TW201516166A - Manifold used for vacuum evaporation device - Google Patents
Manifold used for vacuum evaporation device Download PDFInfo
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- TW201516166A TW201516166A TW103135709A TW103135709A TW201516166A TW 201516166 A TW201516166 A TW 201516166A TW 103135709 A TW103135709 A TW 103135709A TW 103135709 A TW103135709 A TW 103135709A TW 201516166 A TW201516166 A TW 201516166A
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- nozzle
- substrate
- vapor deposition
- manifold
- discharge
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- 238000007738 vacuum evaporation Methods 0.000 title claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 88
- 239000000463 material Substances 0.000 claims abstract description 59
- 238000001704 evaporation Methods 0.000 claims abstract description 37
- 230000008020 evaporation Effects 0.000 claims abstract description 30
- 238000007740 vapor deposition Methods 0.000 claims description 94
- 238000007599 discharging Methods 0.000 claims description 7
- 238000005507 spraying Methods 0.000 abstract 3
- 238000001514 detection method Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005401 electroluminescence Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/12—Organic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/243—Crucibles for source material
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physical Vapour Deposition (AREA)
- Electroluminescent Light Sources (AREA)
Abstract
Description
本發明係關於一種適用於有機EL(電致發光)元件製造的真空蒸鍍裝置用岐管,使用線性源進行聯機(Inline)蒸鍍。 The present invention relates to a tantalum tube for a vacuum vapor deposition apparatus which is suitable for the manufacture of an organic EL (electroluminescence) element, and is subjected to inline vapor deposition using a linear source.
聯機蒸鍍方式是使作為蒸鍍材料的線性源的岐管,沿寬度方向與以固定速度移動的蒸鍍基材相對配置,並且從設置在岐管上的噴出用噴嘴噴出蒸發材料,使得蒸發材料附著在蒸鍍基材的表面上。 In the on-line vapor deposition method, a crucible tube as a linear source of a vapor deposition material is disposed to face the vapor deposition substrate moving at a fixed speed in the width direction, and evaporating material is ejected from a discharge nozzle provided on the manifold to evaporate. The material adheres to the surface of the vapor-deposited substrate.
在聯機蒸鍍方式的真空蒸鍍裝置中,專利文獻1公開了如下裝置:將線性源用岐管作為用於加熱蒸鍍材料使其氣化的坩堝,在坩堝的上表面上沿坩堝的長邊方向形成有多個噴出用噴嘴,並且在各噴出用噴嘴上分別形成有用於噴出蒸鍍材料的噴嘴口。 In the vacuum evaporation apparatus of the in-line vapor deposition method, Patent Document 1 discloses a device in which a tantalum tube for a linear source is used as a crucible for heating a vapor deposition material to vaporize it, and the length of the crucible on the upper surface of the crucible. A plurality of discharge nozzles are formed in the side direction, and nozzle ports for discharging the vapor deposition material are formed in each of the discharge nozzles.
專利文獻1:日本專利公報第4380319號(第1圖) Patent Document 1: Japanese Patent Publication No. 4380319 (Fig. 1)
然而,需要提高價格高的有機EL等蒸鍍材料的利用效率(附著量相對於蒸發量的比例)。因此,可以考慮使得噴出用噴嘴接近蒸鍍基材,從而使得作為節流孔的噴嘴口和蒸鍍基材的蒸鍍距離變短。當使得蒸鍍距離變短時,為了確保附著膜厚的均勻性,需要增加噴嘴口,從而導致噴出用噴嘴相互接近。此外,為了調整噴出量,噴出用噴嘴的噴嘴口成為出口收攏的節流孔,但是如果不將噴嘴口的口徑/噴出用噴嘴內徑之比確保為一定值以上,則從一個噴出用噴嘴噴出的蒸鍍材料的膜厚分布不穩 定。因此,難以使噴嘴口接近設置。 However, there is a need to increase the utilization efficiency (the ratio of the amount of adhesion to the amount of evaporation) of a vapor deposition material such as an organic EL having a high price. Therefore, it is conceivable that the discharge nozzle is brought close to the vapor deposition substrate, so that the vapor deposition distance of the nozzle opening as the orifice and the vapor deposition substrate becomes short. When the vapor deposition distance is made short, in order to ensure the uniformity of the adhesion film thickness, it is necessary to increase the nozzle opening, and the ejection nozzles are brought close to each other. In addition, in order to adjust the discharge amount, the nozzle opening of the discharge nozzle is an orifice that is closed at the outlet. However, if the ratio of the diameter of the nozzle opening/the inner diameter of the discharge nozzle is not constant, the discharge is performed from one discharge nozzle. The film thickness of the vapor deposition material is unstable set. Therefore, it is difficult to make the nozzle opening close to the setting.
作為對策,可以使噴嘴口的口徑變小,但是如果使得噴嘴口的口徑變小,則噴出流道的傳導率變小。因此,為了確保規定的蒸鍍率,必須提高坩堝內的蒸鍍材料的蒸發溫度(加熱溫度),但是如果提高了蒸發溫度,則有些蒸鍍材料容易劣化,而且有可能增加運行成本。 As a countermeasure, the diameter of the nozzle opening can be made small, but if the diameter of the nozzle opening is made small, the conductivity of the discharge flow path becomes small. Therefore, in order to secure a predetermined vapor deposition rate, it is necessary to increase the evaporation temperature (heating temperature) of the vapor deposition material in the crucible. However, if the evaporation temperature is increased, some vapor deposition materials are likely to be deteriorated, and the running cost may be increased.
為了解決上述問題,本發明之目的在於提供能够提高蒸鍍材料的利用效率的真空蒸鍍裝置用岐管。 In order to solve the above problems, an object of the present invention is to provide a manifold for a vacuum vapor deposition apparatus which can improve the utilization efficiency of a vapor deposition material.
