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TWI290769B - Thin film transistor and method of forming the same - Google Patents

Thin film transistor and method of forming the same Download PDF

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Publication number
TWI290769B
TWI290769B TW94124049A TW94124049A TWI290769B TW I290769 B TWI290769 B TW I290769B TW 94124049 A TW94124049 A TW 94124049A TW 94124049 A TW94124049 A TW 94124049A TW I290769 B TWI290769 B TW I290769B
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layer
alloy layer
forming
molybdenum
alloy
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TW94124049A
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TW200703653A (en
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Wen-Kuang Tsao
Hung-I Hsu
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Chunghwa Picture Tubes Ltd
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  • Thin Film Transistor (AREA)

Abstract

A thin film transistor including a gate, a gate insulating layer, a semiconductor layer and a source/drain is provided. The gate is disposed over a substrate, wherein the gate comprises at least one layer of molybdenum-niobium alloy nitride. The gate insulating layer is formed over the substrate to cover the gate. The semiconductor layer is disposed over the gate insulating layer above the gate. The source/drain is disposed over the semiconductor layer.

Description

I29〇mt. doc/006 九、發明說明: 【發明所屬之技術領域】 本發明是有關於一種半導體元件及其费作太本,日胜 別是有關於一種薄膜電晶體及其製作方法、/ ' 【先前技術】 、薄膜電晶體(TFT)-般包括間極、閉絕綾彦^ 與源極/汲極,其通常在顯示器中, 上j (LCD),是作為關元件之用。通常,^疋液晶顯示器 =極。閘極是由铭、鉻,、心等二, 或疋由複數金屬層所組成。 早至屬曰 容』二當二屬:成開極時,_ 致在後續的靖程中無法有效地進;η導 因㈣嶋超“ _證 源则室。此外’上述問題也同樣會發生在形成 【發明内容】 H ^明提Α —轉膜電晶體,其具錄低綱 W或線電阻的間極與源極/汲極。 妹fir,出—觀膜電晶體的形成方法,其係使用 -几氧口抗知蝕的材料來形成閘極和(或)源桎/汲極。 1290769 15380twf.doc/006 本發明係提種細電晶體,此_電晶體包括間 極、閘絕緣層、半導體層以及源極/没極。開極係配置於基 底上,其中,閘極包括至少一層氮化鉬鈮合金。間絕緣層 係形成於基底上以覆蓋閘極。半導體層係配置於基底土之 閘絕緣層上。源極/汲極係配置於半導體層上。 ’ 本發明另提出一種薄膜電晶體,此薄膜電晶體包括閘 ‘ 極、閘絕緣層、半導體層以及源極/汲極。閘極係配置於基 φ 底上。閘絕緣層係形成於基底上以覆蓋間極。半導體層係 配置於基底上之閘絕緣層上。源極/汲極係配置於半導體層 上,其中,源極/汲極包括至少一層氮化鉬鈮合金。 ^在本發明一實施例中,上述之間極係由鉗鈮合金層與 氮化錮銳合金層所組成。 在本發明一實施例中,上述之閘極係由第一氮化鉗鈮 合金層、鉬鈮合金層與第二氮化鉬鈮合金層所組成^ f本發明一實施例中’上述之源極/汲極係由鉬錕合金 層與氮化鉬鈮合金層所組成。 籲 在本發明一實施例中,上述之源極/汲極係由第一氮化 ,鉬鈮合金層、鉬鈮合金層與第二氮化鉬鈮合金層所組成。 • 本發明另提出一種薄膜電晶體的形成方法,此方法先 於基底上形成閘極。其中,閘極包括至少一層氮化姐鈮合 金。然後’於基底上形成閘絕緣層以覆蓋閘極。之後,於 基底上的閘絕緣層上配置半導體層。接下來,於半導體層 上配置源極/汲極。 θ 本發明又提出一種薄膜電晶體的形成方法,此方法係 1290769 15380twf.doc/006 ,於基底上形成·。接著,於基底娜紐絕緣層以覆 孤閘極之後,於基底上的閘絕緣層上形成半導體層。接 下來,於半導體層上形成源極/沒極。其中,源極級極包 括至少一層氮化翻銳合金。 在本發明一實施例中,上述之閘極和(或)源極/汲極係 • 町狀步獅成。錢於絲上軸娜合錢。然後 • f“目,合錢物氮化轉,⑽成lUb舰合金層。接 Φ 者將氮化鉬銳合金層圖案化以形成閘極和(或)源極/;;及極。 y在本發明之一實施例中,上述之閘極和(或)源極/汲極 係以下述之步_成。首先於基底上形成第—鉬抵合金 層二然後於第-銦鈮合金層上形成第二鉬鈮合金層。接著 對第合金層進行氮化步驟m纖合金層上 形成氮化鉬鈮合金層。之後將氮化鉬鈮合金層與第一銦鈮 合金層圖案化以形成閘極和(或)源極/汲極。 少在本發明之一實施例中,上述之閘極和(或)源極/汲極 係以下述之步驟形成。首先,於基底上形成第一翻銳合金 • ^ °,後’對第’銳合金層進行第-氮化步驟,以形成 , 第一氮化鉬鈮合金層。接著,於第一氮化鉬鈮合金層上形 • ^二減合金層。之後,於第二氮化赌合金層上形成 第三翻鈮合金層。賴,對第三域合金層進行第二氮化 步,,以於第二鉬鈮合金層上形成第二氮化翻鈮合金層。 接著’將第二氮化錮鈮合金層、第二銦鈮合金層與第一氮 化銦鈮合金層醜化,⑽成閘極和㈤賴/汲極。 本發明之薄膜電晶體的電極(閘極和(或)源極/沒極) 1290769 15380twf.doc/006 包括至少-層氮化銦銳合金,其因為在減合金的表面上 有-層氮化物保護賴,所以與習知技術中舰的金屬合 金比較起來,較為穩定’以致於電極對於氧化與侵钕具有 較佳的抵抗性。 ▲為讓本發明之上述和其他目的、特徵和優點能更明顧 易懂’下文特舉較佳實補,並配合作詳細說 • 明如下。 ^ 【實施方式】 圖1 %示為依照本發明一較佳實施例之薄膜電晶體的 剖面示意圖。請參照圖卜薄膜電晶體包括閘極102、間絕 緣層104、半導體層105以及源極/汲極11〇。閘極搬係 配置於,底100上,而閘絕緣層1〇4係配置於基底1〇〇上 方以復盍閘極102。閘絕緣層1〇4例如是由氧化石夕層、氮 化發層或氧切層與氮财層的組合層_成。半導體層 105係配置於閘極102上方的閉絕緣層1〇4上。源極/雜 110係配置於半導體層105上。在本實施例中,芈導體_ • 105例如包括形成於閘絕緣層1〇4上的通道層1〇6與形· 於通道層106和源極/汲極no之間的歐姆接觸層1〇8。 特別是,依照本發明之一較佳實施例,閘極1〇2包括 至少一層氮化鉬鈮合金。換句話說,閘極1〇2可以是單層 的氮化鉬鈮合金或包括至少一層氮化鉬鈮合金的複合層。 若閘極102為單層,則閘極1〇2係由氮化鉬鈮合金層所組 成。在本實施例中,形成單層之閘極1〇2的方法如以下步 驟。首先,在濺鍍製程室、蒸鍍製程室或其他習知的沈積 1290769 I5380twf.doc/006 至中2於基底100上形成一層鉬鈮合金層。對錮鈮合金層 進行氮化步驟,以形成氮化翻鈮合金層。舉例來說,減 ,驟可以是在形成鉬鈮合金層之後於上述沈積室中通入氮 ,,或是在沈積鉬鈮合金層的時候於上述沈積室中通入氮 氣。之後,利用微影製程與蝕刻製程將氮化錮鈮合全層圖 案化’以形成閘極102。 • 若閘極102為雙層結構,則閘極1〇2係由銦鋸合金層 φ 1〇2a與氮化鉬鈮合金層10沘所組成。請參照圖2A,在本 例中’形成雙層閘極102的方法如以下步驟。首先,於基 底100上形成第一鉬鈮合金層102a。然後,於第一錮鈮合 金層102a上形成第二鉬銳合金層(未繪示)。對第二鉬銳合 金層進行氮化反應步驟,以形成氮化鉬銳合金層1〇2b。之 後’將氮化銦鈮合金層l〇2b與第一鉬鈮合金層102a圖案 化’以形成閘極102。第一鉬鈮合金層1〇2a與第二錮铌合 金層係以先前所述的方法所形成,而氮化反應步驟也是以 先前所述的相同方法進行。 鲁 右閘極為二層結構’則閘極102係由第一氮化翻 鈮合金層102c、鉬鈮合金層l〇2d以及第二氮化鉬鈮合金 層102e所組成,請參照圖3A。在本實施例中,形成三層 之閘極102的方法如以下步驟。首先,於基底1〇〇上形成 第一鉬銳合金層(未繪示)。接著,對第一鉬銳合金層進行 如之剞所述之氣化步驟’以形成第一氮化銦銳合金層 102c。然後,於第一氮化銦銳合金層i〇2c上形成第二銦鈮 合金層102d。接著,於第二鉬鈮合金層i〇2d上形成第三 I29〇769fd_ 钥銳合金層(未繪示)。之後,對第三銦鈮合金層進行如之 前所述之氮化步驟,以形成第二氮化鉬鈮合金層1〇2e。然 後’將第二氮化顧鈮合金層l〇2e、第二鉬銳合金層i〇2d 以及第一氮化鉬鈮合金層l〇2c圖案化,以形成間極1〇2。 在另一實施例中,源極/汲極110包括至少一層氮化鉬 銳合金,請參照圖1。換句話說,源極/汲極則可以是單 層的氮化鉬鈮合金或包括至少一層氮化錮鈮合金的複合 層。若源極/没極110為單層,則源極/汲極11〇孫由氮化 鉬鈮合金層所組成。同樣地,形成單層源極/汲極^錄的方 法如以下步驟。首先,在濺鍍製程室、蒸鍍製程室或其他 熟知的沈積室中,於閘絕緣層104上形成錮鈮合金層,以 覆蓋半導體層105。對鉬鈮合金層進行氮化步驟,以形成 氮化鉬鈮合金層。舉例來說,氮化步驟可以是在形成鉬鈮 合金層之後於上述沈積室中通入氮氣,或是在沈積鉬鈮合 金層的時候於上述沈積室中通入氮氣。之後,將氮化鉬鈮 合金層圖案化,以形成源極/沒極110。 若源極/汲極110為雙層結構,則源極/汲極11〇係由 鉬鈮合金層ll〇a與氮化鉬鈮合金層11〇b所組成,請參照 圖2B。同樣地,形成雙層之源極/汲極110的方法如以下 步驟。首先,於閘絕緣層104上形成第一鉬鈮合金層11〇&, 以覆蓋半導體層105。然後,於第一鉬鈮合金層11〇a上形 成第二鉬銳合金層(未繪示)。第二鉬鈮合金層進行氮化步 驟,以形成氮化鉬鈮合金層ll〇b。之後,將氨化鉬鈮合金 層110b與第一鉬鈮合金層110a圖案化,以形成源極/汲極 Ι29〇769_/〇〇6 110。第-缺合金層110a與第二翻錕合金層係以先前所 述的方法所形成,而氮化步驟也是以先前所述的相同方法 進行。 當源極/汲極110為三層結構,則源極級極11〇係由 第-氮化純合金層llGe、_合金層麵以及第二氮 化钼銳合金層llGe所組成,請參關3B。觸地,形成 二層之源極/汲極110的方法如以下步驟。首先,於問絕緣 層1〇4亡形成第-麟合金層(未繪示},以覆蓋半導體層 10:。對f -錮鈮合金層進行如之前所述之氮化步驟,以形 成第一氮化鉬鈮合金層ll〇c。然後,於第一氮化鉬鈮合金 層110c上形成第二鉬鈮合金層11〇d。接著,於第二顧鈮 合金層110d上形成第二錮錕合金層(未緣示)。