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TWI247433B - Thin film transistor and method of forming the same - Google Patents

Thin film transistor and method of forming the same Download PDF

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TWI247433B
TWI247433B TW94106903A TW94106903A TWI247433B TW I247433 B TWI247433 B TW I247433B TW 94106903 A TW94106903 A TW 94106903A TW 94106903 A TW94106903 A TW 94106903A TW I247433 B TWI247433 B TW I247433B
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alloy layer
aluminum
layer
forming
bismuth
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TW94106903A
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Chinese (zh)
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TW200633225A (en
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Wen-Kuang Tsao
Hung-I Hsu
Hsiang-Hsien Chung
Min-Huang Chen
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Chunghwa Picture Tubes Ltd
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  • Thin Film Transistor (AREA)

Abstract

A thin film transistor including a gate, a gate insulating layer, a semiconductor layer and a source/drain is provided. The gate is disposed over a substrate, wherein the gate comprises at least one layer of aluminum-yttrium alloy nitride. The gate insulating layer is formed over the substrate to cover the gate. The semiconductor layer is disposed over the gate insulating layer above the gate. The source/drain is disposed over the semiconductor layer.

Description

1247433 15379twf.doc/g 九、發明說明: 【發明所屬之技術領域】 本發明是有關於一種半導體元件及其製作方法,且特 別是有關於一種薄膜電晶體及其製作方法。 【先前技術】 薄膜電晶體(TFT)—般包括閘極、閘絕緣層、通道層 與源極/汲極,其通常在顯示器中,例如是如液晶顯示器 (LCDj,是作為開關元件之用。通常,薄膜電晶體的形成 方法是在基底上依序形成閘極、閘絕緣層、a_Si通道層與 源極/没極。閘極是由銘、絡、鎢、组、鈦等的單一金属層 或是由複數金屬層所組成。 然而,导以單一層的上述金屬形成閘極時,膜層表面 容易被做,且料魏反應而形成金射…物,因而導 ^在後續的似|燦程中紐有效地進行侧。另一方面, 二閘極是域層金屬層所組柄,其例如為鉬(施)辅目, 二和侵姓的問題。但是形成數層金屬層的製程 材以及、㈤為此製程需要超過—個以上的減鑛輕 源極此外,上制題㈣齡射在形成 【發明内容】 電阻5電3=提出—種薄膜電晶體,其具有較低接觸 %阻次、、泉電阻的閘極與源極/汲極。 本發明另提出一種薄膜電晶體的形成方法, 和抗侵崎梢細細極和咖極/汲極。 1247433 15379twf.doc/g 本發明係提出-種薄膜電晶體,此薄膜電晶體包括間 極、閘絕緣層、半導體層以及源極/汲極。閘鋪配置於基 底上,'其中,閘極包括至少—層氮化她合金。閘絕緣層 係形成於基底上以覆蓋祕。半導體層係配置於基底上之 閘絶緣層上。源極/>及極係配置於半導體層上。 本發明另提出一種薄膜電晶體‘,此薄曰膜電晶體包括閘 極、閘絕緣層、半導體相及源極/汲極。祕係配置於基 底上。_緣層係形成於基底上哺蓋·。半導體層係 配置於基底上n緣層上。雜/ & _配置於半導體層 上’其中’源極/沒極包括至少一層氮化紹紀合金。 尸在本發明-實施例中,上述之間極係由錄合金層與 氮化鋁纪合金層所組成。 入在本發明一實施例中,上述之問極係由第一氣化細乙 &金層、她合金層與第二氮化她合金層所組成。 f本發明一實施例中,上述之源極/汲極係由她合金 層與氮化紹紀合金層所組成。 在本购—實施射,上述之齡織極係由第-氮化 航合金層、減合金層與第二氮化诚合金層所組成。 本發明另提出「_膜.電晶體的形成方法,此方法先 ^基底上形成閘極。其中’閘極包括至少—層氮化減合 =°然後’於基底上形賴絕緣層以覆蓋閘極。之後,於 基底上的_緣層上配置半導體層^下來,於半導體層 上配置源極/汲極。 本發明又提出一種_電晶體的形成方法,此方法係 1247433 15379twf.doc/g $於基底上形成閘極。接著,於基底上形成閘絕緣層以覆 蓋閘極。之後,於基底上的閘絕緣層上形成半導體層。接 下來,於半導體層上形成源極/汲極。其中,源極/汲極包 括至少一層氮化鋁釔合金。 在本發明-實施例中,上述之閘極和(或)源極/汲極係 以下述之步驟形成。首先於基底上形成鋁釔合金層。並且 • ,鋁釔合金層進行氮化步驟,以形成氮化鋁釔合金層。接 • 著將氮化鋁釔合金層圖案化以形成閘極和(或)源極/汲極。 /在本發明之-實施例中,上述之閘極和(或)源極/沒極 係以下述之步成。首先於基底上形成第—射乙合金 層^後於第-減合金層上形成第二減合金層。並且 , 對第,1祕合金層進行氮化步驟,⑽第—減合金層上 形成氮化她合金層。之後將氮化紹紀合金層與第一紹紀 合金層圖案化以形成閘極和(或)源極/汲極。 /林發明之-實施例中,上述之閘極和(或)源極/汲極 #、以下述之步_成。首先,於基底上軸第—減合金 擊 @。並且,對第-減合金層進行第—氮化步驟,以形成 ' ^氮化她合金層。接著,於第—氮化減合金層上形 • iU二減合金層。之後,於第二氮化減合金層上形成 弟三減合金層。並且,對第三她合金層進行第二氮化 步,’以於第二合金層上形成第二氮化減合金層。 接著,將第二氮化減合金層、第二銘紀合金層與第一氮 化她合金層®案化,以形成_和⑷雜/汲極。 ' 本發明之薄膜電晶體的電極(閘極和(或)源極/没極)包 1247433 15379twf.doc/g 比較起來 佳的抵抗性 一二層氮化鋁釔合金,其因為在鋁釔合金的表面上有 一I:,保護薄膜,所以與習知技術中使用的金屬合金 • ° ",較為穩定,以致於電極對於氧化與侵蝕具有較 為縣發明之上述和其他目的、特徵和優點能更明顯 紅’下文特舉較佳實闕,並配合賴㈣,作詳細說 %如下。 【實施方式】 圖二繪不為依照本發明一較佳實施例之薄膜電晶體的 二面不意圖。請參照圖1,薄膜電晶體包括閘極102、閘絕 酉層104、半導體層105以及源極/汲極110。閘極102係 配置於基底1〇〇上,而閘絕緣層1〇4係配置於基底1㈨上 方以覆夢間極102。間絕緣層1〇4例如是由氧化石夕層、氮 匕矽層或氧化矽層與氮化矽層的組合層所構成。半導體層 W5係配置於閘極1〇2上方的閘絕緣層ι〇4上。汲 U0係配置於半導體層1〇5上。在本實施例中,半導體層 105例如包括形成於閘絕緣層104上的通道層106與形成 於通道層106和源極/汲極11〇之間的歐姆接觸層丨〇8。 I特別是,依照本發明之一較佳實施例,閘極1〇2包括 至J 一層氮化鋁釔合金。換句話說,閘極1〇2可以是單層 =氮化鋁釔合金或包括至少一層氮化鋁釔合金的複合層。 右閘極102為單層,則閘極1〇2係由氮化鋁釔合金層所組 成。在本實施例中,形成單層之閘極1〇2的方法如以下步 里取 , ^首先’在錢鑛製程室、蒸鍍製程室或其他習知的沈積 1247433 15379twf.doc/g 至中,於基底100上形成一層鋁釔合金層。並且,對鋁釔 合金層進行氮化步驟,以形成氮化鋁釔合金層。其中,上 述之氮化步驟例如是在形成鋁記合金層之後,於沈積室中 通入氮氣即可。或者是,於形成鋁釔合金層的同時通入氮 氣至’尤積至中,以形成氮化銘紀合金層。之後,利用微影 製私與钱刻製程將氮化紹紀合金層圖案化,以形成閘極 102 〇 右間極102為雙層結構’則間極1 〇2係由铭紀合金層 102a與氮化鋁釔合金層i〇2b所組成。請參照圖2A,在本 例中’形成雙層閘極102的方法如以下步驟。首先,於基 底100上形成第一铭紀合金層l〇2a。然後,於第一铭紀合 金層102a上形成第二鋁釔合金層(未繪示)。並且,對第二 紹紀合金層進行氮化反應步驟,以形成氮化鋁釔合金層 102b。之後,將氮化鋁釔合金層1〇2b與第一鋁釔合金層 102a圖案化,以形成閘極1〇2。第一鋁紀合金層i〇2a與第 一紹紀合金層係以先前所述的方法所形成,而氮化反應步 驟也是以先前所述的相同方法進行。 若閘極102為三層結構,則閘極102係由第一氮化鋁 妃合金層102c、鋁纪合金層l〇2d以及第二氮化鋁紀合金 層102e所組成,請參照圖3A。在本實施例中,形成三層 之閘極102的方法如以下步驟。首先,於基底1〇〇上形成 第一鋁釔合金層(未繪示)。並且,對第一鋁釔合金層進行 如上述之氮化步驟,以形成第一氮化鋁纪合金層l〇2c。然 後,於第一氮化鋁釔合金層l〇2c上形成第二鋁釔合金層 1247433 15379twf.doc/g 102d。接著,於第二鋁釔合金層102d上形成第三鋁釔合金 層(未繪示)。並且,對第三鋁釔合金層進行如上述之氮化 步驟,以形成第二氮化鋁釔合金層1〇2e。然後,將第二氮 化銘紀合金層l〇2e、第二鋁釔合金層i〇2d以及第一氮化 紹釔合金層l〇2c圖案化,以形成閘極1〇2。 