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RU2013122017A - METHOD FOR PRODUCING 1-BROMO-2-AZIDO-1,2-DIHYDROS (С60-Ih) [5,6] FULLERENA - Google Patents

METHOD FOR PRODUCING 1-BROMO-2-AZIDO-1,2-DIHYDROS (С60-Ih) [5,6] FULLERENA Download PDF

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RU2013122017A
RU2013122017A RU2013122017/04A RU2013122017A RU2013122017A RU 2013122017 A RU2013122017 A RU 2013122017A RU 2013122017/04 A RU2013122017/04 A RU 2013122017/04A RU 2013122017 A RU2013122017 A RU 2013122017A RU 2013122017 A RU2013122017 A RU 2013122017A
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azido
bromo
fullerene
fullerena
dihydros
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RU2013122017/04A
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RU2551279C2 (en
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Усеин Меметович Джемилев
Айрат Рамилевич Туктаров
Арслан Рифхатович Ахметов
Ильдар Рафисович Яруллин
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Abstract

Способ получения 1-бром-2-азидо-1,2-дигидро(С-I)[5,6]фуллерена формулы (1)характеризующийся тем, что фуллерен Свзаимодействует с азидом брома (BrN), при мольном соотношении С:NBS:TMSN:M(OTf)=0.042:(0.042-0.063):0.754:0.042, при комнатной температуре (~20°С) в сухом хлорбензоле в течение 1-4 ч, под током сухого аргона без доступа дневного света.The method of obtaining 1-bromo-2-azido-1,2-dihydro (CI) [5,6] fullerene of the formula (1) characterized in that fullerene interacts with bromide azide (BrN), in a molar ratio C: NBS: TMSN: M (OTf) = 0.042: (0.042-0.063): 0.754: 0.042, at room temperature (~ 20 ° C) in dry chlorobenzene for 1-4 hours, under a stream of dry argon without access to daylight.

Claims (1)

Способ получения 1-бром-2-азидо-1,2-дигидро(С60-Ih)[5,6]фуллерена формулы (1)The method of obtaining 1-bromo-2-azido-1,2-dihydro (C 60 -I h ) [5,6] fullerene of the formula (1)
Figure 00000001
Figure 00000001
 характеризующийся тем, что фуллерен С60 взаимодействует с азидом брома (BrN3), при мольном соотношении С60:NBS:TMSN3:M(OTf)n=0.042:(0.042-0.063):0.754:0.042, при комнатной температуре (~20°С) в сухом хлорбензоле в течение 1-4 ч, под током сухого аргона без доступа дневного света. characterized in that fullerene C 60 interacts with bromine azide (BrN 3 ), with a molar ratio of C 60 : NBS: TMSN 3 : M (OTf) n = 0.042: (0.042-0.063): 0.754: 0.042, at room temperature (~ 20 ° C) in dry chlorobenzene for 1-4 hours, under a stream of dry argon without access to daylight.
RU2013122017/04A 2013-05-13 2013-05-13 METHOD OF PRODUCING 1-BROMO-2-AZIDO-1,2-DIHYDRO(C60-Ih)[5,6]FULLERENE RU2551279C2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2596876C2 (en) * 2014-12-10 2016-09-10 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing aziridino[2',3':1,9]fullerenes[60], containing framework and polycyclic substitutes

Family Cites Families (1)

* Cited by examiner, † Cited by third party
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RU2484010C2 (en) * 2011-06-16 2013-06-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF PRODUCING 1-IODO-2-AZIDO(C60-Ih)[5,6]FULLERENE

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2596876C2 (en) * 2014-12-10 2016-09-10 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method of producing aziridino[2',3':1,9]fullerenes[60], containing framework and polycyclic substitutes

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