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KR900011817A - 메소제닉 에폭시 화합물 - Google Patents

메소제닉 에폭시 화합물

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Publication number
KR900011817A
KR900011817A KR1019900000447A KR900000447A KR900011817A KR 900011817 A KR900011817 A KR 900011817A KR 1019900000447 A KR1019900000447 A KR 1019900000447A KR 900000447 A KR900000447 A KR 900000447A KR 900011817 A KR900011817 A KR 900011817A
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mesogenic
amount
epoxy resin
weight
carbon atoms
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디. 얼스 지미
쥬니어 로버트 이.헤프너
엠. 퍼키트 폴
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리차드 지. 워터맨
더 다우 케미탈 캄파니
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Publication of KR900011817A publication Critical patent/KR900011817A/ko
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
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    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C09K19/3804—Polymers with mesogenic groups in the main chain
    • C09K19/3814—Polyethers
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    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C09K19/3804—Polymers with mesogenic groups in the main chain
    • C09K19/3823—Polymers with mesogenic groups in the main chain containing heterocycles having at least one nitrogen as ring hetero atom

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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Resins (AREA)
  • Epoxy Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

내용 없음

Description

메소제닉 에폭시 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 하나이상의 메소제닉 또는 로드성 잔기를 함유하는 하기 일반식(Ⅰ)의 에폭시 수지.
    상기식에서, R은 각각 수소 또는, 탄소수 1 내지 4의 지방족 탄화수소 그룹이고, X는 각각 수소, 탄소수 1 내지 12의 하이드로카빌 또는 하이드로카빌 옥시 그룹, 할로겐원자, －NO2또는 －C≡N이며,
    Z은 각각 －CR1=CR1－, －CR1=CR1－CR1=CR1－,－CR1=N－N=CR1－, －CR1=CR1－CO－O－CH2－,－CR1=CR1－CO－O－CH2－CH2－,－CH2－O－CO－CR1=CR1－,－CH2－CH2－O－CO－CR1=CR1－, －CR1=CR1－CO－O－, －O－CO－CR1=CR|1－,－N=N－, －CO－NH－, －NH－CO－, －CO－NH－NH－CO－, －C≡C－,－C≡C－C≡C－,－CO－S－,－S－CO－, 직접 단일결합(n이 1이상일 경우).
    (여기서 P는 0 ,1 또는 2이다.)
    가 벤젠환이 아니고 n이 0이 아닐 경우에는-CR'=N-, -N=CR'-, -CO-, -CR'=CR'-, CR'=CR'-CO-O-, -O-, 및 -O-CO-일수 있고, Z2는 탄소수 5내지 12의 사이클릭 또는 비사이클릭 환계의 그룹이며, 사이클로지방족, 폴리사이클로지방족, 방향족 또는 이들의 혼합물일 수 있고, Z'은 각각 -CO-, -O-CO-, -CO-O-,-CO-NR'- 또는 -NR'- CO-그룹이며, R1은 각각 수소 또는 탄소수 1내지 4의 지방족 탄화수소 그룹이고, n은 0내지 2이며, ,n'은 0또는 1이고, 여기서, -(Z1-Z2)n-Z1-결합 및 글리시딜 에테르 그룹중 80%이상은 서로에 대해 파라위치에 존재한다.
  2. 하나이상의 메소제닉 또는 로드성 잔기를 함유하는 하기 일반식(Ⅱ)의 에폭시 수지.
    상기식에서, Z3은Z4- 또는이고,
    Z4는 -CO-O-, -O-CO-, -NR'- CO-또는 -CO-NR'-이며, X1는 N,O 및 S 중에서 선택된 하나이상의 헤테로원자를 함유할 수 있으며, 포화되거나 불포화될 수 있는탄소수 1내지 10의 하이드로카빌 그룹이고, R, R1, X 및 n'는 제1항에서 정의한 바와 같다.
  3. 4,4'-디하이드록시-α-메틸스틸벤의 디글리시딜 에테르인 에폭시 수지.
  4. 4,4'-디히드록시벤즈아닐리드의 디글리시딜 에테르인 에폭시 수지.
  5. 4,4'-디하이드록시-2,2'-디메틸아족시벤젠의 디글리시딜 에테르인 에폭시 수지.
  6. 하나이상의 메소제닉 또는 로드성 잔기를 함유하는 하기 일반식(Ⅲ)의 모노에폭사이드.