在另一貫加例中’源極/>及極110包括至少一層氮化銘 名乙合金’凊參照圖1。換句話說,源極/j;及極1可以是單 . 層的氮化紹紀合金或包括至少一層氮化銘記合金的複合 層。若源極/汲極110為單層,則源極/汲極11()係由氮化 鋁釔合金層所組成。同樣地,形成單層源極/汲極11()的方 法如以下步驟。首先,在濺鍍製程室、蒸鍍製程室或其他 熟知的沈積室中,於閘絕緣層104上形成鋁釔合金層,以 覆蓋半導體層105。並且,對鋁釔合金層進行氮化步驟, 以形成氮化鋁釔合金層,其中,上述之氮化步驟例如是在 形成鋁釔合金層之後,於沈積室中通入氮氣即可。或者是, 於形成紹紀合金層的同時通入氮氣至沈積室中,以形成氮 ►化鋁釔合金層。之後',將氮化鋁釔合金層圖案化,以形成 源極/汲極110。 若源極/汲極110為雙層結構,則源極/汲極11〇係由 銘紀合金層110a與氮化鋁釔合金層110b所組成,請參照 圖2B。同樣地,形成雙層之源極/汲極11()的方法如以下 步驟。首先,於閘絕緣層104上形成第一鋁釔合金層n〇a, 以覆蓋半導體層105。然後,於第一鋁紀合金層n〇a上形 成第二鋁釔合金層(未繪示)。並且,對第二鋁釔合金層進 1247433 15379twf.doc/g 行氮化步驟,以形成氮化鋁釔合金層110b。之後,將氮化 鋁釔合金層ll〇b與第一鋁釔合金層ii〇a圖案化,以形成 源極/汲極110。第一紹纪合金層ll〇a與第二紹紀合金層係 以先前所述的方法所形成,而氮化步驟也是以先前所述的 相同方法進行。 當源極/汲極110為三層結構,則源極/汲極U0係由 八 第一氮化鋁釔合金層110c、鋁釔合金層ii〇d以及第二氮 φ 化鋁釔合金層110e所組成,請參照圖3B。相同地,形成 三層之源極/汲極110的方法如以下步驟。首先,於閘絕緣 層104上形成第一鋁釔合金層(未繪示),以覆蓋半導體層 105。並且,對第一鋁釔合金層進行如上述之氮化步驟,以 形成第一氮化鋁釔合金層ll〇c。然後,於第一氮化鋁釔合 金層110c上形成第二鋁釔合金層11〇d。接著,於第二鋁 釔,金層110d上形成第三鋁釔合金層(未繪示)。並且,對 第三銘紀合金層進行如上述之氮化步驟,以形成第二氮化 铭紀合金層ll〇e。然後,將第二氮化鋁釔合金層u〇e、第 • 二尬合金層UGd以及第-氮化減合金層llGc圖案 - 化,以形成源極/汲極110。 、在,貝知例中,閘極102與源極/汲極110皆包括至 J 一層氮化魏合金層。換句話說,閘極1()2與源極/汲極 =皆可=是單層的氮化銘齡金或包括至少-層氮化紹 人爲金的複^層。上述包括至少一層氮化鋁釔合金層的複 〇 &可以疋雙層結構或三層結構,請參照圖2A、圖2B、 圖3A以及圖2B。 11BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a semiconductor device and a method of fabricating the same, and in particular to a thin film transistor and a method of fabricating the same. [Prior Art] A thin film transistor (TFT) generally includes a gate, a gate insulating layer, a channel layer, and a source/drain, which is usually used in a display such as, for example, a liquid crystal display (LCDj) as a switching element. Generally, a thin film transistor is formed by sequentially forming a gate, a gate insulating layer, an a_Si channel layer, and a source/danopole on a substrate. The gate is a single metal layer of Ming, Luo, Tung, Titanium, etc. Or consisting of a plurality of metal layers. However, when a single layer of the above-mentioned metal is used to form a gate, the surface of the film layer is easily made, and the material reacts to form a gold-emitting object, and thus the lead is in the subsequent Cheng Zhongxin effectively performs the side. On the other hand, the two gates are the handles of the domain metal layer, which are, for example, the molybdenum (application) auxiliary, the second and the invading problem. However, the process material for forming several metal layers is formed. And (5) for this process, more than one or more of the ore-reducing light source is required. In addition, the above-mentioned problem (four) age is formed. [Inventive content] Resistor 5 electricity 3 = proposed thin film transistor with lower contact % resistance The gate of the secondary, spring resistance and the source/drain. The present invention A method for forming a thin film transistor, and an anti-aggression fine pole and a coffee pole/dip pole are proposed. 1247433 15379twf.doc/g The present invention proposes a thin film transistor including a interlayer electrode and a gate insulating layer. a layer, a semiconductor layer, and a source/drain. The gate is disposed on the substrate, wherein the gate includes at least a layer of nitrided alloy. The gate insulating layer is formed on the substrate to cover the secret. The semiconductor layer is disposed on the substrate. On the insulating layer of the upper gate, the source/> and the pole are disposed on the semiconductor layer. The present invention further provides a thin film transistor which includes a gate, a gate insulating layer, a semiconductor phase and a source /Bunge. The secret system is disposed on the substrate. The edge layer is formed on the substrate. The semiconductor layer is disposed on the n-edge layer on the substrate. The impurity / & _ is disposed on the semiconductor layer 'where the source / immersing comprises at least one layer of nitriding alloy. In the present invention - the embodiment, the intermediate layer is composed of a recorded alloy layer and an aluminum nitride alloy layer. In an embodiment of the invention, The first line is made of the first gasified fine B & gold layer The alloy layer and the second nitrided alloy layer are composed of the same. In an embodiment of the invention, the source/drainage system is composed of a layer of the alloy and a nitrided alloy layer. The above-mentioned age is composed of a first-nitriding alloy layer, a reduced alloy layer and a second nitrided alloy layer. The present invention further proposes a method for forming a film of a transistor. Forming a gate thereon, wherein the 'gate includes at least one layer of nitride reduction=° and then the insulating layer is formed on