TW200810106A - An integrated shadow mask and method of fabrication thereof - Google Patents
An integrated shadow mask and method of fabrication thereof Download PDFInfo
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/17—Passive-matrix OLED displays
- H10K59/173—Passive-matrix OLED displays comprising banks or shadow masks
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- Electroluminescent Light Sources (AREA)
Abstract
Description
200810106 九、發明說明: 【發明所屬之技術領域】 本發明概言之係關於一整合式蘚 口式威陰遮罩及其一製造方 法,及一製造一有機發光裝置之方法。 【先前技術】 0LED係電致發光(EL)裝置,其發射藉由輻射重組〇led 之-個或多個有姐層内所注射之電子及電祠而產生之 光。作為領先之下一代平板顯示哭 。。枝術,OLED提供某些 獨特之顯示器方案’例如低功耗、寬視角、良好之反差 比、視訊速率運作、低電壓運作及輕重量。〇咖顯示写 裝置亦具有熱穩定性’料某些應料有足夠之運作壽 命0 一典型之OLED組離由右擁从&丄 、〜、由有栻功此層夾在兩個電極之間構 成(包括至少一_光有機層)。料電極之-者(陽極)注 € 子’而另―電極(負極)注入負電荷載流子。 f典型OLED裝置中,發光材料可係聚合體或+ μ ^ 陽極層通吊由諸如氧化銦錫(ΙΤ〇)等透明導電材料製成· 而陰極層通常由諸如c_Mg等具有低功函之導電材料構 成。 平板顯示器通常包括一陣列於一基板上經沈積及圖案化 之圖像凡素或像素。此一像素陣列通常係一由列及行構成 車在被動矩陣型〇LED顯示器中,藉由ιτ〇行(陽極) ’、至屬?(陰極)之交疊來定義各像素。為使一特定像素照 、又又於彼特定像素之行(正極化)線與列(負極化)線 121629.doc 200810106 ^ 足夠電壓。可在沈積有機層之前,藉由使用羽 、製私及桌蝕刻製程容易地形成陽極條帶。然 而’無法以相同之方式對該陰極進行圖案化,乃因顯貪叫200810106 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates generally to an integrated mouth-opening mask and a method of manufacturing the same, and a method of fabricating an organic light-emitting device. [Prior Art] An 0LED-based electroluminescence (EL) device that emits light generated by radiating and recombining one or more electrons and electrons injected in a sister layer. As the leading next generation tablet shows crying. . OLEDs offer some unique display solutions such as low power consumption, wide viewing angle, good contrast ratio, video speed operation, low voltage operation and light weight. The coffee maker shows that the writing device also has thermal stability. [Some materials have sufficient operating life. 0 A typical OLED group is separated from the right by & Interposed (including at least one photo organic layer). The electrode (anode) is injected with a sub-portion and the other electrode (negative electrode) is injected with a negative charge carrier. f In a typical OLED device, the luminescent material may be a polymer or a + μ ^ anode layer is made of a transparent conductive material such as indium tin oxide (yttrium oxide), and the cathode layer is usually made of a low work function such as c_Mg. Material composition. Flat panel displays typically include an array of imaged or patterned images or pixels on a substrate. This pixel array is usually composed of columns and rows in a passive matrix type 〇LED display, by means of (ano), to the genus? The overlap of (cathodes) defines each pixel. In order to make a specific pixel and then the line of the specific pixel (positive polarization) line and column (negative) line 121629.doc 200810106 ^ sufficient voltage. The anode strip can be easily formed by using a feather, privacy, and table etching process prior to depositing the organic layer. However, 'the cathode cannot be patterned in the same way, because it is greedy
=!!溶液會引起對底層有機化合物之損壞。形成陰極i ^之攻簡單方法係經由—單獨之《遮罩真空蒸發陰極金 然而,對於此方法,由於遮罩材料之製造精度及強产 ,限制,難以達成精細界定之圖案,即線距為1〇〇職或: 少之圖案。在使用此-輕料之製造過程中,在真办系 統中之對齊亦係„,且遮罩與基板之間的距離將導:模 糊之邊緣。 敫人種可用於保護一 0LED之該等脆弱有機層之技術係一 整合式遮罩,經由該遮罩可自動地對有機層及電極層進行 圖案化。頒予Tang之美國專利申請案第5,294,87〇號(公佈 於1994年!月4日)(有機電致發光多色影像顯示器鴻示在沈 積-有機EL層之前使用一系列由微影蝕刻形成之平行壁, 使得在沈積有機EL媒體後,無需微影㈣㈣化步驟或濕 化學法。為獲得陰極在横向間隔行中之沈積圖t,該沈積 f面相對於欲沈積之金屬源極定位,使得每—壁均插在有 機EL媒體表面之源極與1轉部分之間。當沿此—方向進 行沈積時,料牆壁之插人部分t途攔截自該源極行進之 =屬原子,藉此防止金屬沈積在每一壁一側上之有機££媒 體上。此設置蛾鄰之陰極列之間的間距。然而,該整合式 遮罩而要-固定之極度離軸或大角度沈積,此對於需要移 動傳送帶或旋轉體情況下之大規模生成不可行。 121629.doc 200810106 為解決該問題’整合式遮罩中之平行壁可係—系列具有 逆行輪廓(截面呈梯形)之柱子,使用一多層光阻系統來形 成具有斜邊之光阻柱子。柱子之逆行角度必須足以確保陰 極金屬不塗覆該等側壁及電短接田比鄰之列。所需之柱子輪 廊主要相依於陰極源相對於基板之相對方向。因此,該逆 行柱子輪廓仍保持對沈積角之限制。 頒予等人之美國專利第M07,楊號(公佈於2〇〇2 年6月18日)及6,596,443號(公佈於年7月22日)揭示—種 單層整合式遮罩,盆葬 一稭由使用一不同光阻系統(例如NR7- 副0-ΡΥ)而具有側壁f曲輪廓及懸垂部分之清晰特徵。該 遮ί具有,少1,5之大縱橫比,將縱橫比定義為過切部分 之洙度與局度之比。然而’若需要—精細定義之遮罩,則 大縱橫比使得柱子極為脆弱。而且,即使可用沈積角产已 被放大,在該整合式遮罩中亦仍存在對沈積角度之限:。 雖然在整合式遮罩中廣泛地利用基礎-過切部分-縣垂 部分結構來避免跨遮罩之短接,但用於沈積該電極之製程 千知旱方此避免短接問題。導電材 等平行電極條帶之間的二 擴散在大程金屬原子之擴散,同時該 言,化學塞氣沈積繁^物 沈積之材料。舉例而 散。不合意覆積製程展現出更多之擴 積。離軸沈積係自一不垂直於詨、角度沈 在懸垂部分下方Η # X的沈積’此可 方士成凹進表面,從而失去到正沈積之材料 121629.doc 200810106 源之直接視線保護。因此,為避免習用整合式遮罩之短接 問題,通常將材料及沈積製程限定於彼等產生小擴散之材 料及製程。舉例而言’通常不藉助該等遮罩來上^發光 OLED中之ΓΓΟ實施圖案化,力因通常所需之相關㈣或減 鑛均涉及大程度之擴散。 為減輕限制沈積角度之問題,頒予⑽㈣咖等人之美 國專利第5,7〇1,055號(公佈於彻年12月23日)揭示一具有=!! The solution will cause damage to the underlying organic compounds. The simple method of forming the cathode i ^ is through a separate "mask vacuum evaporation cathode gold. However, for this method, due to the manufacturing precision and strong production of the mask material, it is difficult to achieve a finely defined pattern, that is, the line pitch is 1 dereliction of duty or: less pattern. In the manufacturing process of using this light material, the alignment in the real system is also „, and the distance between the mask and the substrate will be guided: the edge of the blur. The human race can be used to protect the fragile of an OLED. The technique of the organic layer is an integrated mask through which the organic layer and the electrode layer are automatically patterned. U.S. Patent Application No. 5,294,87, issued to Tang, issued on (Organic electroluminescent multi-color image display shows a series of parallel walls formed by lithography etching before the deposition-organic EL layer, so that after deposition of the organic EL medium, no lithography (four) (four) steps or wet chemical methods are required In order to obtain a deposition map t of the cathode in the laterally spaced row, the deposition f-plane is positioned relative to the metal source to be deposited such that each wall is interposed between the source and the 1-turn