TWI241161B - Active compound combinations for protecting animal hides and leather - Google Patents
Active compound combinations for protecting animal hides and leather Download PDFInfo
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- TWI241161B TWI241161B TW090122953A TW90122953A TWI241161B TW I241161 B TWI241161 B TW I241161B TW 090122953 A TW090122953 A TW 090122953A TW 90122953 A TW90122953 A TW 90122953A TW I241161 B TWI241161 B TW I241161B
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- Prior art keywords
- active compound
- skins
- cmk
- composition
- patent application
- Prior art date
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 21
- 241001465754 Metazoa Species 0.000 title claims abstract description 6
- 239000010985 leather Substances 0.000 title abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 29
- -1 iodopropynyl butanamidate Chemical compound 0.000 claims description 20
- KANAPVJGZDNSCZ-UHFFFAOYSA-N 1,2-benzothiazole 1-oxide Chemical compound C1=CC=C2S(=O)N=CC2=C1 KANAPVJGZDNSCZ-UHFFFAOYSA-N 0.000 claims description 10
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 5
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 4
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 244000005700 microbiome Species 0.000 claims description 3
- UBXYXCRCOKCZIT-UHFFFAOYSA-N biphenyl-3-ol Chemical compound OC1=CC=CC(C=2C=CC=CC=2)=C1 UBXYXCRCOKCZIT-UHFFFAOYSA-N 0.000 claims description 2
- ANUSOIHIIPAHJV-UHFFFAOYSA-N fenticlor Chemical compound OC1=CC=C(Cl)C=C1SC1=CC(Cl)=CC=C1O ANUSOIHIIPAHJV-UHFFFAOYSA-N 0.000 claims description 2
- 229950005344 fenticlor Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- JWZXKXIUSSIAMR-UHFFFAOYSA-N methylene bis(thiocyanate) Chemical compound N#CSCSC#N JWZXKXIUSSIAMR-UHFFFAOYSA-N 0.000 claims description 2
- 230000003641 microbiacidal effect Effects 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- DYQFCTCUULUMTQ-UHFFFAOYSA-N 1-isocyanatooctane Chemical compound CCCCCCCCN=C=O DYQFCTCUULUMTQ-UHFFFAOYSA-N 0.000 claims 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims 1
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 claims 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 229960005323 phenoxyethanol Drugs 0.000 claims 1
- 229960003500 triclosan Drugs 0.000 claims 1
- 241000228245 Aspergillus niger Species 0.000 description 8
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- HFOCAQPWSXBFFN-UHFFFAOYSA-N 2-methylsulfonylbenzaldehyde Chemical compound CS(=O)(=O)C1=CC=CC=C1C=O HFOCAQPWSXBFFN-UHFFFAOYSA-N 0.000 description 2
