl)imidazol-4-yl]benzoate Chemical compound C1=CC(C(=O)OC)=CC=C1C1=NC(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OC)C=2C=CC(=CC=2)C(=O)OC)C=2C(=CC=CC=2)C=2C=CC=CC=2)(C=2C(=CC=CC=2)C=2C=CC=CC=2)N=C1C1=CC=C(C(=O)OC)C=C1 CXKMRVPMSQOROU-UHFFFAOYSA-N 0.000 description 1
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- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- BMALCVKJDZHEKP-UHFFFAOYSA-N phenyl 4-[2-(2-cyanophenyl)-2-[2-(2-cyanophenyl)-4,5-bis(4-phenoxycarbonylphenyl)imidazol-2-yl]-5-(4-phenoxycarbonylphenyl)imidazol-4-yl]benzoate Chemical compound C=1C=C(C=2C(=NC(N=2)(C=2C(=CC=CC=2)C#N)C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C(=CC=CC=2)C#N)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 BMALCVKJDZHEKP-UHFFFAOYSA-N 0.000 description 1
- FTOXNEGCZBRBFI-UHFFFAOYSA-N phenyl 4-[2-(2-methylphenyl)-2-[2-(2-methylphenyl)-4,5-bis(4-phenoxycarbonylphenyl)imidazol-2-yl]-5-(4-phenoxycarbonylphenyl)imidazol-4-yl]benzoate Chemical compound CC1=CC=CC=C1C1(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C(=CC=CC=2)C)N=C(C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C(C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)=N1 FTOXNEGCZBRBFI-UHFFFAOYSA-N 0.000 description 1
- MBXBHMNMVMTHSL-UHFFFAOYSA-N phenyl 4-[2-[4,5-bis(4-phenoxycarbonylphenyl)-2-(2,4,6-trichlorophenyl)imidazol-2-yl]-5-(4-phenoxycarbonylphenyl)-2-(2,4,6-trichlorophenyl)imidazol-4-yl]benzoate Chemical compound ClC1=CC(Cl)=CC(Cl)=C1C1(C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C(=CC(Cl)=CC=2Cl)Cl)N=C(C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C(C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)=N1 MBXBHMNMVMTHSL-UHFFFAOYSA-N 0.000 description 1
- LWRAOCDRKBYALH-UHFFFAOYSA-N phenyl 4-[2-[4,5-bis(4-phenoxycarbonylphenyl)-2-(2-phenylphenyl)imidazol-2-yl]-5-(4-phenoxycarbonylphenyl)-2-(2-phenylphenyl)imidazol-4-yl]benzoate Chemical compound C=1C=C(C=2C(=NC(N=2)(C=2C(=CC=CC=2)C=2C=CC=CC=2)C2(N=C(C(=N2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=2C(=CC=CC=2)C=2C=CC=CC=2)C=2C=CC(=CC=2)C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 LWRAOCDRKBYALH-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
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- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
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- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical group CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
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- 235000010199 sorbic acid Nutrition 0.000 description 1
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- 230000003595 spectral effect Effects 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/12—Polymers provided for in subclasses C08C or C08F
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1339—Gaskets; Spacers; Sealing of cells
- G02F1/13394—Gaskets; Spacers; Sealing of cells spacers regularly patterned on the cell subtrate, e.g. walls, pillars
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
- G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
- G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/02—Materials and properties organic material
- G02F2202/022—Materials and properties organic material polymeric
- G02F2202/023—Materials and properties organic material polymeric curable