方式1的發明提供一種真空蒸鍍裝置用岐管,為一聯機式真空蒸鍍裝置用岐管,與以固定速度移動的蒸鍍基材相對配置,從設置在對置面上的複數個噴嘴口噴出蒸鍍材料,並使得蒸鍍材料附著在蒸鍍基材的表面上,其中,在單一岐管的與蒸鍍基材相對的對置面上設置有噴嘴列,這些噴嘴列沿蒸鍍基材的寬度方向隔開規定的噴嘴間距突出設置具有這些噴嘴口的複數個噴出用噴嘴,並且多列噴嘴列沿蒸鍍基材的移動方向間隔規定間隔配置,蒸鍍基材移動方向前方的噴嘴列的噴出用噴嘴和後方的噴嘴列的噴出用噴嘴在蒸鍍基材的移動方向上相對配置。 The invention of the first aspect provides a manifold for a vacuum vapor deposition apparatus, which is a manifold for an in-line vacuum vapor deposition apparatus, and is disposed opposite to an evaporation substrate that moves at a fixed speed, from a plurality of nozzles disposed on opposite surfaces The vapor deposition material is ejected from the mouth, and the vapor deposition material is attached to the surface of the vapor deposition substrate, wherein a nozzle row is disposed on the opposite surface of the single manifold opposite to the vapor deposition substrate, and the nozzle columns are vapor-deposited A plurality of ejection nozzles having the nozzle openings are protruded from the nozzle direction by a predetermined nozzle pitch in the width direction of the substrate, and the plurality of nozzle rows are arranged at predetermined intervals along the moving direction of the vapor deposition substrate, and the vapor deposition substrate is moved forward in the moving direction. The nozzle for discharging the nozzle row and the nozzle for discharging the nozzle row at the rear are arranged to face each other in the moving direction of the vapor deposition substrate.
方式2的發明提供一種真空蒸鍍裝置用岐管,為一聯機式真空蒸鍍裝置用岐管,與以固定速度移動的蒸鍍基材相對地配置岐管,從設置在岐管上的複數個噴嘴口噴出一蒸鍍材料,並使得蒸鍍材料附著在蒸鍍基材的表面上,其中,在單一岐管的與蒸鍍基材相對的對置面上設置有噴嘴列,這些噴嘴列沿蒸鍍基材的寬度方向隔開規定的噴嘴間距突出設置具有噴嘴口的複數個噴出用噴嘴,並且多列噴嘴列沿蒸鍍基材的移動方向 隔開規定間隔配置,相對於蒸鍍基材移動方向前方的噴嘴列的噴出用噴嘴,後方的噴嘴列的噴出用噴嘴配置在偏移1/2噴嘴間距的交錯位置上。 According to a second aspect of the invention, there is provided a manifold for a vacuum vapor deposition apparatus, which is a manifold for an in-line vacuum vapor deposition apparatus, and a manifold is disposed opposite to a vapor deposition substrate that moves at a fixed speed, from a plurality of tubes disposed on the manifold a nozzle material ejects a vapor deposition material, and causes the vapor deposition material to adhere to the surface of the vapor deposition substrate, wherein a nozzle row is disposed on an opposite surface of the single manifold opposite to the vapor deposition substrate, and the nozzle columns A plurality of ejection nozzles having nozzle openings are protruded from a predetermined nozzle pitch in the width direction of the vapor deposition substrate, and a plurality of rows of nozzle rows are moved along the vapor deposition substrate. The discharge nozzles of the nozzle rows in the front direction in the moving direction of the vapor deposition substrate are disposed at a predetermined interval, and the discharge nozzles of the nozzle rows in the rear are arranged at a staggered position shifted by 1/2 nozzle pitch.
方式3的發明在方式1或2記載的結構的基礎上,當各噴嘴列的噴出用噴嘴的噴嘴間距為P、噴嘴口的口徑為D’、噴嘴口和蒸鍍基材的蒸鍍距離為S時,D’<P<1.11×S。 According to the aspect of the invention of the third aspect, the nozzle pitch of the nozzle for discharge of each nozzle row is P, the diameter of the nozzle opening is D', and the vapor deposition distance of the nozzle opening and the vapor deposition substrate is When S, D'<P<1.11×S.
方式4的發明在方式1至3中任意一項記載的結構的基礎上,當噴出用噴嘴的噴嘴內徑為D(mm)、噴嘴長度為L(mm)、噴嘴口的口徑為D’(mm)時,噴出用噴嘴在L9×D時滿足D’2.7×D2/L,並且在L<9×D時滿足D’D/3。 According to the invention of any one of the aspects 1 to 3, the nozzle inner diameter of the nozzle for discharge is D (mm), the nozzle length is L (mm), and the diameter of the nozzle opening is D' ( When mm), the nozzle for ejection is in L Meets D' at 9×D 2.7 × D 2 /L, and satisfy D' when L < 9 × D D/3.
方式5的發明在方式1至4中任意一項記載的結構的基礎上,與蒸鍍基材的寬度對應,在多個噴嘴列中的至少一個噴嘴列上安裝有封閉塞,封閉塞封閉端部側的噴出用噴嘴的噴嘴口。 According to a fifth aspect of the invention, in the configuration of any one of the first to fourth aspects, the closing plug is attached to at least one of the plurality of nozzle rows in accordance with the width of the vapor deposition substrate, and the closed end of the closing plug is closed. The nozzle opening of the nozzle for discharge on the side.
按照方式1所述的發明,透過將前方和後方的噴嘴列的各噴出用噴嘴在蒸鍍基材的移動方向上相對配置,與將噴嘴列配置成一列的情况相比,能够提高蒸鍍率。由此,即使將噴嘴口的口徑縮小而使噴出流道的傳導率變小,也可以透過配置多列來確保規定的蒸鍍率。 According to the invention of the first aspect, the discharge nozzles of the front and rear nozzle rows are arranged to face each other in the moving direction of the vapor deposition substrate, and the vapor deposition rate can be improved as compared with the case where the nozzle rows are arranged in a row. . Thereby, even if the diameter of the nozzle opening is reduced and the conductivity of the discharge flow path is made small, a plurality of rows can be arranged to ensure a predetermined vapor deposition rate.
