TWI404730B - 控制聚合物性質之方法 - Google Patents

控制聚合物性質之方法 Download PDF

Info

Publication number: TWI404730B
Authority: TW; Taiwan
Prior art keywords: ethylene; group; bis; alpha; reactor
Prior art date: 2007-02-05

Application number

TW097101373A

Other languages

English (en)

Chinese (zh)

Other versions

TW200846377A (en

Inventor

Rainer Kolb

James Mcleod Farley

John F Szul

Mark P Ossowski

Original Assignee

Univation Tech Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-02-05

Filing date

2008-01-14

Publication date

2013-08-11

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38180642&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=TWI404730(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2008-01-14 Application filed by Univation Tech Llc filed Critical Univation Tech Llc

2008-12-01 Publication of TW200846377A publication Critical patent/TW200846377A/zh

2013-08-11 Application granted granted Critical

2013-08-11 Publication of TWI404730B publication Critical patent/TWI404730B/zh

Links

238000000034 method Methods 0.000 title claims abstract description 87
229920000642 polymer Polymers 0.000 title abstract description 41
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 144
239000005977 Ethylene Substances 0.000 claims abstract description 144
239000000203 mixture Substances 0.000 claims abstract description 105
238000009826 distribution Methods 0.000 claims abstract description 98
239000004711 α-olefin Substances 0.000 claims abstract description 63
229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 49
239000001257 hydrogen Substances 0.000 claims abstract description 42
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 42
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 32
229920001577 copolymer Polymers 0.000 claims abstract description 14
239000003054 catalyst Substances 0.000 claims description 70
-1 Pentadienyl Chemical group 0.000 claims description 63
239000007789 gas Substances 0.000 claims description 60
230000008859 change Effects 0.000 claims description 34
238000002474 experimental method Methods 0.000 claims description 26
239000012190 activator Substances 0.000 claims description 19
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 11
150000002431 hydrogen Chemical class 0.000 claims description 9
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 8
229930195733 hydrocarbon Natural products 0.000 claims description 8
125000003342 alkenyl group Chemical group 0.000 claims description 7
239000003795 chemical substances by application Substances 0.000 claims description 7
150000002430 hydrocarbons Chemical class 0.000 claims description 7
230000008569 process Effects 0.000 claims description 6
239000004215 Carbon black (E152) Substances 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
125000004104 aryloxy group Chemical group 0.000 claims description 5
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 5
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 4
229910052797 bismuth Inorganic materials 0.000 claims description 4
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 4
239000012876 carrier material Substances 0.000 claims description 4
239000011541 reaction mixture Substances 0.000 claims 12
150000002923 oximes Chemical class 0.000 claims 8
NJRWUXULVYFTTP-UHFFFAOYSA-N 1,2-bis(1-propylcyclopenta-2,4-dien-1-yl)-9H-fluorene Chemical compound C(CC)C1(C=CC=C1)C1=C(C=2CC3=CC=CC=C3C=2C=C1)C1(C=CC=C1)CCC NJRWUXULVYFTTP-UHFFFAOYSA-N 0.000 claims 7
125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims 4
125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 4
ICLFRQRVYHHZAJ-UHFFFAOYSA-N 1-(1-butylcyclopenta-2,4-dien-1-yl)-2-(1-propylcyclopenta-2,4-dien-1-yl)-9H-fluorene Chemical compound C(CC)C1(C=CC=C1)C1=C(C=2CC3=CC=CC=C3C=2C=C1)C1(C=CC=C1)CCCC ICLFRQRVYHHZAJ-UHFFFAOYSA-N 0.000 claims 4
125000005248 alkyl aryloxy group Chemical group 0.000 claims 4
229910052782 aluminium Inorganic materials 0.000 claims 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 4
RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims 4
125000003709 fluoroalkyl group Chemical group 0.000 claims 4
125000004407 fluoroaryl group Chemical group 0.000 claims 4
125000005842 heteroatom Chemical group 0.000 claims 4
150000004678 hydrides Chemical class 0.000 claims 4
DSWNRHCOGVRDOE-UHFFFAOYSA-N n,n-dimethylmethanimidamide Chemical compound CN(C)C=N DSWNRHCOGVRDOE-UHFFFAOYSA-N 0.000 claims 4
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 4
NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims 4
QKNWSIXRZXOFLH-UHFFFAOYSA-N 1,2-bis(1-butylcyclopenta-2,4-dien-1-yl)-9H-fluorene Chemical compound C(CCC)C1(C=CC=C1)C1=C(C=2CC3=CC=CC=C3C=2C=C1)C1(C=CC=C1)CCCC QKNWSIXRZXOFLH-UHFFFAOYSA-N 0.000 claims 3
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
125000002877 alkyl aryl group Chemical group 0.000 claims 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 claims 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
229910052787 antimony Inorganic materials 0.000 claims 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
150000004820 halides Chemical class 0.000 claims 1
239000001282 iso-butane Substances 0.000 claims 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
229910052758 niobium Inorganic materials 0.000 claims 1
239000010955 niobium Substances 0.000 claims 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
239000001294 propane Substances 0.000 claims 1
229920000098 polyolefin Polymers 0.000 abstract description 19
239000000155 melt Substances 0.000 abstract description 8
239000004698 Polyethylene Substances 0.000 description 32