對第三鉬銳 合金層進行如之前所述之氮化步驟,以形成第二氮化鉬鈮 合金層110e。然後,將第二氮化錮鈮合金層11〇e、第二鉬 鈮合金層110d以及第一氮化鉬鈮合金層11〇c圖案化,以 形成源極/汲極110 〇 在另一實施例中,閘極102與源極/汲極110皆包括至 少一層氮化钥鈮合金層。換句話說,閉極102與源極翁極 110白可以疋單層的氮化錮銳合金或包括至少一層氣化銦 鈮合金的複合層。上述包括至少一層氮化鉬鈮合金層的複 合層,可以是雙層結構或三層結構,請參照圖2A、圖2B、 圖3A以及圖2B。 值得注意的是,因為在鉬鈮合金的表面上係有一層氮 化物保護薄膜,所以氮化鉬鈮合金層與習知技術中的金屬 π ⑧ 1290769 15380twf.doc/006 t金比較域更_1峨雜躺蘇錢對於氧化 與侵姓具有較佳的抵抗性。換句話說,包括至__| 層:薄f電晶體的電極對於氧化與侵餘^^ 日士,人寺別疋,若形成三層的閘極或三層的源極/没極 二仙銳合金層中間’嫩 卜錮鈮δi層的沈積製程以及氨化反應步驟,可 反應室(原位)中進行。若形成雙層結構或三層 可以在相同的反應室(原位)中進行。因此,本 或)源極/汲極的製程並不複雜^ 此外’增她的含量,切叫錢於氧化 的抵抗性,但是具有增加鈮含量_銳合絲材則 相當昂貴。在本發财,以對舰合金行步驟^ $增力補合金中的齡量,所以具有節膽 示哭Ϊ,若本發明之是作為液晶顯 丁时的開關几件時,且當使用雙層或三層的搞_以士 在後續各畫素結構的接觸窗開口的飿刻製程 鉬鈮合金層還可以當作蝕刻終止層。 ^^ 限疋本發明,任何熟習此技藝者,在不脫離太鉻脱 、 ,圍内,當可作些許之更動與潤舞,因此本二月之” 範園當視伽之申料觀m所界定者轉。V之呆濩 ⑧ 12 1290769 【圖式簡單說明】I29〇 mt. doc/006 IX. Description of the Invention: [Technical Field] The present invention relates to a semiconductor device and a cost thereof, and the invention relates to a thin film transistor and a method for fabricating the same, [Prior Art] Thin film transistors (TFTs) generally include a pole, a closed gate, and a source/drain, which are usually used in displays, and upper j (LCD), which is used as a shut-off element. Usually, ^疋 LCD display = pole. The gate is composed of Ming, Chromium, and Heart, or is composed of a plurality of metal layers. As early as the grace, the two belong to the second genus: when the opening is open, _ can not be effectively entered in the follow-up Jing Cheng; η lead (4) 嶋 super " _ source of the room. In addition, the above problem will also occur in Forming [Summary of the Invention] H ^明提Α - a transfer film transistor with a low-order W or line resistance between the interpole and the source/drain. Sister fir, the method of forming a film-forming transistor, the system The use of a oxy-peroxide-resistant material to form a gate and/or source/drain. 1290769 15380 twf.doc/006 The present invention provides a fine crystal, which includes a gate and a gate insulating layer. The semiconductor layer and the source/depolarization are disposed on the substrate, wherein the gate electrode comprises at least one layer of a molybdenum nitride alloy. The interlayer insulating layer is formed on the substrate to cover the gate. The semiconductor layer is disposed on the substrate. On the insulating layer of the earth gate, the source/drain is disposed on the semiconductor layer. The present invention further provides a thin film transistor including a gate electrode, a gate insulating layer, a semiconductor layer, and a source/drain The gate is disposed on the base φ. The gate insulating layer is formed on the substrate to cover The semiconductor layer is disposed on the gate insulating layer on the substrate. The source/drain is disposed on the semiconductor layer, wherein the source/drain includes at least one layer of molybdenum nitride. In one embodiment, the interlayer is composed of a pinch alloy layer and a tantalum nitride alloy layer. In an embodiment of the invention, the gate is made of a first nitrided yttrium alloy layer and a molybdenum-niobium alloy layer. The composition of the second molybdenum nitride alloy layer is composed of a molybdenum-niobium alloy layer and a molybdenum nitride-ruthenium alloy layer. In one embodiment of the present invention, The source/drainage layer is composed of a first nitrided, molybdenum-niobium alloy layer, a molybdenum-niobium alloy layer and a second molybdenum-rhenium-ruthenium alloy layer. The present invention further provides a method for forming a thin film transistor. The method first forms a gate on the substrate, wherein the gate includes at least one layer of nitriding alloy. Then, a gate insulating layer is formed on the substrate to cover the gate. Thereafter, a semiconductor layer is disposed on the gate insulating layer on the substrate. Next, configure the source/drain on the semiconductor layer. θ The present invention further proposes a method for forming a thin film transistor which is formed on a substrate by 1290769 15380 twf.doc/006. Then, after the gate insulating layer is overlaid on the substrate, the gate is applied to the substrate. A semiconductor layer is formed on the insulating layer. Next, a source/drain is formed on the semiconductor layer, wherein the source level electrode includes at least one layer of nitrided sharp alloy. In an embodiment of the invention, the gate is Or) source / bungee system • machi-like step lion into the money. Money on the silk shaft Axia money. Then • f “mesh, the money is nitrided, (10) into the lUb ship alloy layer. The Zn-impregnated sharp alloy layer is patterned to form a gate and/or source/; and a pole. In one embodiment of the invention, the gate and/or source/drain electrodes described above are formed in the following steps. First, a first molybdenum-resistant alloy layer 2 is formed on the substrate, and then a second molybdenum-rhenium alloy layer is formed on the first indium-bismuth alloy layer. Next, the first alloy layer is subjected to a nitridation step to form a molybdenum nitride-based alloy layer on the m-fiber alloy layer. The molybdenum nitride-ruthenium alloy layer is then patterned with the first indium-bismuth alloy layer to form a gate and/or source/drain. In one