GB898318A - New phthalocyanine dyes - Google Patents
New phthalocyanine dyesInfo
- Publication number
- GB898318A GB898318A GB2835060A GB2835060A GB898318A GB 898318 A GB898318 A GB 898318A GB 2835060 A GB2835060 A GB 2835060A GB 2835060 A GB2835060 A GB 2835060A GB 898318 A GB898318 A GB 898318A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- chlorine
- mols
- reacting
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000001007 phthalocyanine dye Substances 0.000 title 1
- 239000000975 dye Substances 0.000 abstract 4
- 239000000460 chlorine Substances 0.000 abstract 3
- 229910052801 chlorine Inorganic materials 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 2
- 239000011707 mineral Substances 0.000 abstract 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical group OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 abstract 2
- NCNYEGJDGNOYJX-NSCUHMNNSA-N (e)-2,3-dibromo-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Br)=C(/Br)C=O NCNYEGJDGNOYJX-NSCUHMNNSA-N 0.000 abstract 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- WDEQGLDWZMIMJM-UHFFFAOYSA-N benzyl 4-hydroxy-2-(hydroxymethyl)pyrrolidine-1-carboxylate Chemical compound OCC1CC(O)CN1C(=O)OCC1=CC=CC=C1 WDEQGLDWZMIMJM-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Chemical group 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- PKDBSOOYVOEUQR-UHFFFAOYSA-N mucobromic acid Natural products OC1OC(=O)C(Br)=C1Br PKDBSOOYVOEUQR-UHFFFAOYSA-N 0.000 abstract 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
- C09B62/12—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a pyridazine ring
- C09B62/18—Porphyrins; Prophyrazins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises dyes of the formula <FORM:0898318/IV (c)/1> and the alkali-metal or ammonium salts thereof, wherein Pc is the radical of copper or nickel phthalocyanine or a copper phthalocyanine having 1 to 4 chlorine atoms or phenyl groups in the molecule, Z1 is hydrogen, chlorine, methyl or methoxy, Z2 is hydrogen, chlorine or a sulphonic acid radical, X is chlorine or bromine, m is a whole number from 0 to 5, n is an integer from 1 to 4 and (n+m) is an integer from 1 to 6. The dyes are made by reacting a sulphonyl chloride of the formula [Pc-]-(SO2Cl)(m+n) with n mols of a compound of the formula <FORM:0898318/IV (c)/2> and hydrolysing the unreacted sulphochloride groups, or by reacting the above sulphochloride with n mols of a compound of the formula <FORM:0898318/IV (c)/3> and treating the reaction product with a mineral acid or by reacting a compound of the formula <FORM:0898318/IV (c)/4> with n mols of mucobromic or mucochloric acid in aqueous mineral acid solution. The dyes dye and print wool, silk, synthetic linear polyamides and cellulose textile materials in blue and green shades, in the case of cellulose in conjunction with an alkali and heat treatment.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB54436A DE1123065B (en) | 1959-08-17 | 1959-08-17 | Process for the preparation of dyes of the tetrazaporphin series |
| DEB57711A DE1150478B (en) | 1960-05-04 | 1960-05-04 | Process for the preparation of dyes of the tetrazaporphin series |
| DEB57887A DE1154213B (en) | 1960-05-18 | 1960-05-18 | Process for the preparation of dyes of the tetrazaporphin series |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB898318A true GB898318A (en) | 1962-06-06 |
Family
ID=27209094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2835060A Expired GB898318A (en) | 1959-08-17 | 1960-08-16 | New phthalocyanine dyes |
Country Status (2)
| Country | Link |
|---|---|
| BE (1) | BE594115A (en) |
| GB (1) | GB898318A (en) |
-
1960
- 1960-08-16 GB GB2835060A patent/GB898318A/en not_active Expired
- 1960-08-16 BE BE594115A patent/BE594115A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE594115A (en) | 1961-02-16 |
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