the substrate to cover the gate. Thereafter, the semiconductor layer is disposed on the layer on the substrate. The source/drain is disposed on the semiconductor layer. The present invention further provides a method of forming a transistor, which is 1247433 15379 twf.doc/g $ forms a gate on the substrate. Next, a gate insulating layer is formed on the substrate to cover the gate. Thereafter, a semiconductor layer is formed on the gate insulating layer on the substrate. Next, a source/drain is formed on the semiconductor layer. Wherein, the source/drain includes at least one layer of aluminum nitride. In the present invention-embodiment, the above-described gate and/or source/drain are formed in the following steps. First, an aluminum-bismuth alloy layer is formed on the substrate. And • the aluminum-niobium alloy layer is subjected to a nitriding step to form an aluminum nitride tantalum alloy layer. A layer of aluminum nitride bismuth alloy is patterned to form a gate and/or a source/drain. / In the embodiment of the invention, the above-mentioned gate and/or source/no-pole are formed in the following steps. First, a first alloy layer is formed on the substrate, and then a second alloy layer is formed on the first-minus alloy layer. Further, a nitriding step is performed on the first, first alloy layer, and a nitrided alloy layer is formed on the (10) first-minus alloy layer. The nitrided alloy layer is then patterned with the first Saoki alloy layer to form a gate and/or source/drain. In the embodiment, the above-mentioned gate and/or source/drainage # are formed in the following steps. First, the first axis on the substrate is reduced to the alloy. Further, the first-nitriding layer is subjected to a first nitridation step to form a '^ nitrided alloy layer. Next, an iU diminishing alloy layer is formed on the first-nitrided alloy layer. Thereafter, a third reduction alloy layer is formed on the second nitride-reduced alloy layer. And, a second nitridation step is performed on the third alloy layer to form a second nitride-reduced alloy layer on the second alloy layer. Next, the second nitrided alloy layer, the second alloy layer and the first nitrided alloy layer are patterned to form _ and (4) hetero/deuterium. The electrode of the thin film transistor of the present invention (gate and/or source/no-pole) package 1247433 15379twf.doc/g is a better resistance to a two-layer aluminum nitride tantalum alloy, which is used in aluminum-bismuth alloy. There is an I:, protective film on the surface, so it is more stable with the metal alloy used in the prior art, so that the electrode has more of the above and other purposes, features and advantages of the county invention for oxidation and erosion. Obviously red' The following is a better example, and with Lai (4), the details are as follows. [Embodiment] FIG. 2 is not a schematic view of a two-sided film transistor according to a preferred embodiment of the present invention. Referring to FIG. 1, the thin film transistor includes a gate 102, a gate insulating layer 104, a semiconductor layer 105, and a source/drain 110. The gate 102 is disposed on the substrate 1B, and the gate insulating layer 1〇4 is disposed above the substrate 1 (9) to cover the dream pole 102. The interlayer insulating layer 1〇4 is composed of, for example, a combination of a oxidized stone layer, a ruthenium nitride layer, or a ruthenium oxide layer and a tantalum nitride layer. The semiconductor layer W5 is disposed on the gate insulating layer ι 4 above the gate electrode 1〇2.汲 U0 is disposed on the semiconductor layer 1〇5. In the present embodiment, the semiconductor layer 105 includes, for example, a channel layer 106 formed on the gate insulating layer 104 and an ohmic contact layer 8 formed between the channel layer 106 and the source/drain 11b. In particular, in accordance with a preferred embodiment of the present invention, gate 1 〇 2 includes a layer of aluminum nitride bismuth alloy to J. In other words, the gate 1〇2 may be a single layer = an aluminum nitride tantalum alloy or a composite layer comprising at least one layer of aluminum nitride tantalum alloy. The right gate 102 is a single layer, and the gate 1〇2 is composed of an aluminum nitride-bismuth alloy layer. In this embodiment, the method of forming the gate 1〇2 of a single layer is as follows: ^ Firstly, in the money processing room, the evaporation process chamber or other conventional deposition 1247433 15379twf.doc/g to A layer of an aluminum-bismuth alloy is formed on the substrate 100. Further, a step of nitriding the aluminum-niobium alloy