RU2006113594A - Каталитическая композиция, содержащая эфир монокарбоновой кислоты в качестве внутреннего донора и способ полимеризации пропилена - Google Patents
Каталитическая композиция, содержащая эфир монокарбоновой кислоты в качестве внутреннего донора и способ полимеризации пропилена Download PDFInfo
- Publication number
- RU2006113594A RU2006113594A RU2006113594/04A RU2006113594A RU2006113594A RU 2006113594 A RU2006113594 A RU 2006113594A RU 2006113594/04 A RU2006113594/04 A RU 2006113594/04A RU 2006113594 A RU2006113594 A RU 2006113594A RU 2006113594 A RU2006113594 A RU 2006113594A
- Authority
- RU
- Russia
- Prior art keywords
- dimethoxysilane
- bis
- mixture
- propylene
- alkoxysilane
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 19
- 238000000034 method Methods 0.000 title claims 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims 6
- 230000003197 catalytic effect Effects 0.000 title claims 4
- 238000006116 polymerization reaction Methods 0.000 title claims 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 title 1
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 claims 9
- -1 aromatic monocarboxylic acids Chemical class 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 claims 4
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 claims 4
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical group CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 3
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 125000004122 cyclic group Chemical group 0.000 claims 2
- YRMPTIHEUZLTDO-UHFFFAOYSA-N cyclopentyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCC1 YRMPTIHEUZLTDO-UHFFFAOYSA-N 0.000 claims 2
- ZVMRWPHIZSSUKP-UHFFFAOYSA-N dicyclohexyl(dimethoxy)silane Chemical compound C1CCCCC1[Si](OC)(OC)C1CCCCC1 ZVMRWPHIZSSUKP-UHFFFAOYSA-N 0.000 claims 2
- DGSPRFRFGPAESC-UHFFFAOYSA-N dimethoxy(dipyrrolidin-1-yl)silane Chemical compound C1CCCN1[Si](OC)(OC)N1CCCC1 DGSPRFRFGPAESC-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 125000005842 heteroatom Chemical group 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 1
- 238000012685 gas phase polymerization Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003623 transition metal compounds Chemical class 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/128—Mixtures of organometallic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
- B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/22—Magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Claims (12)
1. Каталитическая композиция для полимеризации пропилена или смеси пропилена с одним или более сополимеризуемых сомономеров, где указанная каталитическая композиция содержит одну или более композиций прокатализаторов Циглера-Натта, содержащих одно или более соединений переходных металлов и один или более моноэфиров ароматических карбоновых кислот в качестве внутренних доноров электронов; один или более сокатализаторов, содержащих алюминий; и смесь двух или более различных агентов, регулирующих селективность, причем указанная смесь SCA содержит от 70 до 98 мол.% одного или более эфиров одной или более ароматических монокарбоновых кислот или их замещенных производных и от 30 до 2 мол.% одного или более алкоксисилановых соединений, содержащих одну или более 5- или 6-членных циклических групп, необязательно, содержащих один или более гетероатомов Групп 14, 15 или 16.
2. Каталитическая композиция по п.1, где внутренним донором электронов является этилбензоат.
3. Каталитическая композиция по п.1, где смесь SCA содержит этил-п-этоксибензоат и алкоксисилан, выбранный из группы, состоящей из дициклопентилдиметоксисилана, метилциклогексилдиметоксисилана, этилциклогексилдиметоксисилана, дициклогексилдиметоксисилана, метилциклопентилдиметоксисилана, циклопентилтриметоксисилана, изопропилциклогексилдиметоксисилана, этилциклопентилдиметоксисилана, циклопентилпирролидинодиметоксисилана, бис(пирролидино)диметоксисилана, бис(пергидроизохинолино)диметоксисилана, бис(пергидрохинолино)диметоксисилана, бис(пергидроизоиндолино)диметоксисилана, бис(пергидроиндолино)диметоксисилана и (пергидрохинолино)(пергидроизохинолино)диметоксисилана.
4. Каталитическая композиция по п.3, где алкоксисиланом является дициклопентилдиметоксисилан или метилциклогексилдиметоксисилан.
