SK19762000A3 - Spôsob úpravy minerálnych plnív fosfátom, tieto plnivá a ich použitie - Google Patents
Spôsob úpravy minerálnych plnív fosfátom, tieto plnivá a ich použitie Download PDFInfo
- Publication number
- SK19762000A3 SK19762000A3 SK1976-2000A SK19762000A SK19762000A3 SK 19762000 A3 SK19762000 A3 SK 19762000A3 SK 19762000 A SK19762000 A SK 19762000A SK 19762000 A3 SK19762000 A3 SK 19762000A3
- Authority
- SK
- Slovakia
- Prior art keywords
- filler
- experiment
- polyol
- mineral
- mineral filler
- Prior art date
Links
- 239000000945 filler Substances 0.000 title claims abstract description 97
- 239000012764 mineral filler Substances 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 65
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 14
- 239000010452 phosphate Substances 0.000 title claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims abstract description 9
- 229920005862 polyol Polymers 0.000 claims abstract description 96
- 150000003077 polyols Chemical class 0.000 claims abstract description 96
- 239000004814 polyurethane Substances 0.000 claims abstract description 41
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 229920002635 polyurethane Polymers 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims abstract description 24
- 239000006260 foam Substances 0.000 claims abstract description 21
- 229920005830 Polyurethane Foam Polymers 0.000 claims abstract description 20
- 239000002131 composite material Substances 0.000 claims abstract description 20
- 238000005187 foaming Methods 0.000 claims abstract description 20
- 239000011496 polyurethane foam Substances 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 39
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 31
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 30
- 239000000725 suspension Substances 0.000 claims description 27
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 20
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 18
- 229920000570 polyether Polymers 0.000 claims description 18
- 239000004604 Blowing Agent Substances 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 17
- 230000002378 acidificating effect Effects 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims description 12
- 235000021317 phosphate Nutrition 0.000 claims description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 11
- 229910021532 Calcite Inorganic materials 0.000 claims description 9
- -1 alkaline earth metal carbonates Chemical class 0.000 claims description 9
- 239000000454 talc Substances 0.000 claims description 9
- 229910052623 talc Inorganic materials 0.000 claims description 9
- 235000012222 talc Nutrition 0.000 claims description 9
- 239000005995 Aluminium silicate Substances 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 8
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 7
- QHAUASBJFFBWMY-UHFFFAOYSA-N didecyl hydrogen phosphate Chemical class CCCCCCCCCCOP(O)(=O)OCCCCCCCCCC QHAUASBJFFBWMY-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- SCIGVHCNNXTQDB-UHFFFAOYSA-N decyl dihydrogen phosphate Chemical compound CCCCCCCCCCOP(O)(O)=O SCIGVHCNNXTQDB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000004579 marble Substances 0.000 claims description 6
- 235000010755 mineral Nutrition 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000010459 dolomite Substances 0.000 claims description 5
- 229910000514 dolomite Inorganic materials 0.000 claims description 5
- 238000001033 granulometry Methods 0.000 claims description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 238000010908 decantation Methods 0.000 claims description 4
- 238000000280 densification Methods 0.000 claims description 4
- 239000000347 magnesium hydroxide Substances 0.000 claims description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 claims description 3
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 159000000007 calcium salts Chemical class 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical class [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 3
- 235000011132 calcium sulphate Nutrition 0.000 claims description 3
- 150000005690 diesters Chemical class 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 235000013980 iron oxide Nutrition 0.000 claims description 3
