TW200819486A - Nano bulletproof glass - Google Patents
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- TW200819486A TW200819486A TW95138658A TW95138658A TW200819486A TW 200819486 A TW200819486 A TW 200819486A TW 95138658 A TW95138658 A TW 95138658A TW 95138658 A TW95138658 A TW 95138658A TW 200819486 A TW200819486 A TW 200819486A
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- 239000011521 glass Substances 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 16
- 230000035939 shock Effects 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000002105 nanoparticle Substances 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- PPQREHKVAOVYBT-UHFFFAOYSA-H aluminium carbonate Inorganic materials [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 claims 1
- 229940118662 aluminum carbonate Drugs 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 229920005668 polycarbonate resin Polymers 0.000 claims 1
- 239000004431 polycarbonate resin Substances 0.000 claims 1
- 238000003980 solgel method Methods 0.000 claims 1
- 210000004127 vitreous body Anatomy 0.000 claims 1
- 239000002086 nanomaterial Substances 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002772 conduction electron Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000011359 shock absorbing material Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010068 moulding (rubber) Methods 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000005381 potential energy Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
Landscapes
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
200819486 九、發明說明: 【發明所屬之技術領域】 利用粒徑lOOnm以下、10% wt·以上之奈米顆粒分散在透明樹 脂中,成為奈米樹脂,以製造奈米防彈玻璃,其特徵是:當玻璃 中彈而發生具破壞作用的震波,待其通過奈米顆粒表面時,由於 奈米表面吸著電子之能位會大幅提升,藉此得有效吸收震波能, 以達成高效率之防彈目的。 【先前技術】200819486 IX. Description of the Invention: [Technical Field] The nanoparticle having a particle diameter of 100 nm or less and 10% wt· or more is dispersed in a transparent resin to form a nano resin to produce a nano-ballistic glass, which is characterized by: When the glass is bombarded and a destructive shock wave occurs, when it passes through the surface of the nanoparticle, the energy of the electron adsorbed on the surface of the nanometer will be greatly increased, thereby effectively absorbing the seismic energy to achieve high-efficiency bulletproof purposes. . [Prior Art]
U 在第二次世界大戰期間所使用的防彈玻璃,係利用液體橡膠 將多層玻璃板黏合成一體的多夾層玻璃板所構成,厚度高達1〇〇 〜120nm,而且極端重。近來則利用吸震功能優良的聚碳酸酯埶塑 型塑料^以取代先前的液體橡膠,層夾在普通玻璃之中,以形成 夾層防彈玻璃,其防彈功能雖已提升,惟此夾層玻璃厚度通常在 70〜75nm,仍然嫌過重,亟待改進的情形。今(2〇〇6)年9月u 曰公告之我國專利第1261578號「奈米強力制震水泥凝固體生成 與本案同申睛人)所依據之自創奈米吸震理論,可供作本案 不米防彈玻璃體」之科學原理依據。 【發明内容】 者認尺!時:ί面原子的面積比率甚高。作 殘鍵’而處於極不安定狀態,此時亟 ΐ,所以即初生態奈米體具有極強烈的化學還原 正電並遺留地面大氣帶負電。由於奈米表 土稀_力,-旦奈米粉體形成,就立即向其周、遭 200819486 ΐίϊίίίί取電子而趨於ί定’、所以奈米體的表面通常都帶 米表面吸著電子的2只電感測11靠近奈米體即可證實奈 表面吸著電表面殘鍵多屬強力的共價鍵,所以 結晶結構,於束缚狀態。設若材料具 能位能隙⑶中的^_就在比價帶(2)最高 ㈣體絲祕料何朗ν型半導财的電子(施 ν 月,其一是奈米體帶有豐富的負電,而 Γ Ο 型半導二不子=;=口= ,綠級料赠能4並餅其能Ξ。 Η弟一圖中’當表面吸著電子所獲得能量大於 電子的能位就進入傳導帶⑴;如第二圖表示4面“電^ 狀ϊ,ίί 即可脫離奈米材料表面成為游離 質奪取電gut由基,然後表面自由基又向周遭物 八私Ϊί討奈米材料的吸震作用,令較高震波阻抗的奈米粉體2 =較低震波阻抗的結合材料3中,即形成吸震材料卜如第三 界面震波進人奈米材料,則震波(壓力波)就在兩種物質 Γ質。