portion of the surface of the organic EL medium. In this direction, when the deposition is carried out, the insertion portion of the material wall intercepts the atom that travels from the source, thereby preventing the metal from depositing on the organic media on the side of each wall. The spacing between the cathode columns. However, the integrated mask is required to be extremely off-axis or large-angle deposition, which is not feasible for large-scale generation in the case of moving a conveyor belt or a rotating body. 121629.doc 200810106 To solve this problem 'integrated mask The parallel wall in the series can be a series of columns with a retrograde profile (a trapezoidal cross section), using a multilayer photoresist system to form a photoresist column with a beveled edge. The retrograde angle of the column must be sufficient to ensure that the cathode metal is not coated. The side wall and the electric short circuit are adjacent to each other. The required column wheel gallery mainly depends on the relative direction of the cathode source relative to the substrate. Therefore, the contour of the retrograde column still maintains the restriction on the deposition angle. M07, Yang (published on June 18, 2nd, 2nd) and 6,596,443 (published on July 22nd) reveal a single-layer integrated mask, which is used by a different photoresist system. (for example, NR7-sub 0-ΡΥ) has a clear feature of the curved contour of the side wall and the overhanging portion. The mask has a large aspect ratio of less than 1,5, and defines the aspect ratio as the degree and degree of the overcut portion. Ratio 'If needed—a well-defined mask, the large aspect ratio makes the column extremely fragile. Moreover, even if the available deposition angle has been amplified, there is still a limit on the deposition angle in the integrated mask: In the type of mask, the base-overcutting part-counternal part structure is widely used to avoid shorting across the mask, but the process for depositing the electrode is to avoid short-circuit problems. Parallel electrode strips such as conductive materials The diffusion between the two bands in the diffusion of the metal atoms in the long-range, and at the same time, the chemical deposition of the material deposited by the gas. The example is scattered. The undesired overburden process shows more expansion. Off-axis deposition system Since one is not perpendicular to the 詨, the angle sinks below the overhanging part Η # X's deposition' This can be recessed into the surface, thus losing the direct line of sight protection of the positively deposited material 121629.doc 200810106 source. Therefore, in order to avoid the short-circuit problem of the integrated mask, the materials and deposition processes are usually limited to those materials and processes that produce small diffusion. For example, the patterning of the luminescent layer in the OLED is typically performed without the aid of such masks, and the force is generally diffused due to the generally required correlation (4) or reduction. In order to alleviate the problem of limiting the deposition angle, U.S. Patent No. 5,7〇1,055 (published on December 23 of the following year) issued by (10) (4), et al.
叫懸垂部分及—聚醯亞胺過切部分之兩層圖案化系統。 藉由微影_製程及反應性離子㈣製程形成該氧化物懸 垂部分,且藉由在鹼性溶液中之一濕式蝕刻或反應性離子 蝕刻與濕式蝕刻之組合形成該聚醯亞胺過切部分。然而, 該懸垂部分由於厚Si〇2與聚醯亞胺之間的弱黏附力^相當 〃匕可‘致在隧後之濕式蝕刻及乾燥製程期間該懸垂 部分自該基礎上之剝落。此外’聚醯亞胺之尺寸在很大程 度上相依於濕式蝕刻參數’濕式蝕刻參數可導致一不合責 之形狀及均句性問題。 “ 同樣,頒予BUrrows等人之美國專利第6,〇13,538號(公 於咖叫们!日)揭示-具有一懸垂部分及一過切部分 於^積有機物、陰極及保護層之多層圖案化系统。在該 有陽極條帶之基板上沈積一 2〇。麵厚之絕緣層⑽, ^ ^lNx或聚酿亞胺)。’使用—合適之方法將該絕 曰^、化成多個條帶以暴露該陽極區域進行光昭射。其 該等絕緣條帶,順次形成另―絕緣層及—光阻層。㈣ 由相應之顯影製程及化學蝕刻製程形成光阻層之懸垂部 121629.doc 200810106 及絕緣層之過切部分。 另一多層整合式遮罩揭示於頒予〇、乃⑽ Roth ^ Isabelle Levesque - John Stapledon - Anne Donat-办⑽"/W之合成金屬422 (2〇〇1) 225_227(公佈於2〇〇1年5月1 曰)中’其使用密集之Si〇2層,隨後係一多孔81〇2層,且藉 由PECVD沈積Si#4覆蓋該Si〇2層,且藉由傳統之微影钱 刻製私進行圖案化。It is called a two-layer patterning system of the overhanging part and the overcutting part of the polyimine. The oxide overhang portion is formed by a lithography process and a reactive ion (4) process, and the polyimine is formed by a wet etching or a combination of reactive ion etching and wet etching in an alkaline solution. Cut the part. However, the overhang portion is equivalent to the weak adhesion between the thick Si〇2 and the polyimide, so that the overhanging portion is peeled off from the foundation during the wet etching and drying process after the tunneling. In addition, the size of the polyimine is largely dependent on the wet etch parameters. The wet etch parameters can result in an unsuitable shape and uniformity problem. U.S. Patent No. 6, 〇 13, 538 (issued to the singer!) of the U.S. Patent No. 6, the disclosure of which is incorporated herein by reference. System. Depositing a layer of 2 Å on the substrate with the anode strip. The insulating layer (10) of surface thickness, ^ ^lNx or poly nitrite. 'Use the appropriate method to convert the ruthenium into a plurality of strips. Exposing the anode region for light exposure. The insulating strips sequentially form another insulating layer and a photoresist layer. (4) forming a suspension portion of the photoresist layer by a corresponding developing process and a chemical etching process 121629.doc 200810106 and Overcutting part of the insulation layer. Another multi-layer integrated mask is revealed in the award of 〇,乃(10) Roth ^ Isabelle Levesque - John Stapledon - Anne Donat-do (10)"/W of synthetic metal 422 (2〇〇1) 225_227 (published in May 1st, 2011), which uses a dense Si〇2 layer, followed by a porous 81〇2 layer, and covers the Si〇2 layer by PECVD deposition of Si#4, and It is patterned by the traditional lithography.
