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AR045802A1 - Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno - Google Patents

Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno

Info

Publication number
AR045802A1
AR045802A1 ARP040103415A ARP040103415A AR045802A1 AR 045802 A1 AR045802 A1 AR 045802A1 AR P040103415 A ARP040103415 A AR P040103415A AR P040103415 A ARP040103415 A AR P040103415A AR 045802 A1 AR045802 A1 AR 045802A1
Authority
AR
Argentina
Prior art keywords
donator
ester
internal
polymerization process
propylene polymerization
Prior art date
Application number
ARP040103415A
Other languages
English (en)
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of AR045802A1 publication Critical patent/AR045802A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Una composición catalizadora para la polimerización de propileno comprendiendo una o más composiciones procatalizadores Ziegler-Natta que comprenden uno o más compuestos de metal de transición y uno o más monoésteres de donadores de electrón interno de ácido carboxílico aromático; uno o más cocatalizadores que contienen aluminio; y una mezcla de dos o más agentes de control de selectividad diferentes; dicha mezcla SCA comprendiendo de 70 a 98 por ciento de mol de uno o más ésteres de uno o más ácidos monocarboxílicos aromáticos o derivados sustituidos de los mismos y de 30 a 2 por ciento de mol de uno o más compuestos de alcoxisilano que contienen uno o más grupos cíclicos de 5 ó 6 miembros que contienen opcionalmente uno o más heteroátomos del grupo 14, 15 ó 16.
ARP040103415A 2003-09-23 2004-09-22 Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno AR045802A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US50531203P 2003-09-23 2003-09-23

Publications (1)

Publication Number Publication Date
AR045802A1 true AR045802A1 (es) 2005-11-16

Family

ID=34434878

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP040103415A AR045802A1 (es) 2003-09-23 2004-09-22 Composicion catalizadora con donador interno de ester de acido monocarboxilico y proceso de polimerizacion de propileno

Country Status (8)

Country Link
US (2) US7393806B2 (es)
EP (1) EP1668045B1 (es)
KR (1) KR101109345B1 (es)
AR (1) AR045802A1 (es)
CZ (1) CZ2006179A3 (es)
PL (1) PL379383A1 (es)
RU (1) RU2361885C2 (es)
WO (1) WO2005035596A1 (es)

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RU2489447C2 (ru) * 2007-12-21 2013-08-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Самоограничивающаяся композиция катализатора с бидентатным внутренним донором
WO2011088754A1 (zh) * 2010-01-22 2011-07-28 中国石油化工股份有限公司 一种具有高熔体强度的丙烯均聚物及其制备方法
US20120116034A1 (en) * 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
US9382342B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same
US9382343B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same
US20120157295A1 (en) 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
EP2707400A1 (en) 2011-05-13 2014-03-19 Reliance Industries Limited Catalyst system for polymerization of propylene
US10647790B2 (en) * 2011-06-30 2020-05-12 W. R. Grace & Co.-Conn. Process for gas-phase polymerization having high bed bulk density
EP2610273B1 (en) * 2011-12-30 2018-02-07 Borealis AG Catalyst component
US10195581B2 (en) 2012-03-26 2019-02-05 Unchained Labs Parallel reactor systems and methods for preparing materials
US9915591B2 (en) 2013-04-30 2018-03-13 Unchained Labs Methods for sampling from non-atmospheric vessels in a parallel reactor system
PL3068809T3 (pl) * 2013-11-15 2021-07-19 W.R. Grace & Co. - Conn. Polimer na bazie propylenu z częścią o zmniejszonej masie cząsteczkowej
CN105524192B (zh) * 2015-12-09 2017-11-14 大唐国际化工技术研究院有限公司 具有高温活性抑制作用的聚丙烯催化剂组合物及其用途
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US11384166B2 (en) 2016-09-08 2022-07-12 Sabic Global Technologies B.V. Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent

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Also Published As

Publication number Publication date
RU2006113594A (ru) 2006-09-10
KR101109345B1 (ko) 2012-01-31
US20070066771A1 (en) 2007-03-22
EP1668045B1 (en) 2012-10-03
US7687426B2 (en) 2010-03-30
RU2361885C2 (ru) 2009-07-20
PL379383A1 (pl) 2006-09-04
US20080319146A1 (en) 2008-12-25
KR20060126942A (ko) 2006-12-11
EP1668045A1 (en) 2006-06-14
US7393806B2 (en) 2008-07-01
CZ2006179A3 (cs) 2007-01-31
WO2005035596A1 (en) 2005-04-21

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