①的震波速度%、質點= 質2在度、歷力A,其抵達承接物質②時,壓力 ίίίΐ賊速度由a變成〜,並行反射和穿入作用此時 係分ίί速度切,S1穿人震波速度為k根猶4和動量守恆】 (1) (2) ^s\+P0lUsl =0 ^'^=p^sl{up2-uplyU The bullet-proof glass used during the Second World War consists of a multi-layered glass plate that is made of a liquid rubber to bond the multiple layers of glass sheets into one body, with a thickness of up to 1 〜 to 120 nm, and is extremely heavy. Recently, the polycarbonate rubber molding resin with excellent shock absorbing function has been used to replace the previous liquid rubber, and the layer is sandwiched between ordinary glass to form a laminated bulletproof glass. Although the ballistic function has been improved, the thickness of the laminated glass is usually 70~75nm, still too heavy, and need to be improved. In this (2〇〇6), September u 之 之 我国 我国 我国 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 The scientific principle of the non-meter bulletproof glass body. [Summary of the Invention] When the ruler is taken! Time: The area ratio of the 面 face atom is very high. As a residual bond, it is in a state of extreme instability. At this time, the initial ecological nano-body has a strong chemical reduction positive charge and leaves the ground atmosphere negatively charged. Because the surface of the nano-soil is thin, the powder of the nano-nano is formed immediately, and it is immediately taken to the end of the week, and it is tempered by the electrons of 200819486 ΐίϊίίί, so the surface of the nano-body usually has two electrons on the surface of the rice. Inductance measurement 11 close to the nano-body can confirm that the residual surface of the surface of the Nai surface is mostly a strong covalent bond, so the crystal structure is in a bound state. If the material has a potential energy gap (3), ^_ is in the parity band (2) the highest (four) body silk secret material Helang ν-type semi-conducting electrons (Shi V, one of which is the nano-body with a rich negative , Γ 半 type semi-conducting two non-sub ==== mouth =, green grade material gift 4 and cake can be Ξ. In the picture of a younger brother, 'when the surface absorbs electrons, the energy obtained is greater than the energy of the electron, then it enters conduction. With the (1); as shown in the second figure, the four sides of the "electric ^ ϊ, ίί can be separated from the surface of the nanomaterial into a free mass to capture the electric gut from the base, and then the surface free radicals are again to the surrounding objects. The effect is that the nano-powder with higher seismic impedance 2 = the lower seismic impedance of the bonding material 3, that is, the shock absorbing material is formed, such as the third interface seismic wave entering the nano-material, the seismic wave (pressure wave) is in the two substances Tannin. 1 shock wave velocity %, mass point = mass 2 in degree, force A, when it arrives to accept material 2, pressure ίίί ΐ thief speed changes from a to ~, parallel reflection and penetration action at this time is divided into ίί speed cut, S1 wears human shock wave velocity for k roots and 4 and conservation of momentum] (1) (2) ^s\+P0lUsl =0 ^'^=p^sl{up2-uply