藉由在一緩衝氫氟酸溶液中蝕刻該絕緣體堆疊來轉印該 圖案。藉由使用不同之蝕刻速率(密集si〇2層(1〇〇 nm/分 鐘)、多孔Si〇2層(25〇 nm/分鐘)及叫队(4〇 nm/分鐘))來形 成一含有一密集Si〇2之基礎層、一多孔以…之過切部分層 及一懸垂部分層之結構。顯而易見,製造該等整合式 遮罩需要物理或化學蒸氣沈積製程,導致較高之製造成 本。此外,用於形成過切部分之化學蝕刻製程中之酸性溶 液亦侵㈣透明陽極層,該透明陽極層通f係氧化鋼錫The pattern is transferred by etching the insulator stack in a buffered hydrofluoric acid solution. By using different etching rates (dense si〇2 layer (1〇〇nm/min), porous Si〇2 layer (25〇nm/min) and called (4〇nm/min)) The base layer of the dense Si〇2, the structure of a porous partial layer and a suspended partial layer. It is apparent that the fabrication of such integrated masks requires a physical or chemical vapor deposition process resulting in higher manufacturing costs. In addition, the acidic solution in the chemical etching process for forming the overcut portion also invades the (iv) transparent anode layer, which is oxidized steel tin.
、因此,存在對提供一謀求解決上述缺點之至少一者之替 代整合蔽蔭遮罩設計及製造方法之需要。 【發明内容】 根據本發明之—第—態樣,提供-種整合«遮罩,其 匕括基板;至少-具有—基礎部分及—由該基礎部分 切之懸垂部分之柱子結構;其中該基礎部分與該懸垂部 '係整體形成,且該懸垂部分包括一過切表面部分,該過 切表面部分自該懸垂部分之一邊緣大致平行於或與分離於 121629.doc -10- 200810106 該基扳之一表面朝該基礎部分延伸β 該過切表面部分可包括一槽。該基礎部分可形成於一形 成於該基板上之基礎層上。該基礎層可自該基礎部分延伸 至該基板表面上至少一個點,在該至少一個點處該表面之 一表面法線與該懸垂部分之邊緣對準。 每一柱子結構均可形成為一延伸於該基板表面上之條 帶。 /Accordingly, a need exists to provide an alternative integrated shade mask design and method for providing at least one of the above disadvantages. SUMMARY OF THE INVENTION According to a first aspect of the present invention, there is provided an integrated «mask comprising a substrate; at least - having a base portion and a pillar structure cut by the base portion; wherein the foundation The portion is integrally formed with the overhang portion, and the overhanging portion includes an overcut surface portion that is substantially parallel to or separated from one of the edges of the overhanging portion from 121629.doc -10- 200810106 One of the surfaces extends toward the base portion. The overcut surface portion may include a groove. The base portion can be formed on a base layer formed on the substrate. The base layer can extend from the base portion to at least one point on the surface of the substrate at which a surface normal to the surface is aligned with the edge of the overhang portion. Each of the pillar structures can be formed as a strip extending over the surface of the substrate. /
。玄迫罩可進一步包括一形成於該基板表面與該柱子之基 礎部分之間的第一電極層。該基板可包括一撓性基板。 根據本發明之一第二態樣,提供一種製造一整合蔽蔭遮 罩之方法’該方法包括:提供—基板;在該基板上形成至 少-個柱子結構’該柱子結構具有—基礎部分及―由該基 礎部分支撐之懸垂部分;其中該基礎部分與該懸垂部分係 整體形成且該懸垂部分包括—過切表面部分,該過切表面 部分自該之-邊緣大致转於或分離於該基板之 一表面朝該基礎部分延伸。 部分中形成一槽。該 基礎層,並在該基礎 該方法可進一步包括在該過切表面 方法可進一步包括在該基板上形成一 層上形成該基礎部分。 至该基板表面上至少一個 該基礎層可自該基礎部分延伸 點’在該至少一個點處該表面之一 处衣曲之表面法線與該懸垂部分 之邊緣對齊。每一柱子結構均可形 僻』4 I成為一於該基板該表面 上延伸之條帶。 面與該柱子之該基礎部 該方法可進一步包括在該基板表 12I629.doc 200810106 分之間形成一第一電極層。 形成該柱子結構可包括在該基板上形成—㈣調整物; 在該過切調整物上沈積-柱子材料;及移除該過切調整物 以自该基板釋放該柱子結構之懸垂部分。 該基板可包括一撓性基板。 根據本發明之-第三態樣,提供一種利用第一態樣中所 界定之遮罩製造一有機發光裝置之方法。 【實施方式】. The sinister cover may further include a first electrode layer formed between the surface of the substrate and a base portion of the pillar. The substrate can include a flexible substrate. According to a second aspect of the present invention, a method of fabricating an integrated shadow mask is provided, the method comprising: providing a substrate; forming at least one pillar structure on the substrate; the pillar structure having a - base portion and An overhanging portion supported by the base portion; wherein the base portion is integrally formed with the overhanging portion and the overhanging portion includes an overcut surface portion that is substantially rotated or separated from the substrate by the edge-edge A surface extends toward the base portion. A groove is formed in the portion. The base layer, and at the basis of the method, the method further comprising the step of forming the base portion on the substrate by forming a layer on the substrate. At least one of the base layers on the surface of the substrate may extend from the base portion. At the at least one point, the surface normal of the bend at one of the surfaces is aligned with the edge of the overhang. Each of the pillar structures can be shaped to form a strip extending over the surface of the substrate. The surface and the base portion of the column. The method can further include forming a first electrode layer between the substrate table 12I629.doc 200810106. Forming the pillar structure can include forming - (iv) an adjustment on the substrate; depositing - a pillar material on the overcut adjustment; and removing the overcut adjustment to release the overhang of the pillar structure from the substrate. The substrate can include a flexible substrate. According to a third aspect of the present invention, there is provided a method of fabricating an organic light-emitting device using a mask as defined in the first aspect. [Embodiment]