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- 241000221832 Amorphotheca resinae Species 0.000 description 2
- 241001123663 Penicillium expansum Species 0.000 description 2
- 241000223261 Trichoderma viride Species 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 230000002079 cooperative effect Effects 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229940070805 p-chloro-m-cresol Drugs 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- NPOMAIJXMCXWGP-UHFFFAOYSA-N (cyanatodisulfanyl) cyanate Chemical compound N#COSSOC#N NPOMAIJXMCXWGP-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- UJVBZCCNLAAMOV-UHFFFAOYSA-N 2h-1,2-benzothiazine Chemical compound C1=CC=C2C=CNSC2=C1 UJVBZCCNLAAMOV-UHFFFAOYSA-N 0.000 description 1
- PILWLJVFXLZGMS-UHFFFAOYSA-N 3-octyl-1,2-thiazol-4-one Chemical group CCCCCCCCC1=NSCC1=O PILWLJVFXLZGMS-UHFFFAOYSA-N 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 241000374462 Aspergillus pseudoglaucus Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical compound CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 241000235527 Rhizopus Species 0.000 description 1
- 240000005384 Rhizopus oryzae Species 0.000 description 1
- 235000013752 Rhizopus oryzae Nutrition 0.000 description 1
- 244000290333 Vanilla fragrans Species 0.000 description 1
- 235000009499 Vanilla fragrans Nutrition 0.000 description 1
- 235000012036 Vanilla tahitensis Nutrition 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- SURLGNKAQXKNSP-DBLYXWCISA-N chlorin Chemical compound C\1=C/2\N/C(=C\C3=N/C(=C\C=4NC(/C=C\5/C=CC/1=N/5)=CC=4)/C=C3)/CC\2 SURLGNKAQXKNSP-DBLYXWCISA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 230000007773 growth pattern Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000005031 thiocyano group Chemical group S(C#N)* 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/02—Curing raw hides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Description
1241161 A7 B7 五、發明說明（i ) 本發明係相關於一含盼活性化合物與殺真菌活性化 α物之活性化合物組成物之使用，用轉存動物之生皮與 熟皮。 已知酚類衍生物及其混合物，或其配方可用為熟皮 5製造過程中保護材料之組成物。然而，目前也發現這些化 合物，不論是單獨使用或結合使用，並無法在經過一段時 間後，有效地保護所儲存之生皮與熟皮不受微生物的破 壞。 目前更進一步知道，苯并咪唑、咪唑、三唑，及/或 10馬琳竹生物與紛化合物結合使用，可在製造與保存過程中 保濩生皮與熟皮(US 5 888 415)。亦已知使用2-氫硫基吡 贫-Ν-氧化物及其鹽類可保護熟皮(w〇 98/56959)。 經濟部智慧財產局員工消費合作社印製 令人意外地，目前已發現將某些殺真菌活性化合 物，如氫硫基笨并噻唑、亞曱基雙硫氰酸鹽、硫氰基曱基 15硫苯并噻唑(TC]V[TB)、苯并異噻唑啉酮(ΒΙΤ)、辛基異噻 唑啉酮（0ΙΤ)、二氣辛基異噻唑啉酮(DCOIT)、四氣異苯 腈、碘丙炔基丁胺曱酸鹽(IPBC)、二碘甲基ρ-甲苯基砜、 Ν-環己基苯并σ塞吩_2_羧基醯胺5,5_二氧化物，以及二硫_ 2,2’-雙苄基曱基醯胺與特殊酚活性化合物結合，相當適用 2〇 於保存動物之生皮與熟皮。 適用之酚活性化合物較佳為酚衍生物，如三溴酶、 二鼠紛、硝基盼、3-曱基-4-氣盼、3,5-二曱基-4-氣盼、笨 氧基乙醇、二氣酚、鄰-苯基苯酚、間_苯基苯酚、對_苯基 苯紛、2-苄基_4_氯酚(chlorophene)、2,4·二氯-3,5-二甲基