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 239000011667 zinc carbonate Substances 0.000 claims description 3
- 235000004416 zinc carbonate Nutrition 0.000 claims description 3
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 150000008064 anhydrides Chemical class 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 125000005442 diisocyanate group Chemical group 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 239000005350 fused silica glass Substances 0.000 claims description 2
- 150000002440 hydroxy compounds Chemical class 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 239000012756 surface treatment agent Substances 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims 4
- 235000012254 magnesium hydroxide Nutrition 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 3
- 235000010210 aluminium Nutrition 0.000 claims 3
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 3
- 239000000391 magnesium silicate Substances 0.000 claims 2
- 235000012243 magnesium silicates Nutrition 0.000 claims 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 239000003365 glass fiber Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 22
- 239000002245 particle Substances 0.000 abstract description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 2
- 238000009826 distribution Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 2
- 230000008961 swelling Effects 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 183
- 239000000047 product Substances 0.000 description 96
- 238000002360 preparation method Methods 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 235000019993 champagne Nutrition 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 101100361281 Caenorhabditis elegans rpm-1 gene Proteins 0.000 description 1
- 241000723347 Cinnamomum Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- DKJLSSBMAKWTLJ-UHFFFAOYSA-N [2,3-di(nonyl)phenyl] dihydrogen phosphate Chemical compound CCCCCCCCCC1=CC=CC(OP(O)(O)=O)=C1CCCCCCCCC DKJLSSBMAKWTLJ-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- NHWZQIYTQZEOSJ-UHFFFAOYSA-N carbonic acid;phosphoric acid Chemical compound OC(O)=O.OP(O)(O)=O NHWZQIYTQZEOSJ-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000005474 octanoate group Chemical group 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920005903 polyol mixture Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2639—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing elements other than oxygen, nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/335—Polymers modified by chemical after-treatment with organic compounds containing phosphorus
- C08G65/3353—Polymers modified by chemical after-treatment with organic compounds containing phosphorus containing oxygen in addition to phosphorus
- C08G65/3355—Polymers modified by chemical after-treatment with organic compounds containing phosphorus containing oxygen in addition to phosphorus having phosphorus bound to carbon and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Polyurethanes Or Polyureas (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9808483A FR2780409B1 (fr) | 1998-06-30 | 1998-06-30 | Procede pour traiter une charge minerale par un phosphate, charge minerale ainsi traitee, mousses de polyurethanne et polyurethannes composites utilisant cette charge, objets moules ou non les contenant |
| PCT/FR1999/001456 WO2000000553A1 (fr) | 1998-06-30 | 1999-06-17 | Traitement de charges minerales par un phosphate, ces charges et leur utilisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK19762000A3 true SK19762000A3 (sk) | 2001-07-10 |
Family
ID=9528188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1976-2000A SK19762000A3 (sk) | 1998-06-30 | 1999-06-17 | Spôsob úpravy minerálnych plnív fosfátom, tieto plnivá a ich použitie |
Country Status (37)
| Country | Link |
|---|---|
| US (2) | US6787575B1 (es) |
| EP (1) | EP1092000B1 (es) |
| JP (1) | JP2002519468A (es) |
| KR (1) | KR20010078758A (es) |
| CN (1) | CN1307619A (es) |
| AR (1) | AR019163A1 (es) |
| AT (1) | ATE275608T1 (es) |
| AU (1) | AU763910B2 (es) |
| BG (1) | BG105092A (es) |