embodiment of the invention, the gate and/or source/drain electrodes described above are formed in the following steps. First, a first sharp alloy is formed on the substrate, ^ °, and a second nitriding step is performed on the first sharp alloy layer to form a first molybdenum nitride alloy layer. Next, an alloy layer is formed on the first molybdenum nitride layer. Thereafter, a third turn-over alloy layer is formed on the second nitrided gambling alloy layer. And performing a second nitridation step on the third domain alloy layer to form a second nitriding ytterbium alloy layer on the second molybdenum-niobium alloy layer. Next, the second tantalum nitride alloy layer, the second indium niobium alloy layer and the first indium niobium nitride alloy layer are smeared, (10) is gated and (5) Lai/dip. The electrode (gate and/or source/no-pole) of the thin film transistor of the present invention 1290769 15380 twf.doc/006 includes at least a layer of indium nitride, which has a layer of nitride on the surface of the reduced alloy Protected, so compared with the metal alloy of the ship in the prior art, it is relatively stable 'so that the electrode has better resistance to oxidation and erosion. The above and other objects, features and advantages of the present invention will become more apparent and understood. [Embodiment] Fig. 1 is a schematic cross-sectional view showing a thin film transistor in accordance with a preferred embodiment of the present invention. Please refer to the wafer transistor including a gate 102, an insulating layer 104, a semiconductor layer 105, and a source/drain 11 〇. The gate transfer system is disposed on the bottom 100, and the gate insulating layer 1〇4 is disposed above the substrate 1 to rewind the gate 102. The gate insulating layer 1〇4 is formed, for example, by a combination of a oxidized stone layer, a nitriding layer, or an oxygen-cut layer and a nitrogen-rich layer. The semiconductor layer 105 is disposed on the closed insulating layer 1〇4 above the gate 102. The source/hybrid 110 is disposed on the semiconductor layer 105. In the present embodiment, the germanium conductor_105 includes, for example, a channel layer 1?6 formed on the gate insulating layer 1?4 and an ohmic contact layer 1 formed between the channel layer 106 and the source/drain pole no. 8. In particular, in accordance with a preferred embodiment of the present invention, gate 1 〇 2 includes at least one layer of a molybdenum nitride alloy. In other words, the gate 1〇2 may be a single layer of a molybdenum nitride alloy or a composite layer comprising at least one layer of a molybdenum nitride alloy. If the gate 102 is a single layer, the gate 1〇2 is composed of a layer of a molybdenum nitride alloy. In the present embodiment, the method of forming the gate 1 2 of a single layer is as follows. First, a layer of molybdenum-niobium alloy is formed on the substrate 100 in a sputtering process chamber, an evaporation process chamber, or other conventional depositions 1290769 I5380twf.doc/006 to 2 . A nitriding step is performed on the tantalum alloy layer to form a nitrided turned-over alloy layer. For example, the step of reducing may be to introduce nitrogen into the deposition chamber after forming the molybdenum-niobium alloy layer, or to introduce nitrogen into the deposition chamber while depositing the molybdenum-niobium alloy layer. Thereafter, the nitride layer is patterned in a full layer by a lithography process and an etching process to form the gate 102. • If the gate 102 has a two-layer structure, the gate 1〇2 is composed of an indium saw alloy layer φ 1〇2a and a molybdenum nitride alloy layer 10沘. Referring to Fig. 2A, the method of forming the double-layer gate 102 in this example is as follows. First, a first molybdenum-rhenium alloy layer 102a is formed on the substrate 100. Then, a second molybdenum alloy layer (not shown) is formed on the first alloy layer 102a. The second molybdenum sharp gold layer is subjected to a nitridation reaction step to form a molybdenum nitride fine alloy layer 1〇2b. Thereafter, the indium-niobium-niobium alloy layer 10b is patterned with the first molybdenum-rhodium alloy layer 102a to form the gate 102. The first molybdenum-niobium alloy layer 1〇2a and the second antimony alloy layer were formed in the manner previously described, and the nitridation reaction step was also carried out in the same manner as previously described. The gate electrode 102 is composed of a first nitrided turned-rhodium alloy layer 102c, a molybdenum-niobium alloy layer 102a, and a second molybdenum-niobium alloy layer 102e. Please refer to FIG. 3A. In the present embodiment, the method of forming the gate 102 of the three layers is as follows. First, a first molybdenum alloy layer (not shown) is formed on the substrate 1 . Next, the first molybdenite alloy layer is subjected to a gasification step as described above to form a first indium nitride sharp alloy layer 102c. Then, a second indium antimony alloy layer 102d is formed on the first indium nitride sharp alloy layer i2c. Next, a third I29〇769fd_ key alloy layer (not shown) is formed on the second molybdenum-rhenium alloy layer i〇2d. Thereafter, the third indium-bismuth alloy