KR900701988A - 계면활성제-함유 과립의 제조방법 - Google Patents
계면활성제-함유 과립의 제조방법Info
- Publication number
- KR900701988A KR900701988A KR1019900701333A KR900701333A KR900701988A KR 900701988 A KR900701988 A KR 900701988A KR 1019900701333 A KR1019900701333 A KR 1019900701333A KR 900701333 A KR900701333 A KR 900701333A KR 900701988 A KR900701988 A KR 900701988A
- Authority
- KR
- South Korea
- Prior art keywords
- water
- weight
- granules
- nonionic surfactant
- insoluble solids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Medicinal Preparation (AREA)
- Colloid Chemistry (AREA)
- Cosmetics (AREA)
- Glanulating (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Abstract
Description
Claims (10)
- (A)임의로 수용성 또는 수불용성 고형분 총량의 일부(50중량%미만)을 용해된 또는 분산된 형태로 함유할 수 있는 비이온성 계면활성제를 물과 혼합하여 점성 겔상을 형성한후, (B)남은 대부분의 양의 수용성 또는 수불용성 고형분을 분말형으로 가하고, 생성되는 혼합물을 기계적으로 처리하여, 무수물로 표시되는 총 고형분 존재량에 대한 겔 상에서의 비이온성 계면활성제 및 물의 중량비가 25:75~65:35인 과립을 형성시킴을 특징으로 하는, 폴리글리콜 에테르 유도체계 유래의 비이온성 계면활성제, 미분쇄된 수용성 및/또는 수불용성 고형분 및 물을 함유하는 고 외견상 밀도를 갖는 자유-유동성 과립의 제조방법.
- 제1항에 있어서, 총 고형분 존재량에 대한 겔 상(A)에서의 비이온성 계면활성제 및 물의 비가 30 : 70∼60 : 40인 방법.
- 제1항 또는 2항에 있어서, 총 고형분 존재량의 0∼40중량%, 바람직하게는 0∼30중량%, 보다 바람직하게는 5∼25중량%가 젤상(A)의 형성시 사용되고, 남은 대부분의 양이 건조분말로 과립상(B)에서 첨가되는 방법.
- 제3항에 있어서, 100㎛미만, 바람직하게는 50㎛미만인 그레인 크기를 갖는 수불용성 고형분이 사용되는 방법.
- 제4항에 있어서, 미세 결정성 제올라이트, 벤토나이트 또는 그의 혼합물이 수불용성 고형분으로 사용되는 방법.
- 제1항 내지 4항중 어느 한 항에 있어서, 형성되는 과립의 외견상 밀도가 최대치에 이를때까지만 겔상을 분말형 고형분과 혼합하는 방법.
- 제1항 내지 4항중 어느 한 항에 있어서, 비이온성 계면활성제가, 무수불을 기준으로 제올라이트 35∼55중량%, 분산안정화제로 작용하는 비이온성 계면활성제 0.5∼5중량%및 물 64.5∼40중량%를 함유하는 미세결정성 제올라이트의 수성 분산액과 혼합되어 겔이 형성되는 방법.
- 제1항 내지 6항중 어느 한 항에 기재된 방법에 의해 제조된 과립.
- 제8항에 있어서, 외견상 밀도가 600∼1,000 g/l, 바람직하게는 650∼900 g/l인 과립.
- 제8항 내지 9항에 기재된 과립을 함유하는 과립상 세제 및 청정제제.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3835918.9 | 1988-10-21 | ||
| DE3835918A DE3835918A1 (de) | 1988-10-21 | 1988-10-21 | Verfahren zur herstellung von tensidhaltigen granulaten |
| PCT/EP1989/001206 WO1990004629A2 (de) | 1988-10-21 | 1989-10-12 | Verfahren zur herstellung von tensidhaltigen granulaten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR900701988A true KR900701988A (ko) | 1990-12-05 |
| KR970001224B1 KR970001224B1 (en) | 1997-02-04 |
Family
ID=6365638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR90701333A Expired - Fee Related KR970001224B1 (en) | 1988-10-21 | 1990-06-21 | Process for the production of surfactant-containing granulates |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5354493A (ko) |
| EP (2) | EP0364881A3 (ko) |
| JP (1) | JP2704020B2 (ko) |
| KR (1) | KR970001224B1 (ko) |
| AT (1) | ATE117718T1 (ko) |
| DE (2) | DE3835918A1 (ko) |
| DK (1) | DK71791D0 (ko) |
| ES (1) | ES2067569T3 (ko) |
| PT (1) | PT92060A (ko) |
| TR (1) | TR24142A (ko) |
| WO (1) | WO1990004629A2 (ko) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3943019A1 (de) * | 1989-12-27 | 1991-07-04 | Henkel Kgaa | Granulares, avivierend wirkendes waschmitteladditiv und verfahren zu seiner herstellung |
| KR0170424B1 (ko) * | 1990-07-05 | 1999-01-15 | 호르스트 헤를레,요한 글라슬 | 세제 및 청정제용 표면 활성제 과립의 제조방법 |
| US5108646A (en) * | 1990-10-26 | 1992-04-28 | The Procter & Gamble Company | Process for agglomerating aluminosilicate or layered silicate detergent builders |
| DE4110510A1 (de) * | 1991-03-30 | 1992-10-01 | Henkel Kgaa | Niederalkalische, chlor- und phosphatfreie maschinengeschirrspuelmittel in form von schwerpulvern und -granulaten |
| DE4127323A1 (de) * | 1991-08-20 | 1993-02-25 | Henkel Kgaa | Verfahren zur herstellung von tensidgranulaten |
| DE4137470A1 (de) * | 1991-11-14 | 1993-05-19 | Henkel Kgaa | Verfahren zur herstellung niederalkalischer, aktivchlor- und phosphatfreier maschinengeschirrspuelmittel in form von schwergranulaten |
| CA2083331C (en) * | 1991-11-26 | 1998-08-11 | Johannes H. M. Akkermans | Detergent compositions |
| DE4203789A1 (de) * | 1992-02-10 | 1993-08-12 | Henkel Kgaa | Verfahren zur stabilisierung von waessrigen zeolith-suspensionen |