| BR (1) | BR9911694A (es) |
| CA (1) | CA2336169C (es) |
| DE (1) | DE69920019T2 (es) |
| DZ (1) | DZ2834A1 (es) |
| EE (1) | EE04469B1 (es) |
| EG (1) | EG22038A (es) |
| FR (1) | FR2780409B1 (es) |
| HR (1) | HRP20000840A2 (es) |
| HU (1) | HUP0103301A3 (es) |
| ID (1) | ID28153A (es) |
| IL (1) | IL140520A0 (es) |
| IS (1) | IS5762A (es) |
| JO (1) | JO2113B1 (es) |
| LT (1) | LT4815B (es) |
| LV (1) | LV12693B (es) |
| MA (1) | MA24909A1 (es) |
| NO (1) | NO20006672L (es) |
| NZ (1) | NZ508529A (es) |
| PL (1) | PL345154A1 (es) |
| RU (1) | RU2242489C2 (es) |
| SI (1) | SI20530A (es) |
| SK (1) | SK19762000A3 (es) |
| TN (1) | TNSN99131A1 (es) |
| TR (1) | TR200003886T2 (es) |
| TW (1) | TWI225874B (es) |
| UY (1) | UY25589A1 (es) |
| WO (1) | WO2000000553A1 (es) |
| ZA (1) | ZA200007407B (es) |
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| KR20030024327A (ko) * | 2001-09-18 | 2003-03-26 | 김홍범 | 다공성을 띤 운모광석 및 세라믹광물을 이용한 기능성우레탄폼 |
| FR2832076B1 (fr) * | 2001-11-09 | 2004-07-23 | Rhodia Chimie Sa | Compositions emulsifiantes comprenant des particules minerales de dimensions nanometriques de surface modifiees et agents tensioactifs formes par de telles particules |
| KR100790856B1 (ko) * | 2005-07-15 | 2008-01-03 | 삼성전기주식회사 | 인산계 분산제를 포함하는 적층 세라믹 콘덴서 |
| RU2332428C2 (ru) * | 2006-05-23 | 2008-08-27 | Ооо "Инстрой" | Композиция для получения жесткого пенополиуретана |
| CN101210066B (zh) * | 2006-12-30 | 2013-01-09 | 比亚迪股份有限公司 | 一种整皮聚氨酯泡沫组合物 |
| WO2008109661A2 (en) * | 2007-03-05 | 2008-09-12 | Vidoop, Llc. | Method and system for securely caching authentication elements |
| FR2913427B1 (fr) * | 2007-03-05 | 2011-10-07 | Omya Development Ag | Procede de broyage a sec d'un ou plusieurs materiaux comprenant au moins un carbonate de calcium |
| EP2155811B1 (en) * | 2007-05-07 | 2016-08-31 | Polymers CRC Limited | Polymer foam and foam articles for fire protection |
| RU2414495C1 (ru) * | 2009-07-01 | 2011-03-20 | Учреждение Российской академии наук Институт металлоорганической химии им. Г.А. Разуваева РАН | Теплоизоляционная композиция |
| US20110054058A1 (en) * | 2009-08-31 | 2011-03-03 | William Crooker | Emulsified polyol and resultant foam therefrom |
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| DE102010060390A1 (de) * | 2010-11-05 | 2012-05-10 | Bayer Materialscience Aktiengesellschaft | Emulsionsförmige Reaktionsmischung und Verfahren zur Herstellung von Polyurethanschäumen aus einer solchen Reaktionsmischung |
| RS53808B1 (sr) | 2012-01-05 | 2015-06-30 | Omya International Ag | Punioci za penaste krute polimerne proizvode |
| US20150079401A1 (en) * | 2012-03-30 | 2015-03-19 | Tokuyama Corporation | Curable resin composition, method for manufacturing the same, high thermal conductive resin composition, and high thermal conductive laminated substrate |
| US20140206800A1 (en) | 2013-01-22 | 2014-07-24 | Sabic Innovative Plastics Ip B.V. | Thermoplastic Compositions Containing Nanoscale-Sized Particle Additives For Laser Direct Structuring And Methods For The Manufacture And Use Thereof |
| HUE026774T2 (en) | 2013-02-22 | 2016-08-29 | Omya Int Ag | New surface treatment of white minerals for use in plastics |
| US20150080515A1 (en) * | 2013-09-13 | 2015-03-19 | Sabic Innovative Plastics Ip B.V. | Mineral reinforced thermoplastic polymer compositions with improved properties |
| ES2660425T3 (es) | 2014-12-02 | 2018-03-22 | Omya International Ag | Proceso para la producción de un material compactado, material así producido y uso del mismo |
| EP3072687A1 (en) | 2015-03-24 | 2016-09-28 | Omya International AG | Easy to disperse calcium carbonate to improve hot tack strength |
| EP3176204A1 (en) | 2015-12-02 | 2017-06-07 | Omya International AG | Surface-treated fillers for ultrathin breathable films |
| KR101687670B1 (ko) * | 2016-02-26 | 2016-12-20 | 재단법인 한국기계전기전자시험연구원 | 냉동 컨테이너 단열재용 우레탄 발포체의 제조 방법 |
| CN108779241B (zh) * | 2016-03-21 | 2021-03-12 | 科思创德国股份有限公司 | 阻燃的醚软质泡沫材料 |
| CN106084892B (zh) * | 2016-06-13 | 2018-10-30 | 中国科学院青海盐湖研究所 | 无水硫酸钙晶须的表面改性方法 |
| EP3272524A1 (en) | 2016-07-21 | 2018-01-24 | Omya International AG | Calcium carbonate as cavitation agent for biaxially oriented polypropylene films |
