TWI384066B - Resin removal agent - Google Patents
Resin removal agent Download PDFInfo
- Publication number
- TWI384066B TWI384066B TW095101608A TW95101608A TWI384066B TW I384066 B TWI384066 B TW I384066B TW 095101608 A TW095101608 A TW 095101608A TW 95101608 A TW95101608 A TW 95101608A TW I384066 B TWI384066 B TW I384066B
- Authority
- TW
- Taiwan
- Prior art keywords
- group
- methyl
- solvent
- mass
- acetate
- Prior art date
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- 239000011347 resin Substances 0.000 title claims description 17
- 229920005989 resin Polymers 0.000 title claims description 17
- 239000011342 resin composition Substances 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 17
- 239000003960 organic solvent Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000004593 Epoxy Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 6
- 150000002576 ketones Chemical class 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- -1 nitrogen-containing compound Chemical class 0.000 description 42
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 125000000753 cycloalkyl group Chemical group 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 150000001925 cycloalkenes Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920002120 photoresistant polymer Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- OHBRHBQMHLEELN-UHFFFAOYSA-N acetic acid;1-butoxybutane Chemical compound CC(O)=O.CCCCOCCCC OHBRHBQMHLEELN-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 150000007514 bases Chemical class 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- HZYHBQLFAGLGQU-UHFFFAOYSA-N 1-butan-2-yloxypropan-2-yl acetate Chemical compound CCC(C)OCC(C)OC(C)=O HZYHBQLFAGLGQU-UHFFFAOYSA-N 0.000 description 2
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 2
- FZXRXKLUIMKDEL-UHFFFAOYSA-N 2-Methylpropyl propanoate Chemical compound CCC(=O)OCC(C)C FZXRXKLUIMKDEL-UHFFFAOYSA-N 0.000 description 2