layer is subjected to a nitridation step as described above to form a second molybdenum nitride-ruthenium alloy layer 1〇2e. Then, the second nitriding alloy layer l〇2e, the second molybdenum sharp alloy layer i〇2d, and the first molybdenum-rhenium alloy layer l〇2c are patterned to form the interpole 1〇2. In another embodiment, the source/drain 110 includes at least one layer of molybdenum nitride sharp alloy, please refer to FIG. In other words, the source/drain may be a single layer of molybdenum nitride or a composite layer comprising at least one layer of tantalum nitride. If the source/dump 110 is a single layer, the source/drain 11 is composed of a layer of a molybdenum nitride alloy. Similarly, the method of forming a single-layer source/drain is as follows. First, a bismuth alloy layer is formed on the gate insulating layer 104 to cover the semiconductor layer 105 in a sputtering process chamber, an evaporation process chamber, or other well-known deposition chamber. The molybdenum-niobium alloy layer is subjected to a nitriding step to form a molybdenum nitride-ruthenium alloy layer For example, the nitriding step may be to introduce nitrogen into the deposition chamber after forming the molybdenum-niobium alloy layer, or to introduce nitrogen into the deposition chamber while depositing the molybdenum-ruthenium alloy layer. Thereafter, the molybdenum nitride-rhodium alloy layer is patterned to form the source/drain 110. If the source/drain 110 is of a two-layer structure, the source/drain 11 is composed of a molybdenum-niobium alloy layer 11a and a molybdenum-niobium alloy layer 11b, see Fig. 2B. Similarly, the method of forming the double-layered source/drain 110 is as follows. First, a first molybdenum-rhenium alloy layer 11 〇 & is formed on the gate insulating layer 104 to cover the semiconductor layer 105. Then, a second molybdenum sharp alloy layer (not shown) is formed on the first molybdenum-rhenium alloy layer 11A. The second molybdenum-rhenium alloy layer is subjected to a nitridation step to form a molybdenum nitride-ruthenium alloy layer 11b. Thereafter, the molybdenum hydride alloy layer 110b is patterned with the first molybdenum-rhenium alloy layer 110a to form a source/drain Ι29〇769_/〇〇6 110. The first-deficient alloy layer 110a and the second turn-over alloy layer are formed by the previously described method, and the nitriding step is also carried out in the same manner as previously described. When the source/drain 110 is a three-layer structure, the source-level electrode 11 is composed of a first-nitrided pure alloy layer llGe, an alloy layer, and a second molybdenum-alkaline alloy layer llGe, please refer to 3B. . The method of forming the source/drain 110 of the second layer is as follows. First, the insulating layer is formed to form a first-lin alloy layer (not shown) to cover the semiconductor layer 10: the f-yttrium alloy layer is subjected to a nitridation step as described above to form the first a molybdenum nitride-ruthenium alloy layer 11〇c. Then, a second molybdenum-rhenium alloy layer 11〇d is formed on the first molybdenum-niobium alloy layer 110c. Next, a second crucible is formed on the second alloy layer 110d. An alloy layer (not shown). The third molybdenum sharp alloy layer is subjected to a nitriding step as described above to form a second molybdenum nitride alloy layer 110e. Then, the second tantalum nitride alloy layer 11 is 〇 e, the second molybdenum-rhenium alloy layer 110d and the first molybdenum-niobium alloy layer 11〇c are patterned to form the source/drain 110. In another embodiment, the gate 102 and the source/drain 110 All include at least one layer of a ruthenium nitride alloy layer. In other words, the closed pole 102 and the source pole 110 may be a single layer of a tantalum nitride or a composite layer comprising at least one layer of a gasified indium bismuth alloy. The composite layer of at least one layer of molybdenum nitride alloy layer may be a two-layer structure or a three-layer structure, please refer to FIG. 2A, FIG. 2B and FIG. 3A and Fig. 2B. It is worth noting that the molybdenum nitride alloy layer and the metal in the prior art are π 8 1290769 15380 twf. The comparison domain is more 峨 躺 躺 钱 钱 对于 对于 对于 对于 对于 对于 对于 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 If the temple is formed, the formation process of the three layers of the gate or the three layers of the source/dipole two Xianrui alloy layer in the middle of the 'nenbu 锢铌i layer and the amination reaction step can be used in the reaction chamber (in situ). If the formation of a two-layer structure or three layers can be carried out in the same reaction chamber (in situ), therefore, the process of the or the source / drain is not complicated ^ In addition, 'increasing her content, cutting money Oxidation resistance, but with increased niobium content _ sharp wire is quite expensive. In this fortune, the amount of the alloy in the alloy is increased by the step of the alloy, so there is a blemish, if the invention is a switch when the liquid crystal is used, and when using double The etching process of the layer or the three layers can also be used as an etch stop layer in the etching process of the contact window opening of the subsequent pixel structures. ^^ Limitation to the present invention, anyone who is familiar with this skill, can not make a little change from the chrome, and within the circumference, when it can make some changes and run the dance, so this February's "Fan Yuan Dangjia gazhi application view m The defined person turns. V's dull 8 12 1290769 [Simple diagram]