layer is performed to form an aluminum nitride-ruthenium alloy layer. Here, the nitriding step may be, for example, after the aluminum alloy layer is formed, and nitrogen gas may be introduced into the deposition chamber. Alternatively, nitrogen gas may be introduced into the aluminum-bismuth alloy layer to form a nitrided alloy layer. After that, the nitriding alloy layer is patterned by the lithography and the engraving process to form the gate 102. The right interpole 102 is a two-layer structure, and the interpole 1 〇2 is composed of the Mingji alloy layer 102a and The aluminum nitride tantalum alloy layer i〇2b is composed. Referring to Fig. 2A, the method of forming the double-layer gate 102 in this example is as follows. First, a first alloy layer l〇2a is formed on the substrate 100. Then, a second aluminum-bismuth alloy layer (not shown) is formed on the first layer of the alloy layer 102a. Further, a second nitriding alloy layer is subjected to a nitridation reaction step to form an aluminum nitride bismuth alloy layer 102b. Thereafter, the aluminum nitride tantalum alloy layer 1〇2b is patterned with the first aluminum-niobium alloy layer 102a to form the gate electrode 1〇2. The first aluminum alloy layer i〇2a and the first Shaoji alloy layer are formed in the manner previously described, and the nitridation reaction step is also carried out in the same manner as previously described. If the gate 102 has a three-layer structure, the gate 102 is composed of a first aluminum nitride yttrium alloy layer 102c, an aluminum alloy layer 〇2d, and a second aluminum nitride alloy layer 102e. Please refer to FIG. 3A. In the present embodiment, the method of forming the gate 102 of the three layers is as follows. First, a first aluminum-bismuth alloy layer (not shown) is formed on the substrate 1A. Further, the first aluminum-niobium alloy layer is subjected to a nitridation step as described above to form a first aluminum nitride alloy layer 10c. Then, a second aluminum-bismuth alloy layer 1247433 15379 twf.doc/g 102d is formed on the first aluminum nitride-bismuth alloy layer 10c. Next, a third aluminum-niobium alloy layer (not shown) is formed on the second aluminum-niobium alloy layer 102d. Further, the third aluminum-niobium alloy layer is subjected to a nitridation step as described above to form a second aluminum nitride-bismuth alloy layer 1〇2e. Then, the second nitriding alloy layer l〇2e, the second aluminum bismuth alloy layer i〇2d, and the first nitriding alloy layer l〇2c are patterned to form the gate 1〇2. In another example, the 'source/> and the pole 110 include at least one layer of nitriding alloy B. Referring to Figure 1. In other words, the source /j; and the pole 1 may be a single layer of nitrided alloy or a composite layer comprising at least one layer of nitrided alloy. If the source/drain 110 is a single layer, the source/drain 11 () is composed of an aluminum-niobium alloy layer. Similarly, the method of forming the single-layer source/drain 11 () is as follows. First, an aluminum-bismuth alloy layer is formed on the gate insulating layer 104 to cover the semiconductor layer 105 in a sputtering process chamber, an evaporation process chamber, or other well-known deposition chamber. Further, the aluminum-bismuth alloy layer is subjected to a nitriding step to form an aluminum nitride-bismuth alloy layer, wherein the nitriding step is carried out, for example, after the aluminum-bismuth alloy layer is formed, and nitrogen gas is introduced into the deposition chamber. Alternatively, nitrogen gas is introduced into the deposition chamber while forming a layer of the Shaoji alloy to form a nitrogen-alloyed aluminum alloy layer. Thereafter, the aluminum nitride bismuth alloy layer is patterned to form a source/drain 110. If the source/drain 110 is of a two-layer structure, the source/drain 11 is composed of an alloy layer 110a and an aluminum nitride alloy layer 110b. Please refer to Fig. 2B. Similarly, the method of forming the double-layer source/drain 11 () is as follows. First, a first aluminum-bismuth alloy layer n〇a is formed on the gate insulating layer 104 to cover the semiconductor layer 105. Then, a second aluminum-bismuth alloy layer (not shown) is formed on the first aluminum alloy layer n〇a. Further, the second aluminum-bismuth alloy layer is subjected to a nitridation step of 1247433 15379 twf.doc/g to form an aluminum nitride-bismuth alloy layer 110b. Thereafter, the aluminum bismuth alloy layer 11b and the first aluminum-bismuth alloy layer ii〇a are patterned to form the source/drain 110. The first Shaoji