| WO2018095515A1 (en) | 2016-11-22 | 2018-05-31 | Omya International Ag | Surface-treated fillers for biaxially oriented polyester films |
| ES2764676T3 (es) | 2016-12-21 | 2020-06-04 | Omya Int Ag | Rellenos tratados en la superficie para películas de poliéster |
| EP3572456A1 (en) | 2018-05-23 | 2019-11-27 | Omya International AG | Surface-treated fillers for polyester films |
| EP3623428A1 (en) | 2018-09-17 | 2020-03-18 | Omya International AG | Compacted polymer-based filler material for plastic rotomoulding |
| EP3628705A1 (en) | 2018-09-28 | 2020-04-01 | Omya International AG | Process for preparing a coarse surface treated filler material product |
| JP2023535318A (ja) | 2020-07-16 | 2023-08-17 | オムヤ インターナショナル アクチェンゲゼルシャフト | エラストマー組成物のガス透過性を低減するための多孔質フィラーの使用 |
| BR112023000805A2 (pt) | 2020-07-16 | 2023-03-28 | Omya Int Ag | Composição formada a partir de um material que compreende carbonato de cálcio e um polímero enxertado |
| WO2022013344A1 (en) | 2020-07-16 | 2022-01-20 | Omya International Ag | A composition formed from a calcium or magnesium carbonate-comprising material and a surface-treatment composition comprising at least one cross-linkable compound |
| WO2022013339A1 (en) | 2020-07-16 | 2022-01-20 | Omya International Ag | Alkaline earth metal minerals as carriers for surfactants in drilling fluids |
| MX2023000613A (es) | 2020-07-16 | 2023-02-13 | Omya Int Ag | Composicion de elastomero reforzado. |
| EP3974385A1 (en) | 2020-09-24 | 2022-03-30 | Omya International AG | A moisture-curing one-component polymer composition comprising a natural ground calcium carbonate (gcc) |
| US20230365812A1 (en) | 2020-10-05 | 2023-11-16 | Omya International Ag | Kit comprising surface-treated calcium carbonate and a peroxide agent for improving the mechanical properties of polyethylene/polypropylene compositions |
| WO2022090384A1 (en) | 2020-11-02 | 2022-05-05 | Omya International Ag | Process for producing precipitated calcium carbonate in the presence of natural ground calcium carbonate |
| JP6954705B1 (ja) * | 2021-05-28 | 2021-10-27 | 株式会社Tbm | 樹脂組成物及び成形品 |
| US20250051539A1 (en) | 2021-12-22 | 2025-02-13 | Omya International Ag | Calcium carbonate-comprising material with high bio-based carbon content for polymer formulations |
| WO2023118361A1 (en) | 2021-12-22 | 2023-06-29 | Omya International Ag | Precipitated calcium carbonate with high bio-based carbon content for polymer formulations |
| WO2025149508A1 (en) | 2024-01-10 | 2025-07-17 | Omya International Ag | Removal of the unpleasant smell in calcium carbonate filled polymer compositions |
| WO2025254835A1 (en) * | 2024-06-03 | 2025-12-11 | Rohm And Haas Company | Flame-resistant flexible polyurethane foams |
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| DE1519544A1 (de) * | 1964-07-23 | 1970-04-30 | Bayer Ag | Leicht dispergierbare pulverige Substanzen |
| DE1792798C3 (de) * | 1964-10-15 | 1978-09-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung leicht dispergierbarer Pigmente |
| DE1467443C3 (de) * | 1964-10-15 | 1978-06-08 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung leicht dispergierbarer Pigmente |
| GB1169352A (en) * | 1965-10-13 | 1969-11-05 | Laporte Titanium Ltd | Improvements in and relating to the Treatment of Pigments |
| GB1506578A (en) * | 1974-09-30 | 1978-04-05 | Ici Ltd | Pigments |
| DE2654746A1 (de) | 1976-12-03 | 1978-06-08 | Bayer Ag | Verfahren zur herstellung von stabilen suspensionen anorganischer fuellstoffe in organischen polyhydroxylverbindungen |
| DE2714291A1 (de) | 1977-03-31 | 1978-10-05 | Bayer Ag | Stabile suspensionen anorganischer fuellstoffe in organischen polyhydroxylverbindungen |
| DE2739620A1 (de) | 1977-09-02 | 1979-03-08 | Bayer Ag | Stabile suspensionen anorganischer fuellstoffe in organischen polyhydroxylverbindungen |
| US4183843A (en) * | 1978-09-20 | 1980-01-15 | Aluminum Company Of America | Phosphate ester coating on inorganic fillers for polyester resins |
| DE2850609A1 (de) * | 1978-11-22 | 1980-06-12 | Basf Ag | Verfahren zur herstellung von stabilen fuellstoff-polyol-dispersionen |
| DE2946549A1 (de) * | 1979-11-17 | 1981-05-27 | Bayer Ag, 5090 Leverkusen | Neuartige tio(pfeil abwaerts)2(pfeil abwaerts) -pigmente mit guter dispergierbarkeit, verfahren zu ihrer herstellung un verwendung |