按照方式2所述的發明,透過將前方和後方的噴嘴列的各噴出用噴嘴配置在交錯位置上,即使在各噴嘴列中使得噴出用噴嘴確保足够的噴嘴間距,也可使得正面觀察蒸鍍基材時的噴出用噴嘴相互接近配置,從而提高了附著膜厚的均勻性。由此,可使得噴出用噴嘴和蒸鍍基材的蒸鍍距離變短,並且使得附著膜厚的均勻性不會變差,從而能够提高材料的利用效率。 According to the invention of the second aspect, by arranging the respective discharge nozzles of the front and rear nozzle rows at the staggered positions, even if the nozzles for the nozzles ensure a sufficient nozzle pitch in each of the nozzle rows, the front side can be vapor-deposited. The nozzles for discharging at the time of the substrate are arranged close to each other, thereby improving the uniformity of the thickness of the adhering film. Thereby, the vapor deposition distance of the discharge nozzle and the vapor deposition substrate can be shortened, and the uniformity of the adhesion film thickness can be prevented from being deteriorated, and the material utilization efficiency can be improved.
按照方式3所述的發明,如果蒸鍍距離為S,則透過使得各噴嘴列的噴出用噴嘴的噴嘴間距P大於噴嘴口的口徑且小於S×1.11,可以實現作為產品所需要的±5%以內的膜厚均勻性來進行蒸鍍。 According to the invention of the third aspect, when the vapor deposition distance is S, the nozzle pitch P of the discharge nozzles of the nozzle rows is made larger than the diameter of the nozzle opening and smaller than S × 1.11, thereby achieving ±5% required as a product. The vapor deposition was performed within the film thickness uniformity.
按照方式4所述的發明,噴出用噴嘴透過使用在L9×D時滿足D’2.7×D2/L、且在L<9×D時滿足D’D/3的噴出用噴嘴,從噴嘴口噴出的蒸發材料的擴散狀態按照cosn θ定則而成為均勻狀態,從而可以提高附著膜厚的均勻性。 According to the invention of the fourth aspect, the nozzle for ejection is used in the L Meets D' at 9×D 2.7 × D 2 /L, and satisfy D' when L < 9 × D In the D/3 discharge nozzle, the diffusion state of the evaporation material ejected from the nozzle opening is uniform in accordance with cos n θ, and the uniformity of the adhesion film thickness can be improved.
按照方式5所述的發明,當蒸鍍基材的寬度變窄時,透過在噴嘴列的端部側的噴出用噴嘴的噴嘴口上安裝封閉塞而將其封閉,可以抑制無謂地噴出蒸發材料,從而可以降低運行成本。 According to the invention of the fifth aspect, when the width of the vapor-deposited substrate is narrowed, the closing plug is attached to the nozzle opening of the discharge nozzle on the end side of the nozzle row, and the evaporating material can be suppressed from being discharged. This can reduce operating costs.
11‧‧‧岐管 11‧‧‧岐管
11a‧‧‧對置面 11a‧‧‧ facing
12‧‧‧基板 12‧‧‧Substrate
12s‧‧‧基板 12s‧‧‧Substrate
13‧‧‧噴出用噴嘴 13‧‧‧Spray nozzle
13a‧‧‧噴嘴主體 13a‧‧‧Nozzle body
13b‧‧‧端板 13b‧‧‧End board
13E‧‧‧噴出用噴嘴 13E‧‧‧Spray nozzle
14F‧‧‧噴嘴列 14F‧‧‧Nozzle column
14R‧‧‧噴嘴列 14R‧‧‧Nozzle column
14Ff‧‧‧前列噴嘴列 14Ff‧‧‧Forefront nozzle column
14Rr‧‧‧後列噴嘴列 14Rr‧‧‧After nozzle row
14Rf‧‧‧前列噴嘴列 14Rf‧‧‧Forefront nozzle column
14Rr‧‧‧後列噴嘴列 14Rr‧‧‧After nozzle row
15‧‧‧噴嘴口 15‧‧‧Nozzle mouth
16‧‧‧材料導入口 16‧‧‧Material import
17‧‧‧材料導入管 17‧‧‧Material introduction tube
18‧‧‧壓力檢測口 18‧‧‧ Pressure detection port
19‧‧‧蒸鍍率檢測口 19‧‧‧ evaporation rate detection port
21‧‧‧封閉塞 21‧‧‧ Closed plug
S‧‧‧蒸鍍距離 S‧‧‧ evaporation distance
P‧‧‧噴嘴間距 P‧‧‧Nozzle spacing
L‧‧‧噴嘴長度 L‧‧‧ nozzle length
D‧‧‧內徑 D‧‧‧Inner diameter
D’‧‧‧口徑 D’‧‧‧ caliber
d‧‧‧內徑 d‧‧‧Inner diameter
CL‧‧‧中心線 CL‧‧‧ center line
SL‧‧‧側線 SL‧‧‧ side line
Hm‧‧‧高度 Hm‧‧‧ Height
Wm‧‧‧寬度 Wm‧‧‧Width
Wn‧‧‧寬度 Wn‧‧‧Width
Ws‧‧‧寬度 Ws‧‧‧Width
Lm‧‧‧長度 Lm‧‧‧ length
Lp‧‧‧噴嘴列間隔 Lp‧‧‧nozzle column spacing
第1A圖~第1C圖為表示本發明的真空蒸鍍裝置用岐管的實施例1,第1A圖為俯視圖,第1B圖為側視圖,第1C圖為主視圖。 1A to 1C are views showing a first embodiment of a crucible for a vacuum vapor deposition device according to the present invention. FIG. 1A is a plan view, FIG. 1B is a side view, and FIG. 1C is a front view.
第2圖為表示噴出用噴嘴的縱斷面圖。 Fig. 2 is a longitudinal sectional view showing a nozzle for discharge.
第3A圖、第3B圖為利用聯機蒸鍍方式進行的蒸鍍的蒸鍍膜厚的說明,第3A圖為表示噴出用噴嘴的配置的簡要俯視圖,第3B圖為表示膜厚的主視圖。 3A and 3B are explanatory views of the vapor deposition film thickness of the vapor deposition by the in-line vapor deposition method, FIG. 3A is a schematic plan view showing the arrangement of the discharge nozzles, and FIG. 3B is a front view showing the film thickness.
第4圖為表示因噴出用噴嘴的噴嘴間距產生的膜厚變化的主視圖,第4A圖表示狹小噴嘴間距的情况,第4B圖表示寬噴嘴間距的情况。 Fig. 4 is a front view showing a change in film thickness due to a nozzle pitch of a discharge nozzle, wherein Fig. 4A shows a narrow nozzle pitch, and Fig. 4B shows a wide nozzle pitch.