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
- G03F7/0388—Macromolecular compounds which are rendered insoluble or differentially wettable with ethylenic or acetylenic bands in the side chains of the photopolymer
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/40—Treatment after imagewise removal, e.g. baking
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Nonlinear Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Optics & Photonics (AREA)
- Mathematical Physics (AREA)
- Liquid Crystal (AREA)
- Materials For Photolithography (AREA)
- Polymerisation Methods In General (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007298177 | 2007-11-16 | ||
| JP2008113856 | 2008-04-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200931177A TW200931177A (en) | 2009-07-16 |
| TWI432894B true TWI432894B (zh) | 2014-04-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW97143985A TWI432894B (zh) | 2007-11-16 | 2008-11-14 | 間隔物形成用感放射線性樹脂組成物、間隔物、間隔物的形成方法及液晶顯示元件 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5178737B2 (ja) |
| CN (1) | CN101855597B (ja) |
| TW (1) | TWI432894B (ja) |
| WO (1) | WO2009063955A1 (ja) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5552266B2 (ja) * | 2009-06-24 | 2014-07-16 | 昭和電工株式会社 | 水系媒体に分散した光硬化性樹脂組成物の製造方法 |
| KR20130047656A (ko) * | 2011-10-31 | 2013-05-08 | 히타치가세이가부시끼가이샤 | 감광성 수지 조성물, 감광성 엘리먼트, 레지스트 패턴의 형성 방법 및 인쇄 배선판의 제조 방법 |
| JP6229256B2 (ja) * | 2011-10-31 | 2017-11-15 | 日立化成株式会社 | 感光性エレメント、レジストパターンの形成方法及びプリント配線板の製造方法 |
| JP2014081456A (ja) * | 2012-10-16 | 2014-05-08 | Sanyo Chem Ind Ltd | 感光性樹脂組成物、硬化物およびスペーサー |
| KR20170028016A (ko) * | 2015-09-03 | 2017-03-13 | 동우 화인켐 주식회사 | 네가티브형 감광성 수지 조성물 및 이로부터 형성된 광경화성 패턴 |
| DE102015119939A1 (de) | 2015-11-18 | 2017-05-18 | ALTANA Aktiengesellschaft | Vernetzbare polymere Materialien für dielektrische Schichten in elektronischen Bauteilen |
| KR20220110775A (ko) * | 2019-12-02 | 2022-08-09 | 에네오스 가부시키가이샤 | 지환식 아크릴레이트 화합물, 지환식 에폭시 아크릴레이트 화합물, 경화성 조성물 및 경화물 |
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| JP5140903B2 (ja) * | 2004-07-02 | 2013-02-13 | 三菱化学株式会社 | 着色樹脂組成物、カラーフィルタ及び液晶表示装置 |
| JP4706847B2 (ja) * | 2005-03-02 | 2011-06-22 | Jsr株式会社 | 感放射線性樹脂組成物および液晶表示素子用スペーサー |
| TWI383253B (zh) * | 2005-03-02 | 2013-01-21 | Jsr Corp | Sensitive linear resin composition and spacers for liquid crystal display elements |
| JP2007148366A (ja) * | 2005-10-25 | 2007-06-14 | Hitachi Chem Co Ltd | 液晶スペーサー及びその製造方法 |
| JP2007199685A (ja) * | 2005-12-28 | 2007-08-09 | Fujifilm Electronic Materials Co Ltd | 光硬化性着色組成物及びカラーフィルタ、並びに液晶表示装置 |
| JP2007206217A (ja) * | 2006-01-31 | 2007-08-16 | Fujifilm Corp | 平版印刷版の作製方法および平版印刷版原版 |
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2008
- 2008-11-13 CN CN200880115544.5A patent/CN101855597B/zh not_active Expired - Fee Related
- 2008-11-13 JP JP2009541176A patent/JP5178737B2/ja not_active Expired - Fee Related
- 2008-11-13 WO PCT/JP2008/070715 patent/WO2009063955A1/ja not_active Ceased
- 2008-11-14 TW TW97143985A patent/TWI432894B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN101855597A (zh) | 2010-10-06 |
| CN101855597B (zh) | 2012-12-12 |
| JP5178737B2 (ja) | 2013-04-10 |
| TW200931177A (en) | 2009-07-16 |
| WO2009063955A1 (ja) | 2009-05-22 |
| JPWO2009063955A1 (ja) | 2011-03-31 |
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