alloy layer 11a and the second Shaoji alloy layer are formed by the method previously described, and the nitriding step is also carried out in the same manner as previously described. When the source/drain 110 is a three-layer structure, the source/drain U0 is composed of an eight first aluminum nitride alloy layer 110c, an aluminum-niobium alloy layer ii〇d, and a second nitrogen-aluminized aluminum alloy layer 110e. Please refer to FIG. 3B for the composition. Similarly, the method of forming the three-layer source/drain 110 is as follows. First, a first aluminum-bismuth alloy layer (not shown) is formed on the gate insulating layer 104 to cover the semiconductor layer 105. Further, the first aluminum-niobium alloy layer is subjected to a nitridation step as described above to form a first aluminum nitride-bismuth alloy layer 11c. Then, a second aluminum-niobium alloy layer 11〇d is formed on the first aluminum nitride tantalum alloy layer 110c. Next, a third aluminum-bismuth alloy layer (not shown) is formed on the second aluminum layer and the gold layer 110d. Further, the third etched alloy layer is subjected to a nitriding step as described above to form a second nitriding alloy layer 11〇e. Then, the second aluminum nitride ruthenium alloy layer u〇e, the second bismuth alloy layer UGd, and the first-nitride reduction alloy layer llGc are patterned to form the source/drain 110. In the example, the gate 102 and the source/drain 110 include a layer of nitrided Wei alloy to J. In other words, the gate 1()2 and the source/drainage = can be a single layer of nitriding age gold or a layer comprising at least a layer of nitrided gold. The above composite layer comprising at least one layer of aluminum nitride bismuth alloy may be a two-layer structure or a three-layer structure. Please refer to FIGS. 2A, 2B, 3A and 2B. 11

1247433 15379twf.doc/g 值得注意的是,因為在銘纪合金的表面上係有— 化物保瘦細’所以纪合金層與習知技術中的金^ 合金比較妓更為穩定,以致於氮化尬合金層對於氧化 與侵兹具妹佳的抵抗性。換姑說,包括至少— 銘紀合金層的薄膜電晶體的電極對於氧化與錢具^較户 2抵抗性。特财,若軸三層的或三層的源極/沒^ 蚪’铭紀合金層會.夾在二層氮化銘紀合金層中間,以避 症呂紀合金層被氧化與侵姓。 α 另外銘紀5孟層的沈積製程以及氮化反應步驟,可 以在相_反魅(原位)巾進行。若形成雙層結構或三層 結構時,也可以在相同的反應室(原位)中進行。因此,^ 發明的.與㈤祕/汲極的製程並不獅,因 製程生產力。 开 一值得注意的是,若本發明之薄膜t晶體是作為液晶顯 示器的開關元件時,对使用雙層或三層的源極/沒極時, 在後續各晝素結構的接觸窗開口的蝕刻製程中,上層氮化 銘紀合金層表面的氮化物薄膜還可以當作姓刻終止^。 雖然本發明已以較佳實施例揭露如上,然其並^用以 限定本發明,任何熟習此技藝者,在不麟本發明之精神 t範圍内,當可作些許之更動與潤飾,因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 圖1繪示為依照本發明一較佳實施例之薄膜電晶體的 剖面示意圖。 _ 12 1247433 15379twf.doc/g 體的=:=::明另-較佳實施例之薄膜&脚之薄膜電 晶 曰曰1247433 15379twf.doc/g It is worth noting that, because the surface of the alloy is bonded to the surface of the alloy, the alloy layer is more stable than the gold alloy in the prior art, so that it is nitrided. The bismuth alloy layer is resistant to oxidation and intrusion. According to the exchange, the electrode of the thin film transistor including at least the alloy layer is resistant to oxidation and money. Special wealth, if the axis of the three-layer or three-layer source / no ^ 蚪 ' Ming Ji alloy layer will be sandwiched in the middle of the two layers of nitrite alloy layer, in order to avoid the oxidation of the alloy layer is oxidized and invaded. α In addition, the deposition process of the 5th layer and the nitridation reaction step can be carried out in the phase _ anti-magic (in situ) towel. If a two-layer structure or a three-layer structure is formed, it can also be carried out in the same reaction chamber (in situ). Therefore, the process of inventing and (5) secret/bungee is not a lion, because of process productivity. It is worth noting that if the thin film t crystal of the present invention is used as a switching element of a liquid crystal display, when a double/three-layer source/no-pole is used, etching of a contact window opening of each subsequent monocyte structure is performed. In the process, the nitride film on the surface of the upper nitriding alloy layer can also be terminated as a surname. Although the present invention has been disclosed in the above preferred embodiments, it is intended to limit the present invention, and those skilled in the art can make some modifications and refinements within the scope of the spirit of the present invention. The scope of the invention is defined by the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cross-sectional view showing a thin film transistor in accordance with a preferred embodiment of the present invention. _ 12 1247433 15379twf.doc / g body =: =:: Ming - the thin film of the preferred embodiment & film of the foot of the film 曰曰