本發明說明一種且有一 ””2 u + « /、百「形柱子輪廓之整合式遮罩。 該遮罩結構實際上對沈積角度、欲沈積之㈣及蒸氣沈積 製紅無限制,且因此使得能夠利Μ前不適用於頂部電極 沈積之製程’例如具有高度離軸沈積之cvd、pvD濺鍍。 本發明亦說明-整合式遮罩製造方法,該方法特定㈣ 合使用先前遮罩難以實現之高解析度〇咖裝置之高良率 大規模生產。 本發明亦說明一種使用整合式遮罩製造一被動型矩陣 OLED裝置之方法。 圖1 a及ib分別示意性地顯示"「"形遮罩丨〇〇、」5〇之截面 圖。設計100與設計! 5〇之間唯—的區別在於設計t 5〇中之 懸垂部分在其底部表面154上具有一額外槽152。 槽152可呈任一可存在之幾何形狀,例如正方形、矩 形、三角形、曲線等。相依於該遮罩設計,過切部分1〇2 之高度可介於約2至约2〇 μηΐ2範圍内,較佳地介於約之至 約4,之範圍内以實現高解析度。縱橫比(定義為過切部 I21629.doc -12- 200810106 分102之深度與高度之比)可自約〇·5至約3〇,較佳地自約 1.0至約2·0 μπι。懸垂部分1〇4之厚度可自約2至約1() μηι, 較k地自約3至約6 μιη。柱子基礎1 〇 6及懸垂部分1㈣係整 體形成,且懸垂部分1 04包括一自懸垂部分丨〇4之邊緣1〇9 朝柱子基礎106基本上平行於基板112之表面11〇延伸之過 切表面部分1 07。在其他遮罩設計中,過切表面部分玉〇7可 自懸垂部分104之邊緣1〇9朝柱子基礎106基本上分離於基 板112之表面11〇延伸。 柱子基礎106之尺寸相依於所期望之裝置解析度。所要 求之解析度愈咼,柱子基礎1 〇6愈小。然而,柱子基礎1 〇6 較佳地足夠寬以達成所期望之柱子強度。較佳地,柱子基 礎106之寬度至少與柱子1〇8之總高度相同。基礎層ιΐ4自 柱子基礎106延伸至基板112之表面u〇之至少一點,其中 表面11 〇之一表面法線(未顯示)與懸垂部分1 04之邊緣1 09對 齊。 在圖la及lb中亦顯示一沈積於遮罩1〇〇及ι5〇上之金屬層 116,其圖解說明金屬層116中由過切部分1〇2所致之不連 績性’攸而’避免金屬層Π6之頂部電極118之毗鄰條帶之 間的電短接。 圖2a顯示’’「η形遮罩1〇〇之典型製造製程。以一形成於 基板201上之經圖案化底部電極(或陽極)200開始,形成 ”有像素自204之基礎層202。基礎層202之材料可係UV 可固化聚合物,例如苯并環丁烯(BCB)及聚醯亞胺且藉由 仏準微餘刻術進行圖案化。另一選擇係,基礎層2〇2可 121629.doc -13- 200810106 由諸如Si02、ai203及Ti〇2等氧化物装A A ” 乳化物猎由溶膠-凝膠沈積或 m沈積並藉由微影蝕刻及/或化學蝕刻進行圖案化而製 成。然後在基礎層2〇2上形成過切調整物2G6。藉由選擇不 同之光阻劑及改變旋韓塗你失杳 义捉轉土怖參數或兩者可調整調整物206 之厚度。過切調整物施之形狀將定義最終之柱子輪廓。 過切調整物2 0 6之材料可待可益士 iθ 杯t十j係了猎由普通顯影劑或溶劑容易 地移除之正性光阻劑或負性光阻劑。。然後在基礎層2〇2The present invention describes an integrated mask having a contour of a column shape and having a shape of a pillar. The mask structure actually has no limitation on the deposition angle, the (4) to be deposited, and the red deposition of vapor deposition, and thus It can be used for the process of top electrode deposition beforehand, for example, cvd, pvD sputtering with high off-axis deposition. The present invention also describes an integrated mask manufacturing method, which is specific to (4) difficult to use with previous masks. High-yield mass production of high-resolution coffee makers. The present invention also illustrates a method of fabricating a passive matrix OLED device using an integrated mask. Figures 1 a and ib schematically show "" Cover, 〇, 5〇 section view. Design 100 and design! The only difference between the five turns is that the overhanging portion of the design t5 has an additional groove 152 on its bottom surface 154. The grooves 152 can be in any geometric shape that may exist, such as squares, rectangles, triangles, curves, and the like. Depending on the mask design, the height of the overcut portion 1 〇 2 may range from about 2 to about 2 〇 μη ΐ 2, preferably from about to about 4, to achieve high resolution. The aspect ratio (defined as the ratio of depth to height of the overcut portion I21629.doc -12- 200810106 points 102) may range from about 55 to about 3 〇, preferably from about 1.0 to about 2.0 μm. The thickness of the overhanging portion 1〇4 may be from about 2 to about 1 () μηι, from about 3 to about 6 μηη from k. The pillar base 1 〇 6 and the overhanging portion 1 (four) are integrally formed, and the overhanging portion 104 includes an overcut surface extending from the edge 1 〇 9 of the tiling portion 朝 4 toward the pillar base 106 substantially parallel to the surface 11 〇 of the substrate 112 Part 1 07. In other mask designs, the overcut surface portion of the maize 7 may extend from the edge 1〇9 of the overhanging portion 104 substantially toward the surface 11〇 of the substrate 112 from the pillar base 106. The size of the column foundation 106 is dependent on the desired resolution of the device. The more the resolution required, the smaller the column base 1 〇6. However, the column foundation 1 〇 6 is preferably wide enough to achieve the desired column strength. Preferably, the width of the column base 106 is at least the same as the total height of the columns 1〇8. The base layer ι 4 extends from the pillar base 106 to at least one point on the surface u of the substrate 112, wherein a surface normal (not shown) of the surface 11 对 is aligned with the edge 109 of the overhang portion 104. Also shown in FIGS. 1a and 1b is a metal layer 116 deposited on the masks 1 and 1 ,5, which illustrates the discontinuity of the metal layer 116 caused by the overcut portion 1〇2. Electrical shorting between adjacent strips of the top electrode 118 of the metal layer Π6 is avoided. Figure 2a shows a typical fabrication process for a '''-type mask. Starting with a patterned bottom electrode (or anode) 200 formed on substrate 201, a base layer 202 having pixels from 204 is formed. The material of the base layer 202 may be a UV curable polymer such as benzocyclobutene (BCB) and polyimine and patterned by 仏 micro-residual. Alternatively, the base layer 2〇2 may be 121629.doc -13- 200810106 by an oxide such as SiO 2 , ai 203 and Ti 〇 2 emulsified by sol-gel deposition or m deposition and by lithography Etching and/or chemical etching is performed by patterning. Then, over-cutting adjustment 2G6 is formed on the base layer 2〇2. By selecting different photoresists and changing the rotation of the Korean coating, you lose the meaning of the soil. Or both can adjust the thickness of the adjustment 206. The shape of the overcut adjustment will define the final column profile. The material of the overcut adjustment 2 0 6 can be used for the cocoa iθ cup t t The agent or solvent is easily removed by a positive photoresist or a negative photoresist. Then in the base layer 2〇2
上及過切調整物206上形成遮罩柱子2〇8。遮罩柱子2〇8之 材料可係UV可固化聚合物且藉由標準微影钱刻術進行圖 案化。該光阻劑較佳地與預形成之過切調整物2〇6相容以 在處理期間避免或最大程度地減小對調整物寫之損壞或 使,、文开y之私度。另一選擇係,類似於基礎層202,柱子 8可由諸如Si〇2、Al2〇3及Τι〇2等氧化物藉由溶膠凝膠沈 積或蒸氣沈積且藉由微影㈣及/或化學㈣予以圖案化 而製成。在使用顯影劑或溶劑移除過切調整物2〇6之後形 成"Γ"形遮罩100。 圖2b顯示”「”形遮罩15〇之典型製造製程(圖ib)。以在形 成於一基板251上之經圖案化之底部電極(或陽極)25〇開 始,形成一具有像素窗口 254之基礎層252。基礎層252之 材料可係uv可固化聚合物,例如BCB及聚醯亞胺且藉由 標準微影蝕刻術進行圖案化。另一選擇係,基礎層M2可 由諸如Si〇2、Α!2〇3及Τι〇2等氧化物藉由溶朦_凝朦沈積或 瘵虱沈積且藉由微影蝕刻及/或化學蝕刻進行圖案化而製 成。然後在基礎層252上形成過切調整物256。藉由選擇不 121629.doc -14- 200810106 =阻劑及改變旋轉塗佈參數或兩者可調整調整物256 、予又。過切調整物256之形狀將定義最終之柱子輪廓。 過切調整物256之材料可係可藉由並 x ^ r 曰由曰通頌衫劑或溶劑容易 地私除之正性光阻劑或負性光阻劑。 25=:,對於_示之製造製程,首先在麵 / " 佈—第一光阻劑且經由—遮罩(未顯示)曝光以 在顯影之後定義過切調整物2 主 ^ 心土版255之間的開孔 =過:調整物256上旋轉塗佈-與形成過切調整物 256主體之光阻劑不同之光阻劑259作為緩衝層,且經曝光 及顯影以形成開孔’用於沈積由與過切調整物…之主體 ⑸相同類型之光阻劑形成之紐結部分⑸。然後在基礎層 252及過切調整物256上形成遮罩柱子258。遮罩柱子Mg之 材料可係UV可固化聚合物且藉由標準微影餘刻進行圖案 化。該光阻劑較佳地與預形成之過切調整物…相容以在 處理期間避免或最大程度地減小對調整物256之損壞或使 其變形之程度。另-選擇係,類似於基礎看⑸,柱子W 可由諸如Si〇2、八12〇3及Ti〇2等氧化物藉由溶膠-凝膠沈積 或蒸氣沈積且藉由微影蝕刻及/或化學蝕刻予以圖案化而 製成。