經濟部智慧財產局員工消費合作社印製 1241161 at B7 五、發明說明（2) 盼、4_氯瑞香草紛、三氣松（triclosan)、盼提氣 (fentichlor)，及其錄鹽、驗金屬鹽與驗土金屬鹽類，或上 述之混合物。 較佳之組成物為包含3,5-二曱基-4氯酚、2-苄基-4-5 氯酚(BP)、3-曱基-4-氣酚(CMK)及/或〇-苯基苯酚(OPP)為 盼組成份，或上述提及之一或多種殺真菌劑。 下列為特別指定之組合物： CMK/氫硫基苯并噻唑 CMK/亞曱基雙硫氰酸鹽 10 CMK/硫氰基曱基硫苯并噻唑(TCMTB) CMK/苯并異噻唑啉酮(BIT) CMK/辛基異噻唑啉酮(0IT) CMK/二氯辛基異噻唑啉酮(DCOIT) CMK/碘丙炔基丁胺甲酸鹽(IPBC) 15 CMK/二碘甲基對·曱苯基砜 CMK/N-環己基苯并噻吩-2-羧基醯胺S，S-二氧化物 0PP/氫硫基苯并咪唑 0PP/亞曱基雙硫氰酸鹽 20 0PP/硫氰基甲基硫苯并噻唑(TCMTB) OPP/苯并異噻唑啉酮(BIT) 0PP/辛基異噻唑啉酮(0IT) 0PP/二氯辛基異噻唑啉酮(DC0IT) 0PP/碘丙炔基丁胺甲酸鹽(IPBC) -4- 本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公釐）
A7 B7 1241161 五、發明說明（3 ) OPP/二碘甲基對-甲苯基砜 OPP/N-環己基苯并噻吩_2-羧醯胺s，s-:氧化物 CMK/OPP/氫硫基笨并噻唾 5 CMK/OPP/亞甲基雙硫氰酸鹽 CMK/OPP/硫氰基甲基硫苯并嗔嗤(TCMTB) CMK/OPP/苯并異π塞嗤琳酮(bit) CMK/OPP/辛基異嗔嗤琳酮(〇工τ) CMK/OPP/二氣辛基異噻唑淋酮(DC〇IT) 10 CMK/OPP/峨丙炔基丁胺甲酸鹽(ipbc) CMK/OPP/二碘甲基對-甲苯基砜 CMK/OPP/N-環己基苯并噻吩冬羧基醯胺s，s•二氧 化物 15 CMK/B P/氫硫基苯并噻唑 CMK/BP/亞甲基雙硫氰酸鹽 CMK/BP/硫氰基甲基硫苯并噻嗤(TcmTB) CMK/BP/苯并異噻唑琳酮(BIT) 經濟部智慧財產局員工消費合作社印製 CMK/BP/辛基異噻唑啉酮(οιτ) 2〇 CMK/BP/二氯辛基異噻唑啉酮(DCOIT) CMK/BP/碳丙炔基丁胺曱酸鹽(ipbc) CMK/BP/二碘曱基對-曱苯基砜 CMK/BP/N-環己基苯并噻吩-2-羧基醯胺S，S-二氧化 本紙張尺度適用中國國家標準(CNS)A4規格（210x297公釐） A7 B7 1241161 五、發明說明（4) 上述殺真菌劑與酚化合物皆為已知，請參照 “Microbicides for the Protection of Materials, Chapmann&Hall，1993”之範例。 5 一般而言，組合物中所使用之上述酚化合物為5至 200份重，較佳為1〇至1〇〇份重，更佳為12至50份重配 合每份重之一或多種之殺黴菌劑。 若根據本發明所述之組合物存在兩種或以上紛化合 物，它們之相對比例範圍可在相當廣限制變化。適用之比 10 例可以習知實驗之簡單方式決定。 原則上，兩酚化合物之重量比例為1:1至1:10。 若0PP同時與CMK存在於本發明之組合物中，較 佳重量比為0PP:CMK為1:1至1:5。 令人意外地，本發明之組合物有協乘效果，組合物 15 之效果超越單一活性化合物之效果。 一般而言，本發明之活性化合物組合物係為配方形 式。使用濃度較佳為0.1至1之活性化合物或活性化合物 混合物，相對於欲保護生皮或熟皮。 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 配方成份為包含活性化合物混合物之量較佳為10-20 50%。一般而言，成份中更進一步包含如下成份·〜3〇% 鹼金屬及/或鹼土金屬氫氧化物；〇_2〇%離子性及/或非離 子性乳化物；5-60%有機溶劑，如特別是，甘油、酮類、 乙二醇喊類、醇類如乙醇 '甲醇、丨，2_丙二醇、n_丙醇， 以及0-0.5%香味物質與香料。剩餘物為水或有機溶劑， A7 B7 1241161 五、發明說明（5) 如1，2-丙二酵。百分比為重量比。 上述依發明製備之活性化合物混合物與組成物一般 可應用於在熟闢製造過程中，保護生皮不受微生物的破 壞。特別適用於抗曲黴屬真菌Aspergillus niger、曲黴屬真 5 菌 Aspergillus repens、Hormoconis resinae、Penicillium glaucum 以及 Trichoderma viride，其中 Penicillium 種如 P. citrinum、P. glaucum、Paecilomyces variotii、Cladosporium species 以及 Mucor species 如 Mucor mucedo、Rhizopus species 如 Rhizopus oryzae、Thizopus rouxii 等，皆可完 10 全抑制且維持效果。 以下範例用以說明本發明，但不侷限於此。 範例1 洋菜培養基種入 Aspergillus niger、Aspergillus 15 repens、Trichoderma viride、Penicillium glaucum 以及 Hormoconis resinae孢子。加入混合物I、ii與in之濕藍 色樣品，置入洋菜培養基，並置於20至30°C中28天，空 氣相對溼度為95%。 經濟部智慧財產局員工消費合作社印製 混合物II 10份重辛基異噻唑啉酮