圖3B繪示為依照本發明又—較佳實施例之薄膜電 體的三層源極/汲極的剖面示意圖。 【主要元件符號說明】 100 :基底 102 :閘極 102a、l〇2d、ll〇a、110d ··鋁記合金層 102b、l〇2c、l〇2e、110b、110c、ll〇e ··氮化鋁釔合 金層 104 :閘絕緣層 105 :半導體層 106 :通道層 108 ··歐姆接觸層 110 ·源極/沒極 13 d:3B is a cross-sectional view showing a three-layer source/drain of a thin film battery in accordance with still another preferred embodiment of the present invention. [Description of main component symbols] 100: Substrate 102: gate 102a, l〇2d, ll〇a, 110d · aluminum alloy layer 102b, l〇2c, l〇2e, 110b, 110c, ll〇e · nitrogen Aluminum bismuth alloy layer 104: gate insulating layer 105: semiconductor layer 106: channel layer 108 · ohmic contact layer 110 · source/dice 13 d:

Claims (1)

1247433 ’ 15379twf.doc/g 十、申請專利範圍: 1·一種薄膜電晶體,包括·· 一閘極,置於一基底上,其中該閘極包括至少一層氮 化鋁釔(A1-Y)合金; 曰 一閘絕緣層,形成於該基底上,以覆蓋該閘極; 一半導體層,配置於該閘極上之該閘絕緣層上;以及 一源極/汲極,配置於該半導體層上。 | 2·如申請專利範圍第1項所述之薄膜電晶體,其中該 閘極包括: 一鋁紀合金層;以及 一氮化紹紀合金層,配置於該銘紀合金層上。 3·如申請專利範圍第丨項所述之薄膜電晶體,其中該 閘極包括: 一第一氮化鋁釔合金層; 一鋁釔合金層,配置於該第一氮化鋁釔合金層上;以 及 &gt; 一第二氮化鋁釔合金層,配置於該鋁釔合金層上。 4·如申請專利範圍第1項所述之薄膜電晶體,其中該 源極/汲極包括至少一層氮化鋁釔合金。 5·如申請專利範圍第4項所述之薄膜電晶體,其中該 源極/汲極包括: 一鋁紀合金層;以及 一氮化鋁釔合金層,配置於該鋁釔合金層上。 6·如申請專利範圍第4項所述之薄膜電晶體,其中該 1247433 15379twf.doc/g 源極/汲極包括: 一第一氮化銘纪合金層; 一銘紀合金層,配置於該第一氮化铭紀合金層上;以 及 一第二氮化鋁釔合金層,配置於該鋁紀合金層上。 7 · —種薄膜電晶體,包括: &quot; 一閘極; | 一閘絕緣層,配置於該基底上,以覆蓋該閘極; 一半導體層,配置於該閘極上之該閘絕緣層上;以及 一源極/汲極,配置於該半導體層上,其中該源極/没 極包括至少一層氮化鋁釔合金。 8·如申請專利範圍第7項所述之薄膜電晶體,其中該 源極/汲極包括: ^ 一鋁釔合金層;以及 一氮化鋁釔合金層,配置於該鋁釔合金層上。 9·如申請專利範圍第7項所述之薄膜電晶體,其中該 ► 源極/汲極包括: 一第一氮化鋁纪合金層; 一鋁釔合金層,配置於該第一氮化鋁釔合金層上;以 及 一第二氮化鋁釔合金層,配置於該鋁釔合金層上。 10·—種薄膜電晶體形成方法,包括: 於一基底上形成一閘極,其中該閘極包括至少一層氮 化铭紀合金;1247433 ' 15379twf.doc / g X. Patent application scope: 1. A thin film transistor comprising: a gate placed on a substrate, wherein the gate comprises at least one layer of aluminum nitride (A1-Y) alloy And a gate insulating layer formed on the substrate to cover the gate; a semiconductor layer disposed on the gate insulating layer on the gate; and a source/drain electrode disposed on the semiconductor layer. The thin film transistor according to claim 1, wherein the gate comprises: an aluminum alloy layer; and a nitrided alloy layer disposed on the alloy layer. 3. The thin film transistor according to claim 2, wherein the gate comprises: a first aluminum nitride bismuth alloy layer; an aluminum bismuth alloy layer disposed on the first aluminum nitride bismuth alloy layer And a second aluminum arsenide alloy layer disposed on the aluminum-bismuth alloy layer. 4. The thin film transistor of claim 1, wherein the source/drain includes at least one layer of aluminum nitride. 5. The thin film transistor of claim 4, wherein the source/drain includes: an aluminum alloy layer; and an aluminum nitride alloy layer disposed on the aluminum-bismuth alloy layer. 6. The thin film transistor according to claim 4, wherein the 1247433 15379 twf.doc/g source/drain includes: a first nitriding alloy layer; an epoch alloy layer disposed thereon a first nitriding alloy layer; and a second aluminum nitride yttrium alloy layer disposed on the aluminum alloy layer. 7 - a thin film transistor, comprising: &quot; a gate; | a gate insulating layer, disposed on the substrate to cover the gate; a semiconductor layer, disposed on the gate insulating layer of the gate; And a source/drainage layer disposed on the semiconductor layer, wherein the source/drain electrode comprises at least one layer of aluminum nitride alloy. 8. The thin film transistor according to claim 7, wherein the source/drain includes: an aluminum-bismuth alloy layer; and an aluminum nitride-ruthenium alloy layer disposed on the aluminum-bismuth alloy layer. 9. The thin film transistor of claim 7, wherein the source/drain includes: a first aluminum nitride alloy layer; an aluminum tantalum alloy layer disposed on the first aluminum nitride And a second aluminum nitride bismuth alloy layer disposed on the aluminum bismuth alloy layer. A method for forming a thin film transistor, comprising: forming a gate on a substrate, wherein the gate comprises at least one layer of a nitrided alloy; 1247433 15379twf.doc/g 於該基底上形成一閘絕緣層以覆蓋該閘極; 於該閘絕緣層上形成一半導體層;以及 於該半導體層上形成一源極/汲極。 11·如申請專利範圍第10項所述之薄膜電晶體形成方 法,其中形成該閘極的步驟包括: 於該基底上形成一銘紀合金層; 對該鋁釔合金層進行一氮化步驟以形成一氮化鋁釔 I 合金層,其中该氮化步驟是在形成該紹紀合金層之後進 行,或是在沈積該鋁釔合金層的時候進行;以及 將該氮化鋁紀合金層圖案化以形成該閘極。 12·如申請專利範圍第1〇項所述之薄膜電晶體形成方 法,其中形成該閘極的步驟包括: 於該基底上形成一第一鋁釔合金層; 於該第一鋁釔合金層上形成一第二鋁釔合金層; 對該第二鋁釔合金層進行一氮化步驟以於該第一鋁 釔合金層上形成一氮化鋁釔合金層,其中該氮化步驟是在 | 形成該第二鋁釔合金層之後進行,或是在沈積該第二鋁釔 合金層的時候進行;以及 將該氮化銘紀合金層與該第一鋁釔合金層圖案化以 形成該閘極。 13·如申請專利範圍第1〇項所述之薄膜電晶體形成方 法’其中形成该閘極的步驟包括: 於該基底上形成一第一鋁釔合金層; 對該第一鋁釔合金層進行一第一氮化步驟以形成一 1247433 15379twf.doc/g 第-氮化脑合金層,其中該第一氮化步驟是在形成該第 二紹紀合金層之後進行,或是在沈積該第—減合金層的 時候進行; 於該第-氮化航合金層上形成—第二減合金層; 於該第二鋁釔合金層上形成一第三她合金層; . 對該第三減合金層進行-第二氮化步驟以於該第 .