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238000006116 polymerization reaction Methods 0.000 description 20
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 18
239000012530 fluid Substances 0.000 description 14
RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 13
239000000463 material Substances 0.000 description 11
239000002245 particle Substances 0.000 description 11
239000003446 ligand Substances 0.000 description 10
238000002425 crystallisation Methods 0.000 description 8
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IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 6
125000005843 halogen group Chemical group 0.000 description 6
238000002347 injection Methods 0.000 description 6
239000007924 injection Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
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230000000694 effects Effects 0.000 description 5
238000012685 gas phase polymerization Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
125000000008 (C1-C10) alkyl group Chemical group 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
229910052804 chromium Inorganic materials 0.000 description 4
239000011651 chromium Substances 0.000 description 4
KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 4
239000012968 metallocene catalyst Substances 0.000 description 4
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 3
238000001816 cooling Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
238000010828 elution Methods 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
230000020169 heat generation Effects 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
230000009467 reduction Effects 0.000 description 3
OSAWXRXVDGWGCJ-UHFFFAOYSA-N 1,2-di(cyclopenta-2,4-dien-1-yl)-9H-fluorene Chemical compound C1(C=CC=C1)C1=C(C=2CC3=CC=CC=C3C=2C=C1)C1C=CC=C1 OSAWXRXVDGWGCJ-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
125000000882 C2-C6 alkenyl group Chemical group 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
YJXRFIQAINUQRQ-UHFFFAOYSA-N [Cl-].[Cl-].C(CC)C1(C=CC=C1)[PH2+]C1(C=CC=C1)CCC.C(CC)C1(C=CC=C1)[PH2+]C1(C=CC=C1)CCC Chemical compound [Cl-].[Cl-].C(CC)C1(C=CC=C1)[PH2+]C1(C=CC=C1)CCC.C(CC)C1(C=CC=C1)[PH2+]C1(C=CC=C1)CCC YJXRFIQAINUQRQ-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
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125000000217 alkyl group Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000004891 communication Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
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125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 2
238000005194 fractionation Methods 0.000 description 2
150000002367 halogens Chemical group 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
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239000003381 stabilizer Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
238000012546 transfer Methods 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
XZOUEIOSOFDNLP-UHFFFAOYSA-N 1,2-bis(1H-inden-1-yl)hydrazine Chemical class C1(C=CC2=CC=CC=C12)NNC1C=CC2=CC=CC=C12 XZOUEIOSOFDNLP-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
YQDSWSPIWVQKBC-UHFFFAOYSA-N 1h-cyclopenta[l]phenanthrene Chemical compound C12=CC=CC=C2C2=CC=CC=C2C2=C1CC=C2 YQDSWSPIWVQKBC-UHFFFAOYSA-N 0.000 description 1
KWQMJXZUGBNSOY-UHFFFAOYSA-N 1h-thieno[2,3-g]indole Chemical compound C1=C2SC=CC2=C2NC=CC2=C1 KWQMJXZUGBNSOY-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
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PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
125000005161 aryl oxy carbonyl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000001354 calcination Methods 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
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125000001309 chloro group Chemical group Cl* 0.000 description 1
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ZMMRKRFMSDTOLV-UHFFFAOYSA-N cyclopenta-1,3-diene zirconium Chemical compound [Zr].C1C=CC=C1.C1C=CC=C1 ZMMRKRFMSDTOLV-UHFFFAOYSA-N 0.000 description 1
125000004663 dialkyl amino group Chemical group 0.000 description 1
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229910052809 inorganic oxide Inorganic materials 0.000 description 1
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150000007517 lewis acids Chemical class 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
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239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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238000013508 migration Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
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229910052901 montmorillonite Inorganic materials 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
238000001637 plasma atomic emission spectroscopy Methods 0.000 description 1
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239000002685 polymerization catalyst Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000004044 response Effects 0.000 description 1
238000005070 sampling Methods 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
125000003396 thiol group Chemical group [H]S* 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
239000010455 vermiculite Substances 0.000 description 1
229910052902 vermiculite Inorganic materials 0.000 description 1
235000019354 vermiculite Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
238000004876 x-ray fluorescence Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerisation Methods In General (AREA)