第5圖為表示使膜厚均勻性小於±5%的噴嘴間距相對於蒸鍍距離的範圍的坐標圖。 Fig. 5 is a graph showing the range of the nozzle pitch with respect to the vapor deposition distance in which the film thickness uniformity is less than ±5%.
第6圖為表示在噴出用噴嘴中,(噴出用噴嘴的長度L)×(噴嘴口的口徑D’)/(噴出用噴嘴內徑D)與cosn θ定則的n值之間關係的坐標圖。 Fig. 6 is a view showing the relationship between (the length L of the discharge nozzle) × (the diameter D' of the nozzle opening) / (the inner diameter D of the discharge nozzle) and the value of n of the cos n θ rule in the discharge nozzle. Figure.
第7圖為表示在噴出用噴嘴中,(噴嘴口的口徑D’)/(噴出用噴嘴內徑D)與cosn θ定則的n值之間關係的坐標圖。 Fig. 7 is a graph showing the relationship between the nozzle opening (diameter D') / (the nozzle inner diameter D of the discharge nozzle) and the n value of cos n θ in the discharge nozzle.
第8圖為表示本發明的真空蒸鍍裝置用岐管的實施例2的俯視圖。 Fig. 8 is a plan view showing a second embodiment of the manifold for a vacuum vapor deposition device of the present invention.
第9A圖~第9C圖表示基板寬度變更時的岐管的使用狀態,第9A圖表示基板沿中心線移動的情况,第9B圖表示基板沿側線移動的情况,第9C圖表示安裝有封閉塞狀態的噴出用噴嘴的縱斷面。以及第10圖為表示本發明的真空蒸鍍裝置用岐管的實施例3的俯視圖。 9A to 9C are diagrams showing the use state of the manifold when the substrate width is changed, FIG. 9A shows the substrate moving along the center line, FIG. 9B shows the substrate moving along the side line, and FIG. 9C shows the closed plug. The longitudinal section of the nozzle for discharge of the state. And Fig. 10 is a plan view showing a third embodiment of the manifold for a vacuum vapor deposition device of the present invention.
下面基於第1圖~第4圖,說明本發明的聯機蒸鍍方式的真空蒸鍍裝置用岐管的實施例1。 Next, a first embodiment of a crucible for a vacuum vapor deposition apparatus of the in-line vapor deposition method of the present invention will be described based on Figs. 1 to 4 .
如第1圖、第2圖所示,在保持為真空狀態的一真空蒸鍍室內,岐管11與以固定速度移動的一基板(蒸鍍基材)12的一蒸鍍面相對配置。在岐管11的一對置面11a上,分別在基板12移動方向的前方和後方設置有噴嘴列14F、14R,噴嘴列14F、14R的複數個噴出用噴嘴13沿寬度方向以規定的噴嘴間距P突出設置。在此,如第2圖所示,噴嘴間距P係指各噴嘴列14F、14R中相鄰的噴出用噴嘴13的噴嘴口15和噴嘴口15的距離。 As shown in FIGS. 1 and 2, the manifold 11 is disposed to face a vapor deposition surface of a substrate (vapor deposition substrate) 12 that is moved at a fixed speed in a vacuum deposition chamber that is kept in a vacuum state. In the pair of surfaces 11a of the manifold 11, nozzle rows 14F and 14R are provided in front of and behind the moving direction of the substrate 12, and a plurality of nozzles 13 of the nozzle rows 14F and 14R are spaced apart in the width direction by a predetermined nozzle pitch. P is highlighted. Here, as shown in FIG. 2, the nozzle pitch P means the distance between the nozzle opening 15 and the nozzle opening 15 of the adjacent discharge nozzles 13 among the nozzle rows 14F and 14R.
前方和後方的噴嘴列14F、14R的噴出用噴嘴13在基板12 的移動方向上相對配置。在噴出用噴嘴13的一前端面上分別形成有一噴嘴口15。此外,為了將由坩堝(圖未示)對蒸鍍材料進行加熱蒸發而得到的蒸發材料導入岐管11內,在岐管11的與噴出用噴嘴13相反的相反面上形成有一材料導入口16,材料導入口16與內徑為d的一材料導入管17相連接。 The nozzles 13 for discharging the nozzle rows 14F and 14R on the front and the rear are on the substrate 12 The relative orientation of the moving direction. A nozzle opening 15 is formed in each of the front end faces of the discharge nozzles 13. Further, in order to introduce the evaporation material obtained by heating and evaporating the vapor deposition material by 坩埚 (not shown) into the manifold 11, a material introduction port 16 is formed on the opposite surface of the manifold 11 opposite to the discharge nozzle 13, The material introduction port 16 is connected to a material introduction pipe 17 having an inner diameter d.
前方和後方的噴嘴列14F、14R配置成與材料導入口16隔開一規定的距離,並且進一步配置成在基板12的移動方向上隔開噴嘴列間隔Lp。前後的噴嘴列14F、14R與材料導入口16的距離是為了使得從材料導入口16供給的蒸發材料均勻地導入噴出用噴嘴13。此外,前後的噴嘴列14F、14R中的兩端部的噴出用噴嘴13配置在與寬度Ws的基板12之兩邊緣部對應的位置上。 The front and rear nozzle rows 14F, 14R are disposed to be spaced apart from the material introduction port 16 by a predetermined distance, and are further arranged to separate the nozzle row spacing Lp in the moving direction of the substrate 12. The distance between the front and rear nozzle rows 14F and 14R and the material introduction port 16 is such that the evaporation material supplied from the material introduction port 16 is uniformly introduced into the discharge nozzle 13 . Further, the discharge nozzles 13 at both end portions of the front and rear nozzle rows 14F and 14R are disposed at positions corresponding to both edge portions of the substrate 12 having the width Ws.