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- XAOGXQMKWQFZEM-UHFFFAOYSA-N isoamyl propanoate Chemical compound CCC(=O)OCCC(C)C XAOGXQMKWQFZEM-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- WSGCRAOTEDLMFQ-UHFFFAOYSA-N nonan-5-one Chemical compound CCCCC(=O)CCCC WSGCRAOTEDLMFQ-UHFFFAOYSA-N 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- VPBZZPOGZPKYKX-UHFFFAOYSA-N 1,2-diethoxypropane Chemical compound CCOCC(C)OCC VPBZZPOGZPKYKX-UHFFFAOYSA-N 0.000 description 1
- ILNDSSCEZZFNGE-UHFFFAOYSA-N 1,3-Di-tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1 ILNDSSCEZZFNGE-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- YCTFNXBMRXMVAM-UHFFFAOYSA-N 1-(2-methylpropoxy)butyl acetate Chemical compound C(C)(=O)OC(CCC)OCC(C)C YCTFNXBMRXMVAM-UHFFFAOYSA-N 0.000 description 1
- PQSCDZCQPMZHQH-UHFFFAOYSA-N 1-(2-methylpropoxy)propan-2-yl acetate Chemical compound CC(C)COCC(C)OC(C)=O PQSCDZCQPMZHQH-UHFFFAOYSA-N 0.000 description 1
- UAIJLTSVXNMMEG-UHFFFAOYSA-N 1-butoxybutyl acetate Chemical compound CCCCOC(CCC)OC(C)=O UAIJLTSVXNMMEG-UHFFFAOYSA-N 0.000 description 1
- FUWDFGKRNIDKAE-UHFFFAOYSA-N 1-butoxypropan-2-yl acetate Chemical compound CCCCOCC(C)OC(C)=O FUWDFGKRNIDKAE-UHFFFAOYSA-N 0.000 description 1
- QPGRPTCYNLFHGR-UHFFFAOYSA-N 1-butylcyclohexa-3,5-diene-1,3-diol Chemical compound CCCCC1(O)CC(O)=CC=C1 QPGRPTCYNLFHGR-UHFFFAOYSA-N 0.000 description 1
- MRVNKFHOCJWEBM-UHFFFAOYSA-N 1-ethylcyclohexa-3,5-diene-1,3-diol Chemical compound CCC1(O)CC(O)=CC=C1 MRVNKFHOCJWEBM-UHFFFAOYSA-N 0.000 description 1
- ZPJLZRZWCSAVSJ-UHFFFAOYSA-N 1-methoxybutyl acetate Chemical compound CCCC(OC)OC(C)=O ZPJLZRZWCSAVSJ-UHFFFAOYSA-N 0.000 description 1
- YKPXTMAQTAVHDA-UHFFFAOYSA-N 1-methylcyclohexa-3,5-diene-1,3-diol Chemical compound CC1(O)CC(O)=CC=C1 YKPXTMAQTAVHDA-UHFFFAOYSA-N 0.000 description 1
- CJEYCKQTMDFTAF-UHFFFAOYSA-N 1-phenylcyclohexa-3,5-diene-1,3-diol Chemical compound C1C(O)=CC=CC1(O)C1=CC=CC=C1 CJEYCKQTMDFTAF-UHFFFAOYSA-N 0.000 description 1
- GBYXGVAFELOPLN-UHFFFAOYSA-N 1-propan-2-yloxybutyl acetate Chemical compound CCCC(OC(C)C)OC(C)=O GBYXGVAFELOPLN-UHFFFAOYSA-N 0.000 description 1
- DMFAHCVITRDZQB-UHFFFAOYSA-N 1-propoxypropan-2-yl acetate Chemical compound CCCOCC(C)OC(C)=O DMFAHCVITRDZQB-UHFFFAOYSA-N 0.000 description 1