了她合金層上形成-第二氮化航合金層,其中該第二 鲁 氮化步驟疋在形成该第二紹紀合金層之後進行,或是在沈 積u亥弟二銘記合金層的時候進行;以及 片將該第二氮化鋁釔合金層、該第二鋁釔合金層與該第 一氮化鋁紀合金層圖案化以形成該閘極。 、14·如中請專利範圍帛10項所述之薄膜電晶體形成方 法,其中形成該源極/汲極的步驟包括: 於該閘絕緣層上形成一鋁釔合金層以覆蓋該半導體 層; _對該鋁釔合金層進行一氮化步驟以形成一氮化鋁釔 S金層,其中该氮化步驟是在形成該紹妃合金層之後進 行,或疋在沈積該銘記合金層的時候進行;以及 將該氮化鋁釔合金層圖案化以形成該源極/汲極。 、I5·如申請專利範圍第ίο項所述之薄膜電晶體形成方 法’其中形成該源極/汲極的步驟包括: 於該閘絕緣層上形成一第一鋁釔合金層以覆蓋該半 導體層; 於該第一鋁釔合金層上形成一第二鋁釔合金層; 17 1247433 15379twf.doc/g 對該第二㈣乙合金層進行—氮化步驟以於該第一結 紀合金層〃上形成—氮化攸合金層,其中錢化步驟是在 形成該第二触合金層之後進行,或是在沈積該第二減 合金層的時候進行;以及 、將該氮化銘紀合金層與第一減合金層圖案化以形 成該源極/没極。 、16·如U利範圍第1G項所述之薄膜電晶體形成方 法,其中开&gt;成該源極/没極的步驟包括: 於该閘絕緣層上形成一第一鋁釔合金層以蓋該 導體層; ^ ,该第一鋁釔合金層進行一第一氮化步驟以形成一 第一氮化鋁釔合金層,其中該第一氮化步驟是在形成該第 紹紀&amp;金層之後進行,或是在沈積該第一銘紀合金層的 時候進行; 於該第一氮化鋁釔合金層上形成一第二鋁釔合金層; 於该第二鋁紀合金層上形成一第三鋁紀合金層; 對該第三鋁釔合金層進行一第二氮化步驟以於該第 二銘紀合金層上形成一第二氮化鋁釔合金層,其中該第二 氮化步驟是在形成該第三鋁釔合金層之後進行,或是在沈 積該第三銘纪合金層的時候進行;以及 將該第二氮化鋁釔合金層、該第二鋁釔合金層與該第 一氮化銘紀合金層圖案化以形成該源極/汲極。 17·—種薄膜電晶體形成方法,包括·· 於一基底上形成一閘極; 18 : &gt; : 1247433 15379twf.doc/g 於該基底上形成一閘絕緣層以覆蓋該閘極; 於該閘極上之該閘絕緣層上形成一半導體; 於该半導體層上形成一源極/汲極,其中誃 包括至少一層氮化銘纪合金。 ^ ’、°及極 、18·如中請專利範圍第Π項所述之薄膜電晶體 法,其中形成该源極/汲極的步驟包括: .於該閘絕緣層上形成—她合金層以覆蓋該半導體 層, _ 對該減合金層進行—氮化步驟以形成—氮化 ,金層’其中該氮化步驟是在形成該純合金層之後進 行,或疋在沈積该紹紀合金層的時候進行;以及 將該氮化铭紀合金層圖案化以形成該源極/沒極。 、19.如申請專利範圍第17項所述之薄膜電晶體形成方 法,其中形成該源極/汲極的步驟包括·· 於该閘絕緣層上形成一第一鋁釔合金層以覆蓋 導體層; Τ 於該第一鋁釔合金層上形成一第二鋁釔合金層; 對該第二鋁釔合金層進行一氮化步驟以於該第一鋁 釔合金層上形成一氮化鋁釔合金層,其中該氮化步驟是在 形成該第二鋁釔合金層之後進行,或是在沈積該第二鋁釔 合金層的時候進行;以及 將該氮化鋁釔合金層與第一鋁釔合金層圖案化以形 成3亥源極/汲極。 20·如申請專利範圍第17項所述之薄膜電晶體形成方 1247433 15379twf.doc/g 法,其中形成該源極/汲極的步驟包括: 於该閘絕緣層上形成一第一鋁紀合金層以覆蓋該半 導體層; 對该第一鋁妃合金層進行一第一氮化步驟以形成一 第一氮化鋁釔合金層,其中該第一氮化步驟是在形成該第 一鋁釔合金層之後進行,或是在沈積該第一鋁釔合金層的 時候進行; 於該第一氮化鋁釔合金層上形成一第二鋁釔合金層; 於該第二鋁釔合金層上形成一第三鋁釔合金層; 對該第二鋁釔合金層進行一第二氮化步驟以於該第 二鋁釔合金層上形成一第二氮化鋁釔合金層,其中該氮化 ^驟是在形成該第三鋁釔合金層之後進行,或是在沈積該 第三鋁釔合金層的時候進行;以及 將戎第二氮化鋁釔合金層、該第二氮化鋁釔合金層與 該第一氮化鋁釔合金層圖案化以形成該源極/汲極。 201247433 15379twf.doc/g forming a gate insulating layer on the substrate to cover the gate; forming a semiconductor layer on the gate insulating layer; and forming a source/drain on the semiconductor layer. The method of forming a thin film transistor according to claim 10, wherein the step of forming the gate comprises: forming an alloy layer on the substrate; performing a nitridation step on the aluminum-bismuth alloy layer Forming an aluminum nitride 钇I alloy layer, wherein the nitriding step is performed after forming the sinter alloy layer, or during depositing the aluminum bismuth alloy layer; and patterning the aluminum nitride alloy layer To form the gate. 12. The method of forming a thin film transistor according to claim 1, wherein the step of forming the gate comprises: forming a first aluminum-bismuth alloy layer on the substrate; on the first aluminum-bismuth alloy layer Forming a second aluminum-bismuth alloy layer; performing a nitriding step on the second aluminum-bismuth alloy layer to form an aluminum nitride-bismuth alloy layer on the first aluminum-bismuth alloy layer, wherein the nitriding step is formed at | The second aluminum-bismuth alloy layer is then performed, or is performed while depositing the second aluminum-bismuth alloy layer; and the nitrided alloy layer and the first aluminum-bismuth alloy layer are patterned to form the gate. The method for forming a thin film transistor according to the first aspect of the invention, wherein the step of forming the gate comprises: forming a first aluminum-bismuth alloy layer on the substrate; and performing the first aluminum-bismuth alloy layer on the substrate a first nitriding step to form a 1247433 15379 twf.doc/g first-nitrite alloy layer, wherein the first nitriding step is performed after forming the second sinter alloy layer, or is deposited in the first When the alloy layer is reduced; forming a second alloy layer on the first-nitriding alloy layer; forming a third alloy layer on the second aluminum-bismuth alloy layer; Performing a second nitriding step to form a second nitrided alloy layer on the first alloy layer, wherein the second nitriding step is performed after forming the second layer of the alloy, or And depositing the second aluminum nitride bismuth alloy layer, the second aluminum bismuth alloy layer and the first aluminum nitride alloy layer to form the gate . The method for forming a thin film transistor according to claim 10, wherein the step of forming the source/drain includes: forming an aluminum-bismuth alloy layer on the gate insulating layer to cover the semiconductor layer; Forming a nitriding step on the aluminum-niobium alloy layer to form an aluminum nitride 钇S gold layer, wherein the nitriding step is performed after forming the Shaohao alloy layer, or when depositing the inscribed alloy layer And patterning the aluminum nitride bismuth alloy layer to form the