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RU2005138300A - Стабилизированные органоборановые инициаторы полимеризации и способные к полимеризации композиции - Google Patents

Стабилизированные органоборановые инициаторы полимеризации и способные к полимеризации композиции Download PDF

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Publication number
RU2005138300A
RU2005138300A RU2005138300/04A RU2005138300A RU2005138300A RU 2005138300 A RU2005138300 A RU 2005138300A RU 2005138300/04 A RU2005138300/04 A RU 2005138300/04A RU 2005138300 A RU2005138300 A RU 2005138300A RU 2005138300 A RU2005138300 A RU 2005138300A
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compounds
composition according
composition
contacting
polymerization
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RU2005138300/04A
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RU2358992C2 (ru
Inventor
Гэри Л. ДЖАЛАНЕЛЛА (US)
Гэри Л. ДЖАЛАНЕЛЛА
Тони РИСТОСКИ (US)
Тони РИСТОСКИ
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Дау Глобал Текнолоджиз Инк. (Us)
Дау Глобал Текнолоджиз Инк.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/55—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C08L77/08—Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (13)

1. Способная к полимеризации композиция из двух частей, содержащая в одной части борорганическое соединение, способное к образованию соединений, образующих свободные радикалы, и одно или более соединение, содержащее дигидрокарбилгидроксиламин или алициклический гидроксиламин или оксид нитрила дигидрокарбиламина или алициклического гидроксиламина, и во второй части содержит одно или более соединение, способное к свободно-радикальной полимеризации.
2. Композиция из двух частей по п.1, в которой вторая часть дополнительно содержит декомплексообразующий агент, способный превращать борорганическое соединение в соединение, образующее свободные радикалы, при контактировании двух частей.
3. Композиция из двух частей по п.2, в которой борорганическое соединение представляет собой комплекс органоборана и амина или органоборатную соль.
4. Композиция из двух частей по п.3, в которой борорганическое соединение представляет собой комплекс органоборана и амина.
5. Композиция из двух частей по п.3, в которой первая часть дополнительно содержит одно или более соединение, способное к свободно-радикальной полимеризации.
6. Композиция из двух частей по п.5, в которой одно или более соединение гидроксиламина соответствует формуле (R13)2N-OH или формуле (R13)2-N-O, где R13 представляет собой, независимо в каждом случае, гидрокарбильный фрагмент или два R13 образуют цикл.
7. Способ полимеризации включающий контактирование компонентов способной к полимеризации композиции по любому из пп.1-6 при таких условиях, что одно или более соединение, способное к свободно-радикальной полимеризации, подвергается полимеризации.
8. Способ связывания двух или более соединений вместе, который содержит
а. совместное контактирование компонентов композиции по любому из пп.1-6 при таких условиях, что инициируется полимеризация,
b. контактирование композиции с двумя или более соединениями,
с. расположение двух или более соединений так, что композиция локализуется между двумя или более соединениями, причем они находятся в контакте друг с другом, и
d. отверждение композиции так, чтобы связать два или более соединения вместе.
9. Способ модифицирования поверхности полимера с низкой поверхностной энергией путем контактирования композиции по любому из пп.1-6, по меньшей мере, с частью поверхности полимера с низкой поверхностной энергией, вызывая превращение борорганического соединения в трехвалентное борорганическое соединение, инициируя таким образом полимеризацию мономера, олигомеров, полимеров или их смесей так, что полимер образуется на поверхности полимера с низкой поверхностной энергией.
10. Способ покрытия соединения, который включает контактирование компонентов композиции по любому из пп.1-6; контактирование контактирующей композиции с одной или более поверхностями соединения и отверждение покрывающей композиции.
11. Покрывающая композиция, которая содержит композицию по любому из пп.1-6.
12. Ламинат, содержащий, по меньшей мере, два соединения, имеющих расположенную между соединениями и связывающую каждое соединение полимеризованную композицию, полученную из композиции по любому из пп.1-6.
13. Одна часть способной к полимеризации композиции, содержащая в комплексе органоборана и амина одно или более соединение, содержащая дигидрокарбилгидроксиламин, алициклический гидроксиламин или оксид нитрила дигидрокарбилгидроксиламина или алициклического гидроксиламина, и одно или более соединение, способное к свободно-радикальной полимеризации.
RU2005138300/04A 2003-06-09 2004-06-09 Стабилизированные органоборановые инициаторы полимеризации и способные к полимеризации композиции RU2358992C2 (ru)

Applications Claiming Priority (2)

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US47713503P 2003-06-09 2003-06-09
US60/477,135 2003-06-09

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RU2005138300A true RU2005138300A (ru) 2006-06-27
RU2358992C2 RU2358992C2 (ru) 2009-06-20

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US (1) US7247596B2 (ru)
EP (1) EP1648944A1 (ru)
KR (1) KR20060081656A (ru)
CN (1) CN100480279C (ru)
BR (1) BRPI0411378A (ru)
CA (1) CA2531694A1 (ru)
RU (1) RU2358992C2 (ru)
WO (1) WO2006001787A1 (ru)

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KR20060081656A (ko) 2006-07-13
US7247596B2 (en) 2007-07-24
CN1839160A (zh) 2006-09-27
US20050004332A1 (en) 2005-01-06
RU2358992C2 (ru) 2009-06-20
WO2006001787A1 (en) 2006-01-05
WO2006001787A8 (en) 2006-05-11

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