- PKIWGLCRDMDKTA-UHFFFAOYSA-N 1-tert-butylcyclohexa-3,5-diene-1,3-diol Chemical compound CC(C)(C)C1(O)CC(O)=CC=C1 PKIWGLCRDMDKTA-UHFFFAOYSA-N 0.000 description 1
- OJRJDENLRJHEJO-UHFFFAOYSA-N 2,4-diethylpentane-1,5-diol Chemical compound CCC(CO)CC(CC)CO OJRJDENLRJHEJO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ADWVSLCVBOTERL-UHFFFAOYSA-N 2-(2-methylpropoxy)ethyl acetate Chemical compound CC(C)COCCOC(C)=O ADWVSLCVBOTERL-UHFFFAOYSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- KBHVSQJJPWSZMN-UHFFFAOYSA-N 2-(3-propan-2-ylphenyl)benzene-1,3-diol Chemical compound C(C)(C)C=1C=C(C=CC=1)C1=C(O)C=CC=C1O KBHVSQJJPWSZMN-UHFFFAOYSA-N 0.000 description 1
- DEONMHMQGQVZNP-UHFFFAOYSA-N 2-(3-propan-2-ylphenyl)benzene-1,4-diol Chemical compound C(C)(C)C=1C=C(C=CC=1)C1=C(O)C=CC(=C1)O DEONMHMQGQVZNP-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- VJIDDJAKLVOBSE-UHFFFAOYSA-N 2-ethylbenzene-1,4-diol Chemical compound CCC1=CC(O)=CC=C1O VJIDDJAKLVOBSE-UHFFFAOYSA-N 0.000 description 1
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 1
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- SDQROPCSKIYYAV-UHFFFAOYSA-N 2-methyloctane-1,8-diol Chemical compound OCC(C)CCCCCCO SDQROPCSKIYYAV-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- HCDJVEYJSSTYSW-UHFFFAOYSA-N 2-propan-2-yloxyethyl acetate Chemical compound CC(C)OCCOC(C)=O HCDJVEYJSSTYSW-UHFFFAOYSA-N 0.000 description 1
- QMAQLCVJIYANPZ-UHFFFAOYSA-N 2-propoxyethyl acetate Chemical compound CCCOCCOC(C)=O QMAQLCVJIYANPZ-UHFFFAOYSA-N 0.000 description 1
- NJRNUAVVFBHIPT-UHFFFAOYSA-N 2-propylbenzene-1,4-diol Chemical compound CCCC1=CC(O)=CC=C1O NJRNUAVVFBHIPT-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- RBQLGIKHSXQZTB-UHFFFAOYSA-N 3-methylpentane-2,4-diol Chemical compound CC(O)C(C)C(C)O RBQLGIKHSXQZTB-UHFFFAOYSA-N 0.000 description 1
- GBSGXZBOFKJGMG-UHFFFAOYSA-N 3-propan-2-yloxypropan-1-ol Chemical compound CC(C)OCCCO GBSGXZBOFKJGMG-UHFFFAOYSA-N 0.000 description 1
- ZGZVGZCIFZBNCN-UHFFFAOYSA-N 4,4'-(2-Methylpropylidene)bisphenol Chemical compound C=1C=C(O)C=CC=1C(C(C)C)C1=CC=C(O)C=C1 ZGZVGZCIFZBNCN-UHFFFAOYSA-N 0.000 description 1