岐管11具有能够使得從材料導入口16導入的蒸發材料均勻擴散的內部空間,岐管11形成為前後長度為Lm、寬度為Wm、高度為Hm的一長方體,並且在基板對置面11a上設置有遮擋來自基板12的輻射熱的一冷却板(圖未示),在左右側面和前後側面上設置有防止蒸發材料附著的一加熱器(圖未示)。並且,基板12相對於噴嘴口15隔開規定的蒸鍍距離S進行移動。一壓力檢測口18設置在岐管11的前側面,一蒸鍍率檢測口19設置在岐管11的後側面。 The manifold 11 has an internal space capable of uniformly diffusing the evaporation material introduced from the material introduction port 16, and the manifold 11 is formed as a rectangular parallelepiped having a front-rear length Lm, a width Wm, and a height Hm, and is on the substrate opposing surface 11a. A cooling plate (not shown) for shielding radiant heat from the substrate 12 is provided, and a heater (not shown) for preventing adhesion of the evaporation material is provided on the left and right side surfaces and the front and rear side surfaces. Further, the substrate 12 is moved with respect to the nozzle opening 15 by a predetermined vapor deposition distance S. A pressure detecting port 18 is provided on the front side of the manifold 11, and an evaporation rate detecting port 19 is provided on the rear side of the manifold 11.
如第2圖所示,噴出用噴嘴13的圓筒狀的噴嘴主體13a直立設置在岐管11的基板對置面11a上,在噴嘴主體13a的前端面上,為了形成節流孔而安裝具有噴嘴口15的一端板13b。 As shown in Fig. 2, the cylindrical nozzle body 13a of the discharge nozzle 13 is erected on the substrate facing surface 11a of the manifold 11, and is attached to the front end surface of the nozzle body 13a so as to form an orifice. One end plate 13b of the nozzle opening 15.
如果噴嘴口15的口徑為D’(mm),則各噴嘴列14F、14R 的噴出用噴嘴13的噴嘴間距P滿足以下的公式(1)。 If the diameter of the nozzle opening 15 is D' (mm), each nozzle row 14F, 14R The nozzle pitch P of the discharge nozzle 13 satisfies the following formula (1).
D’<P<1.11×S…公式(1) D'<P<1.11×S...Formula (1)
即,聯機式岐管11的噴出用噴嘴13的配置如第3A圖所示,相對於具有任意基板寬度的蒸鍍基板12,(理論上)成為無限個數的列,當假設來自全部噴出用噴嘴13的噴出流量固定時,蒸鍍基板12的膜厚均勻性與噴出用噴嘴13的噴嘴間距P相關。如第3B圖所示,在噴出用噴嘴13的排列正上方對蒸鍍基板12蒸鍍的膜厚分布如下:在噴出用噴嘴13的正上方進行蒸鍍的累計膜厚最厚,相鄰的噴出用噴嘴13的中間點(1/2P)的最上方最薄。另外,在此由於D’<P,所以不包含狹縫狀的噴嘴口。並且,如第4A圖所示,如果噴嘴間距P小,則最大膜厚和最小膜厚的膜厚差變小,如第4B圖所示,如果噴嘴間距P大,則最大膜厚和最小膜厚的膜厚差變大。當最大膜厚為dmax、最小膜厚為dmin時,利用以下的公式(2)表示膜厚均勻性。 In other words, as shown in FIG. 3A, the arrangement of the discharge nozzles 13 of the in-line manifold 11 is (in theory) an infinite number of columns for the vapor deposition substrate 12 having an arbitrary substrate width, and it is assumed that all of the discharge nozzles are used for all discharges. When the discharge flow rate of the nozzle 13 is fixed, the film thickness uniformity of the vapor deposition substrate 12 is related to the nozzle pitch P of the discharge nozzle 13. As shown in FIG. 3B, the film thickness distribution of the vapor deposition substrate 12 directly above the arrangement of the discharge nozzles 13 is as follows: the cumulative film thickness of the vapor deposition plate directly above the discharge nozzle 13 is the thickest, and adjacent The uppermost point (1/2P) of the discharge nozzle 13 is the thinnest at the top. Further, since D' < P, the slit-shaped nozzle opening is not included. Further, as shown in Fig. 4A, if the nozzle pitch P is small, the difference in film thickness between the maximum film thickness and the minimum film thickness becomes small, as shown in Fig. 4B, if the nozzle pitch P is large, the maximum film thickness and the minimum film are obtained. The thick film thickness difference becomes large. When the maximum film thickness is dmax and the minimum film thickness is dmin, the film thickness uniformity is expressed by the following formula (2).
膜厚均匀性=[(dmax-dmin)/(dmax+dmin)]×100(%)…公式(2) Film thickness uniformity = [(dmax - dmin) / (dmax + dmin)] × 100 (%)... Formula (2)
如此,由於膜厚均勻性與最大膜厚和最小膜厚相關,所以與噴嘴間距P相關。並且,透過使得上述膜厚均勻性在±5%以內,能够保持產品的質量。 Thus, since the film thickness uniformity is related to the maximum film thickness and the minimum film thickness, it is related to the nozzle pitch P. Further, by making the film thickness uniformity within ±5%, the quality of the product can be maintained.
第5圖為模擬表示不限制噴出用噴嘴13的個數且從全部噴出用噴嘴13噴出相同量的蒸鍍材料時,在蒸鍍距離S下使膜厚均勻性小於±5%的噴嘴間距P的最大值的坐標圖。 5 is a simulation showing a nozzle pitch P in which the film thickness uniformity is less than ±5% at the vapor deposition distance S when the number of the discharge nozzles 13 is not limited and the same amount of the vapor deposition material is ejected from all the discharge nozzles 13. A graph of the maximum value.
按照第5圖,如公式(1)所示,透過使得噴嘴間距P大於D’且小於蒸鍍距離S的1.11倍,可使得膜厚均勻性在作為產品具有實用性 的±5%以內。 According to Fig. 5, as shown in the formula (1), by making the nozzle pitch P larger than D' and smaller than 1.11 times the vapor deposition distance S, the film thickness uniformity can be made practical as a product. Within ±5%.
在此,雖然噴嘴間距P越小、越能够提高膜厚的均勻性,但是材料的利用效率下降。因此,不包含PD’的連續狀、即狹縫狀的噴出用噴嘴13。此外,在各噴嘴列14F、14R中,機械結構上不希望噴嘴間距P在20mm以下。另外,像後述的實施例2那樣,當交錯配置噴嘴列14F、14R的噴出用噴嘴13時,在從正面觀察蒸鍍基板12的情况下,噴嘴間距P可以無限地接近於0,由此,能够兼顧膜厚均勻性和材料的利用效率。 Here, the smaller the nozzle pitch P is, the more uniform the film thickness can be, but the utilization efficiency of the material is lowered. Therefore, does not contain P A continuous nozzle of D', that is, a slit-shaped discharge nozzle 13. Further, in each of the nozzle rows 14F and 14R, it is not preferable that the nozzle pitch P is 20 mm or less in mechanical configuration. Further, when the discharge nozzles 13 of the nozzle rows 14F and 14R are alternately arranged as in the second embodiment to be described later, when the vapor deposition substrate 12 is viewed from the front, the nozzle pitch P can be infinitely close to zero. It is possible to achieve both film thickness uniformity and material utilization efficiency.
