JP2004519814A - 非対称バナジウム還元セルを使用したバナジウム電解液の調整及び稼動中のバナジウムレドックスバッテリの電解液における充電状態を再均衡させるための非対称バナジウム還元セルの使用 - Google Patents
非対称バナジウム還元セルを使用したバナジウム電解液の調整及び稼動中のバナジウムレドックスバッテリの電解液における充電状態を再均衡させるための非対称バナジウム還元セルの使用 Download PDFInfo
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- JP2004519814A JP2004519814A JP2002520344A JP2002520344A JP2004519814A JP 2004519814 A JP2004519814 A JP 2004519814A JP 2002520344 A JP2002520344 A JP 2002520344A JP 2002520344 A JP2002520344 A JP 2002520344A JP 2004519814 A JP2004519814 A JP 2004519814A
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- Prior art keywords
- vanadium
- cell
- electrolyte
- anode
- solution
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 94
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 93
- 239000003792 electrolyte Substances 0.000 title claims abstract description 84
- 230000009467 reduction Effects 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 41
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 28
- 239000000243 solution Substances 0.000 claims abstract description 28
- 230000003647 oxidation Effects 0.000 claims abstract description 27
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000001301 oxygen Substances 0.000 claims abstract description 25
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 25
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 12
- 230000002378 acidificating effect Effects 0.000 claims abstract description 12
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000003993 interaction Effects 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 26
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 238000004090 dissolution Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 4
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 2
- 230000003134 recirculating effect Effects 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims 1
- 239000004063 acid-resistant material Substances 0.000 claims 1
- 238000010907 mechanical stirring Methods 0.000 claims 1
- 239000012811 non-conductive material Substances 0.000 claims 1
- 229910001935 vanadium oxide Inorganic materials 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 24
- 238000006722 reduction reaction Methods 0.000 description 22
- 229910001456 vanadium ion Inorganic materials 0.000 description 19
- 239000012528 membrane Substances 0.000 description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000036647 reaction Effects 0.000 description 6
- 238000007086 side reaction Methods 0.000 description 6
- -1 sulfuric acid Chemical class 0.000 description 6
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 5
- 229940021013 electrolyte solution Drugs 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000010411 electrocatalyst Substances 0.000 description 2
- 238000006056 electrooxidation reaction Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 230000037230 mobility Effects 0.000 description 2
- 230000003071 parasitic effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 206010014418 Electrolyte imbalance Diseases 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229910006253 ZrOy Inorganic materials 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/70—Arrangements for stirring or circulating the electrolyte
- H01M50/77—Arrangements for stirring or circulating the electrolyte with external circulating path
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04186—Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Fuel Cell (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IT2000/000342 WO2002015317A1 (en) | 2000-08-16 | 2000-08-16 | Vanadium electrolyte preparation using asymmetric vanadium reduction cells and use of an asymmetric vanadium reduction cell for rebalancing the state of charge of the electrolytes of an operating vanadium redox battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2004519814A true JP2004519814A (ja) | 2004-07-02 |
Family