在使用I員影劑或溶劑移除過切調整物256(連同紐結 部分257及缓衝層259)之後形成,,「”形遮罩15〇。 圖3a顯示一被動型矩陣〇LED裝置之一製造完成之整厶 式遮罩300之示意性透視圖。複數個具有,,「"形之遮罩^ 帶302相對於底部電極304以一定向空間關係(例如一正交 空間關係)形成於基板306上之底部電極3〇4上方。如在圖 121629.doc -15- 200810106 中所不#由經圖案化之底部電極3〇4與頂部電極條帶 3 G 5之間的交叉來界定發光區域删之像素。製造整合式遮 罩〇〇使知自動圖案化隨後之有機沈積層及金屬頂部電 極沈積層305。 * 纟電極3G4沈積於基板3G6上且係使m微影钱刻術 • 及化子蝕刻衣釭圖案化。底部電極304及基板3〇6可由具 有白用尺寸之習用材料製成。在底部發光及雙面發光裝置 # t示射,基板3〇6可透明,例如為玻璃板、石英板或塑 踢板,且在上部發光裝置之示例中,基板306可不透明, 例如為Si晶圓、氧化物板、金屬板及諸如此類。基板挪 可係撓性基板,例如超薄玻璃、薄金屬及塑膠。在底部發 光及雙面叙光及上部發光裝置之示例中,底部電極可 由諸如導電聚合物、IT〇及其他透明導電氧化物(TC0)等 透明導體製成,而在上部發光裝置之示例中,底部電極 3〇4可不透明,由諸如金屬及類似材料製成。 # 在底部電極304及基板306上方形成有具有用於像素之敞 開窗口之基礎層(未顯示)。然後在基礎層上製造具有'「" . 形條帶或柱子302之整合式遮罩300。然後經由整合式遮罩 . 300沈積一個或多個有機層307(未顯示),使得有機層3〇7電 . 連接至底部電極304。有機層307可包括任何習用之〇led 有機材料。有機層307可係一單層,或可包括多層習用 OLED結構’例如一單層或雙層異質結構,或—個或多個 合有一OLED有機材料混合物之層。有機層3〇7可由旋轉塗 佈、噴墨印花、蒸氣沈積及類似製程形成。 121629.doc -16 - 200810106 然後經由整合式遮罩300且在有機層307上沈積複數個頂 部電極條帶305(未顯示),使得頂部電極3〇5電連接至有機 層307。頂部電極3〇5可係舉例而言一由IT〇、ai、、 Ca、Ca/Al、Mg:Ag或LiF:Al製成。較佳地,一極薄頂部電 極透明,使得發射自有機層之光可穿過頂部電極到達一觀 察者,此示例中之裝置可係一上部發光〇led。Mask pillars 2〇8 are formed on the upper and overcut adjustments 206. The material of the mask column 2〇8 can be a UV curable polymer and patterned by standard lithography. The photoresist is preferably compatible with the preformed overcut adjustment 2〇6 to avoid or minimize the damage to the adjustment written during processing or to the extent that it is private. Another alternative is that, similar to the base layer 202, the pillars 8 can be deposited by sol-gel deposition or vapor deposition from oxides such as Si〇2, Al2〇3, and Τι〇2 and by lithography (4) and/or chemistry (4). Made by patterning. The "Γ" shaped mask 100 is formed after the overcutting adjustment 2〇6 is removed using a developer or solvent. Figure 2b shows a typical manufacturing process for a "" shaped mask 15 (Figure ib). A base layer 252 having a pixel window 254 is formed starting at a patterned bottom electrode (or anode) 25 Å formed on a substrate 251. The material of the base layer 252 can be a uv curable polymer such as BCB and polyimine and patterned by standard lithography. Alternatively, the base layer M2 may be deposited by a solvent such as Si〇2, Α!2〇3, and Τι〇2 by lyotropic deposition or ruthenium deposition and by photolithography etching and/or chemical etching. Made by patterning. Overcutting modifier 256 is then formed on base layer 252. The adjustment 256 can be adjusted by selecting not 121629.doc -14- 200810106 = resist and changing the spin coating parameters or both. The shape of the overcut adjuster 256 will define the final post profile. The material of the overcutting adjustment 256 may be a positive photoresist or a negative photoresist which can be easily detached by a 曰 颂 或 或 或 or a solvent. 25=:, for the manufacturing process of _, first in the face / " cloth - first photoresist and through the - mask (not shown) exposure to define the overcut adjuster 2 after development 255 Opening between the openings = over: the spin coating on the adjuster 256 - a photoresist 259 different from the photoresist forming the body of the overcut adjuster 256 as a buffer layer, and exposed and developed to form an opening 'for A kink portion (5) formed of the same type of photoresist as the body (5) of the overcutting adjustment is deposited. A mask pillar 258 is then formed on the base layer 252 and the overcut adjustment 256. The material of the mask pillar Mg can be a UV curable polymer and patterned by standard lithography. The photoresist is preferably compatible with the preformed overcut adjustments to avoid or minimize the extent of damage to or deformation of the adjustment 256 during processing. Another-selection system, similar to the basic (5), column W can be deposited by sol-gel deposition or vapor deposition and by lithography and/or chemistry by oxides such as Si〇2, 八12〇3, and Ti〇2. Etching is performed by patterning. After the overcutting adjustment 256 (along with the kink portion 257 and the buffer layer 259) is removed using an I agent or solvent, the "" shaped mask 15". Figure 3a shows a schematic perspective view of a finished mask 300 made by one of a passive matrix 〇 LED device. A plurality of "" shaped masks<RTI ID=0.0>>> .doc -15- 200810106 does not define the intersection of the patterned bottom electrode 3〇4 and the top electrode strip 3 G 5 to define the pixels of the light-emitting area. The subsequent organic deposition layer and the metal top electrode deposition layer 305 are patterned. * The ruthenium electrode 3G4 is deposited on the substrate 3G6 and patterned by the m lithography and the etched coating. The bottom electrode 304 and the substrate 3 〇 6 can be made of a conventional material having a white size. In the bottom illumination and double-sided illumination device #t, the substrate 3〇6 can be transparent, such as a glass plate, a quartz plate or a plastic kick plate, and is in the upper light-emitting device. In an example, the substrate 306 may be opaque, such as a Si wafer, an oxide plate, a metal plate, and the like. The substrate may be a flexible substrate such as ultra-thin glass, thin metal, and plastic. Upper illuminator In the example, the bottom electrode may be made of a transparent conductor such as a conductive polymer, IT〇, and other transparent conductive oxide (TC0), and in the example of the upper light emitting device, the bottom electrode 3〇4 may be opaque, such as metal and the like. Made of material. # A base layer (not shown) having an open window for the pixels is formed over the bottom electrode 304 and the substrate 306. Then, an integrated layer having