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RU2008122309A - METHOD FOR PRODUCING ALPHA, GAMMA-DI (AMINOMETHYL) -ALKADIINS - Google Patents

METHOD FOR PRODUCING ALPHA, GAMMA-DI (AMINOMETHYL) -ALKADIINS Download PDF

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Publication number
RU2008122309A
RU2008122309A RU2008122309/04A RU2008122309A RU2008122309A RU 2008122309 A RU2008122309 A RU 2008122309A RU 2008122309/04 A RU2008122309/04 A RU 2008122309/04A RU 2008122309 A RU2008122309 A RU 2008122309A RU 2008122309 A RU2008122309 A RU 2008122309A
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Russia
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aminomethyl
cucl
alkadiins
gamma
producing alpha
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RU2008122309/04A
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Russian (ru)
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RU2440322C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Мария Геннадьевна Шайбакова (RU)
Мария Геннадьевна Шайбакова
Ирина Геннадьевна Титова (RU)
Ирина Геннадьевна Титова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Гилемдар Адыхамович Махмудияров (RU)
Гилемдар Адыхамович Махмудияров
Ильфир Рифович Рамазанов (RU)
Ильфир Рифович Рамазанов
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Priority to RU2008122309/04A priority Critical patent/RU2440322C2/en
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  • Hydrogenated Pyridines (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Способ получения α,ω-ди(аминометил)алкадиинов общей формулы (1) ! ! где R2N = пиперидил, морфолил, N-метилпиперазил, характеризующийся тем, что α,ω-диацетилены С≡СН-(СН2)n-С≡СН, где n=4, 6, 8 подвергают взаимодействию с гем-диаминами R2NCH2NR2, где R2N такое же, как определено выше, в присутствии катализатора однохлористой меди (CuCl), взятыми в мольном соотношении α,ω-диацетилен : бисамин : CuCl=10:20:(0,3-0,7), предпочтительно 10:20:0,5 ммоль, при температуре 80°С и атмосферном давлении в течение 4-6 ч.A method for producing α, ω-di (aminomethyl) alkadiines of the general formula (1)! ! where R2N = piperidyl, morpholyl, N-methylpiperazyl, characterized in that α, ω-diacetylenes C≡CH- (CH2) n-C≡CH, where n = 4, 6, 8 are reacted with heme diamines R2NCH2NR2, where R2N is the same as defined above, in the presence of a copper monochloride (CuCl) catalyst, taken in a molar ratio of α, ω-diacetylene: bisamine: CuCl = 10: 20: (0.3-0.7), preferably 10:20: 0.5 mmol, at a temperature of 80 ° C and atmospheric pressure for 4-6 hours

Claims (1)

Способ получения α,ω-ди(аминометил)алкадиинов общей формулы (1)The method of producing α, ω-di (aminomethyl) alkadiines of the general formula (1)
Figure 00000001
Figure 00000001
 где R2N = пиперидил, морфолил, N-метилпиперазил, характеризующийся тем, что α,ω-диацетилены С≡СН-(СН2)n-С≡СН, где n=4, 6, 8 подвергают взаимодействию с гем-диаминами R2NCH2NR2, где R2N такое же, как определено выше, в присутствии катализатора однохлористой меди (CuCl), взятыми в мольном соотношении α,ω-диацетилен : бисамин : CuCl=10:20:(0,3-0,7), предпочтительно 10:20:0,5 ммоль, при температуре 80°С и атмосферном давлении в течение 4-6 ч. where R 2 N = piperidyl, morpholyl, N-methylpiperazyl, characterized in that α, ω-diacetylenes С≡СН- (СН 2 ) n -С≡СН, where n = 4, 6, 8 are reacted with gem-diamines R 2 NCH 2 NR 2 , where R 2 N is the same as defined above, in the presence of a catalyst of monochloride copper (CuCl), taken in a molar ratio of α, ω-diacetylene: bisamine: CuCl = 10: 20: (0.3- 0.7), preferably 10: 20: 0.5 mmol, at a temperature of 80 ° C and atmospheric pressure for 4-6 hours
RU2008122309/04A 2008-06-03 2008-06-03 METHOD OF PRODUCING α,ω-DI(AMINOMETHYL)ALKADIINES RU2440322C2 (en)

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RU2632674C2 (en) * 2015-12-24 2017-10-09 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method for producing 1-alkyl-1-azacycloalkadienes

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RU2283826C1 (en) * 2005-05-13 2006-09-20 Институт нефтехимии и катализа РАН Method for production of 3,6-dimethyl-1,8-dialkyl(phenyl)-2,6-octadiens

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