S\^ PIS\^ PI
P1 = PoiU^U (3) (4) 200819486 •^2 ~ Ρ〇2^2^Ρ2 , 式中心、/?。2為震波未到時的質量密度,運用⑴至(4)式,即求得·· =__^Poi^Sl PI P〇l^Sl + P〇2^S2 1 =:_2p02L^2 — Pi P〇\Usl + pQ2Ut (5) S2 ⑹P1 = PoiU^U (3) (4) 200819486 •^2 ~ Ρ〇2^2^Ρ2 , the center of the formula, /?. 2 is the mass density when the shock wave is not reached, and the formula (1) to (4) is used to obtain the ·· =__^Poi^Sl PI P〇l^Sl + P〇2^S2 1 =:_2p02L^2 — Pi P 〇\Usl + pQ2Ut (5) S2 (6)
用(5)和⑹式可分析紐吸收體的震;皮吸收能力。考慮下列 雨種h形: J j)田,波從車又低展波阻抗(A而)的結合材進入較高震波阻抗 ^02 S2)的奈米顆粒時,因關係,即得$ >卜 」2 2Ϊ1。此結果表示反射波為震波(壓力波〕。就能量觀點‘ 二’不米材料顆粒具有將壓力波之能送還結合材,使之壓力1大, :此ΐΐ增加壓縮耗能的作用,惟因結合材和奈米顆粒均曰為凝 ,二壓縮率甚小,所以壓縮耗能效果不彰。 、、 二)當震波錄高震波阻抗(外你)的奈米雛進人 Ο 城)的結合材時,因威丨> 祕關係,即得:Ρ23. P2> t/P1。此結果表示反射波為稀釋波(拉力波)。由 二 2 ’首#其衝的奈米表面吸著電子就會被 中’表面吸著電子即因能位提“ η =$彈擊中物體時,速度被崎而降低,_撞擊作用 t的震波(超音速壓力波)超前於子彈向前傳播。 ,與空氣界面時,即行反射而產生反射波^ 至 ,波(超音速拉力波),物體材f就受其拉力作用 而被剝離材料的運動方向怪與子彈穿行方向相 於 彈之行進減輕障礙,所以稀釋波乃是助長子彈貫穿^體的H奸 200819486 ζ雷必備的條件是具強力的吸震功能。惟因之前人們 夕π田* L、乏理4依據,所能獲得材料的吸震魏有限,目前 f二土十璃板和透卿板相間組成厚厚的夾層板作為防彈玻璃, 改進空間。作者研究奈米統合理論,發現奈米材料 二ΐί,Γ的表面吸*f子’如將奈米浦分散在透明樹脂 θ ’ iii璃用板,則該玻璃板就具有強大防彈功能。究其原因 波㈣震波阻抗較大的奈讀體表面進人震波阻抗較小 Γ ο 首被:ίΐ:行i射ϊ產生稀釋波,此時表面吸著電子就 姉表由域於低能位的表面吸著電子被剝離過 耘,孓生此位大幅提升,藉此將震波能有效吸收。 【實施方式】 利用直接摻混法或轉轉法將粒徑議nm以下、10〜_ 阻抗之奈米級吸震材料粉粒2 (例如:奈米二氧化 1、二卡三氧化二紹或奈米碳酸鱗),分散在較低震波阻抗之樹 匕如·聚甲基丙稀酸甲酉旨(通稱亞克力樹脂PMMA)或聚碳 以生成奈米防彈玻璃用材,再利用習知之樹脂加工成 型技術,‘成如第三圖所示之奈米防彈玻璃體i。 【圖式簡單說明】 直二a為奈米表面吸著電子的能位圖。 1^1星為:金屬表面傳導電子之能位圖。 蓋ϋ為:奈米防彈玻璃體。 8 200819486 【主要元件符號說明】 第一圖圖號: (1) 傳導帶5 (2)—價帶,(3)—能隙, 0— 價帶最高能位為零,The shock absorption of the new absorber can be analyzed by the formulas (5) and (6); Consider the following rain type h: J j), the wave from the car and the low impedance of the wave (A) of the combination of the material into the higher seismic impedance ^02 S2) of the nanoparticle, the relationship, that is, get $ > Bu" 2 2Ϊ1. This result indicates that the reflected wave is a shock wave (pressure wave). As far as the energy is concerned, the 'two' non-meter material particles have the ability to return the pressure wave energy to the bonding material, so that the pressure is large, and this increases the compression energy consumption. Both the binder and the nano-particles are coagulated, and the two compression ratios are very small, so the compression energy consumption effect is not good.,, and b) the combination of the high-shock impedance of the shock wave (outside you) into the human city) In the case of material, due to the deterrent relationship, you get: Ρ23. P2> t/P1. This result indicates that the reflected wave is a dilution wave (tension wave). The electrons on the surface of the nanometer that are rushed by the second 2's ## will be absorbed by the surface of the surface. The shock wave (supersonic pressure wave) leads the bullet forward. When the interface with the air is reflected, the reflected wave is generated, and the wave (supersonic tension wave) is applied to the object material by the tensile force. The movement direction blame and the direction of the bullet travel in the direction of the bomb to alleviate the obstacle, so the dilution wave is to encourage the bullet to penetrate the body of the traitor 200819486. The