圖1繪示為依照本發明一 剖面示意圖。 圖2A繪示為依照本發明另 體的雙層閘極的剖面示意圖。 圖2B 1示為依照本發明再—較佳實施例之薄膜電 體的雙層源極/汲極的剖面示意圖。 、 Βθ 圖3Α繪示為依照本發明又一較佳實施例之薄膜電晶 體的三層閘極的剖面示意圖。 圖3Β 4示為依照本發明又—較佳實施例之薄膜電晶 體的三層源極/汲極的剖面示意圖。 【主要元件符號說明】 100 ·基底 102 :閘極 102a、102d、ll〇a、110d :鉬鈮合金層 102b、102c、102e、110b、110c、110e :氮化鉬鈮合 金層 104 :閘絕緣層 1〇5 :半導體層 106 :通道層 108 :歐姆接觸層 110 :源極/汲極BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cross-sectional view showing a portion of the present invention. 2A is a cross-sectional view of a double layer gate in accordance with another aspect of the present invention. Figure 2B is a cross-sectional view showing the double-layer source/drain of a thin film battery in accordance with a further preferred embodiment of the present invention. Βθ FIG. 3A is a cross-sectional view showing a three-layer gate of a thin film transistor according to still another preferred embodiment of the present invention. 3 to 4 are schematic cross-sectional views showing a three-layer source/drain of a thin film transistor according to still another preferred embodiment of the present invention. [Main component symbol description] 100 Base plate 102: Gates 102a, 102d, 11A, 110d: Molybdenum-niobium alloy layers 102b, 102c, 102e, 110b, 110c, 110e: Molybdenum nitride-based alloy layer 104: Gate insulating layer 1〇5: semiconductor layer 106: channel layer 108: ohmic contact layer 110: source/drain

(D 13(D 13

Claims (1)

I290769 twf.doc/006 十、申請專利範圍: L一種薄膜電晶體,包括: 一閘極,置於一基底上,其中該閘極包括至少 化翻銳(Mo-Nb)合金; 一閘絕緣層,形成於該基底上,以覆蓋該閘極; 一半導體層’配置於該閘極上之該閘絕緣層上;以及 一源極/汲極,配置於該半導體層上。I290769 twf.doc/006 X. Patent Application Range: L A thin film transistor comprising: a gate disposed on a substrate, wherein the gate comprises at least a sharp-edged (Mo-Nb) alloy; a gate insulating layer Formed on the substrate to cover the gate; a semiconductor layer 'disposed on the gate insulating layer on the gate; and a source/drainage disposed on the semiconductor layer. 2·如申請專利範圍第1項所述之薄膜電晶體,其中該 閘極包括: 一鉬錕合金層;以及 一鼠化鉬銳合金層,配置於該錮銳合金層上。 3·如申請專利範圍第1項所述之薄膜電晶體,其中該 閘極包括: 一第一氮化鉬銳合金層; 一銦銳合金層,配置於該第一氮化鉬鈮合金層上;以2. The thin film transistor according to claim 1, wherein the gate comprises: a molybdenum-niobium alloy layer; and a murine molybdenum alloy layer disposed on the parenchyloy layer. 3. The thin film transistor according to claim 1, wherein the gate comprises: a first molybdenum nitride alloy layer; an indium sharp alloy layer disposed on the first molybdenum nitride alloy layer ; 一層氮 一弟一氮化銦銳合金層’配置於該銦鈮合金層上。 4 ·如申請專利範圍第1項所述之薄膜電晶體,其中該 源極/汲極包括至少一層氮化鉬鈮合金。 5·如申請專利範圍第4項所述之薄膜電晶體,其中該 源極/汲極包括: 一銦銳合金層;以及 一氮化鉬錕合金層,配置於該鉬銳合金層上。 6·如申請專利範圍第4項所述之薄膜電晶體,其中該 丨 twf.doc/006 1290769 15380t\ 源極/汲極包括: 一第一氮化鉬銳合金層; 一症目鈮合金層,配置於該第一氮化鉬鈮合金層上;以 及 一第二氮化鉬鈮合金層,配置於該鉬鈮合金層上。 7 · 一種薄膜電晶體,包括: 一閘極; 一閘絕緣層,配置於該基底上,以覆蓋談閘極; 一半導體層,配置於該閘極上之該閘絕緣層上;以及 一源極/汲極,配置於該半導體層上,其中該源極/汲 極包括至少一層氮化铜銳合金。 8·如申請專利範圍第7項所述之薄膜電晶體,其中該 源極/汲極包括: 一錮銳合金層;以及 一氮化銦銳合金層,配置於該钥銳合金層上。 9·如申請專利範圍第7項所述之薄膜電晶體,其中該 源極/¾極包括: 一第一氮化鉬銳合金層; 一銦銳合金層,配置於該第一氮化錮銳合金層上;以 及 一苐二氮化銦銳合金層,配置於該鉬銳合全層Ji。 10·—種薄膜電晶體形成方法,包括: 於一基底上形成一閘極,其中該閘極包括至少一層氮 化翻銳合金; ⑤ 15 1290769 15380twf.doc/006 於該基底上形成—閘絕緣層以覆蓋該間極; 於該半導體層上形成一源極/没極。 法 η·如申請專_圍第10項所述之賴糕體形成方 其中形成該閘極的步驟包括: 於該基底上形成一錮鈮合金層; 對該鉬銳合金層進行—氮化步驟以形成一氣化錢 二金層’其巾該氮化步料麵成該減合鑛之後進 行;以及 將該氮化贿合金層圖案化⑽成該_。 *,f利_第10項所述之薄膜電晶體形成爹 法,/、中形成該閘極的步驟包括: 於為基底上形成一銦銳合金層; 合金ί:亥ί 二二:氮化步驟以形成-氮化鉬銳 行;以及 沈積該銦鈮合金層的時候進 將該氮化恤合金層圖案化以形成該·。 13.如申請專利範圍第 體忐古 法,其中形成該·的步驟包括:體域方 於該基底上形成一第一錮銳合金声· 於該第一銦鈮合金層上形成一第^滅鈮合合展. 銳合行—竊轉咖g—銦 形成該i二二:===層以Γ該氮化步驟是在 ⑧ 16 1290769 一 15380twf.doc/006 將該氮化錮鈮合金層與該第一钼鈮合金層圖案化以 形成該閘極。 14·如申請專利範圍第1〇項所述之薄膜電晶體形咸方 法,其中形成該閘極的步驟包括: 於該基底上形成一第一錮鈮合金層; 於該第一鉬鈮合金層上形成一第二鉬鈮合金層; 對該第二鉬鈮合金層進行一氮化步驟以於該第一鉬 鈮合金層上形成-氮化娜合金層,其中該氮化步驟是在 沈積該第二鉬錕合金層的時候進行;以及 、將該氮化鉬鈮合金層與該第一鉬鈮合金層圖索化以 形成該閘極。 Γη 丄5·如甲請專利範圍第川項所 法’其中形成該閘極的步驟包括: 於该基底上形成一第一翻銳合金層; 對該第-銷鈮合金層進行一第^化步驟以形成— =鼠化峽合金層,其中該第—氮化步驟可以是在形成 =一f化錮鈮合金層上形成-第二銷銳合金層; 合金層上形成—第三_合金層; 二鳴合金層進行—第二氮化步㈣於該第 翁仆立_上形成一第二氮化鉬鈮合金層,a中咳第二 ν驟可以是在形成該第三鉬鈮合金層之後i行了以^ 將該第二氮化銷銳合金層、該㈣ 17 1290769 15380twf.doc/006 -氮化贿合金層圖案細形成該_。 16.如申凊專利範圍第1〇項所述之薄膜電晶體形成方 法,其中形成該閘極的步驟包括: 於η玄基底上形成一第一錮銳合金層; ^ ^ it $ ^ iLib ^ 鈮合金層之後進行,或是在沈__鉬_金 層的時候進行; 於该ί一氮化鉬鈮合金層上形成一第二錮鈮合金層; 於該錮鈮合金層上形成一第三鉬鈮合金層; 對該第三域合金層進行一第二氮化步驟以於該第 合金層上形成一第二氮化錮鈮合金層,其中該第二 及V驟可以疋在沈積該第三銦鈮合金層的時候進行;以 —一將忒第一氮化鉬鈮合金層、該第二鉬鈮合金層與該第 鼠化錮鈮合金層圖案化以形成該閘極。^ 生,申印專利範圍第10項所述之薄膜電晶體形成方 /、中形成該源極/没極的步驟包括: 層;於該_緣層上形成—銦錕合金相覆蓋該半導體 人入^銦銳合金層進行—氣化步驟以形成—氮化鉬錕 =€ ’其巾該氮化步驟可以是在形成該敏合金層之後 %订,以及 將該氮化_合金層随化以形顏源極級極。 、18·如^專她圍帛10項所述之薄膜電晶體形成方 法,其中形成該源極/汲極的步驟包括·· 層 於該閘絕緣層上形成一钥銳合金層以覆蓋該半專體 對該_合金層進行一氮化步驟以形成-氮化祕 合金層,其中該氮化步驟可以是在沈積該_合金層的時 候進行;以及 . ....'.. 將該氮化鉬鈮合金層圖案化以形成該源極/汲極。 、10 法,其中形成該源極/汲極的步驟包括·· 導體Γ關絕緣層上形成—第―1目錕合金層以覆蓋該半 於該第厂錮銳合金層上形成一第二翻銳合金層; 4尸入第二翻鈮合金層進行—氮化步驟以於談第一錮 ❿ 成一氮化_合金層,其中該氮化步驟可以 疋在形成该弟二鉬鈮合金層之後進行;以及 將該氮化錮銳合金層與第-銦k合全斧圄幸化卿 成該源極/汲極。 口孟層圖案化以形 20·如申請專利範圍第10項所诚々 ‘ 法’其中形成該源極/汲極的步驟‘:缚膜電晶體形成方 於該閘絕緣層上形成一第—鉬入 導體層; 13 i 層以覆蓋該半 於該第-域合金層上形成一第二人八廢. 對該第二鉬鈮合金層進行一氮半4口 , 氣化步驟以於該第一鉬 ⑧ 19 以 ‘層圖案化以形A layer of nitrogen, an indium nitride alloy layer, is disposed on the indium-bismuth alloy layer. 