5. Каталитическая композиция по п.1, где общее количество используемых агентов регулирования селективности определяется молярным соотношением в расчете на переходный металл, находящимся в пределах от 1 до 100.
6. Способ полимеризации пропилена или смеси пропилена и одного или более сополимеризующихся сомономеров, включающий контактирование указанного мономера или смеси мономеров при температуре от 45 до 90°C с каталитической композицией, содержащей одну или более прокаталитических композиций Циглера-Натта, содержащую одно или более соединений переходных металлов и один или более внутренних доноров электронов, выбранных из группы, состоящей из эфиров ароматических монокарбоновых кислот; один или более алюминийсодержащих сокатализаторов; и смесь двух или более различных агентов регулирования селективности, причем указанная смесь SCA содержит от 70 до 98 мол.% одного или более эфиров одной или более ароматических монокарбоновых кислот или их замещенных производных, и от 30 до 2 мол.% одного или более алкоксисилановых соединений, содержащих одну или более 5- или 6-членных циклических групп, необязательно, содержащих один или более гетероатомов групп 14, 15 или 16.
7. Способ по п.6, который проводят при температуре от 67 до 90°C.
8. Способ по п.6, где внутренним донором электронов является этилбензоат.
9. Способ по п.6, где смесь SCA содержит этил-п-этоксибензоат и алкоксисилан, выбранный из группы, состоящей из дициклопентилдиметоксисилана, метилциклогексилдиметоксисилана, этилциклогексилдиметоксисилана, дициклогексилдиметоксисилана, метилциклопентилдиметоксисилана, циклопентилтриметоксисилана, изопропилциклогексилдиметоксисилана, этилциклопентилдиметоксисилана, циклопентилпирролидинодиметоксисилана, бис(пирролидино)диметоксисилана, бис(пергидроизохинолино)диметоксисилана, бис(пергидрохинолино)диметоксисилана, бис(пергидроизоиндолино)диметоксисилана, бис(пергидроиндолино)диметоксисилана и (пергидрохинолино)(пергидроизохинолино)диметоксисилана.
10. Способ по п.6, где алкоксисилан представляет собой дициклопентилдиметоксисилан или метилциклогексилдиметоксисилан.
11. Способ по п.6, который проводят в условиях газофазной полимеризации.
12. Способ по п.6, который проводят в более чем одном из реакторов, работающих последовательно.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50531203P | 2003-09-23 | 2003-09-23 | |
| US60/505,312 | 2003-09-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006113594A true RU2006113594A (ru) | 2006-09-10 |
| RU2361885C2 RU2361885C2 (ru) | 2009-07-20 |
Family
ID=34434878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006113594/04A RU2361885C2 (ru) | 2003-09-23 | 2004-08-18 | Каталитическая композиция, содержащая эфир монокарбоновой кислоты в качестве внутреннего донора, и способ полимеризации пропилена |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US7393806B2 (ru) |
| EP (1) | EP1668045B1 (ru) |
| KR (1) | KR101109345B1 (ru) |
| AR (1) | AR045802A1 (ru) |
| CZ (1) | CZ2006179A3 (ru) |
| PL (1) | PL379383A1 (ru) |
| RU (1) | RU2361885C2 (ru) |
| WO (1) | WO2005035596A1 (ru) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5740159B2 (ja) * | 2007-12-21 | 2015-06-24 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 二座内部供与体を有する自己制限性触媒組成物 |
| WO2011088754A1 (zh) * | 2010-01-22 | 2011-07-28 | 中国石油化工股份有限公司 | 一种具有高熔体强度的丙烯均聚物及其制备方法 |
| US20120116034A1 (en) * | 2010-11-08 | 2012-05-10 | Dow Global Technologies, Inc. | Solution polymerization process and procatalyst carrier systems useful therein |