混合物I 30份重對-氯-間-甲酚 13份重鄰-苯基苯酚
混合物III 30份重對·氯·間-甲盼 本紙張尺度適用中國國家標準(CNS)A4規格（210x297公釐） 1241161 A7 B7 五、發明說明（6) 10份重2-苄基-4-氣酚 2份重辛基異噻唑啉酮 濕藍色物以混合物I與II保存，培養至少10天時間 後，觀察試驗樣品之生長模式。混合物III培養20天時間 後，觀察並無任何生長情況。 範例2
酉己方I
30份重對-氯-間·甲酚 13份重鄰-苯基苯酚 2份重辛基異噻唑啉酮 12份重NaOH
14份重1，2-丙二醇 至100份重之剩餘物：水 配方II 27份重對-氣-間-甲酚 12份重2-苄基-4氯酚 1份重辛基異噻唑啉酮 至100份重之剩餘物 丙二醇 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格（210x297公釐）
Claims (1)
1241161 A8 B8 C8 D8
六、申請專利範圍 專利申請案第90122953號 ROC Patent At 修正後無劃線之&請、 Amended Claims _ (民國94萃6月b日送呈） (Submitted on June t ? 2005) 茶笫yui22y5j锨 ^ppln. No.90122953 •專利範圍中文本一附件(一） is in Chinese - Enel. (Ί)^ 10 15 20 經濟部智慧財產局員工消費合作社印製 2. 25 3. 一種具有殺真菌活性之組合物，其包含選自於氫琉基 苯并噻唑、亞甲基雙硫氰酸鹽、硫氰基甲基硫笨并^ 唑(TCMTB)、苯并異噻唑啉酮(BIT)、辛基異噻唑啉_ (OIT)、二氣辛基異噻唑啉酮(DC0IT)、四氣異苯猜、 碘丙炔基丁胺曱酸鹽(IPBC)、二碘甲基對-甲苯基砚、 N_環己基苯基並噻吩-2-羧基醯胺5,5-二氧化物，以及 二硫-2,2’-雙苄基甲基醯胺所組成群組之至少一種殺真 菌效用之活性化合物作為活性成份，與選自於三溴 盼、二氟紛、硝基齡、3-曱基-4氣齡、3，5_二甲基-4 氣酚、苯氧基乙醇、二氯酚、鄰_苯基苯酚、間_苯基 苯酚、對苯基苯酚、2-苄基-4氣酚(chl〇rophene)、 2,4_ 一氣_3,5_二甲基酚、4_氯瑞香草酚、三氣松 (triclosan)、酚提氯(fentichlor)，及其銨鹽、鹼金屬鹽 與驗土金屬鹽類所組成群組之至少一種盼活性化合 物。 一種保護動物生皮與熟皮免於微生物傷害之方法，其 特徵在於將生皮或熟皮以申請專利範圍第1項之組合 物處理。 一種殺微生物組成物，其包含根據申請專利範圍第 1項之組合物，以及慣用於保護動物生皮與熟皮之 組成物中的成分。 -9 本紙張尺度適用中國國家標準(CNS)A4規格（210 X 297公羞） 90391B-接 1
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10133545A1 (de) * | 2001-07-11 | 2003-02-06 | Ge Bayer Silicones Gmbh & Co | Benzothiophen-2-cyclohexylcarboxamid-S,S-dioxid enthaltende schimmelresistente Dichtstoff-Formulierungen |
| WO2004011682A1 (en) * | 2002-07-26 | 2004-02-05 | Microban Products Company | Durable antimicrobial leather |
| AU2004201059B2 (en) * | 2003-03-26 | 2009-06-04 | Rohm And Haas Company | Microbicidal composition |
| DE10318366A1 (de) * | 2003-04-23 | 2004-12-02 | Bayer Chemicals Ag | Mikrobizide Mittel |
| ES2330123T3 (es) * | 2005-03-04 | 2009-12-04 | Buckman Laboratories International, Inc. | Composiciones fungicidas y metodos que usan cianoditiocarbimatos. |
| CN100381052C (zh) * | 2006-05-13 | 2008-04-16 | 林贤荣 | 床垫(沙发)用抗菌防螨剂 |
| DE102008038709A1 (de) | 2008-08-12 | 2010-02-18 | Lanxess Deutschland Gmbh | Flüssige Präparationen phenolischer Wirkstoffe |
| US9997007B2 (en) * | 2009-10-01 | 2018-06-12 | Patent Investment & Licensing Company | Method and system for implementing mystery bonus in place of base game results on gaming machine |
| JP5604094B2 (ja) * | 2009-12-17 | 2014-10-08 | 地方独立行政法人東京都立産業技術研究センター | 防かび剤組成物、およびそれを使用した木材および木製品 |
| CN101864702B (zh) * | 2010-05-26 | 2011-07-20 | 广东省石油化工研究院 | 一种造纸杀菌防腐剂 |