4. The thin film transistor of claim 1, wherein the source/drain includes at least one layer of molybdenum nitride. 5. The thin film transistor of claim 4, wherein the source/drain includes: an indium sharp alloy layer; and a molybdenum nitride alloy layer disposed on the molybdenum alloy layer. 6. The thin film transistor according to claim 4, wherein the 丨twf.doc/006 1290769 15380t\ source/drain includes: a first molybdenum sharp alloy layer; And disposed on the first molybdenum nitride alloy layer; and a second molybdenum nitride alloy layer disposed on the molybdenum-ruthenium alloy layer. a thin film transistor comprising: a gate; a gate insulating layer disposed on the substrate to cover the gate; a semiconductor layer disposed on the gate insulating layer on the gate; and a source And a drain is disposed on the semiconductor layer, wherein the source/drain includes at least one layer of copper nitride sharp alloy. 8. The thin film transistor of claim 7, wherein the source/drain includes: a sharp alloy layer; and an indium nitride alloy layer disposed on the key alloy layer. 9. The thin film transistor of claim 7, wherein the source/3⁄4 pole comprises: a first molybdenum nitride alloy layer; an indium sharp alloy layer disposed on the first tantalum crucible And an indium dinitride fine alloy layer disposed on the molybdenum plump full layer Ji. 10. A method of forming a thin film transistor, comprising: forming a gate on a substrate, wherein the gate comprises at least one layer of nitrided sharp alloy; 5 15 1290769 15380 twf.doc/006 forming a gate insulating on the substrate a layer to cover the interpole; a source/nopole is formed on the semiconductor layer. The method of forming the gate according to the method of claim 10, wherein the step of forming the gate comprises: forming a tantalum alloy layer on the substrate; performing a nitriding step on the molybdenum sharp alloy layer To form a vaporized money two gold layer 'the towel after the nitriding step surface is formed into the reduced ore; and patterning (10) the nitride brittle alloy layer into the _. The method of forming a thin film transistor according to claim 10, wherein the step of forming the gate comprises: forming an indium sharp alloy layer on the substrate; alloy ί: ίί 二 二: nitriding The step of forming a molybdenum nitride sharp line; and depositing the indium-niobium alloy layer to pattern the nitriding alloy layer to form the layer. 13. The method according to claim 1, wherein the step of forming the first surface comprises: forming a first sharpening alloy sound on the substrate; forming a second on the first indium-bismuth alloy layer.合合合展. 锐合行—Stealing coffee g—indium to form the i22:=== layer to Γ The nitriding step is at 8 16 1290769 a 15380 twf.doc/006 Patterning with the first molybdenum-rhenium alloy layer to form the gate. 14. The method according to claim 1, wherein the step of forming the gate comprises: forming a first tantalum alloy layer on the substrate; and forming the first molybdenum alloy layer Forming a second molybdenum-rhenium alloy layer thereon; performing a nitriding step on the second molybdenum-rhenium alloy layer to form a-nitride alloy layer on the first molybdenum-niobium alloy layer, wherein the nitriding step is to deposit the The second molybdenum-niobium alloy layer is performed; and the molybdenum nitride-ruthenium alloy layer and the first molybdenum-niobium alloy layer are patterned to form the gate. The method of forming the gate in the method of the invention is as follows: forming a first sharp alloy layer on the substrate; a step of forming a layer of a ratified gorge alloy, wherein the first nitriding step may be to form a second pin sharp alloy layer on the layer forming the bismuth alloy; forming a third alloy layer on the alloy layer The second ringing alloy layer is formed by the second nitriding step (4) forming a second layer of molybdenum nitride bismuth alloy on the first slab, and the second ν step of a coughing may be forming the third layer of the lanthanum lanthanum alloy After that, the second nitriding pin sharp alloy layer and the (4) 17 1290769 15380 twf.doc/006 - nitriding alloy layer pattern are finely formed to form the _. 16. The method of forming a thin film transistor according to claim 1, wherein the step of forming the gate comprises: forming a first sharp alloy layer on the θ-base; ^ ^ it $ ^ iLib ^ After the bismuth alloy layer is performed, or when the __molybdenum-gold layer is formed; a second bismuth alloy layer is formed on the 一-molybdenum nitride bismuth alloy layer; a first layer is formed on the bismuth alloy layer a third molybdenum alloy layer; a second nitriding step is performed on the third domain alloy layer to form a second tantalum nitride alloy layer on the first alloy layer, wherein the second and V steps can be deposited The third indium-bismuth alloy layer is performed; the first layer of the molybdenum nitride alloy layer, the second layer of the molybdenum-niobium alloy and the layer of the first layer of the niobium alloy are patterned to form the gate. ^, the step of forming the source/drain in the thin film transistor forming method described in claim 10, comprising: forming a layer; forming an indium-bismuth alloy layer on the layer to cover the semiconductor person Into the indium sharp alloy layer - gasification step to form - molybdenum nitride 锟 = 'the towel, the nitriding step may be after the formation of the sensitive alloy layer %, and the nitriding alloy layer The shape of the source is extremely extreme. The method for forming a thin film transistor according to the above, wherein the step of forming the source/drain includes: forming a layer of a sharp alloy on the gate insulating layer to cover the half The nitriding layer is subjected to a nitriding step to form a nitriding alloy layer, wherein the nitriding step may be performed while depositing the _ alloy layer; and ..... The molybdenum-rhenium alloy layer is patterned to form the source/drain. And 10, wherein the step of forming the source/drain includes: forming a first-thick alloy layer on the insulating layer of the conductor to cover the half of the layer of the sharp alloy on the first plant to form a second turn a sharp alloy layer; 4 corps into the second layer of bismuth alloying - a nitriding step to form a nitriding alloy layer, wherein the nitriding step may be performed after forming the bismuth molybdenum alloy layer And the bismuth nitride alloy layer and the first-indium k-total axe 圄 化 化 成 成 该 into the source / bungee. The mouth layer is patterned to form a shape. 20, as claimed in claim 10, the 'method of forming the source/drainage step': the formation of the film-forming transistor forms a first layer on the gate insulating layer Molybdenum enters the conductor layer; 13 i layer covers the half of the first-domain alloy layer to form a second person and eight wastes. The second molybdenum-niobium alloy layer is subjected to a nitrogen half of 4, and a gasification step is used for the first a molybdenum 8 19 is patterned with a 'layer 1290769 15380twf.doc/006 鈮合金層上形成一氮化鉬銳合金層,甘山 是在沈積該第二賊合金層的時候進^/·=化步驟可 將該氮化鉬鈮合金層與第一鉬鈮合金及 成該源極/沒極。 “ 法,範圍第10項所述之薄膜電晶體形成方 法’其中形成该源極/>及極的步驟包括: 導體=閘絕緣層上形成—第—錮銳合金層以覆蓋該半 第-對rfz合金層㈣—第—氮姆驟以形成一 t鼠化織合金層,其巾該第—氮化轉誠是在形成 鈮合金層之後進行,或是在沈積該第—減合全 層的時候進行; 於該第-氮化峨合金層上形成一第二翻絲金層; 於該第二鉬鈮合金層上形成一第三錮鈮合金層; 一對該第三鉬鈮合金層進行一第二氮化步驟^於該第 一錮錕5金層上形成一第二氮化翻銳合金層,其中該第二 氮化步驟了 IX疋在形成該第三I目铌合金層之後進行;以及 斤將该第二氮化鉬鈮合金層、該第二鉬鈮合金層與該第 一氮化銦銳合金層圖案化以形成該源極/汲極。 、22·如申請專利範圍第10項所述之薄膜電晶體形成方 法’其中形成該源極/汲極的步驟包括: 於該閘絕緣層上形成一第一鉬鈮合金層以覆蓋該半 導體層; 對該第一鉬鈮合金層進行一第一氮化步驟以形成一 ⑧ 20 1290769 15380twf.doc/0〇6 層的時候進行 於該第-氮化錮銳合金層上形成一第二_合金層; 於該第二鉬銳合金層上形成一第三翻銳合金層; 對該第三純合金層進行—第二氮化步驟以於該第 了翻銳合金層上形成-第二氮化雜合金層,其中該第二 乳化步驟可以是在沈積該第三纟鳴合金層的時候進行;以 及 ’將該第二氮化錮鈮合金層、該第二雜合金層與該第 —氮化鉬鈮合金層圖案化以形成該源極/汲極。 23·一種薄膜電晶體形成方法,包括: 於一基底上形成一閘極; 於該基底上形成一閘絕緣層以覆蓋該閘極 於該閘極上之該閘絕緣層上形成一半導體層;以及 於5亥半導體層上形成一源極/汲極,其中該源極級極 包括至少一層氮化鉬鈮合金。 、、24.如申請專利範圍第23項所述之薄膜電晶體形成方 法’其中形成該源極/汲極的步驟包括·· 於該閘絕緣層上形成一鉬鈮合金層以覆蓋該半導體 _對該翻銳合金層進行-氮化步驟以形成一氣化減 合金層’其中該氮化步驟可以是在形成該鉬銳合金層之祕 進行;以及 21 1290769 15380twf.doc/006 將該氮化鉬鈮合金層圖案化以形成該源極/汲極。 25·如申請專利範圍第23項所述之薄膜電晶體形成方 法’其中形成该源極/>及極的步驟包括: 於該閘絕緣層上形成一鉬鈮合金層以覆蓋該半導體 層; 對该鉬鈮合金層進行一氮化步驟以形成一氮化鉬鈮 合金層,其中該氮化步驟可以是在沈積該鉬銳合金層的時 候進行;以及 將該氮化錮銳合金層圖案化以形成該源極/没極。 、26·如申明專利範圍第23項所述之薄膜電晶體形成方 法,其中形成該源極/汲極的步驟包括·· Γ °现%簡上形成—*—纟晚合金職覆蓋該半 導體層; 於該第-銦銳合金層上形成一第二銦媒合全層; 奸入f二_合金層進行—氮化步驟以於該第一錮 疋在y成該弟—鉬鈮合金層之後進行·以及 成該㈣合金層衫-顺合金韻案化以形 如申請專利範圍第23項所述薄物 法,其中形成該源極/汲極的步驟包^賴^日體形成方 於該閘絕緣層上形成一第一入人应 導體層; 鉬鈮合金層以覆蓋該半 於該第一銦鎚合金層上形成一第二她合金層; 22 I29〇769£d〇c/006 妒入亥第二鉬鈮合金層進行一氮化步驟以於該第-鉬 成—氮化赌合金層’其中該侧步驟可以 疋在/尤積u亥苐一錮銳合金層的時候進行·以及 成該==贱合金層鮮金層圖·以形 法it申:月專利觀圍*23項所述之薄膜電晶蠢形成方 忐,其中形成該源極/汲極的步驟包括·· 導^該_緣層上形成—第—喊合金層以覆蓋該半 第-金層進行—第—氮化步驟以形成一 兮第ΐΓΠ ,其巾該第—氮化步驟可以是在形成 層::;金層之後進行’或是在沈積該第-舰合金 於该弟二鉬鈮合金層上形成一第三鉬鈮合全声. 二相銳合金層進行—第二氮化步驟^ 4口孟層上形成一第二氮化鉬鈮合金層,1中爷第二 成該第三錮銳合金層之後進行^ 兮當/弟—統她合金層、該第二氮化銦鈮合金声盘 氮化舰合金層_切職娜極後極。、…、 29·如申請專利範圍第23 磁 法,其中形成該源極她的步驟=賴嗔形成方 導體層Γ閉巴、表層上形成一第一銦銳合金層以覆蓋該半 23 1290769 15380twf.doc/006 對該第一鉬鈮合金層進 ^ 第一氮化鉬鈮合金層,龙中 "一鼠化步驟以形成— 該第-贿合金層之後化步驟可以是在形成 層的時候進行; $疋在沈積该第一鉗銀合金 ,^氮化_合金層上形成—第二姻 於该第-賊合金層上形成—第三崎合金層; -對該第三鈿r匕合金層進行一第二氮化步驟以於該第 了鉬鈮合金層上形成一第二氮化鉬鈮合金層,其中讀第二 氮化步驟可以是在沈積該第三鉬鈮合金層的時^進行;= 及 將該第二氮化鉬鈮合金層、該第二氮化鉬鈮合金層與 該第一氮化鉬鈮合金層圖案化以形成該源極/汲極。 241290769 15380twf.doc/006 A layer of molybdenum nitride is formed on the bismuth alloy layer, and the mountain is deposited in the second thief alloy layer during the deposition of the second thief alloy layer. A molybdenum-niobium alloy and the source/no-pole. The method of forming a thin film transistor according to the method of claim 10, wherein the step of forming the source/gt; and the pole comprises: forming a conductor-first insulating layer on the gate insulating layer to cover the half- The rfz alloy layer (4)-the first-n-methane is formed to form a t-woven alloy layer, and the first-nitriding is performed after the formation of the bismuth alloy layer, or the first-thickness reduction layer is deposited. And forming a second rectifying gold layer on the first layer of tantalum nitride alloy; forming a third tantalum alloy layer on the second molybdenum-niobium alloy layer; and the third molybdenum-niobium alloy layer Performing a second nitriding step to form a second nitrided sharp alloy layer on the first 锢锟5 gold layer, wherein the second nitriding step IX 疋 after forming the third I 铌 alloy layer And performing: patterning the second molybdenum-rhenium-ruthenium alloy layer, the second molybdenum-rhenium alloy layer and the first indium-fluoride alloy layer to form the source/drain. 