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JP (1)	JP5441717B2 (es)
KR (1)	KR101553413B1 (es)
CN (1)	CN101605822B (es)
AR (1)	AR065030A1 (es)
AU (1)	AU2008214434B2 (es)
BR (1)	BRPI0807837B1 (es)
CA (1)	CA2675112C (es)
CL (1)	CL2008000345A1 (es)
MX (1)	MX2009008330A (es)
MY (1)	MY153215A (es)
RU (1)	RU2447089C2 (es)
TW (1)	TWI404730B (es)
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2008
- 2008-01-14 TW TW097101373A patent/TWI404730B/zh not_active IP Right Cessation
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- 2008-01-18 CN CN200880004155.5A patent/CN101605822B/zh active Active
- 2008-01-18 RU RU2009133212/04A patent/RU2447089C2/ru active
- 2008-01-18 KR KR1020097018496A patent/KR101553413B1/ko active Active
- 2008-01-18 CA CA2675112A patent/CA2675112C/en active Active
- 2008-01-18 EP EP08724657.5A patent/EP2109629B2/en active Active
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- 2008-01-25 AR ARP080100307A patent/AR065030A1/es unknown
- 2008-02-04 CL CL200800345A patent/CL2008000345A1/es unknown
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JP2010518225A (ja)	2010-05-27
EP2109629A4 (en)	2009-11-25
EP2109629A2 (en)	2009-10-21
BRPI0807837B1 (pt)	2019-09-03
KR101553413B1 (ko)	2015-09-15
CA2675112A1 (en)	2008-08-14
US20100144989A1 (en)	2010-06-10
TW200846377A (en)	2008-12-01
MY153215A (en)	2015-01-29
US8497329B2 (en)	2013-07-30
WO2008097422A3 (en)	2008-09-25
BRPI0807837A2 (pt)	2014-08-05
RU2447089C2 (ru)	2012-04-10
WO2008097422A2 (en)	2008-08-14
AU2008214434A1 (en)	2008-08-14
CA2675112C (en)	2016-02-16
CN101605822B (zh)	2014-10-29
US8227552B2 (en)	2012-07-24
EP2109629B2 (en)	2019-11-13
AR065030A1 (es)	2009-05-13
US20120041164A1 (en)	2012-02-16
CN101605822A (zh)	2009-12-16
RU2009133212A (ru)	2011-03-20
JP5441717B2 (ja)	2014-03-12
AU2008214434B2 (en)	2013-01-24
CL2008000345A1 (es)	2008-09-05
EP2109629B1 (en)	2015-02-25
MX2009008330A (es)	2009-10-07
KR20090117784A (ko)	2009-11-12

Publication	Publication Date	Title
TWI404730B (zh)	2013-08-11	控制聚合物性質之方法
KR101272391B1 (ko)	2013-06-07	저밀도, 중밀도 및 고밀도 폴리에틸렌용 단일 촉매
TWI575009B (zh)	2017-03-21	聚乙烯組成物、生產其之方法、由其所製造之物體以及其製造方法
EP2797967B1 (en)	2019-01-23	Catalyst composition and method for preparing the same
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EP2032617B1 (en)	2011-03-09	Ethylene-alpha olefin copolymer's and polymerization processes for making the same
CA2951113C (en)	2023-09-19	Polyethylene resins
CA2628547A1 (en)	2007-06-14	High density polyethylene
TW201206968A (en)	2012-02-16	Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers
CN107206655B (zh)	2019-09-06	用于控制聚合物链断裂的方法
TW201718664A (zh)	2017-06-01	用於流體化床反應器中的聚合方法
EP4359450A1 (en)	2024-05-01	Improving catalyst performance in multi-stage polyolefin production
CN118900855A (zh)	2024-11-05	聚烯烃和包含聚烯烃的膜

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