- GXDIDDARPBFKNG-UHFFFAOYSA-N 4,4'-(Butane-1,1-diyl)diphenol Chemical compound C=1C=C(O)C=CC=1C(CCC)C1=CC=C(O)C=C1 GXDIDDARPBFKNG-UHFFFAOYSA-N 0.000 description 1
- OVVCSFQRAXVPGT-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)cyclopentyl]phenol Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCC1 OVVCSFQRAXVPGT-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- CLMNUWIUDGZFCN-UHFFFAOYSA-N 4-[2-(4-hydroxyphenoxy)ethoxy]phenol Chemical compound C1=CC(O)=CC=C1OCCOC1=CC=C(O)C=C1 CLMNUWIUDGZFCN-UHFFFAOYSA-N 0.000 description 1
- BGKMFFFXZCKKGJ-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)propyl]phenol Chemical compound C1=CC(O)=CC=C1CCCC1=CC=C(O)C=C1 BGKMFFFXZCKKGJ-UHFFFAOYSA-N 0.000 description 1
- OAHMVZYHIJQTQC-UHFFFAOYSA-N 4-cyclohexylphenol Chemical compound C1=CC(O)=CC=C1C1CCCCC1 OAHMVZYHIJQTQC-UHFFFAOYSA-N 0.000 description 1
- 125000004861 4-isopropyl phenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- XUPXMIAWKPTZLZ-UHFFFAOYSA-N 4-methylhexan-2-one Chemical compound CCC(C)CC(C)=O XUPXMIAWKPTZLZ-UHFFFAOYSA-N 0.000 description 1
- CYYZDBDROVLTJU-UHFFFAOYSA-N 4-n-Butylphenol Chemical compound CCCCC1=CC=C(O)C=C1 CYYZDBDROVLTJU-UHFFFAOYSA-N 0.000 description 1
- JVERADGGGBYHNP-UHFFFAOYSA-N 5-phenylbenzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(=O)O)=CC(C=2C=CC=CC=2)=C1C(O)=O JVERADGGGBYHNP-UHFFFAOYSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IJMWOMHMDSDKGK-UHFFFAOYSA-N Isopropyl propionate Chemical compound CCC(=O)OC(C)C IJMWOMHMDSDKGK-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical group CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 1
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004450 alkenylene group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 125000004419 alkynylene group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000000490 cinnamyl group Chemical group C(C=CC1=CC=CC=C1)* 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- CGZZMOTZOONQIA-UHFFFAOYSA-N cycloheptanone Chemical compound O=C1CCCCCC1 CGZZMOTZOONQIA-UHFFFAOYSA-N 