a '"" . strip or column 302 is fabricated on the base layer. a mask 300. One or more organic layers 307 (not shown) are then deposited via the integrated mask 300 such that the organic layer 3〇7 is electrically connected to the bottom electrode 304. The organic layer 307 can include any conventionally used The organic material 307 may be a single layer, or may comprise a plurality of conventional OLED structures 'eg a single or double layer heterostructure, or one or more layers combined with an OLED organic material mixture. Organic layer 3〇7 It can be formed by spin coating, ink jet printing, vapor deposition, and the like. 121629.doc -16 - 200810106 Then a plurality of top electrode strips 305 are deposited via the integrated mask 300 and on the organic layer 307 (not The top electrode 3〇5 is electrically connected to the organic layer 307. The top electrode 3〇5 may be made, for example, of IT〇, ai, Ca, Ca/Al, Mg:Ag or LiF:Al. Preferably, a very thin top electrode is transparent such that light emitted from the organic layer can pass through the top electrode to an observer, and the device in this example can be an upper illuminator.
吾一電流經由有機層穿行於底部電極3〇4與頂部電極% 之間時,所形成之裝置發光。㈣置可係—規則底部發力 OLED ’使得經由底部電極及基板發光;或係一上部發y OLED ’使得經由頂部電極發光。 整合式遮罩300藉由提供_平行於基板鳩之過 =!:地避免電極之間的電短接。另外,整合式遮, A大對沈㈣度之限制,使得整合式遮罩 口大規极生產。較佳地’當所製 313時,在遮罩過切部分 卓柱子-有榍 使使用嚴重擴散之材料及擊炉Λ是存在一死角,即 有機材料i ‘ 卜、王進行沈積,遮罩亦可不會受 有栻材枓及導電材料影響。 曰又 應瞭解,可製造甚大於彼等 詈陳列。雜姑、π 承文中具體所述之有機裝 置陣列雖然圖3a及3b顯示一 令栻衣 更大之陣列。而卫 ^ ^ 之裝置陣列,但可製造 下轉換層或使用不同裝置中之、員技術中所習知之各種 顯示器。亦可藉由大量其二同有機材料來製造-多色 光之O L E D結合多個濾色片或—八例如使用一陣列白色發 造一多色陣列。 分佈式布拉格反射鏡來製 121629.doc 200810106 在下文中’將說明—使用正性光阻劑作為過切調整物材 料並使用-負性光阻劑作為柱子材料來製造—整合式遮罩 之具體實例。 以2500 rpm之轉逮蔣_古工士 # i 、市面有σ之正性光阻劑AZ462〇旋 轉塗佈至-玻璃基板上達約卿。將該光 下供培達5分鐘'然後經由-光遮罩將其暴露於2 mWW之寬帶紫外輻射下達%秒鐘,使得僅暴露在顯影 之後欲移除之光阻劑部分。然後在一市面有售之顯影劑 AZ400K令使該光阻劑顯影。過切調整物之高度係約帽 米。 然後以1000 rpm之轉速將一與製造過切調整物之Az462〇 光阻劑相容之負性光阻劑(例如MF4〇)塗覆該面板達秒 鐘’隨後在75。(:下進行預烘培20分鐘。厚度為〇8 _之經 乾燥負性光阻劑用作緩衝層以在隨後之製程期間保護該過 切調整物不受損壞 '然後以测rpm之轉速旋轉塗佈另一 負性光阻劑(例如經稀釋之銲料遮罩)達6〇秒。 在7 5 °C下預烘焙達3 〇分鐘後,將該負性光阻劑層經由一 光遮罩使得僅將在曝光之後預保留之光阻劑部分暴露於來 自一以12.5 mW/cm2之功率運作之高壓汞燈紫外線輻射下 達10秒鐘。然後在室溫下將經曝光之負性層在一含有工至2 %碳酸鈉之水成溶液中且然後在sp 9899顯影劑中顯影, 以移除未曝光之負性層,隨後在與第一次曝光相同之2件 下進行充溢式(flood)UV曝光達至少1 〇分鐘。 然後將已乾燥之面板置入一含有AZ400K之液體中及一 121629.doc 18- 200810106 含有丙酮之液體中以移 々夕降由正性光阻劑製成 物,且最後在一 15〇t 务成之過切調整When a current flows between the bottom electrode 3〇4 and the top electrode % via the organic layer, the formed device emits light. (4) The system can be used to illuminate the OLED through the bottom electrode and the substrate; or to emit an OLED through the top electrode. The integrated mask 300 avoids electrical shorting between the electrodes by providing _parallel to the substrate = =!:. In addition, the integrated cover, A large and heavy (four) degree limit, make the integrated cover mouth large gauge production. Preferably, 'when the 313 is made, in the mask overcutting part of the pillars - there is a flaw in the use of the material that is heavily diffused and the furnace is flawed, that is, the organic material i ' Bu, the king is deposited, the mask is also Can not be affected by the coffin and conductive materials. It should be understood that more than one of them can be produced. The array of organic devices specifically described in the apes, π, although Figures 3a and 3b show a larger array of garments. And the array of devices, but can make the down conversion layer or use various displays as known in the art of different devices. It can also be fabricated from a large number of its organic materials - multi-color light O L E D in combination with a plurality of color filters or - eight, for example, using an array of white to produce a multi-color array. Distributed Bragg Reflector Manufactured 121629.doc 200810106 In the following 'will be explained - using a positive photoresist as a overcut modifier material and using a negative photoresist as a pillar material - a specific example of an integrated mask . At 2500 rpm, Jiang _ Gu Shishi # i, the market has σ positive photoresist AZ462 〇 spin coating onto the glass substrate Daoqing. The light was allowed to pass for 5 minutes' and then exposed to 2 mWW of broadband ultraviolet radiation for up to 2 seconds via a light mask such that only the portion of the photoresist to be removed after development was exposed. The photoresist is then developed by a commercially available developer, AZ400K. The height of the overcutting adjustment is about the cap. A negative photoresist (e.g., MF4 crucible) compatible with the Az462(R) photoresist from which the overcutting modifier was made was then coated at 1000 rpm for a second of seconds followed by 75. (: pre-bake for 20 minutes. The dried negative photoresist with a thickness of 〇8 _ is used as a buffer layer to protect the over-cutting modifier from damage during subsequent processes' and then rotate at rpm Apply another negative photoresist (such as a diluted solder mask) for 6 sec. After pre-baking at 75 ° C for 3 〇 minutes, the negative photoresist layer is passed through a light mask. So that only the portion of the photoresist that is pre-retained after exposure is exposed to ultraviolet radiation from a high-pressure mercury lamp operating at a power of 12.5 mW/cm 2 for 10 seconds. The exposed negative layer is then exposed at room temperature. Containing an aqueous solution of up to 2% sodium carbonate and then developing in sp 9899 developer to remove the unexposed negative layer, followed by flooding at the same 2 pieces as the first exposure UV exposure for at least 1 。 minutes. The dried panel is then placed in a liquid containing AZ400K and a 121629.doc 18-200810106 liquid containing acetone to make a positive photoresist preparation. And finally at the 15 〇t
