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RU2004111010A - Получение водорода - Google Patents

Получение водорода Download PDF

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RU2004111010A
RU2004111010A RU2004111010/15A RU2004111010A RU2004111010A RU 2004111010 A RU2004111010 A RU 2004111010A RU 2004111010/15 A RU2004111010/15 A RU 2004111010/15A RU 2004111010 A RU2004111010 A RU 2004111010A RU 2004111010 A RU2004111010 A RU 2004111010A
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Russia
Prior art keywords
fuel composition
preferably less
gasoline
hydrocarbon fuel
alkylation
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RU2004111010/15A
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English (en)
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RU2311339C2 (ru
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Грэм ХОДЖЕЗ Майкл (GB)
Грэм ХОДЖЕЗ Майкл
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Бп П.Л.К. (Gb)
Бп П.Л.К.
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Publication of RU2311339C2 publication Critical patent/RU2311339C2/ru

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Claims (11)

1. Способ получения водорода для топливного элемента из углеводородной топливной композиции, включающий следующие стадии:
подготовка углеводородной топливной композиции, которую получают введением жидкого углеводородного сырья, включающего алкилирующий агент, в контакт с кислотным катализатором в условиях, эффективных для алкилирования по меньшей мере части углеводородного сырья;
превращение углеводородной топливной композиции в водород; и
необязательное введение полученного водорода в топливный элемент.
2. Способ по п.1, в котором жидкое углеводородное сырье выбирают из группы, включающей легкий лигроин, тяжелый лигроин, бензин, керосин, бензин легкого крекинга, бензин каталитического крекинга, бензин установки для коксования, легкий рецикловый газойль, бензино-лигроиновую фракцию из процесса каталитического крекинга и бензино-лигроиновую фракцию селективной гидроочистки.
3. Способ по п.1, в котором жидкое углеводородное сырье дополнительно включает серусодержащие примеси, по меньшей мере часть которых алкилируют на стадии алкилирования.
4. Способ по п.3, в котором на стадии алкилирования алкилируют больше 30%, более предпочтительно больше 50%, а наиболее предпочтительно больше 90%, серусодержащих материалов.
5. Способ по п.1, в котором жидкое углеводородное сырье дополнительно включает ароматические соединения, которые алкилируют на стадии алкилирования.
6. Способ по п.1, в котором со стадии алкилирования в качестве топливной композиции выделяют более низкокипящую фракцию, включающую углеводороды и в пониженной концентрации серусодержащие примеси и/или ароматические соединения.
7. Способ по п.6, в котором более низкокипящую фракцию выделяют перегонкой.
8. Способ по п.6 или 7, в котором более низкокипящая фракция характеризуется температурой выкипания ниже 215°С, более предпочтительно ниже 180°С, например в пределах 100 и 175°С.
9. Способ по одному из пп.1-7, в котором углеводородная топливная композиция, выделенная на стадии алкилирования, характеризуется:
содержанием олефинов меньше 40 мас.%, предпочтительно меньше 30 мас.%, более предпочтительно меньше 20 мас.%, а наиболее предпочтительно меньше 10 мас.%;
содержанием ароматических продуктов меньше 35 мас.%, предпочтительно меньше 25 мас.%, а более предпочтительно меньше 5 мас.%;
конечной температурой кипения (КТК) ниже 215°С, более предпочтительно ниже 180°С, например в пределах 100 и 175°С; и
содержанием серы меньше 60 част./млн, предпочтительно меньше 10 част./млн, более предпочтительно меньше 5 част./млн, наиболее предпочтительно меньше 2 част./млн.
10. Способ по п.1, в котором углеводородная топливная композиция характеризуется октановым числом, определенным по моторному методу (МОЧ), по меньшей мере 80 и октановым числом, определенным исследованиями (ОЧИ), по меньшей мере 90, предпочтительно МОЧ по меньшей мере 85 и ОЧИ по меньшей мере 95.
11. Способ по п.1, который дополнительно включает стадию введения в углеводородную топливную композицию одной или нескольких присадок перед превращением этой углеводородной топливной композиции в водород.
RU2004111010/15A 2001-09-11 2002-08-28 Получение водорода RU2311339C2 (ru)

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