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000000422 delta-lactone group Chemical group 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical group C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- UHKJHMOIRYZSTH-UHFFFAOYSA-N ethyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OCC UHKJHMOIRYZSTH-UHFFFAOYSA-N 0.000 description 1
- WHRLOJCOIKOQGL-UHFFFAOYSA-N ethyl 2-methoxypropanoate Chemical compound CCOC(=O)C(C)OC WHRLOJCOIKOQGL-UHFFFAOYSA-N 0.000 description 1
- FJAKCEHATXBFJT-UHFFFAOYSA-N ethyl 2-oxobutanoate Chemical compound CCOC(=O)C(=O)CC FJAKCEHATXBFJT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 125000000457 gamma-lactone group Chemical group 0.000 description 1
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical compound OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 1
- BQWORYKVVNTRAW-UHFFFAOYSA-N heptane-3,5-diol Chemical compound CCC(O)CC(O)CC BQWORYKVVNTRAW-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- YVWPDYFVVMNWDT-UHFFFAOYSA-N methyl 2-ethoxypropanoate Chemical compound CCOC(C)C(=O)OC YVWPDYFVVMNWDT-UHFFFAOYSA-N 0.000 description 1
- XPIWVCAMONZQCP-UHFFFAOYSA-N methyl 2-oxobutanoate Chemical compound CCC(=O)C(=O)OC XPIWVCAMONZQCP-UHFFFAOYSA-N 0.000 description 1
- BDJSOPWXYLFTNW-UHFFFAOYSA-N methyl 3-methoxypropanoate Chemical compound COCCC(=O)OC BDJSOPWXYLFTNW-UHFFFAOYSA-N 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- PBKYSIMDORTIEU-UHFFFAOYSA-N pentan-3-yl acetate Chemical compound CCC(CC)OC(C)=O PBKYSIMDORTIEU-UHFFFAOYSA-N 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- GTCCGKPBSJZVRZ-UHFFFAOYSA-N pentane-2,4-diol Chemical compound CC(O)CC(C)O GTCCGKPBSJZVRZ-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- TWSRVQVEYJNFKQ-UHFFFAOYSA-N pentyl propanoate Chemical compound CCCCCOC(=O)CC TWSRVQVEYJNFKQ-UHFFFAOYSA-N 0.000 description 1
- DYUMLJSJISTVPV-UHFFFAOYSA-N phenyl propanoate Chemical compound CCC(=O)OC1=CC=CC=C1 DYUMLJSJISTVPV-UHFFFAOYSA-N 0.000 description 1