| US20120157645A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
| US9382342B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same |
| US20120157295A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| US9382343B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same |
| EP2707400A1 (en) | 2011-05-13 | 2014-03-19 | Reliance Industries Limited | Catalyst system for polymerization of propylene |
| US10647790B2 (en) * | 2011-06-30 | 2020-05-12 | W. R. Grace & Co.-Conn. | Process for gas-phase polymerization having high bed bulk density |
| EP2610273B1 (en) * | 2011-12-30 | 2018-02-07 | Borealis AG | Catalyst component |
| WO2013148669A1 (en) | 2012-03-26 | 2013-10-03 | Freeslate, Inc. | Parallel reactor systems and methods for preparing materials |
| ES2671929T3 (es) | 2013-04-30 | 2018-06-11 | Unchained Labs | Métodos de muestreo de recipientes no atmosféricos en un sistema de reactor paralelo |
| US9908952B2 (en) * | 2013-11-15 | 2018-03-06 | W.R. Grace & Co.-Conn. | Propylene-based polymer with reduced high-molecular weight portion |
| CN105524192B (zh) * | 2015-12-09 | 2017-11-14 | 大唐国际化工技术研究院有限公司 | 具有高温活性抑制作用的聚丙烯催化剂组合物及其用途 |
| US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
| EP3510056B2 (en) * | 2016-09-08 | 2023-07-19 | SABIC Global Technologies B.V. | Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5106806A (en) | 1990-10-18 | 1992-04-21 | Shell Oil Company | Olefin polymerization catalyst |
| US5077357A (en) | 1990-10-22 | 1991-12-31 | Shell Oil Company | Olefin polymerization catalyst |
| US5066737A (en) | 1990-10-22 | 1991-11-19 | Shell Oil Company | Olefin polymerization catalyst |
| US5082907A (en) | 1990-10-18 | 1992-01-21 | Shell Oil Company | Olefin polymerization catalyst |
| US4107413A (en) | 1971-06-25 | 1978-08-15 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
| IT1042711B (it) | 1975-09-19 | 1980-01-30 | Montedison Spa | Compnenti di catalizzatori per la polimerizzazione di olefine |
| GB1603724A (en) | 1977-05-25 | 1981-11-25 | Montedison Spa | Components and catalysts for the polymerisation of alpha-olefins |
| IT1114822B (it) | 1977-07-04 | 1986-01-27 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione delle alfa-olefine |
| JPS56811A (en) | 1979-06-18 | 1981-01-07 | Mitsui Petrochem Ind Ltd | Preparation of olefin polymer or copolymer |
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| US4442276A (en) | 1982-02-12 | 1984-04-10 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing or copolymerizing olefins |
| JPS5991107A (ja) | 1982-11-17 | 1984-05-25 | Toho Titanium Co Ltd | オレフイン類重合用触媒成分の製造方法 |
| US4472521A (en) | 1982-12-20 | 1984-09-18 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
| JPS6023404A (ja) | 1983-07-20 | 1985-02-06 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| US4540679A (en) | 1984-03-23 | 1985-09-10 | Amoco Corporation | Magnesium hydrocarbyl carbonate supports |
| US4548915A (en) | 1984-04-10 | 1985-10-22 | Shell Oil Company | Olefin polymerization catalyst composition |
| JPS6155104A (ja) | 1984-08-24 | 1986-03-19 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| JPS61203105A (ja) | 1985-03-06 | 1986-09-09 | Idemitsu Petrochem Co Ltd | α−オレフインの重合方法 |
| JPS61213150A (ja) | 1985-03-19 | 1986-09-22 | 株式会社 名南製作所 | 積層板の製造方法 |
| JPH06104693B2 (ja) | 1986-01-06 | 1994-12-21 | 東邦チタニウム株式会社 | オレフイン類重合用触媒 |
| US4728705A (en) | 1986-02-28 | 1988-03-01 | Shell Oil Company | Olefin polymerization catalyst composition |