| DE4216629A1 (de) * | 1992-05-20 | 1993-11-25 | Henkel Kgaa | Verfahren zur Herstellung aniontensidhaltiger Wasch- und Reinigungsmittel |
| EP0622454A1 (en) * | 1993-04-30 | 1994-11-02 | The Procter & Gamble Company | Structuring liquid nonionic surfactants prior to granulation process |
| ATE188991T1 (de) * | 1993-09-13 | 2000-02-15 | Procter & Gamble | Granulare waschmittelzusammensetzungen mit nichtionischem tensid und verfahren zu ihrer herstellung |
| GB9324129D0 (en) * | 1993-11-24 | 1994-01-12 | Unilever Plc | Detergent compositions and process for preparing them |
| US5496486A (en) * | 1994-06-30 | 1996-03-05 | Amway Corporation | Process for increasing liquid surfactant loading in free flowing powder detergents |
| EP0694608A1 (en) * | 1994-07-28 | 1996-01-31 | The Procter & Gamble Company | Process for making granular detergents and detergent compositions comprising nonionic surfactant |
| TW326472B (en) * | 1994-08-12 | 1998-02-11 | Kao Corp | Method for producing nonionic detergent granules |
| WO1996025482A1 (en) * | 1995-02-13 | 1996-08-22 | The Procter & Gamble Company | Process for producing detergent agglomerates in which particle size is controlled |
| US5574005A (en) * | 1995-03-07 | 1996-11-12 | The Procter & Gamble Company | Process for producing detergent agglomerates from high active surfactant pastes having non-linear viscoelastic properties |
| US5888419A (en) * | 1995-06-07 | 1999-03-30 | The Clorox Company | Granular N-alkyl ammonium acetontrile compositions |
| GB9513327D0 (en) * | 1995-06-30 | 1995-09-06 | Uniliver Plc | Process for the production of a detergent composition |
| DE19603760A1 (de) * | 1996-02-02 | 1997-08-07 | Henkel Kgaa | Feste Reinigungsmittelzubereitungen |
| GB9605534D0 (en) * | 1996-03-15 | 1996-05-15 | Unilever Plc | Detergent compositions |
| GB9711356D0 (en) † | 1997-05-30 | 1997-07-30 | Unilever Plc | Particulate detergent composition |
| US7625855B2 (en) * | 1999-08-11 | 2009-12-01 | Gonzalez Gustavo M | Cleaning compositions for removing organic deposits in hard to reach surfaces |
| US6057280A (en) | 1998-11-19 | 2000-05-02 | Huish Detergents, Inc. | Compositions containing α-sulfofatty acid esters and methods of making and using the same |
| DE19913995A1 (de) | 1999-03-29 | 2000-10-05 | Basf Ag | Verfahren zur Herstellung von körnigen N-Alkylamoniumacetonitril-Salzen |
| DE10008815A1 (de) * | 2000-02-25 | 2001-08-30 | Sued Chemie Ag | Schichtmineralhaltige Agglomerate mit nichtionischen Tensiden |
| CN108837784A (zh) * | 2018-06-07 | 2018-11-20 | 曾婧 | 一种改进的用于生产洗涤剂组合物颗粒的方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2874123A (en) * | 1954-09-07 | 1959-02-17 | Colgate Palmolive Co | Process for the preparation of granular compositions |
| US3769222A (en) * | 1971-02-09 | 1973-10-30 | Colgate Palmolive Co | Free flowing nonionic surfactants |
| ZA734721B (en) | 1972-07-14 | 1974-03-27 | Procter & Gamble | Detergent compositions |
| AT330930B (de) | 1973-04-13 | 1976-07-26 | Henkel & Cie Gmbh | Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen |
| US4166039A (en) * | 1973-10-15 | 1979-08-28 | The Proctor & Gamble Company | Detergent composition and process |
| AT335035B (de) * | 1974-10-10 | 1977-02-25 | Henkel & Cie Gmbh | Stabile suspensionen wasserunloslicher, zum binden von calciumionen befahigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln |
| US4169075A (en) * | 1974-10-10 | 1979-09-25 | Henkel Kommanditgesellschaft Auf Aktien | Process for the production of powdery washing agents by spray-drying |
| GB1545810A (en) * | 1976-11-02 | 1979-05-16 | Albright & Wilson | Manufacture of detergents |
| DE2837504C2 (de) * | 1978-08-28 | 1983-07-07 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur Herstellung eines schüttfähigen, nichtionische Tenside enthaltenden Wasch- und Reinigungsmittelgranulates |