22, as claimed in the patent application The thin film transistor forming method of claim 10, wherein the step of forming the source/drain includes: Forming a first molybdenum-niobium alloy layer on the edge layer to cover the semiconductor layer; performing a first nitridation step on the first molybdenum-rhenium alloy layer to form an 8 20 1290769 15380 twf.doc/0〇6 layer Forming a second alloy layer on the first tantalum nitride alloy layer; forming a third sharp alloy layer on the second molybdenum sharp alloy layer; performing a second nitriding step on the third pure alloy layer Forming a second nitride alloy layer on the first sharp alloy layer, wherein the second emulsification step may be performed while depositing the third squeaking alloy layer; and 'the second bismuth nitride layer The bismuth alloy layer, the second impurity alloy layer and the first molybdenum nitride ruthenium alloy layer are patterned to form the source/drain. 23 A method for forming a thin film transistor, comprising: forming a gate on a substrate Forming a gate insulating layer on the substrate to cover the gate insulating layer on the gate to form a semiconductor layer; and forming a source/drain on the 5-well semiconductor layer, wherein the source level The pole includes at least one layer of molybdenum nitride alloy. The method for forming a thin film transistor according to claim 23, wherein the step of forming the source/drain includes: forming a layer of molybdenum-niobium alloy on the gate insulating layer to cover the semiconductor The alloy layer is subjected to a nitridation step to form a gasification minus alloy layer 'where the nitridation step may be performed in forming the molybdenum sharp alloy layer; and 21 1290769 15380 twf.doc/006 The method for forming a thin film transistor according to claim 23, wherein the step of forming the source/gt; and the pole comprises: forming a gate on the gate insulating layer a molybdenum-niobium alloy layer covering the semiconductor layer; performing a nitriding step on the molybdenum-niobium alloy layer to form a molybdenum nitride-ruthenium alloy layer, wherein the nitriding step may be performed while depositing the molybdenum sharp alloy layer; The tantalum nitride alloy layer is patterned to form the source/no. The method of forming a thin film transistor according to claim 23, wherein the step of forming the source/drain includes: Γ 现 现 现 — — — * 合金 合金 合金 合金 合金 合金 合金 合金 合金 合金 合金 合金Forming a second indium-bonded full layer on the first indium sharp alloy layer; displacing into the f-alloy layer to perform a nitriding step, after the first yt is formed into the bis-molybdenum-bismuth alloy layer Carrying out and forming the (four) alloy layer shirt-shun alloy rhyme to form a thin object method as described in claim 23, wherein the step of forming the source/drainage is performed on the gate Forming a first input conductor layer on the insulating layer; a molybdenum-niobium alloy layer covering the half of the first indium alloy layer to form a second alloy layer; 22 I29〇769£d〇c/006 The second molybdenum-niobium alloy layer is subjected to a nitriding step to perform the first-molybdenum-nitriding gambling alloy layer, wherein the side step can be carried out when the eutectic alloy layer is formed The == 贱 alloy layer fresh gold layer map · by the shape method it Shen: monthly patent view circumference * 23 said thin film electric crystal stupid formation The step of forming the source/drain includes: forming a first-calling alloy layer to cover the semi-gold layer to perform a first-nitriding step to form a first ΐΓΠ, The first-nitriding step of the towel may be performed after forming the layer::; gold layer or forming a third molybdenum-kneaded full sound on the layer of the second-molybdenum alloy. The phase sharp alloy layer is carried out - the second nitriding step ^ 4 is formed on the Meng layer to form a second layer of molybdenum nitride alloy, and the second layer is formed into the third layer of the tantalum alloy. Her alloy layer, the second indium nitride bismuth alloy sound disk nitriding alloy layer _ cut off the pole pole. For example, in the 23rd magnetic method of the patent application, in which the source is formed, the step of forming the source is the formation of a square conductor layer, and a first indium alloy layer is formed on the surface layer to cover the half 23 1290769 15380 twf .doc/006 The first molybdenum-niobium alloy layer is subjected to a first molybdenum-niobium-niobium alloy layer, and the dragon is <a ratification step to form - the first bribe alloy layer after the formation step may be when the layer is formed疋 疋 沈 沈 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该The layer performs a second nitriding step to form a second molybdenum nitride alloy layer on the first molybdenum-rhenium alloy layer, wherein the reading the second nitriding step may be when depositing the third molybdenum-niobium alloy layer And performing: patterning the second molybdenum nitride layer, the second molybdenum nitride layer, and the first molybdenum niobium alloy layer to form the source/drain. twenty four
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