| EP0268685B2 (en) | 1986-05-06 | 1996-08-07 | Toho Titanium Co. Ltd. | Catalyst for polymerizing olefins |
| CA1310955C (en) | 1987-03-13 | 1992-12-01 | Mamoru Kioka | Process for polymerization of olefins and polymerization catalyst |
| US5066738A (en) | 1987-04-09 | 1991-11-19 | Fina Technology, Inc. | Polymerization of olefins with an improved catalyst system using a new electron donor |
| US4927797A (en) | 1987-04-09 | 1990-05-22 | Fina Technology, Inc. | Catalyst system for the polymerization of olefins |
| CA1312173C (en) * | 1988-05-12 | 1992-12-29 | Fred Chun-Chien Twu | Process for the preparation of random copolymers |
| DE3819577A1 (de) | 1988-06-09 | 1989-12-14 | Hoechst Ag | Verfahren zur herstellung eines polypropylens |
| DE68913375T3 (de) | 1988-06-17 | 2002-05-02 | Mitsui Chemicals, Inc. | Olefinpolymerisationsverfahren und dabei anwendbarer Polymerisationskatalysator. |
| ATE122060T1 (de) | 1989-03-02 | 1995-05-15 | Mitsui Petrochemical Ind | Verfahren zur polymerisation von olefinen und katalysator für olefinpolymerisation. |
| US5034361A (en) | 1990-05-24 | 1991-07-23 | Shell Oil Company | Catalyst precursor production |
| US5146028A (en) | 1990-10-18 | 1992-09-08 | Shell Oil Company | Olefin polymerization catalyst and process of polymerization |
| FR2669639A1 (fr) | 1990-11-27 | 1992-05-29 | Atochem | Cocatalyseur de polymerisation du propylene a base de silane et de monoether. |
| US5432244A (en) * | 1990-12-12 | 1995-07-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| BE1005792A3 (fr) * | 1992-05-04 | 1994-02-01 | Solvay | Systeme catalytique utilisable pour la polymerisation stereospecifique des alpha-olefines, procede pour cette polymerisation et polymeres obtenus. |
| TW300235B (ru) | 1992-12-04 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| US5414063A (en) | 1993-03-30 | 1995-05-09 | Huntsman Polypropylene Corporation | Process for the production of polypropylene |
| EP0657477B1 (en) | 1993-12-07 | 2001-03-14 | Sumitomo Chemical Company Limited | Process for producing olefin polymers for biaxially oriented film and olefin-polymerizing catalyst |
| JP3095177B2 (ja) | 1994-02-04 | 2000-10-03 | エクソン・ケミカル・パテンツ・インク | オレフィンの重合用の二重供与体触媒系 |
| US6133385A (en) | 1994-04-06 | 2000-10-17 | Fina Technology, Inc. | Catalyst systems for improved stereoselectivity and broader molecular weight distribution in polymerization of olefins |
| US6184328B1 (en) | 1994-09-07 | 2001-02-06 | Showa Denko Kabushiki Kaisha | Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production |
| US5869418A (en) | 1994-05-31 | 1999-02-09 | Borealis Holding A/S | Stereospecific catalyst system for polymerization of olefins |
| EP0717053B1 (en) | 1994-11-25 | 2001-03-14 | Japan Polyolefins Co., Ltd. | Catalyst for olefin polymerization and process for producing polyolefin using the same |
| KR100334167B1 (ko) | 1997-05-08 | 2002-11-22 | 삼성종합화학주식회사 | 알파-올레핀중합방법 |
| TW458993B (en) | 1997-09-04 | 2001-10-11 | Chisso Corp | Propylene copolymer and process for the production thereof |
| WO1999020663A2 (en) | 1997-10-17 | 1999-04-29 | Exxon Chemical Patents Inc. | High impact, flexural moduli polymeric materials formed using sequential donors |
| CA2327427C (en) | 1998-05-14 | 2008-09-02 | Exxon Chemical Patents, Inc. | Polymeric materials formed using blends of electron donors |
| US6087459A (en) | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
| WO2002096957A1 (en) * | 2001-05-29 | 2002-12-05 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| US6825146B2 (en) * | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