| EP2570502A1 (de) | 2011-09-13 | 2013-03-20 | LANXESS Deutschland GmbH | Flüssige Wirkstoffpräparationen zum fungiziden Schutz von collagenfaserhaltigen Substraten |
| EP2777396A1 (de) | 2013-03-12 | 2014-09-17 | LANXESS Deutschland GmbH | Wirkstoffpräparationen zum fungiziden Schutz von collagenfaserhaltigen Substraten |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE137846C (zh) | ||||
| US27217A (en) * | 1860-02-21 | Of city railkoad-cars | ||
| US147227A (en) * | 1874-02-03 | Improvement in door-checks | ||
| US3256187A (en) * | 1963-05-17 | 1966-06-14 | Socony Mobil Oil Co Inc | Cutting fluid |
| US3555159A (en) * | 1967-03-14 | 1971-01-12 | Baxter Laboratories Inc | Antimicrobial composition and method of use |
| DD137846A1 (de) * | 1978-07-17 | 1979-09-26 | Ulf Thust | Waschmittel mit desinfizierender wirkung |
| JPS6058202B2 (ja) * | 1979-09-27 | 1985-12-19 | クミアイ化学工業株式会社 | 非医療用殺菌組成物 |
| JPS56113706A (en) * | 1980-02-09 | 1981-09-07 | Nissan Chem Ind Ltd | Mildewcide composition for industrial use |
| JPS5798303A (en) * | 1980-12-12 | 1982-06-18 | Sanyo Wood Preserving | Conservative agent for wood |
| JPS58201864A (ja) * | 1982-05-20 | 1983-11-24 | Pentel Kk | ボ−ルペン用水性インキ |
| JPS6019704A (ja) | 1983-07-15 | 1985-01-31 | Hokko Chem Ind Co Ltd | 防腐防かび剤 |
| JPS6023940A (ja) | 1983-07-19 | 1985-02-06 | Matsushita Electric Ind Co Ltd | 画像表示装置の電極製造方法 |
| JPS60239402A (ja) * | 1984-05-12 | 1985-11-28 | Earth Chem Corp Ltd | ダニ防除剤 |
| US4803236A (en) | 1986-02-25 | 1989-02-07 | Celanese Corporation | Stabilization of aromatic polyesters with mercaptobenzothiazole |
| CA1303773C (en) * | 1986-02-25 | 1992-06-16 | Jerold C. Rosenfeld | Stabilization of aromatic polyesters with mercaptobenzothiazole |
| FR2620306B1 (fr) | 1987-09-14 | 1990-10-12 | Solvay | Compositions contenant des produits pesticides biosynthetiques, procedes pour leur production et leur utilisation |
| DD265421A1 (de) * | 1987-10-01 | 1989-03-01 | Zeitz Hydrierwerk | Multifunktioneller schmierstoffzusatz |
| JPH01193372A (ja) | 1988-01-29 | 1989-08-03 | Sakura Color Prod Corp | 描画用水彩絵具 |
| US4964892A (en) * | 1988-12-22 | 1990-10-23 | Rohm And Haas Company | Synergistic microbicidal combinations containing 2-N-octyl-3-isothiazolone and certain commercial biocides |
| JPH02247104A (ja) * | 1989-03-17 | 1990-10-02 | Kurita Water Ind Ltd | 工業用殺菌組成物 |
| US4983618A (en) * | 1989-07-14 | 1991-01-08 | Buckman Laboratories International, Inc. | Combination of 2-(thiocyanomethylthio)benzothiazole and a trihalogenated phenol |