如此,噴嘴間距P越小、越能够提高膜厚的均勻性,但是材料的利用效率下降。如果使膜厚的均勻性在±5%以內左右,則可以使噴嘴間距P變寬而提高材料的利用效率。 As described above, the smaller the nozzle pitch P is, the more uniform the film thickness can be, but the utilization efficiency of the material is lowered. When the uniformity of the film thickness is within about ±5%, the nozzle pitch P can be widened to improve the utilization efficiency of the material.
在此,當噴嘴主體13a的內徑為D(mm)、噴嘴長度為L(mm)、噴嘴口15的口徑為D’(mm)時,噴出用噴嘴13滿足如下的公式(3)。 Here, when the inner diameter of the nozzle body 13a is D (mm), the nozzle length is L (mm), and the diameter of the nozzle opening 15 is D' (mm), the discharge nozzle 13 satisfies the following formula (3).
L9×D時,D’2.7×D2/L L When 9×D, D' 2.7×D 2 /L
L<9×D時,D’D/3…公式(3) When L<9×D, D' D/3...Formula (3)
對於形成有機EL膜的有機材料得到上述公式(3)。滿足上述公式(3)時[第6圖中(L9×D時)LD’/D2大於0且在2.7以下的區域,或者是第7圖中(L<9×D時)D’/D大於0且在1/3以下的區域],從各噴出用噴嘴13的噴嘴口15向基板12噴出的蒸發材料按照cosn θ定則、即與cosn θ曲線近似。此時,由於從噴出用噴嘴13的噴嘴口15噴出的蒸發材料在基板12的表面(蒸鍍面)充分擴散來進行蒸鍍,所以能够提高膜厚的均勻性。 The above formula (3) is obtained for the organic material forming the organic EL film. When the above formula (3) is satisfied [Fig. 6 (L) 9 × D) LD' / D 2 is greater than 0 and below 2.7, or in Figure 7 (L <9 × D) D' / D is greater than 0 and below 1/3 of the region], from each discharge nozzle 13 of the nozzle opening 15 θ cos n set according to the discharged with the evaporation material for the substrate 12, i.e., approximately the cos n θ curve. At this time, since the evaporation material discharged from the nozzle opening 15 of the discharge nozzle 13 is sufficiently diffused on the surface (vapor deposition surface) of the substrate 12 to perform vapor deposition, the uniformity of the film thickness can be improved.
如第6圖所示,L9×D時,在D’×L/D2大於0且在2.7以下的區域內,n值約為4.00~4.25。此外,如第7圖所示,L<9×D時,在D’/D大於0且在1/3以下的區域內,n值約為4.05~4.25。在cosn θ定則中n值越小、蒸發材料越在基板12的表面擴散來進行蒸鍍,從而提高了膜厚的均勻性。最優選n值約為4.05~4.10,此時,第6圖所示的L9×D時,為D’×L/D2大於1.1且在1.8以下的區域,第7圖所示的L<9×D時,為D’/D大於0且在0.18以下的區域。 As shown in Figure 6, L In the case of 9 × D, the value of n is about 4.00 to 4.25 in a region where D' × L / D 2 is larger than 0 and is less than 2.7. Further, as shown in Fig. 7, when L < 9 × D, the value of n is about 4.05 to 4.25 in a region where D'/D is larger than 0 and is 1/3 or less. In the cos n θ rule, the smaller the value of n, the more the evaporation material diffuses on the surface of the substrate 12 to perform vapor deposition, thereby improving the uniformity of the film thickness. Most preferably, the value of n is about 4.05 to 4.10. At this time, the L shown in Fig. 6 In the case of 9 × D, where D' × L / D 2 is larger than 1.1 and 1.8 or less, when L < 9 × D shown in Fig. 7, D'/D is larger than 0 and is not more than 0.18.
在此,如果是如第6圖所示,L9×D時D’×L/D2大於2.7,或者是如第7圖所示,L<9×D時D’/D大於1/3,則從各噴出用噴嘴13的噴嘴口15向基板12噴出的蒸發材料未按照cosn θ定則,未在基板12上均勻地進行蒸鍍。其結果,基板12的與噴嘴口15相對的部分的膜厚過度變厚,妨礙了均勻性。另外,此處從加工精度的觀點考慮,例如將噴嘴口15的口徑D’設定在1mm以上。 Here, if it is as shown in Figure 6, L When 9 × D, D' × L / D 2 is larger than 2.7, or as shown in Fig. 7, when L < 9 × D, D' / D is larger than 1/3, from the nozzle opening 15 of each of the discharge nozzles 13 The evaporation material ejected from the substrate 12 is not fixed in accordance with cos n θ, and is not uniformly vapor-deposited on the substrate 12. As a result, the film thickness of the portion of the substrate 12 facing the nozzle opening 15 is excessively thick, which hinders uniformity. In addition, from the viewpoint of processing accuracy, for example, the diameter D′ of the nozzle opening 15 is set to 1 mm or more.
按照上述實施例1,在基板12移動方向的前方和後方設置有噴嘴列14F、14R,噴嘴列14F、14R以規定的噴嘴間距P配置噴出用噴嘴13,透過在基板12的移動方向上相對配置各噴出用噴嘴13,可提高蒸鍍速度。由此,即使噴嘴口15的口徑小而使得噴出流道的傳導率變小,也可透過多列配置來確保規定的蒸鍍率。 According to the first embodiment, the nozzle rows 14F and 14R are provided in front of and behind the moving direction of the substrate 12, and the nozzle rows 14F and 14R are disposed at a predetermined nozzle pitch P, and the discharge nozzles 13 are arranged to face each other in the moving direction of the substrate 12. Each of the discharge nozzles 13 can increase the vapor deposition speed. Thereby, even if the diameter of the nozzle opening 15 is small and the conductivity of the discharge flow path becomes small, it is possible to ensure a predetermined vapor deposition rate through a plurality of rows.