source/drain. The method for forming a thin film transistor according to the invention of claim </ RTI> wherein the step of forming the source/drain includes: forming a first aluminum-bismuth alloy layer on the gate insulating layer to cover the semiconductor layer Forming a second aluminum-bismuth alloy layer on the first aluminum-bismuth alloy layer; 17 1247433 15379 twf.doc/g performing a nitridation step on the second (four)-ethyl alloy layer to form the first joint alloy layer Forming a layer of tantalum nitride alloy, wherein the step of molyzing is performed after forming the second contact alloy layer, or when depositing the second alloy layer; and A reduced alloy layer is patterned to form the source/no. The method of forming a thin film transistor according to the item 1G, wherein the step of forming the source/depolarization comprises: forming a first aluminum-bismuth alloy layer on the gate insulating layer to cover The first aluminum nitride alloy layer is subjected to a first nitridation step to form a first aluminum nitride tantalum alloy layer, wherein the first nitriding step is to form the first Shaoji & Thereafter, or when depositing the first alloy layer; forming a second aluminum-bismuth alloy layer on the first aluminum nitride alloy layer; forming a first layer on the second aluminum alloy layer a third aluminum nitride alloy layer is subjected to a second nitriding step to form a second aluminum nitride bismuth alloy layer on the second etched alloy layer, wherein the second nitriding step is After the forming of the third aluminum-bismuth alloy layer, or when depositing the third alloy layer; and the second aluminum nitride alloy layer, the second aluminum-bismuth alloy layer and the first The nitrided alloy layer is patterned to form the source/drain. 17. A method of forming a thin film transistor, comprising: forming a gate on a substrate; 18: &gt; : 1247433 15379 twf.doc / g forming a gate insulating layer on the substrate to cover the gate; A semiconductor is formed on the gate insulating layer of the gate; a source/drain is formed on the semiconductor layer, wherein the germanium comprises at least one layer of nitrided alloy. </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; Covering the semiconductor layer, _ performing a nitriding step on the alloying layer to form a nitridation, a gold layer, wherein the nitriding step is performed after forming the pure alloy layer, or immersing in the pillar alloy layer And at the same time; and patterning the nitrided alloy layer to form the source/no. 19. The method of forming a thin film transistor according to claim 17, wherein the step of forming the source/drain includes: forming a first aluminum-bismuth alloy layer on the gate insulating layer to cover the conductor layer Forming a second aluminum-bismuth alloy layer on the first aluminum-bismuth alloy layer; performing a nitriding step on the second aluminum-bismuth alloy layer to form an aluminum nitride-bismuth alloy on the first aluminum-bismuth alloy layer a layer, wherein the nitriding step is performed after forming the second aluminum-bismuth alloy layer, or when depositing the second aluminum-bismuth alloy layer; and the aluminum arsenide alloy layer and the first aluminum-bismuth alloy layer The layers are patterned to form 3 hp source/drain. The method of forming a thin film transistor according to claim 17, wherein the step of forming the source/drain includes: forming a first aluminum alloy on the gate insulating layer. a layer to cover the semiconductor layer; performing a first nitridation step on the first aluminum-bismuth alloy layer to form a first aluminum nitride-bismuth alloy layer, wherein the first nitriding step is to form the first aluminum-bismuth alloy After the layer is performed, or when depositing the first aluminum-bismuth alloy layer; forming a second aluminum-bismuth alloy layer on the first aluminum nitride-bismuth alloy layer; forming a layer on the second aluminum-bismuth alloy layer a third aluminum bismuth alloy layer; a second nitriding step of the second aluminum bismuth alloy layer to form a second aluminum arsenide alloy layer on the second aluminum bismuth alloy layer, wherein the nitriding layer is After the forming the third aluminum-bismuth alloy layer, or when depositing the third aluminum-bismuth alloy layer; and depositing the second aluminum nitride aluminum alloy layer, the second aluminum nitride alloy layer and the The first aluminum nitride bismuth alloy layer is patterned to form the source/drain . 20
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