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| FR2531971B1 (fr) | 1982-08-09 | 1986-03-14 | Pluss Stauffer Ag | Carbonates de calcium traites en surface et procede pour leur preparation |
| US4704165A (en) | 1985-05-21 | 1987-11-03 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Pigment composition |
| GB8521131D0 (en) * | 1985-08-23 | 1985-10-02 | English Clays Lovering Pochin | Aqueous suspensions of mixtures |
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| FR2651236B1 (fr) | 1989-08-23 | 1993-06-25 | Acome | Procede de polymerisation du methacrylate de methyle. |
| FR2671555B1 (fr) | 1991-01-16 | 1993-03-19 | Coatex Sa | Agent dispersant utilise dans des compositions thermodurcissables, compositions thermodurcissables le contenant et leurs applications. |
| ZA916851B (en) * | 1991-01-25 | 1993-03-01 | Kerr Mc Gee Chem Corp | Pigments of improved dipersibility in thermoplastic resins. |
| KR0171426B1 (ko) * | 1991-12-18 | 1999-02-01 | 가와무라 요시부미 | 13-(치환 티오) 아세톡시밀베마이신 유도체, 그의 제조방법 및 농화학적 용도 |
| TW261577B (es) | 1993-07-14 | 1995-11-01 | Krypton Internat Sa | |
| DE4422568C1 (de) | 1994-06-28 | 1996-02-15 | Bayer Ag | Verfahren und Vorrichtung zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| FR2729964B1 (fr) * | 1995-01-31 | 2003-02-28 | Omya Sa | Charges minerales traitees. suspensions de ces charges dans des polyols et leurs utilisations dans les mousses polyurethannes |
-
1998
- 1998-06-30 FR FR9808483A patent/FR2780409B1/fr not_active Expired - Fee Related
-
1999
- 1999-06-17 AT AT99925121T patent/ATE275608T1/de not_active IP Right Cessation
- 1999-06-17 CA CA002336169A patent/CA2336169C/fr not_active Expired - Fee Related
- 1999-06-17 SI SI9920046A patent/SI20530A/sl not_active IP Right Cessation
- 1999-06-17 CN CN99808094A patent/CN1307619A/zh active Pending
- 1999-06-17 TR TR2000/03886T patent/TR200003886T2/xx unknown
- 1999-06-17 DE DE69920019T patent/DE69920019T2/de not_active Expired - Fee Related
- 1999-06-17 NZ NZ508529A patent/NZ508529A/en unknown
- 1999-06-17 US US09/719,574 patent/US6787575B1/en not_active Expired - Fee Related
- 1999-06-17 ID IDW20002724A patent/ID28153A/id unknown
- 1999-06-17 EP EP99925121A patent/EP1092000B1/fr not_active Expired - Lifetime
- 1999-06-17 SK SK1976-2000A patent/SK19762000A3/sk unknown
- 1999-06-17 BR BR9911694-4A patent/BR9911694A/pt not_active IP Right Cessation
- 1999-06-17 EE EEP200000786A patent/EE04469B1/xx not_active IP Right Cessation
- 1999-06-17 HR HR20000840A patent/HRP20000840A2/hr not_active Application Discontinuation
- 1999-06-17 HU HU0103301A patent/HUP0103301A3/hu unknown
- 1999-06-17 PL PL99345154A patent/PL345154A1/xx unknown
- 1999-06-17 AU AU41517/99A patent/AU763910B2/en not_active Ceased
- 1999-06-17 IL IL14052099A patent/IL140520A0/xx unknown
- 1999-06-17 JP JP2000557308A patent/JP2002519468A/ja not_active Withdrawn
- 1999-06-17 RU RU2001102619/15A patent/RU2242489C2/ru not_active IP Right Cessation
- 1999-06-17 KR KR1020007015019A patent/KR20010078758A/ko not_active Ceased
- 1999-06-17 WO PCT/FR1999/001456 patent/WO2000000553A1/fr not_active Ceased
- 1999-06-22 EG EG76099A patent/EG22038A/xx active
- 1999-06-22 TW TW088110416A patent/TWI225874B/zh not_active IP Right Cessation
- 1999-06-23 MA MA25642A patent/MA24909A1/fr unknown
- 1999-06-23 TN TNTNSN99131A patent/TNSN99131A1/fr unknown
- 1999-06-23 JO JO19992113A patent/JO2113B1/en active
- 1999-06-24 AR ARP990103041A patent/AR019163A1/es active IP Right Grant
- 1999-06-28 DZ DZ990134A patent/DZ2834A1/xx active
- 1999-06-28 UY UY25589A patent/UY25589A1/es unknown
-
2000
- 2000-12-08 IS IS5762A patent/IS5762A/is unknown
- 2000-12-12 ZA ZA200007407A patent/ZA200007407B/xx unknown
- 2000-12-27 BG BG105092A patent/BG105092A/xx unknown
- 2000-12-28 NO NO20006672A patent/NO20006672L/no not_active Application Discontinuation
- 2000-12-29 LT LT2000130A patent/LT4815B/lt not_active IP Right Cessation
-
2001
- 2001-01-30 LV LV010015A patent/LV12693B/xx unknown
-
2003
- 2003-10-29 US US10/694,799 patent/US20040106701A1/en not_active Abandoned
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