此外,透過使得各噴嘴列14F、14R的噴出用噴嘴13的噴嘴間距P大於噴嘴口15的口徑D’且小於蒸鍍距離S的1.11倍,可使得膜厚均勻性在作為產品所需要的±5%以內。 Further, by making the nozzle pitch P of the discharge nozzles 13 of the nozzle rows 14F and 14R larger than the diameter D' of the nozzle opening 15 and smaller than 1.11 times the vapor deposition distance S, the film thickness uniformity can be made ± as a product. Within 5%.
此外,在各噴出用噴嘴13中,透過使用L9×D時滿足D’ 2.7×D2/L,L<9×D時滿足D’D/3的噴出用噴嘴13,可使得從噴嘴口15噴出的蒸發材料的擴散狀態按照cosn θ定則而變得均勻,從而可以提高附著膜厚的均勻性。 Further, in each of the discharge nozzles 13, the passage of L is used. Meets D' at 9×D 2.7×D 2 /L, L<9×D satisfies D' The discharge nozzle 13 of the D/3 can make the diffusion state of the evaporation material discharged from the nozzle opening 15 uniform according to the cos n θ rule, and the uniformity of the adhesion film thickness can be improved.
第8圖、第9圖表示真空蒸鍍裝置用岐管的實施例2。在本實施例2中,與實施例1相同的構件采用相同的附圖標記,並省略了說明。 Fig. 8 and Fig. 9 show a second embodiment of a manifold for a vacuum vapor deposition apparatus. In the second embodiment, the same members as those in the first embodiment are denoted by the same reference numerals, and the description thereof will be omitted.
在單一岐管11的與基板12s相對的對置面11a上,在基板12s移動方向的前方和後方分別設置有噴嘴列14F、14R,噴嘴列14F、14R沿寬度方向以規定的噴嘴間距P突出設置複數個具有噴嘴口15的噴出用噴嘴13。上述前方和後方的噴嘴列14F、14R的噴出用噴嘴13中,後方的噴嘴列14R的噴出用噴嘴13相對於前方的噴嘴列14F的噴出用噴嘴13配置在位置偏移1/2P的交錯位置上。 On the opposing surface 11a of the single manifold 11 facing the substrate 12s, nozzle rows 14F and 14R are provided in front of and behind the moving direction of the substrate 12s, and the nozzle rows 14F and 14R protrude at a predetermined nozzle pitch P in the width direction. A plurality of discharge nozzles 13 having nozzle openings 15 are provided. In the discharge nozzles 13 of the front and rear nozzle rows 14F and 14R, the discharge nozzles 13 of the rear nozzle row 14R are disposed at a position shifted by 1/2 P with respect to the discharge nozzles 13 of the front nozzle row 14F. on.
噴出用噴嘴13的結構與實施例1相同。 The structure of the discharge nozzle 13 is the same as that of the first embodiment.
第9圖表示在實施例2中對寬度為Wn的基板12s進行成膜時的使用狀態,基板12s的寬度小於通常時的寬度為Ws的基板12。在這種情况下,由於從噴嘴列14F、14R的端部的噴出用噴嘴13E噴出的蒸發材料無謂地噴出,所以如第9C圖所示,在端部的噴出用噴嘴13E上安裝有一封閉塞21,以此端部的噴出用噴嘴13E不噴出蒸發材料的方式進行蒸鍍。 Fig. 9 is a view showing a state of use in the case where a substrate 12s having a width Wn is formed in the second embodiment, and the width of the substrate 12s is smaller than the substrate 12 having a width Ws in a normal state. In this case, since the evaporating material ejected from the discharge nozzles 13E at the end portions of the nozzle rows 14F and 14R is unnecessarily ejected, as shown in FIG. 9C, a closing plug is attached to the end discharge nozzle 13E. 21, the discharge nozzle 13E at the end portion is vapor-deposited so that the evaporation material is not ejected.
在上述實施例2中,相對於前方的噴嘴列14F的噴出用噴嘴13E的設置數量,後方的噴嘴列14R的噴出用噴嘴13少一個。例如第9A圖所示,當以中心線CL為基準使得基板12s移動時,在噴出用噴嘴13設置數量多的前方的噴嘴列14F中,在兩端側的噴出用噴嘴13E上安裝封閉 塞21,以兩端側的噴出用噴嘴13E不噴出蒸發材料的方式進行蒸鍍。此外,當以側線SL為基準使基板12s移動時,在前方的噴嘴列14F中的與側線SL相反側的兩個噴出用噴嘴13E、以及後方的噴嘴列14R中的與側線SL相反側的一個噴出用噴嘴13E上安裝封閉塞21,以上述噴出用噴嘴13E不噴出蒸發材料的方式進行蒸鍍。由此,即使是對寬度小的基板12s進行蒸鍍時,也不會無謂地噴出蒸發材料,從而可提高蒸鍍材料的利用效率。並且,也可以將上述封閉塞21安裝於實施例1的噴出用噴嘴13。 In the second embodiment, the number of the discharge nozzles 13E of the nozzle row 14F in the front is smaller than the number of the nozzles 13 for the nozzle row 14R in the rear. For example, as shown in FIG. 9A, when the substrate 12s is moved with respect to the center line CL, the nozzle row 14F in the front side in which the number of the discharge nozzles 13 is provided is closed on the discharge nozzles 13E on both end sides. The plug 21 is vapor-deposited so that the ejecting nozzle 13E on both end sides does not eject the evaporating material. Further, when the substrate 12s is moved with respect to the side line SL, one of the two discharge nozzles 13E on the side opposite to the side line SL and the nozzle line 14R on the rear side opposite to the side line SL in the front nozzle row 14F The closing plug 21 is attached to the discharge nozzle 13E, and vapor deposition is performed so that the discharge nozzle 13E does not discharge the evaporation material. Thereby, even when the substrate 12s having a small width is vapor-deposited, the evaporation material is not unnecessarily ejected, and the utilization efficiency of the vapor deposition material can be improved. Further, the closing plug 21 may be attached to the discharge nozzle 13 of the first embodiment.