| JPH0725644B2 (ja) | 1990-02-26 | 1995-03-22 | 神東塗料株式会社 | 工業用防カビ剤組成物 |
| JP2634483B2 (ja) * | 1990-06-18 | 1997-07-23 | オリンパス光学工業株式会社 | 防菌防黴清拭軟膏および光学機器の清拭方法 |
| JPH04244003A (ja) * | 1991-01-31 | 1992-09-01 | Lomb & Haasu Japan Kk | 木材用防かび剤 |
| DE4115184A1 (de) * | 1991-05-09 | 1992-11-12 | Bayer Ag | Benzothiophen-2-carboxamid-s,s-dioxide |
| DE4202051A1 (de) | 1992-01-25 | 1993-07-29 | Bayer Ag | Fliessfaehige mikrobizide mittel |
| DE4217523A1 (de) * | 1992-05-27 | 1993-12-02 | Bayer Ag | Mittel zum Schutz von Schnittholz |
| US5373016A (en) | 1993-05-28 | 1994-12-13 | Zeneca, Inc. | Protection of isothiazolinone biocides from free radicals |
| JPH0769815A (ja) * | 1993-06-29 | 1995-03-14 | Yoshitomi Pharmaceut Ind Ltd | 水中防汚剤 |
| GB9318170D0 (en) * | 1993-09-02 | 1993-10-20 | Kodak Ltd | Antimicrobial polymers and compositions containing them |
| JPH07247201A (ja) * | 1994-03-09 | 1995-09-26 | Mitsui Toatsu Chem Inc | 殺菌殺かび組成物 |
| JPH08183704A (ja) | 1994-12-28 | 1996-07-16 | Nippon Soda Co Ltd | 抗菌抗カビ剤組成物 |
| US5498344A (en) | 1995-02-02 | 1996-03-12 | Morton International, Inc. | Low-temperature-stabilized isothiazolinone concentrates |
| JPH08277371A (ja) | 1995-02-09 | 1996-10-22 | Kanebo Kasei Kk | 抗菌・防黴性塗料組成物 |
| JPH08245318A (ja) | 1995-03-06 | 1996-09-24 | Shoei Kagaku Kk | 工業用殺菌・防腐剤及びその殺菌・防腐方法 |
| GB9504501D0 (en) | 1995-03-07 | 1995-04-26 | Hickson Int Plc | Method for preserving wood and other substrates |
| DE19517840A1 (de) * | 1995-05-16 | 1996-11-21 | Bayer Ag | Wirkstoffkombinationen |
| DE19534868A1 (de) * | 1995-09-20 | 1997-03-27 | Bayer Ag | Benzothiophen-2-carboxamid-S,S-dioxide für den Antifouling-Einsatz |
| US5629350A (en) * | 1996-03-20 | 1997-05-13 | The Dow Chemical Company | Suspension formulations of ortho-phenylphenol |
| US5730907A (en) | 1996-08-27 | 1998-03-24 | Mississippi State University | Enhanced wood preservative composition |
| US6221374B1 (en) * | 1997-05-28 | 2001-04-24 | Rohm And Haas Company | Controlled release compositions |
| DE19725017A1 (de) * | 1997-06-13 | 1998-12-17 | Bayer Ag | Verwendung von 2-Mercapto-pyridin-N-oxid |
| US6090399A (en) | 1997-12-11 | 2000-07-18 | Rohm And Haas Company | Controlled release composition incorporating metal oxide glass comprising biologically active compound |
| JPH11180806A (ja) | 1997-12-22 | 1999-07-06 | Kurita Water Ind Ltd | 抗菌性組成物 |
| JP4805432B2 (ja) | 1998-12-28 | 2011-11-02 | ランクセス・ドイチュランド・ゲーエムベーハー | 木質材又は木質複合材を製造する際に使用される接着剤混入用薬剤 |
| US20030026833A1 (en) * | 2001-07-10 | 2003-02-06 | Payne Stephen A. | Synergistic antimicrobial textile finish |