- 229940049953 phenylacetate Drugs 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229940095574 propionic acid Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- GQKZRWSUJHVIPE-UHFFFAOYSA-N sec-amyl acetate Natural products CCCC(C)OC(C)=O GQKZRWSUJHVIPE-UHFFFAOYSA-N 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- MCZDHTKJGDCTAE-UHFFFAOYSA-M tetrabutylazanium;acetate Chemical compound CC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC MCZDHTKJGDCTAE-UHFFFAOYSA-M 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Paints Or Removers (AREA)
- Cleaning Or Drying Semiconductors (AREA)
Description
本發明係關於一種含有特定之環氧化合物而成、且用於自固體表面除去或清洗去樹脂或樹脂組合物之除去劑。
於樹脂或樹脂組合物之製造、使用中，為除去附著於容器、裝置、配管、製品等上之樹脂，而使用以有機溶劑為主體之清洗劑。例如於專利文獻1中，報告有含有γ－丁內酯而成之清洗劑，於專利文獻2中，報告有含有酮系溶劑及/或酯系溶劑與醚系溶劑之混合物之清洗劑，於專利文獻3中，報告有含有含氮化合物而成之清洗劑。
又，於印刷配線基板、IC等之電子電路配線、顯示元件用彩色濾光器、CCD用彩色濾光器等之圖案化中，使用有正性或負性抗蝕劑。作為用於除去使用於該等之硬化或未硬化之抗蝕劑組合物的有機系除去劑(顯像液、剝離液)，使用有醇系、醚系、酯系溶劑。
上述有機溶劑系之清洗劑或除去劑，存有因殘留液體揮發而樹脂殘渣附著於固體表面之問題點。又，使用含氮化合物等之鹼性化合物之清洗劑或除去劑，於已除去樹脂之固體表面上殘存樹脂之分解物或鹼性化合物，故而於除去樹脂後之固體表面上使用時，有時可帶來不良影響。
專利文獻1：日本專利特開平8－117707號公報專利文獻2：日本專利特開平8－165496號公報專利文獻3：日本專利特開2001－518552號公報
故而，本發明之目的在於提供一種除去劑，其係用於自固體表面除去或清洗去樹脂或樹脂組合物者，其除去效果較佳，且並未影響及除去樹脂或樹脂組合物後之固體表面之使用。
本發明者等經過反覆研究，結果發現特定之環氧化合物可用於除去樹脂成分。
本發明係基於上述發現而完成者，其係提供一種除去劑，其特徵為其係用於自固體表面除去或清洗去樹脂或樹脂組合物，且係使於100質量份之一種以上有機溶劑中含有1~100質量份之如下述通式(I)所示之環氧化合物而成者。
於上述通式(1)中，至於以R所表示之碳數1~18之烴基，於p為0之情形時，可列舉有：於鏈中亦可具有苯環、環烷烴環、環烯烴環等烴環之烷基；直鏈中亦可具有支鏈，且鏈中亦可具有苯環、環烷烴環、環烯烴環等烴環之烯基；直鏈中亦可具有支鏈，且鏈中可具有苯環、環烷烴環、環烯烴環等烴環之炔基；環烷基及芳基等，於該等之中，考慮到環氧化合物廉價，且化學性穩定之方面，較好的是烷基、芳基。
又，至於以R表示之碳數1~18之烴基，於p為1之情形時，可列舉有：直鏈中亦可具有支鏈，且鏈中亦可具有苯環、環烷烴環、環烯烴環等烴環之伸烷基；直鏈中亦可具有支鏈，且鏈中亦可具有苯環、環烷烴環、環烯烴環等烴環之亞烯基；直鏈中亦可具有支鏈，且鏈中亦可具有苯環、環烷烴環、環烯烴環等烴環之亞炔基，亞環烷基及伸芳基等，於該等之中，考慮到環氧化合物廉價，且化學性穩定之方面，較好的是伸烷基、伸芳基。
至於p為0時作為R之較好之基即上述烷基，可列舉有：甲基、乙基、丙基、異丙基、丁基、第二丁基、第三丁基、異丁基、戊基、異戊基、第三戊基、己基、2－己基、3－己基、環己基、1－甲基環己基、庚基、2－庚基、3－庚基、異庚基、第三庚基、正辛基、異辛基、第三辛基、2－乙基己基、壬基、異壬基、癸基、十二烷基、十三烷基、十四烷基、十五烷基、十六烷基、十七烷基、十八烷基、苯甲基、苯乙基、2－苯基丙烷－2－基、二苯甲基、苯乙烯基、肉桂基等。
又，與上述烷基相同，至於p為0之情形時作為R之較好之基即上述芳基，可列舉有：苯基、萘基、2－甲基苯基、3－甲基苯基、4－甲基苯基、3－異丙基苯基、4－異丙基苯基、4－丁基苯基、4－異丁基苯基、4－第三丁基苯基、4－己基苯基、4－環己基苯基、4－辛基苯基、4－(2－乙基己基)苯基、2,3－二甲基苯基、2,4－二甲基苯基、2,5－二甲基苯基、2,6－二甲基苯基、3,4－二甲基苯基、3,5－二甲基苯基、2,4－二第三丁基苯基、2,5－二第三丁基苯基、2,6－二－第三丁基苯基、2,4－二第三戊基苯基、2,5－二第三戊基苯基、環己基苯基、聯苯、2,4,5－三甲基苯基等。