ID=11133546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002520344A Pending JP2004519814A (ja) | 2000-08-16 | 2000-08-16 | 非対称バナジウム還元セルを使用したバナジウム電解液の調整及び稼動中のバナジウムレドックスバッテリの電解液における充電状態を再均衡させるための非対称バナジウム還元セルの使用 |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP1310008A1 (es) |
| JP (1) | JP2004519814A (es) |
| KR (1) | KR20030034146A (es) |
| CN (1) | CN1502141A (es) |
| AU (1) | AU2000267249A1 (es) |
| BR (1) | BR0017317A (es) |
| CA (1) | CA2420014A1 (es) |
| IL (1) | IL154098A0 (es) |
| MX (1) | MXPA03001330A (es) |
| NZ (1) | NZ523752A (es) |
| TR (1) | TR200300178T2 (es) |
| TW (1) | TW531934B (es) |
| WO (1) | WO2002015317A1 (es) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010533934A (ja) * | 2007-07-16 | 2010-10-28 | レンネベック、クラウス | レドックスバッテリ |
| JP2014532284A (ja) * | 2011-10-14 | 2014-12-04 | ディーヤ エナジー，インコーポレーテッド | バナジウムフローセル |
| KR20160008212A (ko) * | 2013-05-03 | 2016-01-21 | 유나이티드 테크놀로지스 코포레이션 | 흐름 배터리의 상태를 유지시키는 방법 |
| JP2018503222A (ja) * | 2014-12-11 | 2018-02-01 | フラウンホーファー−ゲゼルシャフト ツール フエルデルング デア アンゲヴァンテン フォルシュング エー．ファオ． | レドックス・フロー電池の電解質溶液を再生させる方法 |
| WO2020162375A1 (ja) * | 2019-02-05 | 2020-08-13 | Ｌｅシステム株式会社 | 電解液製造装置及び電解液の製造方法 |
| US11056698B2 (en) | 2018-08-02 | 2021-07-06 | Raytheon Technologies Corporation | Redox flow battery with electrolyte balancing and compatibility enabling features |
| JP2021168296A (ja) * | 2015-11-18 | 2021-10-21 | インビニティ エナジー システムズ(カナダ)コーポレイションInvinity Energy Systems(Canada)Corporation | 電解液の分散が改善された電極組立体およびフロー電池 |
| US11271226B1 (en) | 2020-12-11 | 2022-03-08 | Raytheon Technologies Corporation | Redox flow battery with improved efficiency |
| US12166253B2 (en) | 2021-01-04 | 2024-12-10 | Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C | Electrolytic reduction system and method of vanadium electrolyte |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP4140691B2 (ja) * | 2002-04-23 | 2008-08-27 | 住友電気工業株式会社 | レドックスフロー電池の運転方法 |
| AU2003901763A0 (en) | 2003-04-14 | 2003-05-01 | Michael Kazacos | Novel bromide redox flow cells and batteries |
| CA2517690C (en) * | 2003-03-14 | 2012-06-19 | Michael Kazacos | Novel vanadium halide redox flow battery |
| AU2003901183A0 (en) * | 2003-03-14 | 2003-03-27 | Michael Kazacos | Novel vanadium bromide redox flow cell |
| AU2004219551B2 (en) * | 2003-03-14 | 2008-12-11 | Newsouth Innovations Pty Limited | Novel vanadium halide redox flow battery |
| CA2671349C (en) * | 2006-12-15 | 2015-01-20 | Lion Laboratories Limited | A fuel cell having a channel for containing electrolyte |
| DE102007011311A1 (de) * | 2006-12-22 | 2008-06-26 | Mtu Cfc Solutions Gmbh | Vanadium-Redox-Batterie und Verfahren zu ihrem Betrieb |
| CN101619465B (zh) * | 2008-07-02 | 2010-12-22 | 中国科学院大连化学物理研究所 | 一种钒电池溶液的制备或容量调节的方法及其专用装置 |
| DE102009035314B4 (de) * | 2009-07-30 | 2011-07-21 | Bauer, Bernd, Dr., 71665 | Redoxbatterie mit Flüssigelektrolyt und Verfahren zum Erzeugen elektrischer Energie unter Einsatz einer solchen Batterie |
| WO2011137895A2 (de) * | 2010-05-04 | 2011-11-10 | Bani, Ibrahim | Redoxakkumulatoranlage |
| WO2012067338A2 (ko) * | 2010-11-15 | 2012-05-24 | Wy Soon Myung | 레독스 흐름 전지용 전극, 그 전극의 제조방법, 레독스 흐름 전지용 전해액 제조장치, 그 제조방법, 전해액의 선택이온 농도계, 선택이온 농도 측정방법 및 자립용 전지 시스템 |
| CN102011135A (zh) * | 2010-12-06 | 2011-04-13 | 上海林洋储能科技有限公司 | 一种循环电解反应装置及其制备钒电池电解液的方法 |
| CN102324547A (zh) * | 2011-07-27 | 2012-01-18 | 四川省川威集团有限公司 | 全钒离子氧化还原液流电池电解液的制备方法 |
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| EP2926400B1 (en) | 2012-11-30 | 2019-03-20 | Hydraredox Technologies Holdings Ltd. | Back plate-electrode-membrane assembly for a redox, flow energy storage electrochemical cell |
| CN102978647B (zh) * | 2012-12-05 | 2014-08-27 | 湖南汇锋高新能源有限公司 | 用于制备钒电池电池液的电解系统和电解方法 |
| ES2769406T3 (es) | 2012-12-14 | 2020-06-25 | Hydraredox Tech Holdings Ltd | Sistema de batería de flujo redox y procedimiento de control del mismo |
| CN103066312A (zh) * | 2012-12-21 | 2013-04-24 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种钒液流电池用电解液的制备方法 |