-
2000
- 2000-09-19 DE DE10046265A patent/DE10046265A1/de not_active Withdrawn
-
2001
- 2001-08-27 AR ARP010104081A patent/AR030496A1/es unknown
- 2001-09-07 CN CNA2006101002264A patent/CN1891043A/zh active Pending
- 2001-09-07 CN CN018159141A patent/CN1217576C/zh not_active Expired - Lifetime
- 2001-09-07 BR BRPI0113924A patent/BRPI0113924B1/pt active IP Right Grant
- 2001-09-07 NZ NZ524752A patent/NZ524752A/en not_active IP Right Cessation
- 2001-09-07 MX MXPA03002334A patent/MXPA03002334A/es active IP Right Grant
- 2001-09-07 CA CA2422582A patent/CA2422582C/en not_active Expired - Fee Related
- 2001-09-07 PL PL386766A patent/PL209118B1/pl unknown
- 2001-09-07 AU AU2002218161A patent/AU2002218161B2/en not_active Expired
- 2001-09-07 EP EP01985227.6A patent/EP1328155B1/de not_active Expired - Lifetime
- 2001-09-07 JP JP2002528033A patent/JP2004509137A/ja active Pending
- 2001-09-07 KR KR1020037003883A patent/KR100841182B1/ko not_active Expired - Lifetime
- 2001-09-07 PL PL36054601A patent/PL360546A1/xx not_active IP Right Cessation
- 2001-09-07 CN CNA2005100819536A patent/CN1701664A/zh active Pending
- 2001-09-07 WO PCT/EP2001/010303 patent/WO2002023985A2/de not_active Ceased
- 2001-09-07 AU AU1816102A patent/AU1816102A/xx active Pending
- 2001-09-13 US US09/952,252 patent/US7201854B2/en not_active Expired - Fee Related
- 2001-09-19 TW TW090122953A patent/TWI241161B/zh not_active IP Right Cessation
-
2003
- 2003-03-18 ZA ZA200302153A patent/ZA200302153B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NZ524752A (en) | 2005-09-30 |
| MXPA03002334A (es) | 2003-10-15 |
| CA2422582C (en) | 2011-11-29 |
| BR0113924A (pt) | 2003-07-29 |
| WO2002023985A2 (de) | 2002-03-28 |
| CN1460001A (zh) | 2003-12-03 |
| JP2004509137A (ja) | 2004-03-25 |
| AU1816102A (en) | 2002-04-02 |
| BRPI0113924B1 (pt) | 2016-07-26 |
| KR100841182B1 (ko) | 2008-06-24 |
| US20020066879A1 (en) | 2002-06-06 |
| AU2002218161B2 (en) | 2007-05-17 |
| KR20030032039A (ko) | 2003-04-23 |
| CA2422582A1 (en) | 2003-03-14 |
| AR030496A1 (es) | 2003-08-20 |
| ZA200302153B (en) | 2004-05-25 |
| PL209118B1 (pl) | 2011-07-29 |
| WO2002023985A3 (de) | 2002-10-24 |
| CN1891043A (zh) | 2007-01-10 |
| EP1328155A2 (de) | 2003-07-23 |
| DE10046265A1 (de) | 2002-03-28 |
| EP1328155B1 (de) | 2016-04-27 |
| CN1701664A (zh) | 2005-11-30 |
| CN1217576C (zh) | 2005-09-07 |
| US7201854B2 (en) | 2007-04-10 |
| PL360546A1 (en) | 2004-09-06 |
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