@ …、火、相中乾燥達2個小時。# A 結果,一具有,,广,,形杈 才作為一 製造。 +之整5 —遮罩準備好用於裝置 牡卜又甲 用一正性光阻劑作為過切 料、使用-負性光阻劑作為一續徐…,、爾物材 光阻劑作為柱子材料製造—整合式遮罩 另们生@ ..., fire, phase drying for 2 hours. # A Result, a possession, a wide, a shape is only made as one. + of the whole 5 - the mask is ready for the device, the matte and the use of a positive photoresist as the over-cut, the use of -negative photoresist as a continuation of Xu..., the material resist as a pillar Material manufacturing - integrated masks
以2500 rpni之轉速將古品士也 八粗κ例。 之轉逮將市面有售之ΑΖ462〇正性 轉塗佈至一玻璃基板 J疋 板上達40移釦。在105tB共焙該光阻 層達5:知,且然後經由-光遮罩將其暴露於一 125 之寬帶紫外線輻射下達35秒鐘,使得僅暴露在顯 衫後欲移除之光阻劑部分。然後將該光阻劑在—市面有隹 之顯影劑AZ4GGK中顯影。該已乾燥之正性光阻層係約°4 μπι 〇 然後以1000 rpm之轉速使用—與製造過切調整物之 AZ4620正性光阻劑相容之負性光阻劑(例如mf4㈧塗覆該 面板達30秒鐘’隨後在饥下進行預洪培達2()分鐘。乾燥 後之負性光阻劑具有0.8 μη1之厚度,用作緩衝層以在以下 製程中保護該過切調整物免受損土裹。然後將該負性光阻層 經由一光遮罩使得僅將在顯影之後欲保留之光阻劑部分^ 露於一 12.5 mW/cm之寬帶紫外線輻射下達6〇秒鐘,。然後 將該經曝光之面板在SP9899顯影劑中顯影以移除該等未曝 光之負性層。然後以2000 rpm之轉速旋轉塗佈入22〇〇14〇 正性光阻劑達約30秒鐘。以下步驟與上文所述關於 121629.doc -19- 200810106 AZ4620之光阻劑相同,但使用—不同之光遮罩。所形成 之兩層光阻旨在製造—具有槽之遮罩柱子之過切調整物 (比較圖1(b)) 〇 另負性光阻劑緩衝層(例如MF40)同樣用以保護調整物 之正性光阻劑部分且以下程序與實例1相同。 整合式«鱗之職設計可佔據—較小空間且較先前 技術達成更高效用。 所述之整合式遮罩製造方法具體地適用於使用現有遮罩 難以達成之OLED裝置之高良率大規模生產。 所述整合式遮罩有效地避免電極之間的電短接。 此外戶/f述整合式遮罩實務上對沈積角度無限制,且因 此較現有遮罩更適合大規模生產。 可藉由設計使用所述沈積之過切調整物準確地調整所述 遮罩中之過切部分及懸垂部分。與例如依賴於兹刻金屬之 底切技術(例如濕式餘刻形成過切部分}相比 改良。 风 可在-單㈣料中而非藉由現有遮罩中之多層 造所述具有”「"形之整合蔽餐遮罩。 所述遮罩結構實際上對沈積角度、欲沈積之_及墓氣 沈積製程無限制,且因此使能夠 π用无刖不適用於頂部電 極沈積之製程,例如離軸沈積之Cvd、pvD濺鍍。、 熟習此項技術者應㈣’可對具體實施例中所示之本發 明進行諸多改變及/或修改, " 、 ^ 此並不背離廣泛所述之本發 明之精神或範脅。因此,兮智每 口此以貫施例在所有態樣中皆應視 I21629.doc -20- 200810106 為僅為例示性而無限定性。 舉例而言,應瞭解’本發明並 陣型裝置,且可用於各心㈤厅达之特夂被動矩 本發明可用於製造諸容咕 i而&, ㈣哭… 費產品’包括平板顯示器、光電 d卩。及先電光電二極體陣列。 此外’用於製造整合式遮罩中之過切調整物及遮罩柱子 之材料可係有機物、無機物及其混合物At the speed of 2500 rpni, the ancient stone is also eight rough κ cases. The transfer will be applied to the commercially available ΑΖ ΑΖ ΑΖ positive transfer to a glass substrate J 疋 board up to 40 shift buckle. The photoresist layer is co-baked at 105tB for 5 minutes and then exposed to a 125 broadband ultraviolet radiation via a light mask for 35 seconds so that only the photoresist portion to be removed after exposure to the shirt is exposed . The photoresist was then developed in a commercially available developer AZ4GGK. The dried positive photoresist layer is about 4 μm 〇 and then used at 1000 rpm—a negative photoresist (eg, mf4 (8)) that is compatible with the AZ4620 positive photoresist that produces the overcut modifier. The panel is up to 30 seconds' and then pre-flooded for 2 minutes in hunger. The dried negative photoresist has a thickness of 0.8 μη1 and acts as a buffer layer to protect the overcutting modifier from damage during the following processes. The negative photoresist layer is then passed through a light mask such that only the portion of the photoresist that is to be retained after development is exposed to a broadband ultraviolet radiation of 12.5 mW/cm for 6 seconds. The exposed panels were developed in SP9899 developer to remove the unexposed negative layers. The 22 〇〇 14 Å positive photoresist was then spin coated at 2000 rpm for about 30 seconds. The procedure is the same as that described above for the photoresist of 121629.doc -19- 200810106 AZ4620, but using a different light mask. The two layers of photoresist formed are intended to be fabricated - the overcut of the masked column with grooves Adjustments (compare Figure 1(b)) 〇Another negative photoresist buffer layer (eg MF40) Also used to protect the positive photoresist portion of the adjustment and the following procedure is the same as in Example 1. The integrated «scale design can occupy - a smaller space and is more efficient than prior art. The integrated mask The manufacturing method is particularly suitable for high-yield mass production of OLED devices that are difficult to achieve using existing masks. The integrated mask effectively avoids electrical shorting between electrodes. There is no limitation on the deposition angle, and thus it is more suitable for mass production than the existing mask. The overcut portion and the overhang portion in the mask can be accurately adjusted by designing the overcut adjustment using the deposition. Improved undercutting techniques for metal undercuts (eg, wet-formed overcuts). Wind can be made in a single (four) material rather than by multiple layers in existing masks. The integrated masking mask. The mask structure actually has no limitation on the deposition angle, the deposition to be deposited, and the tomb deposition process, and thus enables the use of π without flaws for the top electrode deposition process, such as off-axis. Cvd, pvD sputtering. Those skilled in the art should (4) 'may make many changes and / or modifications to the invention shown in the specific embodiments, ", ^ does not deviate from the broadly described invention The spirit or the norm. Therefore, each of the following examples should be considered in all aspects, I21629.doc -20- 200810106 is merely illustrative and not limiting. For example, it should be understood that the present invention And the array device, and can be used for each heart (five) hall to achieve the special passive moment. The invention can be used to manufacture the contents of the 咕i and &, (four) crying ... fee products 'including flat panel display, photoelectric d 卩. and electric photodiode Body array. In addition, the materials used to make overcutting adjustments and mask pillars in integrated masks can be organic, inorganic, and mixtures thereof.