按照上述實施例2,在基板12s移動方向的前方和後方設置有噴嘴列14F、14R,上述噴嘴列14F、14R以規定的噴嘴間距P配置噴出用噴嘴13,透過使得各噴出用噴嘴13配置成在寬度方向上位置偏移的交錯狀,不使得噴出用噴嘴13相互接近就可以設置複數個噴嘴口15。由此,可使得噴嘴口15和基板12s的蒸鍍距離變短,而且可以保持附著膜厚的均勻性且提高材料的利用效率。 According to the second embodiment, the nozzle rows 14F and 14R are provided in front of and behind the moving direction of the substrate 12s. The nozzle rows 14F and 14R are disposed at a predetermined nozzle pitch P, and the discharge nozzles 13 are disposed so that the discharge nozzles 13 are arranged so that In the staggered manner in which the positions are shifted in the width direction, a plurality of nozzle openings 15 can be provided without causing the discharge nozzles 13 to approach each other. Thereby, the vapor deposition distance between the nozzle opening 15 and the substrate 12s can be shortened, and the uniformity of the adhesion film thickness can be maintained and the utilization efficiency of the material can be improved.
此外,當對寬度小的基板12s進行蒸鍍時,透過在噴嘴列14F、14R端部側的噴出用噴嘴13E上安裝封閉塞21,不會無謂地噴出蒸發材料,從而可以提高蒸發材料的利用效率。 In addition, when the substrate 12s having a small width is vapor-deposited, the sealing plug 21 is attached to the discharge nozzle 13E on the end side of the nozzle rows 14F and 14R, so that the evaporation material is not unnecessarily discharged, and the use of the evaporation material can be improved. effectiveness.
第10圖表示真空蒸鍍裝置用岐管的實施例3。與上述實施例1、2相同的構件采用相同的附圖標記,並省略了說明。 Fig. 10 shows a third embodiment of a manifold for a vacuum vapor deposition apparatus. The same members as those of the above-described first and second embodiments are denoted by the same reference numerals, and the description thereof will be omitted.
在岐管11的基板對置面11a上配置有前方和後方的噴嘴列14F、14R,並且使得噴嘴列14F、14R分別為前後兩列14Ff、14Fr、14Rf、14Rr。並且,各前列14Ff、14Rf的噴出用噴嘴13相對於後列14Fr、14Rr的 噴出用噴嘴13在基板12的寬度方向上偏移1/2P而配置在交錯位置上。 The front and rear nozzle rows 14F and 14R are disposed on the substrate facing surface 11a of the manifold 11, and the nozzle rows 14F and 14R are respectively front and rear rows 14Ff, 14Fr, 14Rf, and 14Rr. Further, the discharge nozzles 13 of the front rows 14Ff and 14Rf are opposed to the rear rows 14Fr and 14Rr. The discharge nozzles 13 are arranged at the staggered position by shifting by 1/2P in the width direction of the substrate 12.
按照上述實施例3,可以獲得與實施例1和實施例2相同的作用效果。 According to the above embodiment 3, the same operational effects as those of the embodiment 1 and the embodiment 2 can be obtained.
11‧‧‧岐管 11‧‧‧岐管
11a‧‧‧對置面 11a‧‧‧ facing
12‧‧‧基板 12‧‧‧Substrate
13‧‧‧噴出用噴嘴 13‧‧‧Spray nozzle
14F‧‧‧噴嘴列 14F‧‧‧Nozzle column
14R‧‧‧噴嘴列 14R‧‧‧Nozzle column
16‧‧‧材料導入口 16‧‧‧Material import
18‧‧‧壓力檢測口 18‧‧‧ Pressure detection port
19‧‧‧蒸鍍率檢測口 19‧‧‧ evaporation rate detection port
P‧‧‧噴嘴間距 P‧‧‧Nozzle spacing
Wm‧‧‧寬度 Wm‧‧‧Width
Ws‧‧‧寬度 Ws‧‧‧Width
Lm‧‧‧長度 Lm‧‧‧ length
Lp‧‧‧噴嘴列間隔 Lp‧‧‧nozzle column spacing
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| KR102367988B1 (en) * | 2017-07-31 | 2022-02-28 | 삼성디스플레이 주식회사 | Apparatus and method for manufacturing a display apparatus |
| CN108570645B (en) * | 2017-11-30 | 2023-09-29 | 上海微电子装备(集团)股份有限公司 | Vacuum evaporation device, evaporation head thereof and vacuum evaporation method |
| CN114341357B (en) | 2019-08-30 | 2024-09-10 | 国立大学法人筑波大学 | Fruit plants showing high temperature tolerance, high yield and parthenocarpy |
| JP7247142B2 (en) * | 2020-06-25 | 2023-03-28 | キヤノントッキ株式会社 | Vapor deposition device and evaporation source |
| WO2022002349A1 (en) * | 2020-06-29 | 2022-01-06 | Applied Materials, Inc. | Nozzle assembly, evaporation source, deposition system and method for depositing an evaporated material onto a substrate |
| US20220033958A1 (en) * | 2020-07-31 | 2022-02-03 | Applied Materials, Inc. | Evaporation source, vapor deposition apparatus, and method for coating a substrate in a vacuum chamber |
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| TWI263690B (en) * | 2004-01-06 | 2006-10-11 | Ind Tech Res Inst | Evaporation coating apparatus |
| JP4476019B2 (en) * | 2004-05-20 | 2010-06-09 | 東北パイオニア株式会社 | Deposition source, vacuum film formation apparatus, organic EL element manufacturing method |
| JP4545010B2 (en) * | 2005-02-18 | 2010-09-15 | 日立造船株式会社 | Vapor deposition equipment |
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| CN101803462B (en) * | 2007-09-10 | 2012-06-27 | 株式会社爱发科 | Vapor emitting device, organic thin film vapor deposition device, and organic thin film vapor deposition method |
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| CN201751427U (en) * | 2010-03-25 | 2011-02-23 | 彩虹显示器件股份有限公司 | Linear evaporation source |
| CN103430624A (en) * | 2011-03-03 | 2013-12-04 | 东京毅力科创株式会社 | Vapor-deposition device, vapor-deposition method, organic EL display, and lighting device |
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