RU2001110089A - Носитель катализатора эпоксидирования, его получение и применение - Google Patents
Носитель катализатора эпоксидирования, его получение и применениеInfo
- Publication number
- RU2001110089A RU2001110089A RU2001110089/04A RU2001110089A RU2001110089A RU 2001110089 A RU2001110089 A RU 2001110089A RU 2001110089/04 A RU2001110089/04 A RU 2001110089/04A RU 2001110089 A RU2001110089 A RU 2001110089A RU 2001110089 A RU2001110089 A RU 2001110089A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- carrier
- support
- particles
- transfer
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 9
- 238000006735 epoxidation reaction Methods 0.000 title claims 3
- 238000000034 method Methods 0.000 claims 7
- 239000002245 particle Substances 0.000 claims 4
- 239000007789 gas Substances 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 230000007928 solubilization Effects 0.000 claims 2
- 238000005063 solubilization Methods 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000010668 complexation reaction Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- -1 hydrogen ions Chemical class 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 230000001737 promoting effect Effects 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Claims (9)
1. Носитель катализатора со скоростью солюбилизации натрия, определенной по количеству, выделившемуся при погружении в 3:1 мас./мас. кипящей воды, составляющему не более 5 мас.ч. на млн, из расчета на общую массу носителя, за 5 мин.
2. Способ получения носителя катализатора по п.1, в котором упомянутую скорость солюбилизации натрия достигают методом, эффективным для перевода ионизуемых частиц, находящихся на поверхности носителя, в ионное состояние, и удалении, по меньшей мере, части этих частиц, или перевода ионизуемых частиц в нерастворимое состояние, или перевода ионизуемых частиц в стационарное состояние.
3. Способ по п.2, в котором упомянутый метод выбирают из промывания, ионного обмена, испарения, удаления примесей, осаждения, комплексообразования и их сочетания.
4. Катализатор, содержащий носитель по п.1 и один или более каталитически активных металлов и, необязательно, одно или более промотирующих веществ, нанесенных на упомянутый носитель.
5. Катализатор по п.4, отличающийся тем, что он пригоден для эпоксидирования олефинов в газовой фазе.
6. Катализатор по п.5, отличающийся тем, что упомянутый носитель является носителем на основе оксида алюминия, а упомянутый каталитически активный металл представляет собой серебро.
7. Способ получения катализатора по любому из пп.4-6, отличающийся тем, что упомянутый каталитически активный металл наносят на упомянутый носитель путем погружения этого носителя в раствор для пропитки, активность водородных ионов в котором снижена.
8. Способ каталитического эпоксидирования алкена кислородсодержащим газом, в котором используют катализатор по любому из пп.4-6, или катализатор, полученный по п.7.
9. Способ по п.8, отличающийся тем, что к кислородсодержащему газу добавляют, по меньшей мере, один из оксидов азота.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10019698P | 1998-09-14 | 1998-09-14 | |
| US60/100,196 | 1998-09-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2001110089A true RU2001110089A (ru) | 2003-08-10 |
| RU2225255C2 RU2225255C2 (ru) | 2004-03-10 |
Family
ID=22278562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2001110089/04A RU2225255C2 (ru) | 1998-09-14 | 1999-09-10 | Носитель катализатора эпоксидирования, его получение и применение |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US6579825B2 (ru) |
| EP (1) | EP1140354A1 (ru) |
| JP (1) | JP4794042B2 (ru) |
| KR (1) | KR100641542B1 (ru) |
| CN (1) | CN1154538C (ru) |
| AU (1) | AU757735B2 (ru) |
| BR (1) | BR9913602A (ru) |
| CA (1) | CA2343836C (ru) |
| GC (1) | GC0000068A (ru) |
| ID (1) | ID28790A (ru) |
| IN (1) | IN2001DE00173A (ru) |
| MX (1) | MX257765B (ru) |
| MY (1) | MY130360A (ru) |
| RU (1) | RU2225255C2 (ru) |
| TR (1) | TR200100749T2 (ru) |
| TW (1) | TW442331B (ru) |
| WO (1) | WO2000015335A1 (ru) |
| ZA (1) | ZA200101902B (ru) |
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-
1999
- 1999-09-10 TR TR2001/00749T patent/TR200100749T2/xx unknown
- 1999-09-10 BR BR9913602-3A patent/BR9913602A/pt not_active Application Discontinuation
- 1999-09-10 AU AU59770/99A patent/AU757735B2/en not_active Ceased
- 1999-09-10 KR KR1020017003173A patent/KR100641542B1/ko not_active Expired - Fee Related
- 1999-09-10 ID IDW20010576A patent/ID28790A/id unknown
- 1999-09-10 RU RU2001110089/04A patent/RU2225255C2/ru not_active IP Right Cessation
- 1999-09-10 JP JP2000569914A patent/JP4794042B2/ja not_active Expired - Lifetime
- 1999-09-10 CN CNB998109037A patent/CN1154538C/zh not_active Expired - Lifetime
- 1999-09-10 WO PCT/EP1999/006725 patent/WO2000015335A1/en not_active Ceased
- 1999-09-10 EP EP99969045A patent/EP1140354A1/en not_active Withdrawn
- 1999-09-10 CA CA002343836A patent/CA2343836C/en not_active Expired - Fee Related
- 1999-09-13 GC GCP1999281 patent/GC0000068A/xx active
- 1999-09-14 MY MYPI99003961A patent/MY130360A/en unknown
- 1999-10-19 TW TW088118046A patent/TW442331B/zh not_active IP Right Cessation
-
2001
- 2001-02-26 IN IN173DE2001 patent/IN2001DE00173A/en unknown
- 2001-03-07 ZA ZA200101902A patent/ZA200101902B/en unknown
- 2001-03-12 MX MXPA01002587 patent/MX257765B/es not_active IP Right Cessation
- 2001-11-06 US US09/992,787 patent/US6579825B2/en not_active Expired - Lifetime
- 2001-11-06 US US09/992,784 patent/US7247600B2/en not_active Expired - Lifetime
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2007
- 2007-04-25 US US11/739,930 patent/US7439375B2/en not_active Expired - Fee Related
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