p為1之情形時作為R之較好之基即上述伸烷基，可自二醇化合物中導入。至於該二醇化合物，例如可列舉有：乙二醇、1,2－丙二醇、1,3－丙二醇、2－甲基－1,3－丙二醇、2－丁基－2－乙基－1,3－丙二醇、1,4－丁二醇、新戊二醇、3－甲基－2,4－戊二醇、2,4－戊二醇、1,5－戊二醇、3－甲基－1,5－戊二醇、2－甲基－2,4－戊二醇、2,4－二乙基－1,5－戊二醇、1,6－己二醇、1,7－庚二醇、3,5－庚二醇、1,8－辛二醇、2－甲基－1,8－辛二醇、1,9－壬二醇、1,10－癸二醇等之脂肪族二醇化合物；環己烷二甲醇、環己烷二醇、氫化雙酚A等脂環式二醇化合物。於該等之中，尤其好的是自碳數2~8之二醇化合物中導入之伸烷基。
又，與上述伸烷基相同，p為1之情形時較好之基即上述伸芳基，可自二羥基芳香族化合物導入。至於該羥基芳香族化合物，例如可列舉有：間苯二酚、鄰苯二酚、對苯二酚、3－甲基間苯二酚、3－乙基間苯二酚、3－丙基間苯二酚、3－丁基間苯二酚、3－第三丁基間苯二酚、3－苯基間苯二酚、3－異丙苯基間苯二酚、3－甲基對苯二酚、3－乙基對苯二酚、3－丙基對苯二酚、3－丁基對苯二酚、3－第三丁基對苯二酚、3－苯基對苯二酚、3－異丙苯基對苯二酚、4,4'－二羥基二苯基等之二羥基芳基化合物；1,1－雙(4－羥基苯基)環戊烷、1,1－雙(4－羥基苯基)環己烷等之雙(羥基芳基)環烷類；雙(4－羥基苯基)甲烷、1,1－雙(4－羥基苯基)乙烷、1,2－雙(4－羥基苯氧基)乙烷、1,3－雙(4－羥基苯基)丙烷、2,2－雙(4－羥基苯基)丙烷、2,2－雙(4－羥基－3,5－二甲基苯基)丙烷、1,1－雙(4－羥基苯基)丁烷、1,1－雙(4－羥基苯基)異丁烷、2,2－雙(4－羥基苯基)丁烷、2,4－雙(4－羥基苯基2－甲基)丁烷等之雙(羥基芳基)烷類。
又，於上述通式(I)中，m及n各自獨立為0、1或2。作為於上述通式(I)中m及n各自獨立為0或1之環氧化合物，其流動性較大，且適宜清洗故而較好。
又，本發明之除去劑中之於上述通式(I)中所示之環氧化合物的含量，相對於有機溶劑100質量份，為1~100質量份。若小於1質量份則無法得到充分之使用效果，即使超出100質量份亦未發現使用效果之進一步提高。以上述通式(I)所表示之環氧化合物之含量，較好的是10~85質量份，更好的是20~75質量份。
至於本發明相關之以上述通式(I)所表示之環氧化合物之較好具體例，可列舉有下述所示之化合物No.1~No.45。
又，作為於本發明之除去劑中所使用之有機溶劑，並不受特別限制，可使用眾所周知之通常之有機溶劑。至於該有機溶劑，例如可列舉有：醇系溶劑、多元醇系溶劑、酮系溶劑、酯系溶劑、醚系溶劑、聚醚系溶劑、脂肪族烴系溶劑、芳香族烴系溶劑、氯系溶劑、具有氰基之烴溶劑、吡咯酮溶劑，該等可使用1種或混合2種以上使用。尤其為自可使上述通式(I)中所示之環氧化物穩定溶解，價格低廉，且對樹脂或樹脂組合物之除去效果較大方面考慮，較好的是使用碳數為3~18之酮系溶劑以及/或者碳數2~18之酯系溶劑。該酮系溶劑，較好的是有機溶劑中之50~100質量%，尤其好的是50~90質量%。該酯系溶劑，較好的是有機溶劑中之10~100質量%，尤其好的是10~50質量%。
至於於本發明之除去劑中所使用之較好之有機溶劑即碳數3~18之酮系溶劑，可列舉有：丙酮、丁酮、甲基丙基酮、甲基異丙基酮、丁基甲基酮、異丁基甲基酮、第2丁基甲基酮、第3丁基甲基酮、二乙基酮、2－庚酮、3－庚酮、二丁基酮、二異丁基酮、二第3丁基酮、環庚酮、環己酮、4－甲基己酮等。該等可單獨使用，亦可組合兩種以上使用。
又，作為用於本發明之除去劑中較好之有機溶劑之碳數2~18的酯系溶劑，可列舉有：甲酸甲酯、甲酸乙酯、乙酸甲酯、乙酸乙酯、乙酸異丙酯、乙酸丁酯、乙酸異丁酯、乙酸第2丁酯、乙酸第3丁酯、乙酸戊酯、乙酸異戊酯、乙酸第3戊酯、乙酸苯酯、丙酸甲酯、丙酸乙酯、丙酸異丙酯、丙酸丁酯、丙酸異丁酯、丙酸第2丁酯、丙酸第3丁酯、丙酸戊酯、丙酸異戊酯、丙酸第3戊酯、丙酸苯酯、乳酸甲酯、乳酸乙酯、甲氧基丙酸甲酯、乙氧基丙酸甲酯、甲氧基丙酸乙酯、乙氧基丙酸乙酯、乙二醇甲醚醋酸酯、二乙二醇甲醚醋酸酯、乙二醇乙醚醋酸酯、乙二醇丙醚醋酸酯、乙二醇異丙醚醋酸酯、乙二醇丁醚醋酸酯、乙二醇第2丁醚醋酸酯、乙二醇異丁醚醋酸酯、乙二醇第3丁醚醋酸酯、丙二醇甲醚醋酸酯、丙二醇乙醚醋酸酯、丙二醇丙醚醋酸酯、丙二醇異丙醚醋酸酯、丙二醇丁醚醋酸酯、丙二醇第2丁醚醋酸酯、丙二醇異丁醚醋酸酯、丙二醇第3丁醚醋酸酯、丁二醇甲醚醋酸酯、丁二醇乙醚醋酸酯、丁二醇丙醚醋酸酯、丁二醇異丙醚醋酸酯、丁二醇丁醚醋酸酯、丁二醇第2丁醚醋酸酯、丁二醇異丁醚醋酸酯、丁二醇第3丁醚醋酸酯、乙醯醋酸甲酯、乙醯醋酸乙酯、氧代丁酸甲酯、氧代丁酸乙酯、γ－內酯、δ－內酯等。該等可單獨使用，亦可組合兩種以上使用。
