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RU2014150139A - METHOD FOR PRODUCING N-ALKYLAZIRIDINO [2 ', 3': 1.9] FULLERENES [60] - Google Patents

METHOD FOR PRODUCING N-ALKYLAZIRIDINO [2 ', 3': 1.9] FULLERENES [60] Download PDF

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RU2014150139A
RU2014150139A RU2014150139A RU2014150139A RU2014150139A RU 2014150139 A RU2014150139 A RU 2014150139A RU 2014150139 A RU2014150139 A RU 2014150139A RU 2014150139 A RU2014150139 A RU 2014150139A RU 2014150139 A RU2014150139 A RU 2014150139A
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Russia
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producing
otf
alkylaziridino
fullerenes
alkylaziridinofullerenes
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RU2014150139A
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Russian (ru)
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RU2594561C2 (en
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Усеин Меметович Джемилев
Айрат Рамилевич Туктаров
Арслан Рифхатович Ахметов
Регина Адиковна Туктарова
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Способ получения N-алкилазиридинофуллеренов общей формулы (1)R=Me; Et; i-Pr; Bu,отличающийся тем, что фуллерен Свзаимодействует с линейными азидами RN(где R=Me, Et, i-Pr, Bu) в присутствии трифлата иттербия Yb(OTf), взятыми в мольном соотношении С: RN: Yb(OTf)=1:(0.5-2):(0.5-2), при комнатной температуре (~ 20ºС), в хлорбензоле в течение 18-30 ч.A method of producing N-alkylaziridinofullerenes of the general formula (1) R = Me; Et; i-Pr; Bu, characterized in that fullerene interacts with linear azides RN (where R = Me, Et, i-Pr, Bu) in the presence of ytterbium triflate Yb (OTf), taken in the molar ratio C: RN: Yb (OTf) = 1: (0.5-2) :( 0.5-2), at room temperature (~ 20ºС), in chlorobenzene for 18-30 hours.

Claims (1)

Способ получения N-алкилазиридинофуллеренов общей формулы (1)The method of obtaining N-alkylaziridinofullerenes of the General formula (1)
Figure 00000001
R=Me; Et; i-Pr; Bu,
Figure 00000001
R is Me; Et; i-Pr; Bu, отличающийся тем, что фуллерен С60 взаимодействует с линейными азидами RN3 (где R=Me, Et, i-Pr, Bu) в присутствии трифлата иттербия Yb(OTf)3, взятыми в мольном соотношении С60: RN3: Yb(OTf)3=1:(0.5-2):(0.5-2), при комнатной температуре (~ 20ºС), в хлорбензоле в течение 18-30 ч. characterized in that the fullerene C 60 interacts with linear azides RN 3 (where R = Me, Et, i-Pr, Bu) in the presence of ytterbium triflate Yb (OTf) 3 , taken in a molar ratio of C 60 : RN 3 : Yb (OTf ) 3 = 1: (0.5-2) :( 0.5-2), at room temperature (~ 20ºС), in chlorobenzene for 18-30 hours.
RU2014150139/04A 2014-12-10 2014-12-10 Method of producing n-alkil aziridino[2',3':1,9] fullerene [60] RU2594561C2 (en)

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Publication number Priority date Publication date Assignee Title
DE4427489A1 (en) * 1994-08-03 1996-02-08 Hoechst Ag Polar reactive fullerene-azirine derivs. useful in opto-electrical devices
RU2466990C2 (en) * 2010-12-07 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of obtaining aziridino[2',3':1,2] fullerene[60]
RU2455283C1 (en) * 2010-12-07 2012-07-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of producing aziridino[2',3':1,2]fullerene[60]

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Effective date: 20161211