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RU2017102868A - METHOD FOR PRODUCING DICHLORDI N-COMPLEXES - [(4- (BENZylSULFANIL) METHYL) -3,5-DIMETHYL-1H-PYRAZOLE] PALLADIUM (II) AND PLATINUM (II) - Google Patents

METHOD FOR PRODUCING DICHLORDI N-COMPLEXES - [(4- (BENZylSULFANIL) METHYL) -3,5-DIMETHYL-1H-PYRAZOLE] PALLADIUM (II) AND PLATINUM (II) Download PDF

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Publication number
RU2017102868A
RU2017102868A RU2017102868A RU2017102868A RU2017102868A RU 2017102868 A RU2017102868 A RU 2017102868A RU 2017102868 A RU2017102868 A RU 2017102868A RU 2017102868 A RU2017102868 A RU 2017102868A RU 2017102868 A RU2017102868 A RU 2017102868A
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Russia
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palladium
pyrazole
dimethyl
methyl
complexes
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RU2017102868A
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Russian (ru)
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RU2017102868A3 (en
RU2672265C2 (en
Inventor
Внира Рахимовна Ахметова
Наиль Салаватович Ахмадиев
Артур Радисович Тулябаев
Равиль Ахметзянович Хисамутдинов
Асхат Габдрахманович Ибрагимов
Усеин Меметович Джемилев
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Priority to RU2017102868A priority Critical patent/RU2672265C2/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/555—Heterocyclic compounds containing heavy metals, e.g. hemin, hematin, melarsoprol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)

Claims (3)

Способ получения серосодержащих N-комплексов дихлорди-[(4-(бензилсульфанил)метил)-3,5-диметил-1H-пиразол]палладия(II) или платаны(II) общей формулы (1):The method for producing sulfur-containing N-complexes of dichlorodi - [(4- (benzylsulfanyl) methyl) -3,5-dimethyl-1H-pyrazole] palladium (II) or plane trees (II) of the general formula (1):
Figure 00000001
Figure 00000001
 взаимодействием бидентатного реагента с солями палладия(II) или платины(II) в среде растворителя, отличающийся тем, что в качестве бидентантного реагента используют 4-[(бензилсульфанил)метил]-3,5-диметил-1H-пиразол, реакцию проводят с хлоридом палладия(II) в среде ацетонитрила или тетрахлорплатинатом калия в водно-ацетоновой среде при мольном соотношении 4-[(бензилсульфанил)метил]-3,5-диметил-1H-пиразол : хлорид палладия(II) или тетрахлорплатинат калия, равном 2:1, при температуре 15-25°C и атмосферном давлении в течение 3-5 ч.the interaction of the bidentate reagent with salts of palladium (II) or platinum (II) in a solvent medium, characterized in that 4 - [(benzylsulfanyl) methyl] -3,5-dimethyl-1H-pyrazole is used as the bidentate reagent, the reaction is carried out with chloride palladium (II) in acetonitrile or potassium tetrachloroplatinate in an aqueous-acetone medium with a molar ratio of 4 - [(benzylsulfanyl) methyl] -3,5-dimethyl-1H-pyrazole: palladium (II) chloride or potassium tetrachloroplatinate, equal to 2: 1 , at a temperature of 15-25 ° C and atmospheric pressure for 3-5 hours
RU2017102868A 2017-01-27 2017-01-27 Method for preparing n-complexes of dichlorodi-[(4-(benzylsulfanyl)methyl)-3,5-dimethyl-1h-pyrazole]palladium (ii) and platinum (ii) RU2672265C2 (en)

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RU2017102868A RU2672265C2 (en) 2017-01-27 2017-01-27 Method for preparing n-complexes of dichlorodi-[(4-(benzylsulfanyl)methyl)-3,5-dimethyl-1h-pyrazole]palladium (ii) and platinum (ii)

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RU2716138C1 (en) * 2019-02-18 2020-03-06 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук N,N-COMPLEX OF DICHLORODI-[3,5-DIMETHYL-4-((BENZYLSULFANYL)METHYL)-1H-PYRAZOLE]DIHYDRATE OF COPPER (II) - SELECTIVE INHIBITOR OF α-AMYLASE ENZYME

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RU2596874C1 (en) * 2015-03-18 2016-09-10 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing chelate cis-s,s-complexes of dichlorodi-1,6-(3,5-dimethyl isoxazole-4-yl)-2,5-ditiahexane palladium (ii) and platinum (ii)

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