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| JPH04149965A (ja) * | 1990-10-15 | 1992-05-22 | Agency Of Ind Science & Technol | バナジウム系電解液の製造方法 |
| JPH1179748A (ja) * | 1997-08-29 | 1999-03-23 | Kashimakita Kyodo Hatsuden Kk | 高純度バナジウム電解液の連続的製造法 |
| PT1051766E (pt) * | 1998-01-28 | 2002-01-30 | Squirrel Holdings Ltd | Sistema de baterias redox de fluxo e pilha de celulas |
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- 2000-08-16 NZ NZ523752A patent/NZ523752A/en unknown
- 2000-08-16 CA CA002420014A patent/CA2420014A1/en not_active Abandoned
- 2000-08-16 BR BR0017317-7A patent/BR0017317A/pt not_active IP Right Cessation
- 2000-08-16 TR TR2003/00178T patent/TR200300178T2/xx unknown
- 2000-08-16 AU AU2000267249A patent/AU2000267249A1/en not_active Abandoned
- 2000-08-16 KR KR10-2003-7002313A patent/KR20030034146A/ko not_active Withdrawn
- 2000-08-16 CN CNA008198233A patent/CN1502141A/zh active Pending
- 2000-08-16 MX MXPA03001330A patent/MXPA03001330A/es unknown
- 2000-08-16 EP EP00954901A patent/EP1310008A1/en not_active Withdrawn
- 2000-08-16 JP JP2002520344A patent/JP2004519814A/ja active Pending
- 2000-08-16 WO PCT/IT2000/000342 patent/WO2002015317A1/en not_active Ceased
- 2000-08-16 IL IL15409800A patent/IL154098A0/xx unknown
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2001
- 2001-08-01 TW TW090118754A patent/TW531934B/zh not_active IP Right Cessation
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| JP2010533934A (ja) * | 2007-07-16 | 2010-10-28 | レンネベック、クラウス | レドックスバッテリ |
| JP2014532284A (ja) * | 2011-10-14 | 2014-12-04 | ディーヤ エナジー，インコーポレーテッド | バナジウムフローセル |
| KR20160008212A (ko) * | 2013-05-03 | 2016-01-21 | 유나이티드 테크놀로지스 코포레이션 | 흐름 배터리의 상태를 유지시키는 방법 |
| JP2016517160A (ja) * | 2013-05-03 | 2016-06-09 | ユナイテッド テクノロジーズ コーポレイションＵｎｉｔｅｄ Ｔｅｃｈｎｏｌｏｇｉｅｓ Ｃｏｒｐｏｒａｔｉｏｎ | フロー電池の健全性維持方法 |
| KR101969625B1 (ko) * | 2013-05-03 | 2019-04-16 | 유나이티드 테크놀로지스 코포레이션 | 흐름 배터리의 상태를 유지시키는 방법 |
| JP2018503222A (ja) * | 2014-12-11 | 2018-02-01 | フラウンホーファー−ゲゼルシャフト ツール フエルデルング デア アンゲヴァンテン フォルシュング エー．ファオ． | レドックス・フロー電池の電解質溶液を再生させる方法 |
| JP7203451B2 (ja) | 2015-11-18 | 2023-01-13 | インビニティ エナジー システムズ（カナダ）コーポレイション | 電解液の分散が改善された電極組立体およびフロー電池 |
| JP2021168296A (ja) * | 2015-11-18 | 2021-10-21 | インビニティ エナジー システムズ(カナダ)コーポレイションInvinity Energy Systems(Canada)Corporation | 電解液の分散が改善された電極組立体およびフロー電池 |
| US11056698B2 (en) | 2018-08-02 | 2021-07-06 | Raytheon Technologies Corporation | Redox flow battery with electrolyte balancing and compatibility enabling features |
| US11637298B2 (en) | 2018-08-02 | 2023-04-25 | Raytheon Technologies Corporation | Redox flow battery with electrolyte balancing and compatibility enabling features |
| JP2020126773A (ja) * | 2019-02-05 | 2020-08-20 | Ｌｅシステム株式会社 | 電解液製造装置及び電解液の製造方法 |
| AU2020218439B2 (en) * | 2019-02-05 | 2022-12-22 | Le System Co., Ltd. | Electrolyte manufacturing device and method for manufacturing electrolyte |
| WO2020162375A1 (ja) * | 2019-02-05 | 2020-08-13 | Ｌｅシステム株式会社 | 電解液製造装置及び電解液の製造方法 |
| JP7244058B2 (ja) | 2019-02-05 | 2023-03-22 | Ｌｅシステム株式会社 | 電解液製造装置及び電解液の製造方法 |
| US11271226B1 (en) | 2020-12-11 | 2022-03-08 | Raytheon Technologies Corporation | Redox flow battery with improved efficiency |
| US12166253B2 (en) | 2021-01-04 | 2024-12-10 | Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C | Electrolytic reduction system and method of vanadium electrolyte |
Also Published As
| Publication number | Publication date |
|---|---|
| TW531934B (en) | 2003-05-11 |
| NZ523752A (en) | 2005-10-28 |
| BR0017317A (pt) | 2003-07-15 |
| IL154098A0 (en) | 2003-07-31 |
| TR200300178T2 (tr) | 2007-01-22 |
| WO2002015317A1 (en) | 2002-02-21 |
| AU2000267249A1 (en) | 2002-02-25 |
| CA2420014A1 (en) | 2002-02-21 |
| EP1310008A1 (en) | 2003-05-14 |
| MXPA03001330A (es) | 2004-12-13 |
| CN1502141A (zh) | 2004-06-02 |
| KR20030034146A (ko) | 2003-05-01 |
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