    상기 식에서, R은 각각 수소 또는 탄소수 1내지 4의 지방족 탄화수소 그룹이고, X는 각각 수소, 탄소수 1내지 12의 하이드로카빌 또는 하이드로 카빌옥시 그룹, 할로겐 원자, -NO2또는 -C≡N이며,
    Z'은 각각 각 －CR1=CR1－, －CR1=CR1－CR1=CR1－,－CR1=N－N=CR1－, －CR1=CR1－CO－O－CH2－,－CR1=CR1－CO－O－CH2－CH2－,－CH|2－O－CO－CR1=CR1－,－CH2－CH2－O－CO－CR1=CR1－, －CR1=CR1－CO－O－, －O－CO－CR1=CR|1－,－N=N－, －CO－NH－, －NH－CO－, －CO－NH－NH－CO－, －C≡C－,－C≡C－C≡C－,－CO－S－,－S－CO－, CR1=N-, -N=CR1, -CO-O-, -O-CO-,
    직접 단일 결합(n이 1이상일 경우)
    (여기서, P는 0, 1 또는 2이다),
    및이고, Z2는 탄소수 5내지 12의 사이클릭 또는 비사이클릭 환계의 그룹이며, R1',Z',n 및 n'는 제1항에서 정의한 바와 같고, 여기서, -(Z1-Z2)n-Z1-결합 및 글리시딜 에테르 그룹중 80%이상은 서로에 대해 파라 위치에 존재한다.
  7. 하나이상의 메소제닉 또는 로드성 잔기를 함유하는 하기 일반식(Ⅳ)의 모노에폭사이드.
    상기식에서,
    Z4는 －CO－O－, -O-CO-, NR1-CO- 또는 －CO-NR1-이며, R,R'X,X1및 n'는 제1항에서 정의한 바와 같다.
  8. (A)제1항 내지 5항중 어느한 항에 에폭시 수지 또는 조성물 하나이상과 (B)분자당 평균 하나이상의 활성수소 원자를 함유하는 화합물 하나이상을 반응시킴〔여기서, 성분(A) 및 (B)는 에폭사이드 그룹에 대한 활성 수소원자의 비율이 0.01:1내지 0.95:1이 되도록 하는 양으로 사용된다〕으로써 제조한 , 개질된 에폭시수지 조성물.
  9. (A)제1항 내지 5항중 어느 한 항에 에폭시 수지 또는 조성물 하나이상과 (B)분자당 평균 하나이상의 활성수소 원자를 함유하는 화합물 하나이상을 개질 반응시킴〔여기서, 성분(A) 및 (B)는 에폭사이드 그룹에 대한 활성수소원자의 비율이 0.96:1내지 1.05:1이 되도록 하는 양을 사용된다〕으로써 제조된 열가소성 수지 조성물.
  10. 제1항 내지 9항중 어느 한 항에 있어서, 메소제닉 또는 로드성 잔기가 배향되어 있는 에폭시 수지 조성물 또는 모노에폭사이드.
  11. 제10항에 있어서, 전기장 또는 자기장, 또는 전단 유동에 의해 배향시킨 에폭시 수지 조성물.
  12. (A)제1항 내지 7항중 어느 한 항에 따른, 하나이상의 메소제닉 또는 로드성 잔기를 함유하는 에폭시-함유수지 또는 화합물 하나이상과 (B)메소제닉 또는 로드성 잔기를 사실상 함유하지 않는 폴리에폭사이드 하나 이상을 함유하며, 여기서, 성분 (A)와(B)를 합한 중량을 기준으로 하여, 성분(A)는 1내지 99중량%의 양으로 존재하며, 성분(B)는 99내지 1중량%의 양으로 존재함을 특징으로 하는 혼합물.
  13. (A)제8항에 따른, 하나이상의 메소제닉 또는 로드성 잔기를 함유하는 에폭시 함유 수지 또는 화합물 하나이상과 (B)메소제닉 또는 로드성 잔기를 함유하지 않는 폴리에폭사이드 하나이상을 함유하며, 여기서 성분(A)와(B)를 합한 중량을 기준으로 하여, 성분(A)는 1내지 99중량%의 양으로 존재하며, 성분(B)는 99내지 1중량%의 양으로 존재함을 특징으로 하는 혼합물.
  14. 제1항내지 5항, 8항 12항 또는 13항중 어느 한항에 따른 에폭시 수지, 조성물 또는 혼합물 하나이상 및 이를 위한 경화량의 경화제 하나이상을 함유함을 특징으로 하는 경화성 조성물.
  15. (A)제1항 ,2항 또는 에폭시 수지 또는 조성물 하나이상, (B)제6항 또는 7항에 따른 모노에폭사이드 하나이상, 및 (C)이를 위한 경화량의 경화제 하나이상을 함유하며, 여기서, 성분 (A)와 (B)를 합한 중량을 기준으로 하여, 성분(A)는 1내지 99중량%의 양으로 존재하며, 성분(B)는 99내지 1중량%의 양으로 존재함을특징으로 하는 경화성 조성물.
  16. 제14항 또는 15항에 따른 조성물을 경화시켜 수득한 생성물.
  17. 제16항에 있어서, 경화시키기 전 및 또는 경화 시키는 동안 전기장, 자기장 또는 전단 유동을 적용함으로써 수득한 생성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900000447A 1989-01-17 1990-01-16 메소제닉 에폭시 화합물 Ceased KR900011817A (ko)

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US29843189A 1989-01-17 1989-01-17
US298,431 1989-01-17

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EP (1) EP0379057B1 (ko)
JP (1) JP3099956B2 (ko)
KR (1) KR900011817A (ko)
AT (1) ATE197956T1 (ko)
AU (1) AU638690B2 (ko)
BR (1) BR9000162A (ko)
CA (1) CA2007798A1 (ko)
DE (1) DE69033670T2 (ko)
ES (1) ES2152206T3 (ko)
MY (1) MY106402A (ko)
SG (1) SG52478A1 (ko)

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KR20180002441U (ko) 2017-02-03 2018-08-13 조수호 벽돌 제조기의 성형틀 진동 장치

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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EP0379057A3 (en) 1993-03-17
ATE197956T1 (de) 2000-12-15

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