-
2004
- 2004-08-18 PL PL379383A patent/PL379383A1/pl not_active Application Discontinuation
- 2004-08-18 WO PCT/US2004/026836 patent/WO2005035596A1/en not_active Ceased
- 2004-08-18 CZ CZ20060179A patent/CZ2006179A3/cs unknown
- 2004-08-18 EP EP04781510A patent/EP1668045B1/en not_active Expired - Lifetime
- 2004-08-18 US US10/568,982 patent/US7393806B2/en not_active Expired - Fee Related
- 2004-08-18 KR KR1020067005663A patent/KR101109345B1/ko not_active Expired - Fee Related
- 2004-08-18 RU RU2006113594/04A patent/RU2361885C2/ru not_active IP Right Cessation
- 2004-09-22 AR ARP040103415A patent/AR045802A1/es unknown
-
2008
- 2008-06-24 US US12/145,061 patent/US7687426B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CZ2006179A3 (cs) | 2007-01-31 |
| US7393806B2 (en) | 2008-07-01 |
| US20070066771A1 (en) | 2007-03-22 |
| RU2361885C2 (ru) | 2009-07-20 |
| US20080319146A1 (en) | 2008-12-25 |
| KR20060126942A (ko) | 2006-12-11 |
| PL379383A1 (pl) | 2006-09-04 |
| KR101109345B1 (ko) | 2012-01-31 |
| US7687426B2 (en) | 2010-03-30 |
| EP1668045B1 (en) | 2012-10-03 |
| WO2005035596A1 (en) | 2005-04-21 |
| EP1668045A1 (en) | 2006-06-14 |
| AR045802A1 (es) | 2005-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2006113594A (ru) | Каталитическая композиция, содержащая эфир монокарбоновой кислоты в качестве внутреннего донора и способ полимеризации пропилена | |
| RU2006113602A (ru) | Самозатухающаяся композиция катализатора, включающая внутренний донор в виде сложного эфира монокарбоновой кислоты, и способ полимеризации пропилена | |
| RU2006113604A (ru) | Композиция катализатора с самоограничением реакции, включающая внутренний донор в виде сложного эфира дикарбоновой кислоты, и способ полимеризации пропилена | |
| BRPI0916648B1 (pt) | “Componente de catalisador de titânio sólido, sistema de catalisador, e, métodos de produção de um componente de catalisador de titânio sólido para um sistema de catalisador, e de polimerização ou copolimerização de uma olefina" | |
| CN1235917C (zh) | 乙烯均聚或共聚用催化剂的生产方法 | |
| JP2021502469A (ja) | ポリオレフィンポリマー組成物 | |
| RU99125662A (ru) | (со)полимеры полибутена-1 и способ их получения | |
| SG181835A1 (en) | Gas-phase polymerization process having multiple flow regimes | |
| RU2000102918A (ru) | Компоненты катализаторов полимеризации олефинов | |
| EP1188739A1 (en) | Phthalic diester derivatives and electron donors | |
| EP3486263A3 (en) | Self-limiting catalyst composition with no silane | |
| CN1670043A (zh) | 烯烃聚合用催化剂及其制备和聚合方法 | |
| WO2003014166A1 (fr) | Procede de fabrication de polymeres | |
| JP2005529230A5 (ru) | ||
| CN1714105A (zh) | 用于烯烃聚合反应的组分和催化剂 | |
| KR101539286B1 (ko) | 올레핀 중합을 위한 촉매 시스템 | |
| CN1220706C (zh) | 乙烯的均聚物和共聚物的生产方法 | |
| CN1227572A (zh) | 催化剂 | |
| CA2057688C (en) | A stereospecific catalyst system intended for the polymerization of olefins | |
| EP2601224A1 (en) | Catalyst components for the polymerization of olefins | |
| EA201200289A1 (ru) | Каталитическая система и способ получения полиэтилена | |
| FI95278C (fi) | Menetelmä olefiinipolymeerin valmistamiseksi | |
| CN104804112B (zh) | 一种主催化剂、其制备方法、应用和含其的催化剂组合物 | |
| CN104254551B (zh) | 用于烯烃聚合的催化剂组分 | |
| JP2018168276A (ja) | 重合触媒 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PD4A | Correction of name of patent owner | ||
| PC41 | Official registration of the transfer of exclusive right |
Effective date: 20140812 |
|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20150819 |