necessary condition for the smashing is a strong shock absorbing function. According to the lack of 4 basis, the shock absorption Wei of the material can be obtained. At present, the thick sandwich panel of the two soils and the transparent plate is used as the bulletproof glass to improve the space. The author studies the theory of nano integration and finds the nanometer. The material is ΐί, the surface of the 吸 吸 f f ' 如 如 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈 奈Body surface into the earthquake The wave impedance is smaller Γ ο First: ΐ ΐ: The line i emits a dilute wave. At this time, the surface attracts electrons, and the surface is absorbed by the electrons on the surface of the low-energy surface. Thereby, the seismic wave can be effectively absorbed. [Embodiment] The nanometer-sized shock absorbing material powder 2 having a particle diameter of less than nm and 10 to _ impedance is used by a direct blending method or a transfer method (for example, nanometer oxidation 1, Dikasan trioxide or nanocarbonate scales, scattered in the lower seismic impedance of the tree such as polymethyl methacrylate forging (known as acrylic resin PMMA) or polycarbon to produce nano bulletproof glass, Using the conventional resin processing and forming technology, 'the nano bulletproof glass body i as shown in the third figure. [Simple description of the figure] Straight two a is the energy level diagram of the electrons adsorbed on the surface of the nanometer. : Energy level map of metal surface conduction electrons. Cover is: nano bulletproof glass body. 8 200819486 [Main component symbol description] First picture number: (1) Conductive tape 5 (2) - valence band, (3) - Energy gap, 0—the highest energy level of the valence band is zero.
Ea—表面吸著電子的基態能位,Ea—the surface absorbs the ground state energy of the electron,
Eg一-傳導帶的最低能位, _ Ε—-傳導帶的最高能位,Ed=Eg-Ea。 第二圖圖號· ①---功函數, ( Ερ - - -Fermi 能位, E〇---表面傳導電子從最低能位0脫離表面所需能量, 0 —傳導帶的最低能位為零, ①--傳導帶’②---真空,③---表面。 第三圖圖號: 1- --奈米防彈玻璃體。 2— 較高震波阻抗之奈米級顆粒。 3- 一較低震波阻抗之樹脂(結合材)。Eg--the lowest energy level of the conduction band, _ Ε - the highest energy level of the conduction band, Ed = Eg-Ea. Fig. 1 · 1-- work function, ( Ερ - - -Fermi energy level, E〇---the energy required to remove the surface conduction electrons from the lowest energy level 0, 0 - the lowest energy level of the conduction band is Zero, 1--conducting band '2---vacuum, 3---surface. Figure 3: 1--Nano bullet-proof vitreous. 2—Nano-grade particles with higher seismic impedance. Resin (bonding material) with lower seismic impedance.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW95138658A TW200819486A (en) | 2006-10-20 | 2006-10-20 | Nano bulletproof glass |
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| Application Number | Priority Date | Filing Date | Title |
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| TW95138658A TW200819486A (en) | 2006-10-20 | 2006-10-20 | Nano bulletproof glass |
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| TW200819486A true TW200819486A (en) | 2008-05-01 |
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