整合=罩中之過切調整物及柱子之塗覆製程可係濕 覆療氣沈積及其組合。此外,本發明並不限於OLED應 用,且可用於各種各樣之電子裝置。關於〇led,本發明 亚不限於所述之特定實例及實施例。 【圖式簡單說明】 圖la及b顯示,,Γ,,型整合蔽蔭遮罩之示意性截面圖。 圖2a及b顯示分別圖解說明圖“及^之,,「”型遮罩之製造 的相應之示意性截面圖序列。 圖3a及b分別顯示藉由使用圖lb之”「”型遮罩製造之一 被動矩陣型0LED顯示器裝置之一示意性透視圖及一示意 性截面圖。 【主要元件符號說明】 100 遮罩 102 過切部分 104 懸垂部分 106 柱子基礎 108 柱子 121629.doc -21 - 200810106Integration = the overcutting adjustment in the hood and the coating process of the column can be wetted and deposited and combinations thereof. Moreover, the invention is not limited to OLED applications and can be used in a wide variety of electronic devices. With regard to 〇led, the present invention is not limited to the specific examples and embodiments described. BRIEF DESCRIPTION OF THE DRAWINGS Figures la and b show schematic cross-sectional views of a Γ, 整合 type integrated shadow mask. Figures 2a and b show respective schematic cross-sectional sequence sequences illustrating the fabrication of the "and", "" type masks, respectively. Figures 3a and b respectively show a schematic perspective view and a schematic cross-sectional view of a passive matrix type OLED display device fabricated by using the "" shaped mask of Figure lb. [Key component symbol description] 100 Mask 102 Overcutting part 104 Overhanging part 106 Column foundation 108 Column 121629.doc -21 - 200810106
109 邊緣 110 表面 112 基板 114 基礎層 116 金屬層 118 頂部電極 150 遮罩 152 槽 154 底部表面 200 底部電極 201 基板 202 基礎層 204 像素窗 206 過切調整物 208 柱子 250 底部電極 251 基板 252 基礎層 253 開?L 254 像素窗口 25 5 主體 256 過切調整物 257 紐結部分 258 遮罩柱子 12l629.doc -22 200810106 259 緩衝層 300 整合式遮罩 3 02 遮罩條帶 304 底部電極 305 金屬頂部電極沈積層 306 基板 307 有機沈積層 308 發光區域 312 過切部分之表面 313 槽109 edge 110 surface 112 substrate 114 base layer 116 metal layer 118 top electrode 150 mask 152 slot 154 bottom surface 200 bottom electrode 201 substrate 202 base layer 204 pixel window 206 overcut adjuster 208 pillar 250 bottom electrode 251 open? L 254 pixel window 25 5 body 256 overcut adjuster 257 kink portion 258 mask pillar 12l629.doc -22 200810106 259 buffer layer 300 integrated mask 3 02 mask strip 304 bottom electrode 305 metal top electrode deposition layer 306 Substrate 307 organic deposition layer 308 light-emitting region 312 surface 313 of the overcut portion
121629.doc -23 -121629.doc -23 -
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/SG2006/000148 WO2007142603A1 (en) | 2006-06-09 | 2006-06-09 | An integrated shadow mask and method of fabrication thereof |
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| TW200810106A true TW200810106A (en) | 2008-02-16 |
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| CN110767683B (en) * | 2018-10-31 | 2022-04-15 | 云谷(固安)科技有限公司 | Display panel, mask and display terminal |
| KR102665230B1 (en) * | 2018-12-14 | 2024-05-09 | 엘지디스플레이 주식회사 | Display device |
| CN111969034A (en) | 2020-09-03 | 2020-11-20 | 深圳市华星光电半导体显示技术有限公司 | Display panel and preparation method thereof |
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| US3808058A (en) * | 1972-08-17 | 1974-04-30 | Bell Telephone Labor Inc | Fabrication of mesa diode with channel guard |
| US3849136A (en) * | 1973-07-31 | 1974-11-19 | Ibm | Masking of deposited thin films by use of a masking layer photoresist composite |
| FR2469804A1 (en) * | 1979-11-07 | 1981-05-22 | Labo Electronique Physique | METHOD FOR PRODUCING A SEMICONDUCTOR DEVICE INCLUDING A DIODES ASSEMBLY IN SERIES AND DEVICE RESULTING THEREFROM |
| US4654295A (en) * | 1983-12-05 | 1987-03-31 | Energy Conversion Devices, Inc. | Method of making short channel thin film field effect transistor |
| JPH06104206A (en) * | 1992-09-18 | 1994-04-15 | Seiko Instr Inc | Method and apparatus for manufacturing semiconductor device |
| US6013538A (en) * | 1997-11-24 | 2000-01-11 | The Trustees Of Princeton University | Method of fabricating and patterning OLEDs |
| US6384529B2 (en) * | 1998-11-18 | 2002-05-07 | Eastman Kodak Company | Full color active matrix organic electroluminescent display panel having an integrated shadow mask |
| US7427529B2 (en) * | 2000-06-06 | 2008-09-23 | Simon Fraser University | Deposition of permanent polymer structures for OLED fabrication |
| US8025831B2 (en) * | 2004-05-24 | 2011-09-27 | Agency For Science, Technology And Research | Imprinting of supported and free-standing 3-D micro- or nano-structures |
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