| EP0026529B2 (en) | 1979-09-29 | 1992-08-19 | THE PROCTER & GAMBLE COMPANY | Detergent compositions |
| ATE5896T1 (de) * | 1979-11-03 | 1984-02-15 | The Procter & Gamble Company | Granulare waschmittelzusammensetzungen. |
| AU549000B2 (en) | 1981-02-26 | 1986-01-09 | Colgate-Palmolive Pty. Ltd. | Base beads for detergent compositions |
| GB8329880D0 (en) * | 1983-11-09 | 1983-12-14 | Unilever Plc | Particulate adjuncts |
| DE3444311A1 (de) * | 1984-12-05 | 1986-06-05 | Degussa Ag, 6000 Frankfurt | Waessrige stabile suspension wasserunloeslicher, zum binden von calciumionen befaehigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln |
| DE3444960A1 (de) * | 1984-12-10 | 1986-06-12 | Henkel KGaA, 4000 Düsseldorf | Koerniges adsorptionsmittel |
| US4970017A (en) * | 1985-04-25 | 1990-11-13 | Lion Corporation | Process for production of granular detergent composition having high bulk density |
| DE3526405A1 (de) * | 1985-07-24 | 1987-02-05 | Henkel Kgaa | Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln |
| US4894117A (en) * | 1988-04-28 | 1990-01-16 | Colgate-Palmolive Company | Process for manufacturing high bulk density particulate fabric softening synthetic anionic organic detergent compositions |
| US4925585A (en) * | 1988-06-29 | 1990-05-15 | The Procter & Gamble Company | Detergent granules from cold dough using fine dispersion granulation |
-
1988
- 1988-10-21 DE DE3835918A patent/DE3835918A1/de not_active Withdrawn
-
1989
- 1989-10-04 TR TR89/0820A patent/TR24142A/xx unknown
- 1989-10-12 AT AT89911804T patent/ATE117718T1/de not_active IP Right Cessation
- 1989-10-12 DE DE58908952T patent/DE58908952D1/de not_active Expired - Fee Related
- 1989-10-12 JP JP1510987A patent/JP2704020B2/ja not_active Expired - Lifetime
- 1989-10-12 WO PCT/EP1989/001206 patent/WO1990004629A2/de not_active Ceased
- 1989-10-12 EP EP89118962A patent/EP0364881A3/de active Pending
- 1989-10-12 US US07/678,358 patent/US5354493A/en not_active Expired - Fee Related
- 1989-10-12 ES ES89911804T patent/ES2067569T3/es not_active Expired - Lifetime
- 1989-10-12 EP EP89911804A patent/EP0536110B1/de not_active Expired - Lifetime
- 1989-10-20 PT PT92060A patent/PT92060A/pt not_active Application Discontinuation
-
1990
- 1990-06-21 KR KR90701333A patent/KR970001224B1/ko not_active Expired - Fee Related
-
1991
- 1991-04-19 DK DK91717A patent/DK71791D0/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO1990004629A2 (de) | 1990-05-03 |
| DE3835918A1 (de) | 1990-04-26 |
| US5354493A (en) | 1994-10-11 |
| TR24142A (tr) | 1991-04-09 |
| JP2704020B2 (ja) | 1998-01-26 |
| DK71791A (da) | 1991-04-19 |
| ES2067569T3 (es) | 1995-04-01 |
| EP0536110B1 (de) | 1995-01-25 |
| KR970001224B1 (en) | 1997-02-04 |
| WO1990004629A3 (de) | 1991-05-30 |
| ATE117718T1 (de) | 1995-02-15 |
| EP0364881A2 (de) | 1990-04-25 |
| PT92060A (pt) | 1990-04-30 |
| JPH04501129A (ja) | 1992-02-27 |
| EP0536110A1 (de) | 1993-04-14 |
| DK71791D0 (da) | 1991-04-19 |
| EP0364881A3 (de) | 1990-06-06 |
| DE58908952D1 (de) | 1995-03-09 |
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Legal Events
| Date | Code | Title | Description |
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| PA0105 | International application |
St.27 status event code: A-0-1-A10-A15-nap-PA0105 |
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| R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
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| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
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| A201 | Request for examination | ||
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
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| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
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| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
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