於本發明之除去劑中，除上述通式(I)所述之環氧化合物、上述有機溶劑之外，亦可根據需要使用各種添加劑。至於該添加劑，可列舉有：無機鹼化合物、有機胺、氨、四級銨鹽等之鹼性化合物；有機酸等酸性化合物；黏度調節劑；勻化劑；消泡劑；抗膠凝劑；分散穩定劑；靜電防止劑；離子性界面活性劑、非離子性界面活性劑等之界面活性劑；水等。該等添加劑之使用量，根據所使用之添加劑之種類加以適宜選擇，通常，相對於上述有機溶劑100質量份，於全部添加劑之合計量為20質量份以下之範圍內進行選擇。
至於本發明之除去劑之用途，可列舉有：於IC或印刷配線基板中作為密封劑使用之樹脂組合物之清洗，附著於金屬模具、加工機械等之塑膠加工用器材上之樹脂組合物之清洗，用於混合或製造樹脂或樹脂組合物的混合或製造裝置之清洗，光阻劑之顯像液、光阻劑之剝離液、光阻.劑裝置之清洗等。
以下，藉由實施例及比較例對本發明進行更詳細之說明。然而，本發明不受以下實施例之任何限制。
於30 mm×50 mm×1 mm之SUS304板上，浸漬塗布藉由下述製造方法製造之黑色樹脂組合物而製為檢測試片。將該檢測試片於除去劑試料(參照表1~表3)中浸漬60秒。此時，於檢驗試片浸漬過程中，以電磁攪拌器攪拌除去劑試料。取撈出檢測試片後，觀察其表面狀態。又，將附著於檢測試片表面之黑色樹脂組合物轉印至玻璃紙膠帶，以馬克貝斯濃度計(馬克貝斯公司製RD－933型)測定轉印前後之玻璃紙膠帶之OD值，算出其增量(△OD)。其等結果示於表1~3。
添加43 g 1,1－雙(4'－環氧丙氧基苯基)－1－(1'－聯苯)－1－環己甲烷，11 g丙烯酸，0.05 g 2,6－二－第三丁基對甲酚，0.11 g四丁基銨醋酸鹽及23 g丙二醇－1－甲醚－2－醋酸酯23g，於120℃下攪拌16小時。冷卻至室溫，加入35 g丙二醇－1－甲醚－2－醋酸酯及9.4 g聯苯四羰酸二酸酐，於120℃下攪拌8小時。進而加入6.0 g四氫苯二甲酸酐，分別於120℃下攪拌4小時，100℃下攪拌3小時，80℃下攪拌4小時，60℃下攪拌6小時，40℃下攪拌11小時後，加入29 g丙二醇－1－甲醚－2－醋酸酯。於12 g該組合物中加入8 g三羥甲基丙烷三丙烯酸酯，1.8 g二苯甲酮，3.2 g碳黑(三菱化學公司製「MA100」)及75 g乙基溶纖劑充分攪拌，獲得黑色樹脂組合物。
如表1~3所表明，若使用於有機溶液中含有特定之環氧化合物而成之本發明之除去劑，則固體表面得以均勻清洗，殘存於固體表面之樹脂組合物較少(實施例1~8)。與其相對，若使用未含有本發明之特定環氧化合物之除去劑，則固體表面無法得以均勻清洗且形成斑狀，殘存於固體表面之樹脂組合物亦較多(比較例1)。
藉由本發明，可提供一種除去劑，其除去效果較大，且未影響及除去樹脂或樹脂組合物後之固體表面之使用。
Claims (3)
- 一種除去劑，其係用於自固體表面除去或清洗樹脂或樹脂組合物，該除去劑係於100質量份之一種以上有機溶劑中、含有1~100質量份之以下述化學式(I)所表示之環氧化合物者：
- 如請求項1之除去劑，其中上述有機溶劑係含有50質量%以上之碳數3~18之酮系溶劑者。
- 如請求項1之除去劑，其中上述有機溶劑係含有10質量%以上之碳數2~18之酯系溶劑者。
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| JPH1036890A (ja) * | 1996-07-22 | 1998-02-10 | Asahi Chem Ind Co Ltd | インキ洗浄剤 |
| JPH1135993A (ja) * | 1997-07-23 | 1999-02-09 | Sanyo Chem Ind Ltd | スクリーン印刷版用洗浄剤組成物 |
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| JPH07216398A (ja) * | 1994-01-31 | 1995-08-15 | Asahi Chem Ind Co Ltd | 洗浄剤 |
| CN1159478A (zh) * | 1995-11-13 | 1997-09-17 | 株式会社日本能源 | 低腐蚀性清洗剂组合物 |
| JPH1036890A (ja) * | 1996-07-22 | 1998-02-10 | Asahi Chem Ind Co Ltd | インキ洗浄剤 |
| JPH1135993A (ja) * | 1997-07-23 | 1999-02-09 | Sanyo Chem Ind Ltd | スクリーン印刷版用洗浄剤組成物 |
| US6828295B2 (en) * | 2001-09-10 | 2004-12-07 | Proacter & Gamble Company | Non-silicone polymers for lipophilic fluid systems |
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